bo~Llo02 nu Lo POCCMIACKOE ATEHTCTBO lo IATEHTAM 4 TOBAPHBIM SHAKAM ® RU" 2077 201" C1 (61) Mnké A 01 N 43/50, C 07 D 233/84 (2) ONVCAHVE V3OBPETEHMA K NATEHTY POCCUMCKON SEQEPALINN (21), (22) Sanska: 4743986/04, 04.05.1990 (80) Mpvepurer: 05.05.1989 FR 249,682 (48) Hava nyOnvnaynn: 20.04.1997 (68) Cetsne: Nateur BonmxoSpuranna N 1325762, xn. 01 N 43/50, 1989. (71) Sasenrens Por-flynenn Arpoumnn (FR) (72) Vsc6perarens: Feiin Crotron Moyan(US], Aawna Hun Cunonnc(US], Onnan Pea, Tuwwonc{US], Tait Ts By{US] (73) Narexroo6nagarens: Por-flynenk Arpoulnnn (FR) (64) NPONSBOPHBIE 1-EHANMMMAASONA, CNOCOB BOPLBbI C BPENMTENPMM CEMbCKOrO XOSAACTBA W KOMNOSMUMR [VIF TECTMUMBHOM OBPABOTKA (67) Pesbepar: Vicnonssosanne: & censcioM xosacree & ope6e ¢ speaiaTanamm pacresih. Cyuocrs ao8peTeHns MpowseonHLe ‘-chehinawnnacona popwynts |, ykasaHHor 6 chopwyne wso6pereHnn, 8 KOTOpOH X o6osnavaer rpynny S(O),R. rae - R= Cr-Cy ~ arkyn unW MOTUR, SAMEWjeHHIA c>rOpOM UNM xropom; = 0,1 wna 2, R2 - H, ranona, arancynedoann, weTuneynepenun, RS R° HRY - ranowa, Tpacbropmenan, rpucpropmerorex, R° - ranowg: Z - 4 ranowa, ynawo, Cy-Cg - ankan, rprcbropwern, Coy 7 ankancynbepennn, 1-Cy-antaneynecpenan, C 1-Ce-ankarnap6onMn, ammHorapbonAn, C y-Cy-ankoxcukapGonnnoynacbennn, Y =H, C y-Ce-anaan, ‘anitno, ranowa, C +-Cy-ankunamnvo, merancyntcbownn 6 1-Cx-aneunoynecponan, C1-Cy-annoxcuarknnagesmuuno, rpm yonoBiM, ro Tonk onla va rpynn YX copepKar cepy. Kounosmusia, conepxauyan @ xavecrae KTHBHOTO BeUjecTaa COSAMHEHHE chopKyynts | 8 konmectae 0,05 - 0%. Mlonyueune TpAgMUMOHHLIM cnocoBaMn. 3.6.2 a.n. nbs 47961 27077201 Ci RUbo~Llo02 nu Lo RUSSIAN. AGENCY FOR PATENTS AND TRADEMARKS: (2) ABSTRACT OF INVENTION “) Ry" 2077 201°" C1 NEES 04 N 43/50, C 07 D 233/84 (21), (22) Application: 4743986/04, 04.05.1990 (30) Prioity 05.05.1989 FR 248.682 (48) Date of publication: 20.04.1997 (71) Applicant Ron-Pulenk Agroshimi (FR) (72) Inventor: _ Gojl Skotton PouehiUS}, David Nil Sinodis[US}, Filip Red ‘Timmons[US}, Taj Teh VulUS} (73) Proprietor: Ron-Pulenk Agroshimi (FR) (64) DERIVATIVES OF 1-PHENYLIMIDAZOLE, METHOD OF STRUGGLE AGAINST AGRICULTURE PESTS AND COMPOSITION FOR PESTICIDE TREATMENT (67) Abstract FIELD. organic chemistry, _agrouture. SUBSTANCE product derivatives. of Tphenylimidazole of the formula (I) oven in the rs} invention claim where: X means group S(0),R! where: R! = Cy-Cyalkyl or methyl substituted with fluorine or chlorine; n= 0, 1 or 2; R? - H, halide, methytsuifony! methylsuliny, R® and RE - HRY - halide ‘riuoromethyl, thfuoromethany; R® - halide ZH, halide, cyano, Cy-Cyakyl tetuorometnyl, C-Ce-alkylsulfony! G 4-Ceaylsultenyl, Cr-Ce-alkysulteny G 4-Cealylsulfeny, Ci-Ce-alkyloarbony!, aminocarbonyl, Cy-C¢-akoxycarbonyisulfeny Y=, CrGealkyl, amino, halide © 1-Cyalkylamino, methylsuifony! G j-Cy-alkyisutfony! G4-Cealkonyalkyideneimine at condition that only one group of Y and X contains sulur. Invention proposes ‘also. the compostion containing compound of the formula (1) as an active. component taken at amount 0.05-50%. EFFECT. improved method of synthesis. 50, 4th 27077201 Ci RUna hozlloz VeoGpereHne orHocwron x o6nacTa xmanvecknx cpenicra saujrTé! pacTeHni, Bonee KonKperio, wa0GpeTeHve OTHOOHTOR K HORE powssoaiim 1=peHnnmnanaasonos, ‘Onanarouyn OHONOTAECKOM AXTHBHOCTHIO, WK vononbsogaHnio wx x Gops6e ¢ epenmrensin acter 6 centcKoM xossifcTse. 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Tpudropmeroxen, Re ranoren, Z wopopoa, ranona, ywaHo, Cy-Ceankun, pacbropmeTan, Cy-Ca-ankancynacbennn, C y-Cy-ankaneynecponwn, C4-Cy-ankarnapGonnn, ammnorapbonan, C 1-Cy-ankoxcnkapSonunwerancynscheHAn, Y-aonopon, Cy-Ca-ankan, awwvo, —ranomp, 6 y-Ce-ankunamnwa, metaneynacpoHIAn, C 4-Cy-anaancynecperna, C +-Cy-annorcvarnnnngenamano, rpm yenoBn, veto Tonsko oma va pynn Y #Z conepxur copy. Coeannenna Guar chopwynes (|) MOryT ure nonytenti B pesynbrare npHweNeHAA Hn ananrauyn —ySBBCTHEX Ma _mMTeparypsl eracedos, oko aaKricvalcuyxon OOpasosannn —wMwAasOMsHOrO KoMYa ocnenyiowen saMeHoR saMecruTeneh, eon 90 HeobxonMwo. Creayer TajKe HMeTb 8 AMY, Wo BCOTMCaHHEK = Be MeTORaK ocnenosarensHocTa BReReHHA panini py MMWnasonsHoe — KOMLYyOMoryT CoyWecranaTizcA B paanMsHoM nOpABKE # MOrYT oTpebosaTbca NoRKOARIyNe SaUIATHENE Fyn, Kae 9TO AOMKHO GuiTe RcHO chaynanvcTy 2 anol obnacru. 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Siw Mon Neobxoaimrcera, pm oBecreNenin orwre Avcneprmposaan § cMecb —o6paGarbisaior eyo [inn yonurannit © oxo anmoycon GnouKo” “pacTaop nh cyereHaMO rorORsT Tak ko O6pa90M, aK MEXONHIA —pacréop ronuenrpayhoit 200 slvr Aan zowaunan myn aren arinkB0Te! ato} peuenryps) 200 han pasGasnnor one 1 TpebyeMoR nM frnomranit Konuorrpaun Tis crctenariioc HonsiTanitl ¢YoxHOM HewaTonom KopHOaGr HapocTa Hc JOKHSIMA ToxoBn “opera cupsesoM pacraop nn Cyenenawo roreaAT NocpaseTeaM nobaanenhs 15 wr vontiryeMoro coopivonHs K 250. Mr yncrancpopwannsa, 1250 wr ayeTona 3 MF cnet auynsraropoe, yRBsahiom Be. SaTeM 7077201 C1 RUna hozlloz ‘HoGaensior Bony, AOBOAA cyteMapHEIA O6LEM LO 45 Mn KOH\eHTpAYNO —wenbITyeMOrO cosniwehna no 333 wiMni. —B cnyvae HeoGxonmocrM, BAIA ObecneveHAA nonHoro Bucnepiposanna cMece —oOpabarsisaior sayKoM. 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Cawka amor orfioxnrs Arua 8 TeweHne nepvona NovMepHo 24 4, nocne 4ero weT’A pacTeHKA norpyxaicT = pacTaop Terpasranancbocipara (TEPP) nk Toro, wTO6es yausToxnr —oneveiie chops Rpeaoreparirs AonanwuTensKyo KNAEKy AN, ‘Sra weTOnHKa norpyxeNns, KoTORYIO NoBTOpAOT ocne sbicywnMBaHMA pacreHAh, He anMAeT Ha xvaHecnocoOH0cTs RM, BLICAKEHHBO 8 TODLKA Pactenna (1 ropulor Ha 1 coeaMHeHne) Nomewalor Ha Bpawjarouwien Cronk A OnpbicMBAIoT ANA Toro, TOO yanaxHAre acteHna go oTekaww Boge, 100 mn eyenypss, conepxaujeA 100 whan enbiTyeMorO CoeAMHeHMA, © UonombsoaaHNEM acnsinurena @ fleBAn6vec, ycraHoanenHoro pn nasneHan soanyxa 2,8 ar. B KavecTee HeorpaGoranvoro —KOHTponA _wononssyior Sapaxenisle PACTeNMA, KOTOPHIE CNpHiCKMBAIOT 100 wa ppacreopa Bonbrayerowa-pmmeTancbopmannna A ‘omynsraropa, He conepKaujero wensiTyeMoro vosnnienne. 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