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KVPY-SX_2017 (CHEMISTRY)

3. (D)
G.I. Chiral centre
*
CH3–CH=CH–CH–CH3
OH
n=2
 Number of possible stereoisomers = 2n = 22 = 4
G.I. → Can be cis/trans.
Chiral centre → can be R/S.
 possible combination
Cis – R
Cis – S
Trans – R
Trans – S

4. (C)

Cl can show
–I effect and +R effect

But the dominating one is +R effect. That is why it act as o,p-directing group.
  
Cl Cl Cl Cl
 

 

Cl

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