Scribd Logo
Upload

Welcome to Scribd!

  • Caustic Soda

    Uploaded by

    Yiftach Katzir
    2 views11 pages

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    2 views11 pages

    Caustic Soda

    Uploaded by

    Yiftach Katzir

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 11
    : @ AICL Haifa . > ooees Met. Corr.1 290 May be corrasive to metals, ‘Skin Cort. 1A H314 Causes severe skin bums and eye damage, (Contd on page 2) NI CL Haifa Setter needs take us Page 2/11 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 22082016 Version mumber: 6 Revision date: 22.08 2016 Trade name: Sodium hydroxide 50% solution (Contd of page 1) -2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 ‘The product is classified and labelled according to the CLP regulation. - Hazard pictograms & GHSos Signal word Danger ~ Hazard-determining components of labelling: sodium hydroxide - Hazard statements 290 May be corrosive to metals H314 Causes severe skin bums and eye damage. - Precautionary statements 260 Do not breathe dustfume’gas/mist'vapours/spray. 280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340___IF INHALED: Remove person to fresh air and keep comfortable for breathing, P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call 2 POISON CENTER /doctor. PSOL Dispose of contents/container in accordance with local/regional/national/international regulations. +23 Other hazards Results of PBT and vPvB assessment -PBT: Not applicable. : Not applicable. -3.2 Mixtures -Deseription: Mixture: consisting of the following components: = Components: CAS: 7732-18-35 7 | water, distilled, conductivity or of similar purity 50-53% EINECS: 231-791.2 | €asri310-732— sodium hydroxide __ ~[A5-50% EINECS: 215-185-5 [© Met. Cori, 1290; Skin Gor Index number: 011-002-0046 “SVC None = Additional information: Fo the wording ofthe listed hazard phrases refer to section 16 wt (Cont on page 3) AICL Haifa : Xt X ine pe Page 3/11 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 22.08.2016 Version number: 6 Revision date: 22.08.2016 Trade name: Sodium hydroxide 50% solution | (Contd of page 2) -4.1 Description of first aid measures ~ General information: Immediately remove any clothing soiled by the product. Do not leave affected persons unattended, Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident, After inhalation: ‘Take affected persons into fresh air and keep quiet. [Frequired, provide artificial respiration Seek immediate medical advice. Use a respiratory bag or breathing device, In case of unconsciousness place patient stably in side position for transportation. - After skin contact: Change contaminated clothing immediately. Rinse with plenty of water for atleast 20 minutes. Seek immediate medical advice. Wash clothing before reuse. After eve contact: Rinse opened eye for atleast 15 minutes under running water. Protect unharmed eye. Call a doctor immediately. + After swallowing: Rinse out mouth and then drink plenty of water. Do not attempt to neutralize, Do not induce vomiting; cal for medical help immediately NOTE: Never give an unconscious person anything to drink, -4.2 Most important symptoms and effects, both acute and delayed Corrosive to skin, eyes, and respiratory system. Symptoms: Breathing difficulties, cough, chemicalpneumonitis, plumonary oedema. Repeated or prolonged exposure: risk of sore throat, nose bleeds, chronic bronchitis, ‘causes severe eye and skin bums, Severe bums of the mouth and throat, danger of perforation of oesophagus and the stomach. ‘Nausea, abdominal pain, bloody vomiting, diarthoea. Information for doctor: Very corrosive to tissue body. ~Hazards Danger of gastric perforation. Danger of pulmonary oedema, Danger of pneumonia, ~4.3 Indication of any immediate medical attention and special treatment needed swallowed or in case of vomiting, danger of entering the lungs. If swallowed, gastric irigation Later observation for pneumonia and pulmonary oedema, Jse fire extinguishing methods suitable to surrounding conditions. (Const onraae) | AICL Haifa : SMTA pierernis tates Page 4/11 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 22,08, 2016 Version number: 6 Revision date: 22.08.2016 Trade name: Sodium hydroxide 50% solution [ (Com fee 52 Spectal hazards arising from the substance or mistre The product is not combustible. Incase of fire, the following can be released: Hazardous vapours of sodium oxides (Na,O).. Hydrogen may form upon contact with light metals (danger of explosion). +53 Advice for firefighters Special fire fighting procedures : Use water sprays to cool fire-exposed containers and structures, to disperse ‘vapours and to protect personne! Avoid disposal of contaminated fie fighting water to the environment Protective equipment: Wear fully protective suit. Wear self-contained respiratory protective device. Do not inhale explosion gases or combustion gases. ~ Additional information Dispose of fire debris and contaminated fire fighting water in accordance with offical regulations. | Stay upwind and uphill Pi -6.1 Personal precautions, protective equipment and emergency procedures Keep people at a distance and stay on the windward side. Use respiratory protective device against the effects of fumes/dust/aerosol Wear protective equipment. Keep unprotected persons away. Wear self-contained breathing apparatus, chemical safety goggles, rubber boots and heavy rubber gloves, 6.2 Environmental precautions: Prevent from spreading (e.g. damming in by dry sand, earth, or vermiculite) Do not allow to enter sewers! surface or ground water. ~6.3 Methods and material for containment and cleaning up: Stop leak if it can be done without risk. If possible pump up spilled material or take up with liquid-absorbent material (eg. dry sand, earth, or vermiculite). Collect leakage in sealed suitable container. Forward for disposal. ‘Wash area after clean-up is complete. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation, ‘Wash spill site after material pickup is complete. - 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information, ayes -7:1 Precautions for safe handling When diluting always pour product into water and not vice versa Avoid contact with eyes, skin and clothing. ‘Wear all recommended personal protective clothing when handling. Ensure good ventilation/exhaustion atthe workplace. Prevent formation of aerosols. (Contd. on pase 9) AICL Haifa Sa ~ Change in condition ‘Meling poinMeing range: 12°C Bolling polnBolling ange: 140°C Flashpoint Not applicable, | | -tanmabitny (old gaseous: Not applicable | | -Jgnition temperature: Deconpestion tenpertures Not determined Selgin Product isnot selfing | Danger of explosion: Contet with some metals il Rberate hydrogen ges explosion dak —| | ~Biploston mits Tower! Not determined Upper: Not determine. Vapour pressure at 20°C: Tara [bens t 20°C: La gen? (Cont on azo) AICL Haifa SLA tere needs takous Page 7/11 Safety data sheet according to 1907/2006/EG, Article 31 Printing date 22.08.2016 Version number: 6 Revision date: 22.08.2016 Trade name: Sodium hydroxide 50% solution (Cont of page 6) ~Relative density Not determined, Vapour density ‘Not determined. ~Evaporation rate Not determined. ~Solubiity in /Miscibiiey with water: Fully miscible. Partition coefficient (n-octanoliwater): Not determined, = Viscosity: Dynamic: Not determined, Kinematic: Not determined. Solvent content: Organic solvents: 0.0% Water: 30,0 % -9.2 Other information [No further relevant information available. 10.1 Reactivity ‘Attacks many metals with liberation of hydrogen, which is flammable and forms explosive mixture with ar. -10.2 Chemical stability Stable under recommended storage conditions. = Thermal decomposition / conditions tbe avoided: No decomposition if used and stored aecording to specifications. Avoid exposure to air. Reacts with carbon dioxide from air to farm sodium carbonate. ‘Avoid freezing + 10.3 Possibility of hazardous reactions Strong exothermic reaction with acids Reacts with alcohols, amines, aqueous acid and alkalis Reacts with metals forming hydrogen. Reacts with fats and ols. Reacts with light alloys to form hydrogen. Reacts with carbon dioxide. Attacks materials containing glass and silicate. May be corrosive to metals. = 10.4 Conditions to avoid Moisture, exposure to moist air or water, prolonged exposure to ar. Extreme temperatures =10.5 Incompatible materials: Strong acids Reducing agents, organic combustibile substances. Strong oxidizing agents. Meals suchas aluminium, magnesium, tn and zine: Formation of hydrogen (isk of explosion!) Ammonium compounds: formation of ammonia Flammable materials Organic halogen compounds (especialy trichloroethylene) Nitro compounds. (Conon pe 8) AICL Haifa SST iitere needs taeus Page /11 Safety data sheet according to 1907/2006/EG, Article 31 Printing date 22.08.2016 Version number: 6 Revision date: 22.08.2016 Trade name: Sodium hydroxide 50% solution (Contd of page 7) - 10.6 Hazardous decomposition products: Nitrogen oxides - 11-1 Information on toxicological effects ~ Acute toxicity Based on available data, the classification criteria are not met, ~Primary irritant effect: - Skin corrosion/rritation ‘Causes severe skin burns and eye damage. Serious eye damagefrritation Burns, risk of blindness! Causes severe skin bums and eye damage, ~by Inhalation: Corrosive to mucous membranes and upper respiratory tract. by Ingestion: Ingestion might cause gastrointestinal iritation, nausea, vomiting and diarrhea, Burs, nausea, vomiting, diarthea, and stomach pain, - Respiratory or skin sensitisation Based on available data the classification criteria are not met. - Additional toxicological information: ONSET OF TOXIC SYMPTOMS MAY BE DELAYED 2 T0 4 HOURS OR LONGER, ~ CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Not listed as a carcinogen by NTP, IARC, ACGIH ot OSHA. = Germ cell mutagenicity Based on available data the classification eriteria are not met. = Carcinogenicity Based on available data, the classification criteria are not me, = Reproductive toxicity Based on available data, the classification criteria are not met -STOT-single exposure Based on available data, the classification criteria are not met -STOT-repeated exposure Based on available data, the classification criteria are not met. ~ Aspiration hazard Based on available data, the classification criteria are not met. Dee - 121 Toxicity ~Aquatic toxicity: Toxic effect on fish and plankton. Harmful effect due to pH shift, Death of fish possible, Does not eause biological oxygen deficit, ‘Neutralization possible in waste water treatment plants, 1310-73-2 sodium hydroxide ] ECSU148h 404 me) | 12.2 Persisence and degradable The mais einorgane d WOT ARjoTA o IORI “123 Bioaceumulative potential Bioaccumulation is no Hkly to our sine the materials ighy soluble in water =12.4 Mobi in sil This substance is highly water soluble and dissociating “Adtomaleologea information: General noes: Water hazh class 1 (Geman Regulation), (Sei asessment: slightly hazardous for water Do not allow undiluted product or large quantities of to reah ground water, watercourse or sewage system. Mast not reach sewage water or drainage ditch undued or unease. “12.5 Result of PBT and sPeB assesoment PBT: Not applicable (Contd. on page 9) AICL ae S

    You might also like