1 ideal Versi 1

CH4 + H2O-> CO + 3H2

CH4 + 2H2O-> CO2 + 4H2

T 810 C 1083.15 K ε1 0.32405

T reff 298.15 K ε2 0.23136
P 32 Bar
R 8.314 J/mol.K

∆Hf ∆Gf
V1 V2 dHf dGf
Rx1 Rx2 Rx1
CH4 -1 -1 -74520 -50460 74520 74520 50460
H2O -1 -2 -241818 -228572 241818 483636 228572
CO 1 0 -110525 -137169 -110525 0 -137169
H2 3 4 0 0 0 0 0
CO2 0 1 -393509 -394359 0 -393509 0
2 2 205813 164647 141863

(P/P0)^-V
n0 ni yi yi^(Vi.1) yi^(Vi.2)
Rx1 Rx2
CH4 2 1.44459 0.23640 4.23013 4.23013 0.00098 0.00098
H2O 3 2.21323 0.36218 2.76104 7.62332
CO 0 0.32405 0.05303 0.05303 1.00000 KT
H2 0 1.89758 0.31053 0.02994 0.00930 Rx1 Rx2
CO2 0 0.23136 0.03786 1.00000 0.03786 18.99064 11.62503
5 6.11081 1.00000 0.01855 0.01135
Error 8E-06 8.80251E-06
Konversi 27.77%
 Versi 2

T 1083.15 K
T reff 298.15 K
ε1 0.917162
ε2 0.666641

∆Gf K 298 cp
Rx2 Rx1 Rx2 comp A B C D
50460 1.39732E-25 1.44288E-20 CH4 1.702 0.009081 -2.164E-06 0
457144 H2O 3.47 0.00145 0 12100
0 KT CO 3.376 0.000557 0 -3100
0 Rx1 Rx2 H2 3.249 0.000422 0 8300
-394359 18.99063 11.62504 CO2 5.457 0.001045 0 -115700
113245 Campuran

n0 ni yi yi^(Vi.1)

CH4 2 0.41620 0.05096 19.62438

H2O 3 0.74956 0.09177 10.89659
CO 0 0.91716 0.11229 0.11229
H2 0 5.41805 0.66336 0.29191
CO2 0 0.66664 0.08162 1.00000
5 8.16761 1.00000 7.00943
 v.Cp1 v.Cp2 Delta H
A B C D A B C D Rx1
-1.702 -0.00908 2.164E-06 0 -1.702 -0.009081 2.164E-06 0 226111.7
-3.47 -0.00145 0 -12100 -6.94 -0.0029 0 -24200
3.376 0.000557 0 -3100 0 0 0 0 KT
9.747 0.00127 0 24900 12.996 0.001688 0 33200 Rx1
0 0 0 0 5.457 0.001045 0 -115700 7177.66
7.951 -0.00871 2.164E-06 9700 9.811 -0.00925 2.164E-06 -106700
6241.535 -4721.13 897.52844 23.5786 7701.635 -5013.898 897.52844 -259.3646

(P/P0)^-V
yi^(Vi.2)
Rx1 Rx2
19.62438 0.00098 0.00098
118.73570
1.00000 KT
0.19364 Rx1 Rx2
0.08162 7177.65931 37710.93650
36.82709
Error 8E-04 0.0005003934
Konversi 79.19%
 Versi 3

T 1083.15 K
T reff 298.15 K
ε1 1.66806
ε2 0.17552

Delta H cp y1.Cp
rx 2 comp A B C D A B
192298.5 CH4 1.702 0.009081 -2.164E-06 0 0.090217 0.0004813514803
H2O 3.47 0.00145 0 12100 -0.077968 -3.258047652E-05
KT CO 3.376 0.000557 0 -3100 1.279995 0.0002111840821
Rx2 H2 3.249 0.000422 0 8300 3.556421 0.0004619296985
37710.94 CO2 5.457 0.001045 0 -115700 0 0
Campuran 4.848665 0.0011218847844
3806.202 608.24

(P/P0)^-V
n0 ni yi yi^(Vi.1) yi^(Vi.2)
Rx1
CH4 2 0.43294 0.05301 158.61304 1.02740 0.00098
H2O 3 -0.18352 -0.02247 3975.56278 1.00347
CO 0 3.09671 0.37915 0.00062 0.99878 KT
H2 0 8.94043 1.09462 0.01831 0.99948 Rx1
CO2 0 0.00000 0.00000 1.00000 1.00000 7.36E+03
5 12.28655 1.50430 7.18297 1.02918
Error 7E+03
Konversi 78.35%
 y2.Cp
C D A B C D
-1.147E-07 0 0.090217 0.000481 -1.147059E-07 0
0 -271.8785 -0.077968 -3.26E-05 0 -271.8785
0 -1175.351 1.279995 0.000211 0 -1175.351
0 9085.347 3.556421 0.000462 0 9085.347
0 0 0 0 0 0
-1.147E-07 7638.117 4.848665 0.001122 -1.147059E-07 7638.117
-47.57479 18.56661 3806.202 608.2413 -47.57479 18.56661

(P/P0)^-V
Rx2
0.00098

KT
Rx2
1.05E+03

1053.8755