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Applied Energy
journal homepage: www.elsevier.com/locate/apenergy
Liquid air energy storage – Analysis and first results from a pilot scale
demonstration plant q
Robert Morgan a,⇑, Stuart Nelmes b, Emma Gibson b, Gareth Brett b
a
School of Computing, Engineering and Mathematics, University of Brighton, Brighton BN2 4GJ, United Kingdom
b
Highview Power Storage, 1 Northumberland Avenue, London WC2N 5BW, United Kingdom
h i g h l i g h t s
a r t i c l e i n f o a b s t r a c t
Article history: Energy storage is an important technology for balancing a low carbon power network. Liquid Air Energy
Received 28 February 2014 Storage (LAES) is a class of thermo-electric energy storage that utilises a tank of liquid air as the energy
Received in revised form 18 June 2014 storage media. The device is charged using an air liquefier and energy is recovered through a Rankine
Accepted 30 July 2014
cycle using the stored liquid air as the working fluid. The cycle efficiency is greatly improved through
Available online 20 August 2014
the storage and recycling of thermal energy released during discharge and used to reduce the work
required to liquefy air during charging. Analysis and results from the design and testing of novel LAES
Keywords:
concept at pilot scale are presented. Fundamental analysis of the LAES cycle is first described to deter-
Liquid air
Energy storage
mine the theoretical cycle performance and in particular the value of cold recycle. The pilot plant is then
Cryogenic described together with the results of a series of comprehensive technical and commercial trials. The
Cold recycle paper concludes with a discussion on the future potential of LAES in particular the fit with the require-
ments for bulk energy storage and the transition of the LAES technology from pilot to commercial scale.
Ó 2014 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.apenergy.2014.07.109
0306-2619/Ó 2014 Elsevier Ltd. All rights reserved.
846 R. Morgan et al. / Applied Energy 137 (2015) 845–853
Nomenclature
required to liquefy air during charging. The LAES cycle is particu- application where the storage device shifts significant quantities of
larly interesting to the power utilities, as the component parts energy [10]. However, Strbac’s work identified a valuable balancing
are commonly found in power stations and industrial air separa- service requiring a low cost – modest efficiency device that can be
tion plant. As such, the components are mature, have well under- deployed at significant scale. As will be discussed in the rest of this
stood maintenance requirements and are available at the scales paper, this application is a good fit with the characteristics of a
compatible with plant sizes from 10’s to 100’s MW. LAES device.
Variants of the LAES cycle were first described by Smith [5] and
more recently by Ameel [6]. Smith proposed a cycle utilising adia- 2. Theoretical performance of a liquid air storage plant
batic compression and expansion devices, resulting in a high cycle
efficiency of 72% but high temperatures (1048 K) and pressures 2.1. The liquid air energy storage cycle
(85 bar) in the thermal stores. Ameel described a process utilising
a combined Linde refrigeration and Rankine cycle, and calculated The LAES cycle contains three principal parts (Fig. 1); a charging
efficiencies of up to 43%. The cycles proposed here differ from pre- device, a liquid and various thermal stores and a generation device.
vious studies in two respects. First, the thermal store is operated at Thermal energy is captured, stored and recycled between the
low pressure to overcome the practical difficulties of manufactur- charge and discharge cycles. In a LAES system, unlike a battery
ing a large pressurised store. Secondly, the liquefier utilises the these are three physically different components that can be inde-
Claude cycle, where cooling is provided through isentropic expan- pendently sized, i.e. a storage device with a slow charging rate
sion in one or more cold turbines as well as isenthalpic expansion and large storage capacity is possible leading to the opportunity
through a Joule Thomson valve. The Claude cycle is the most com- to optimise the LAES system for different applications. The LAES
monly used process for large scale air liquefaction, being signifi- be analysed as follows, referring to the Fig. 2.
cantly more efficient than the Linde cycle [7]. The round trip efficiency, defined as the net work recovered
In this paper, the role of energy storage in the power network during discharge/compression work during charging can be
will be discussed first, to provide market context to the LAES sys- expressed as:
tem and generic performance targets for a bulk storage device.
ðW t W p Þ
The LAES cycle is then described using classical analysis to investi- v¼y ð1Þ
gate the theoretical performance and then detailed cycle analysis Wc
to understand the practical potential of the technology. Results where y is the liquid yield (mass of liquid produced/total mass) of
from a pilot scale demonstration project are then presented, the isenthalpic expansion process through the throttle valve (3–4),
including performance and commercial trials. The paper concludes Wt is the turbine work (2–1), Wp is the pump work (40 –3) and Wc
with a discussion on the future potential of LAES technology and is the compressor work (1–2). Referring to Fig. 2b, assuming the
the likely configuration and performance of a mature commercial gas compression (1–2) and expansion (2–1) processes are isother-
scale LAES plant. mal and the working fluid behaves as an ideal gas, the main losses
in the cycle are the adiabatic work (40 –3) in compressing the
cryogenic fluid and isenthalpic expansion (3–4) resulting in
1.1. Role of storage in the power network incomplete condensation of the working fluid. Using the analysis
described by Haywood [11] for a Linde refrigeration cycle modified
Recent research by Strbac et al. [8] has shown energy storage to include the cooling contribution of the cold recycle (2–3), the
could deliver significant efficiency savings in operating and balanc- yield at (4) is:
ing a power grid with a high contribution of intermittent renew-
able generation. The most valuable contribution of storage h1 h2 þ Q r
y¼ ð3Þ
identified by Strbac was increasing the overall network efficiency, h1 hl
and in particular the utilisation of highly valuable renewable where h1 and h2 are the enthalpies at (1) and (2), hl is the enthalpy
energy generation assets. The surprising conclusion from this work at the bubble point at the same pressure as (4), and Qr is enthalpy
was the relatively low sensitivity of the value of storage to the effi- recovered during discharge available for cold recycle:
ciency of the storage device. The consequences of Strbac’s analysis
on the target cost and performance metrics for a large scale energy Q r ¼ h2 ðhl þ W p Þ ð4Þ
storage system were discussed in the liquid air report produced by The isothermal compression and expansion work can be
the Centre for Low Carbon Futures [9]. A net round trip efficiency calculated from the pressure ratio Pr of the process, temperature,
(AC out to AC in) of >50% was proposed at a cost target 750– T1 and gas constant R:
1250 £/kW. It should be noted that in some storage applications,
round trip efficiency is much more important, such as in arbitrage W ¼ RT 1 lnPr ð5Þ
R. Morgan et al. / Applied Energy 137 (2015) 845–853 847
Fig. 2. Process flow (a) and TS diagram (b) of the LAES cycle.
Hence, from Eqs. (2)-(5), the round trip efficiency (1) can be cal- by the increase in work recovery during discharge. Higher charging
culated as a function of the charge and discharge pressure ratio as pressures also increase round trip efficiency by increasing the yield
shown in Fig. 3. It should be noted that the cycle analysed in this at (4).
manner does not achieve mass equilibrium from cycle to cycle as
the mass of working fluid re-liquefied during the charging phase
of the cycle reduces slightly with every repeat cycle due to incom-
2.2. Cycle analysis
plete condensation at (4). To balance the stored mass over repeat
charge and discharge cycles, a supplementary refrigeration device
The analysis described above although useful in illustrating the
would be required to top up the storage tank. Bearing this limita-
principles of the LAES cycle but does not account for second law
tion in mind, it is apparent from inspection of Fig. 3 that the cycle
losses in the heat transfer processes and air is normally liquefied
efficiency improves with increasing discharge pressure but beyond
using more efficient refrigeration processes, such as the Claude
120 bar, the benefit is reduced and a theoretical round trip effi-
cycle [7]. To capture these effects, full cycle analysis is required
ciency of the cycle trends to a maximum of 86%. From Eq. (4), we
to provide a more accurate prediction of the cycle performance.
can see that increasing the discharge cycle working pressure
For this analysis, the Aspen HYSYS [12] process simulation code
reduces the quantity of cold recycle, but this is more than offset
was selected.
A diagram of the LAES cycle model is shown in Fig. 4. In this
case, a two turbine Claude cycle is used for the liquefier and four
expansion stages with interstage ambient re-heating for discharge.
The following assumptions were made regarding machine
efficiency (Table 1).
The model was run at a range of peak liquefier pressures and
peak first stage turbine inlet pressures to investigate the optimal
process conditions. The effect of the pressure at the inlet to the
Joule Thomson valve on the specific work of the liquefier is shown
in Fig. 5a. A minima is observed at 54 bar. Inspection of the model-
ling results showed little improvement in the liquid yield from the
95% at 54 bar for higher pressures, for the penalty of increased
compression work. Most modern air liquefiers operate at between
50 and 60 bar and so cold recycle has not fundamentally changed
Fig. 3. Theoretical effect of charging pressure on round trip efficiency for different the optimal operating pressure of the liquefier, implying current
discharge pressures. components are likely to be suitable for a LAES plant.
848 R. Morgan et al. / Applied Energy 137 (2015) 845–853
Table 1 part of the process being built and run first, and then the liquefier
Modelling assumptions. being added to demonstrate the complete cycle. The discharge
Component Value
plant was run on tanker supplied liquid nitrogen until the liquefier
was available to provide liquid air. The site was located on Scottish
Compressor 89%
and Southern Energy’s Slough Heat and Power station in Slough,
Turbine 90%
Electrical machine 97% United Kingdom.
Cryogenic pump 80% A process flow diagram (PFD) of the process is shown in Fig. 6
Minimum approach temperature 1K and diagram of the plant in Fig. 7. Key process parameters are
in heat exchangers
shown in Table 2. The peak process pressure in the discharge unit
was 60 bar and 13 bar in the air liquefier. These are below the
Moving to the power recovery unit, higher peak cycle pressures expected optimal working pressures of a mature LAES system,
improve work recovery but as shown in Section 2, reduce the 150 bar and 55 bar being more typical, but were selected to fit in
quantity of cold recycle. Fig. 5b shows the effect of peak power with available equipment at pilot scale and the project budget.
recovery cycle pressure on overall net cycle efficiency. The Only 51% of the available cold thermal energy (defined as the
increased work recovery from higher pressures more than offsets enthalpy recovered from the cold store during charging divided
the reduction in cold recycle, but above 150 bar, the benefit is lim- by the enthalpy added to the working fluid during charging
ited. This would suggest the optimal LAES power recovery cycle between the cryo pump outlet to 273 K) was recycled, again to
pressure is between 150 and 200 bar, which is comparable with keep the project within the available financial resources.
the peak operating pressures of modern steam plant expanders The discharge unit consisted of a pair of reciprocating cryogenic
which could form the basis for a large air expander. pumps, connected via a thermosyphon to the cryogenic liquid stor-
age tank. This ensured the pump’s cold head was maintained at the
3. Pilot plant cryogenic liquid temperature. The pumps were driven through a
variable speed motor to enable the process pressure to be varied.
To prove the LAES concept, a pilot scale demonstration plant The cryogenic fluid was heated in three stages, the first two by
was constructed. The project started in 2008, with the discharge the exhaust gas from the final turbine stage, and finally by a
Fig. 5. Effect of liquefier (a) and power recovery (b) pressures on specific work and net round trip efficiency.
R. Morgan et al. / Applied Energy 137 (2015) 845–853 849
water–glycol warmed heat exchanger. Cold recycle was only recov- the turbine stage inlets to be varied from 288 K to 343 K, simulat-
ered from the first heat exchanger. The process fluid was expanded ing the use of heat from the environment or from various waste
in four stages through a series of radial inlet turbines, supplied by heat sources.
Concepts NREC. The process gas was re-heated between stages to The liquefier was supplied by Chengdu Air Separation Corpora-
achieve quasi isothermal expansion. The re-heaters and superheat- tion and was of a single turbine Claude design. A liquid submerged
ers were heated using a water–glycol heating circuit. Thermal sub cooler was used at the low temperature end of the cold box.
energy was supplied to the process from steam supplied from an Although this is not the most efficient process for liquid produc-
adjacent power station. This enabled the process temperature at tion, it was selected to reduce the risk of ignition of condensed
850 R. Morgan et al. / Applied Energy 137 (2015) 845–853
Pressure (bar) Temperature (K) Mass flow (kg/s) The liquefier was commissioned during April 2010. The target
1 10 301 2.3 bulk thermal store temperature of 115 K was achieved and the spe-
2 12 298 2.3 cific work of the liquefier was measured across a range of specific
3 1.3 84 1.8 cold recycle rates, expressed as the kW h per unit mass of liquid
4 12 98 0.4 production. The cold recycle rate was controlled by varying the
5 1.2 106 2
6 56 104 2
mass flow of the blower circulating dry air between the cold store
7 56 109 2 and cold box, at a constant cold store exit temperature. The results
8 51 337 2 of these tests and the predicted results from a cycle simulation
9 1.7 262 2 model are shown in Fig. 9. Close agreement between simulation
10 1.2 115 0.4
and test results was observed. As predicted, the specific liquefier
11 1.0 296 0.4
work reduced as the cold recycle rate was increased. This demon-
strates liquefier efficiency can be controlled by varying the dis-
charge rate of the cold store. This flexibility would enable a
commercial plant to exploit low energy prices to generate liquid
hydrocarbons due to boiling of locally oxygen enriched liquid. Two without depleting the cold store, which could be used to reduce
screw compressors, supplied by Atlas Copco were used to supply the energy input to the liquefier when energy prices are high,
and recycle air in the process. Both machines had variable speed whilst still enabling the liquefier to be operated economically to
motors to enable the air mass flow to be controlled. Cold was cap- charge the system.
tured and stored in a series of eight packed gravel beds, filled with
a quartzite based river shingle sized by a 15 mm sieve. The col-
4.3. Commercial trials
umns of gravel were installed inside a shipping container and insu-
lated using perlite. The columns were interconnected through a
Tests were undertaken to evaluate the performance of the LAES
series of valves that allowed columns to be connected in parallel
technology against a range of reserve and response services. These
and series to optimise cold recovery and minimise pressure drop.
services are used today to balance differences between supply and
This concept of parallel series operation of the cold store is
demand over a range of timescales from seconds to hours, and pro-
described more completely in [13].
vide reserve capacity in the event of the loss of a generating asset.
It is expected more of these ‘ancillary services’ will be required in
4. Results the future to balance the power network when there is a significant
contribution from intermittent generation [15].
4.1. Discharge unit testing
4.3.1. Reserve service trials
The effect of peak cycle pressure and temperature were investi- Reserve services provide capacity to balance differences
gated. Fig. 8a shows the electrical energy generated at a 289 K tur- between predicted and actual demand. The United Kingdom
bine inlet temperature. A linear relationship between turbine work National Grid STOR service [16] was used to assess the reserve
and pressure was observed. Further testing was performed at capability of the pilot plant. The STOR service requires the generat-
48 bar turbine inlet temperature to investigate the impact of recy- ing assets to be on load within 15 min of a call from the network
cled or waste heat on the cycle (Fig. 8b). 45% of the supplied ther- operator with a very high level of reliability and availability. A sim-
mal energy (referenced to ambient temperature) was converted to ulated STOR service trial was undertaken over a ten day period
work. This high conversion rate of low grades of waste heat is a key during which the pilot plant was made available at pre-defined
features of the LAES and compares very favourably with the 5–15% times and calls were made at random to bring the pilot plant on
efficiency from other systems such as an organic Rankine cycle line. The results of the trial are shown in Table 3.
[14]. The STOR trials indicate even at pilot stage impressive reliabil-
The outlet temperature of the low pressure stream of HX1 is ity and good fit with a reserve type of service. At larger scale, it
critical to the overall performance of the cycle, as it indicates the would take longer to load up the turbines and generate power from
quality of the cold thermal energy captured for storage and recycle. a standby condition due to the higher rotational inertia of larger
A 1–2 K approach temperature between the high pressure liquid turbomachinary. However, in the case of a LAES plant thermal iner-
and low pressure gas outlet was observed across the full operating tia is much less of an issue during start up compared with other
range of the pilot plant, demonstrating very efficient cold recovery thermal generating technologies such as gas turbines. The thermal
from the process. inertia in the system provides a heat sink to heat the cold liquid
Fig. 8. (a) Effect of stage 1 turbine inlet pressure at 289 K and (b) turbine inlet temperature at 48 bar stage 1 inlet pressure on generated power.
R. Morgan et al. / Applied Energy 137 (2015) 845–853 851
Table 4
Parameters for a 100 MW/600 MW h LAES system.
Component parameter
Discharge turbine mass flow rate 233 kg/s
RAC mass flow rate 103 kg/s
Cold Store volume 5800 m3
Warm store mass 1763 tonnes
Liquid air tank mass 5032 tonnes
5.3. Scale up
6. Conclusions
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