You are on page 1of 11

Journal of Cleaner Production 205 (2018) 995e1005

Contents lists available at ScienceDirect

Journal of Cleaner Production


journal homepage: www.elsevier.com/locate/jclepro

An affordable solution for micro-miners in Colombia to process gold


ores without mercury
Marcello M. Veiga a, *, Pierre Masson b, Denis Perron c, Annie-Claude Laflamme d,
Robert Gagnon e, Gabriel Jimenez a, Bruce G. Marshall a
a
Norman B. Keevil Institute of Mining Engineering, University of British Columbia, Vancouver, BC, Canada
b
CEGEP of Sherbrooke, Qu ebec, Canada
c 
CEGEP from l'Abitibi-T
emiscamingue, Rouyn-Noranda, Qu ebec, Canada
d
CICAN, Colleges and Institutes Canada, Project Coordinator in Colombia, Canada
e
ExploLab Inc. Val-d’Or, Quebec, Canada

a r t i c l e i n f o a b s t r a c t

Article history: Simple and affordable pieces of equipment to concentrate gold were developed by the Colleges and
Received 6 June 2018 Institutes Canada (CICAN) Project in Colombia using locally available materials found in junk yards and
Received in revised form metal shops. A chain mill, shaking table and flotation cell were built in Colombia and demonstrated to
2 August 2018
micro-miners, who typically process less than 2 tonnes per day (tpd) of ore. An economic feasibility study
Accepted 4 September 2018
was conducted for four different ore processing rates (0.2, 0.5, 1 and 2 tpd) and different levels of gold
Available online 8 September 2018
recovery (30, 50, 70 and 85%) that were compared with the current practice of taking ores to processing
centers (entables), where the whole ore is typically amalgamated in small ball mills called cocos. For the
processing rates of 0.2, 0.5 and 1 tpd, miners must sell their concentrates to cyanidation plants at 65% of
the gold content. At 2 tpd, miners could further leach the concentrates with cyanide using a mill-leaching
technique. Although the results show that the CICAN approach is profitable at all levels of production,
gold recovery must be higher than what is normally achieved at the entables using amalgamation (~30%).
For miners processing 0.5 tpd or less of ore, their recoveries must be much higher than 50% to be more
profitable than using mercury in entables. Miners using the CICAN techniques of gravity and flotation
concentration to process 1 tpd of ore with a gold grade of 15 g/t and 85% recovery would generate a Net
Present Value of US$315,693 with an Internal Rate of Return of 1754%. This would generate US$150,000
more profit over a 5-year period when compared with miners taking their ores to entables. Even for the
micro-miners who have no capacity to leach gold from the concentrates using cyanide, the CICAN
techniques are very feasible, as they can sell the concentrates afterwards for a value above 65% of the
gold content. The capital cost for the CICAN equipment ranges from US$ 2,600 (0.2 tpd) to US$ 10,500 (2
tpd) and the estimated operating cost fluctuates between US$ 4,500 (0.2 tpd) and US$ 10,309 (2 tpd).
© 2018 Published by Elsevier Ltd.

1. Introduction a large variety of socio-economic and health problems are gener-


ated (Hinton et al., 2003; Tschakert, 2009; Veiga, 2009; Malm et al.,
It has been estimated that about 16 million artisanal gold (AGM) 2010; Swenson et al., 2011; Gibb and O'Leary, 2014; Toledo and
miners, in more than 70 developing countries, produce between Veiga, 2018). This is usually a result of inadequate policies from
337 and 447 tonnes of Au/a or approximately 12e15% of the annual governments, thorny bureaucracies, lack of education of miners,
world gold production (Seccatore et al., 2014; UNEP, 2017). As a poverty, poor employment opportunities in rural areas, high price
result, dramatic environmental impacts, such as deforestation, river of gold, among many other factors (Hentschel et al., 2002; Hilson,
siltation, mercury and cyanide releases, land degradation, as well as 2002, 2007, 2016; Vieira, 2006; McDaniels et al., 2010; Siegel and
Veiga, 2010; Spiegel, 2012).
Mercury (Hg) use by artisanal gold miners (AGM) is the largest
source of global anthropogenic Hg pollution, with approximately
* Corresponding author. 1400 tonnes of mercury annually released to the environment
E-mail address: veiga@mining.ubc.ca (M.M. Veiga).

https://doi.org/10.1016/j.jclepro.2018.09.039
0959-6526/© 2018 Published by Elsevier Ltd.
996 M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005

(Schmidt, 2012). The poor techniques used by AGM in the amal- UN COMTRADE data (2017), official mercury imports in 2014 were
gamation of gold ores is the main cause of these large Hg losses to 127.2 tonnes, 133.2 tonnes in 2015 and nearly 119 tonnes in 2016
the environment (Gonçalves et al., 2017; Zolnikov and Ramirez- and only 4.7 tonnes in 2017. Meanwhile, Bolivia that has imported
Ortiz, 2018). According to UNEP (2018), AGM emitted 838 tonnes 12 tonnes of Hg in 2014, imported 238 in 2016 tonnes and 180
of mercury to the atmosphere in 2015, which represent approxi- tonnes in 2017. It seems clear where the mercury used in Colombia
mately 38% of the total global anthropogenic mercury atmospheric is coming from.
emissions. Although the large mercury use by Colombian artisanal miners
Colombia has a long history of mercury pollution caused by is a consequence of many factors, the unwieldy bureaucracy
AGM and is still the world's largest mercury consumer per capita inherent within the formalization process, in conjunction with the
(Veiga, 2010). The mercury pollution has caused Hg bio- mercury ban, are creating major hurdles for legitimate AGM miners
accumulation in fish (Olivero and Solano, 1998; Marrugo-Negrete to overcome. Rochlin (2018) stated that failure of the formalization
et al., 2008; Salazar-Camacho et al., 2017), which can lead to process in the country is “due to a combination of a weak State,
increased risk of Hg intoxication for fish-eating populations powerful insurgent and criminal organizations, as well as government
downriver from Hg hotspots. Similarly, there is evidence of policies that generally have not taken into account the interests of
neurological problems in individuals exposed to Hg vapor in artisanal miners”. This statement leads to believe that the solution
Colombian mining towns, where processing centers and gold shops for mercury pollution will not be resolved solely via the bureau-
burn amalgams openly without any concern for resident pop- cratic formalization of informal miners, which the government
ulations (De Miguel et al., 2014; Garcia et al., 2015). Rodríguez- tends to promote. With insufficient capital, technical assistance and
Villamizar et al. (2015) have proven that routine exposure to enforcement, neither formalized nor non-formalized artisanal
alarmingly high levels of Hg atmospheric pollution in Colombian miners will simply adopt Hg-free techniques due to implementa-
mining areas is associated with a higher prevalence of irregular tion of a mercury ban. Without first consulting the miners, the
menstruation in women. The main source of this overwhelming passing and implementation of new Colombian laws aimed at the
pollution is the entables, which are processing centers where the AGM sector will continue to generate poor results.
miners take their ores to be processed for a nominal fee. As the According to a report by the Universidad de Co  rdoba (2015) for
centers are usually the only solution for artisanal miners who do the MME, technical support is crucially needed for Colombian
not have the capital to implement their own processing facilities, artisanal miners and must be accompanied by economic incentives,
the entable owners end up taking advantage of this situation. Many as technology alone is insufficient to reduce and eventually elimi-
centers, located in the heart of populated areas, use mercury to nate the use of mercury in artisanal gold mining in Colombia or
amalgamate the whole ore brought by AGM miners in small ball elsewhere. Due to little capital and no permanent technical assis-
mills called cocos, extracting less than 30% of the gold and retaining tance, miners are and will continue to be dependent on the entables
the Hg-contaminated tailings as payment for their services. The to extract gold from their ores (Veiga et al., 2014b).
residual gold is then extracted using cyanide (Veiga et al., 2014b), Although the number of artisanal (formal or informal) gold
which ends up forming Hg-cyanide complexes that are usually miners in Colombia is not well known, it has been estimated that
dumped untreated into local drainages, thereby exacerbating the there are likely 200,000 miners directly involved in this activity
pollution (Drace et al., 2016). Virtually all entables in Colombia use (Cordy et al., 2011). A large number of these miners can be
cyanide to leach Hg-contaminated tailings left by the miners. The considered micro-miners, who pan alluvial ores on the riverbanks
management of cyanide by entables in Colombia is very poor and or extract weathered ores from open pits or even primary ores from
they annually release thousands of tonnes of cyanide to the envi- underground deposits, processing 60e100 kg of ore per day per
ronment in the form of free cyanide and cyanide complexes, such as miner and producing 0.3e1 g/gold/day. These micro-miners usually
Hg(CN)2 (aq) (Veiga et al., 2014a). The environmental consequences use either a primitive sluice box or the entables to extract the gold
of this chemical discharge of mercury and cyanide into the from their ores using amalgamation of the whole ore, which
Colombian watercourses is still not well understood (Bustamante generally yields 30% of the total gold in the ore (Veiga et al., 2014b).
et al., 2016). As amalgamation of the whole ore results in losses For the sake of this paper, artisanal micro-miners are classified as
of approximately 50% of the mercury entering the process (Garcia those who mine and process less than 2 tonnes of ore per day using
et al., 2015), implementation of gravity concentration techniques rudimentary techniques.
before applying mercury is vital to reduce Hg pollution. Further- This article brings the experience of the Colleges and Institutes
more, in order to avoid the dangerous formation of mercury cya- Canada (CICAN) Project in Colombia that introduced a simple
nide complexes, a combination of gravity concentration, flotation approach to micro-miners and trainers to fabricate their own pro-
and cyanide leaching would be the best solution over the long term. cessing equipment using inexpensive locally available materials.
In 2016, gold production in Colombia was 61.8 tonnes (MME, The CICAN Project, led by a Colle ge d'Enseignement Ge  ne
ral et
2016), of which the informal miners produced 87% of the gold  
Professionnel (CEGEP) group from l'Abitibi-Temiscamingue, Rouyn-
(VerdadeAbierta.com, 2017). In 2017, the official gold production
Noranda, Que bec, left an important legacy in the country that has
decreased 34% (El Espectador, 2018).
the potential to dramatically reduce the use of mercury by the AGM
As Colombia signed the UNEP Minamata Convention in 2013,
sector, since miners with the CICAN-introduced knowledge and
heralding a commitment to reduce the use of mercury, imple-
assistance would not need to process their ores in the Hg-polluting
mentation of Law 1658 confirms mercury prohibition in all gold
processing centers (entables). In this study, the technical and eco-
mining operations by July 2018 and total elimination by all sectors
nomic feasibilities of the CICAN approach were evaluated.
in the country by 2023. In addition, Law 1658 introduces new al-
ternatives and incentives for the formalization of small-scale
mining in the country, including the availability of loans for arti- 2. The MacGyver approach
sanal and small-scale miners. According to the Strategic Plan to
Eliminate the Use of Mercury in Colombia (MME, 2016), 193 tonnes The CICAN Project implemented the “MacGyver approach”,
of Hg were consumed in artisanal gold mining (AGM) in 2014, of whereby gold processing equipment can be made using local
which 105 tonnes were used in illegal-informal artisanal mining available materials at a very low cost. MacGyver is an American
activities and 88 tonnes by formalized operations. As reported by action television series, in which MacGyver is a secret agent that is
M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005 997

able to make equipment and find solutions using ordinary objects ground ore) is fed and rapidly distributed across the table. As par-
found at home and in supermarkets. The attraction of the series is ticles of heavier minerals, such as gold and sulphides, cannot pass
that he uses his scientific knowledge to make tools in order to through the riffles, they move slowly and get collected down in the
resolve problems. The CICAN approach is based on manufacturing feed-opposite corner of the table (Wills and Finch, 2016). Shaking
gold processing equipment using chains, truck wheels, scrap iron, tables are typically used by conventional gold mining companies to
and other items found in junk yards and metal shops in the mining upgrade the concentrates after passing through other gravity sep-
areas. This is an extremely noble and valuable approach that is very aration equipment (Wotruba and Weitka €mper, 2015). The capacity
much in line with what Schumacher (1973) described as “appro- of a conventional table to process 1e2 tonnes per hour of ore de-
priate technology” in his best seller “Small is Beautiful”. pends on the size of the feed that usually ranges from 3 to 0.1 mm
After a series of field visits and consultations with Colombian (Wills and Finch, 2016).
micro-miners in different regions, the CICAN project started to The small CICAN shaking table is built using plywood, plastic
develop pieces of equipment from discussions with the miners. buckets, and iron bars. This shaking table is able to process
When electric power was not available, the CICAN Project devel- 100e200 kg/h of ground ore, using either a small 1 HP electric
oped concentration sluice boxes and shaking tables operated by a motor or a manual lever or foot pedal to generate the horizontal
pedal or a manual lever to work alluvial and colluvial ores, which stroke (Fig. 2). The provided energy also works a pump that recir-
do not always require comminution. When electricity was available culate the water that is previously filtered (domestic water filter) or
and miners were working with primary rocks, dry grinding decanted. The shaking table produces 3 products: tailings, mid-
equipment using a type of hammer mill technique (herein called dlings and concentrate. The tailings can still have small specks of
“chain mills”) was developed. Concentrators, like the shaking ta- very fine gold particles that can be recovered using a flotation
bles, would be able to be operated with a small electric motor. system. The middlings carry unliberated gold that must be re-
Blueprints were given to local manufacturers, as this equipment circulated back to the grinder. If the concentrates reach a high
would not be subjected to patents, as the copyrights belong to grade of gold, above 30,000 g Au/t, they can then be melted with
Global Affairs Canada, which has the intention to freely promote borax (Appel and Na-Oy, 2011). As concentrates with high sul-
these techniques. The most viable pieces of equipment are briefly phides and lower grades of gold usually lose gold to the slag during
described as follows: the smelting process (Veiga et al., 2014b), it is better to sell the
concentrates or to leach them with cyanide using small ball mills as
2.1. Chain mills the reaction vessel (Veiga et al., 2009). However, in some cases
shaking tables are not always the best primary gold concentrators,
This is a creative modification of the hammer mill, in which the as flaky gold particles, by their natural hydrophobicity, float over
hammers are made of an ordinary steel chain that are fixed with the riffles and end up going to the tailings (Lins and Farid, 1992).
screws and rotated using a 1.5 HP or 0.5 HP (smaller version) Overall, a well-operated shaking table can provide better results
electric motor. Although the chains wear out every 100e200 kg of than a poorly fabricated sluice box, which is typically seen in arti-
material, they can easily be changed. The body of the chain mill is sanal gold mining operations.
built with a truck wheel supported by iron frames with a rubber tire In total, the cost of building this shaking table in Colombia range
as the base. In the tests conducted in Quebec, the mill was fed with from US$ 100 to US$ 200, depending on the accessibility of mate-
ore from a local Canadian gold mine, previously crushed below ½ rials and welders.
inch. The mill works dry or wet and the grinding is extremely fast,
producing output material with a grain size below 1 mm (Fig. 1). A 2.3. Flotation cell
large chain mill can process 0.15e0.4 tonnes of ore per hour,
depending on the hardness of the material. After initial tests in Gravity concentration usually does not work well for very fine
Quebec, the chain mill was constructed in Colombia together with gold particles (below 0.074 mm). In conventional gold mining
artisanal gold miners, costing less than US$ 400 in equipment and plants, gravity concentration is used at the discharge of the ball
labor. mills to remove coarse gold from the circuit, which can become
lodged in pumps or pipelines. Part of the fine gold (below 0.1 mm)
2.2. Shaking tables not recovered by the gravity circuit can then be concentrated by
flotation.
Shaking tables concentrate gold in a flat, inclined surface with Froth flotation is a process to separate minerals of interest from
parallel riffles that shake horizontally after a pulp (water þ 20e30% gangue minerals based on the hydrophobicity (water repulsion) of

Fig. 1. Chain mill from the CICAN project being tested in the lab and fabricated in the field.
998 M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005

Fig. 2. Shaking table operated by foot or manual lever.

each mineral, which varies in relation to changes in pH of the water. so, the miners would not need to take their ores to be processed in
Surfactants and wetting agents are used to increase the difference entables using whole ore amalgamation, whereby they receive less
in hydrophobicity between minerals, thereby creating selectivity. than 30% of the gold in their ores and the process generates high
Froth flotation is a process widely used industrially to separate levels of pollution.
sulphides, carbonates, oxides and phosphates and works well for In 2016, different types of home-made equipment were tested
grain sizes between 0.1 and 0.01 mm (Leja, 1982). in Colombia to test their capacity to grind and concentrate gold. The
A CICAN flotation cell was fabricated using fiberglass and PVC advantages and disadvantages of each piece of equipment were
tubes, which was designed for a 0.5 HP motor to run the impeller discussed with a team of experts, the artisanal miners and SENA
that agitates the pulp and pumps air into the cell by natural suction. (Servicio Nacional de Aprendizaje), the Colombian vocational in-
The volume of the tank is 71 L and it can process approximately struction service. After deciding on which pieces of equipment
20 kg of ore per batch (Fig. 3). This cell can easily be built as part of a should be locally fabricated, approximately 30 miners and teachers
bank of cells. The cost to make this cell in Colombia was ~ US$ 300, from SENA were trained. In March 2017, the prototypes previously
in which 30% was labor cost. The flotation process takes more skill tested in Quebec were built in Puerto Berrio, Department of Anti-
to operate, as this involves a series of reagents such as collectors, oquia and demonstrated to the local metal shop owners and arti-
frothers and depressants that are specific for each type of ore, as sanal miners. In June 2017, the locally built prototypes were
well as requiring strict control of pH. demonstrated in Minas del Vapor, Puerto Berrio, to government
authorities, miners and participants of other mercury elimination
3. Implementation projects throughout the country.
Tests with the CICAN shaking table using gold ore from Que bec
In June 2015, the CICAN Project assessed the needs and interests resulted in 88% gold recovery when the ore was ground in the chain
of artisanal micro-miners in Colombia before taking equipment mill to 1 mm. In November 2017, two tests with the shaking tables
blueprints to the local mechanical shops to devise prototypes. The using a sample from Minas del Vapor with a grade of 5.8 g/t Au
idea was that these technologies would allow for the micro-miners resulted in 51% and 53% gold recovery, respectively. This was a
to process their own ores, thereby increasing their income. In doing remarkable outcome, as the ores from this locality usually is hard to

Fig. 3. Home-made flotation cell.


M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005 999

concentrate due to large amounts of carbonaceous clayminerals. In technology applied and the subsequent gold recovery, as well as
comparison, whole amalgamation of these ores was only able to capital and operating costs.
extract less than 30% of the gold.
4.1. Assumptions and limitations of the feasibility study
4. Economic feasibility of the approach
The gold price used in this study was based on the LME gold
An economic feasibility study was conducted on the pieces of price of March 14, 2018 (US$ 1325/oz, which is equivalent to US$
equipment developed by the CICAN project, considering 4 levels of 42.60 per gram of gold content in the dore). As the price considered
ore processing: 0.2 tonnes of ore processed per day (tpd)(with 3 .
only the gold, no value was given to the amount of silver in the dore
miners), 0.5 tpd (with 5 miners), 1 tpd (with 8 miners) and 2 tpd In fact, this also represents the sad reality the micro-miners face
(with 12 miners). The economic analysis considered production of when they sell gold to the Colombian gold shops.
concentrates from different ores with grades of 8, 15 and 25 g Au/t. Gold production using CICAN equipment was based on variables
The premise of this feasibility study was to promote the idea such as production rate, grade, gold recovery and the number of
that micro-miners should be able to process their own gold ores working days per year. This study considered that micro-miners
using mercury-free techniques instead of having to take the ores to processing 0.2, 0.5 and 1 tpd, do not have capital and knowledge
processing centers (entables), which practice whole-ore amalgam- to implement a cyanidation plant, therefore they must sell their
ation using small ball mills that process 60e70 kg at a time with concentrates to local cyanidation plants or smelters (Fig. 4a). The
100e200 g of mercury, resulting in average gold recovery of plants processing 0.2 and 0.5 tpd of ore would only use CICAN
approximately 30% (Garcia et al., 2015). The following two situa- gravity concentration equipment, while the plant processing 1 tpd
tions were compared for the feasibility study: would use CICAN gravity concentration equipment plus a flotation
cell also manufactured according to CICAN design. For the 2 tpd
1. Micro-miners buy the equipment designed by CICAN (chain plant, the CICAN gravity and flotation concentrates would be
mills, shaking tables and flotation cells) from metal shops that further processed in a mill-leaching circuit with cyanide where the
construct the pieces locally to process their own ores without total gold recovery including gravity þ flotation þ cyanidation of
mercury to obtain concentrates that can either be sold to cya- concentrates would be between 70% and 85%. (Fig. 4b). Plants with
nidation plants, directly melted or leached with cyanide using the capacity to process more than 2 tpd of gold ores using CICAN
the mill-leaching technique. In this situation, the production techniques were not considered in this analysis, first because these
level determines the fate of the concentrate. plants need more capital and management and second because the
2. Micro-miners continue with the “business as usual” approach, CICAN techniques, as conceived for micro-miners, inherently have
where they take their gold ores to entables to be processed using limitations for use in larger production plants.
whole-ore amalgamation. It is important to stress that the recommendation of cyanide
leaching for the 2 tpd plants is only for gravity and flotation con-
For the sake of comparison, as mining costs were considered to centrates and not for the whole ore, which reduces at least 90% of
be the same in both situations, they were not factored into the the mass to be leached. However, it is imperative to promote the
feasibility study. In general, the economic analysis applied is responsible use of cyanide at the same time. Worldwide, all con-
simplistic, since the mineralogy and gold grade of each ore needs to ventional gold mines use this reagent based on its low price, effi-
be determined a priori in order to generate accurate results. In turn, ciency, simple application and ability to be easily degraded after
this can make a substantial difference in the gold extraction use. In general, cyanide use requires adequate management, which

(a) (b)
Fig. 4. Processing plant flow sheets for a) 0.2, 0.5 and 1 tpd; b) 2 tpd of gold ore. Note: Dashed lines (flotation) in (a) only refer to 1 tpd operations.
1000 M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005

is also the same for mercury use. Although cyanide is acutely toxic 4000 tpd, the CAPEX is approximately US$ 10,000/tpd (Prospect
to organisms, it does not bioaccumulate in organisms nor bio- Resources, 2018). For complete gold processing plants using con-
magnify up the food chain like mercury, and there is no evidence ventional and new pieces of equipment for comminution, con-
that cyanide is carcinogenic (ICMI, 2018). The mill-leaching cyani- centration, cyanidation, infrastructure, laboratory, offices, power
dation process herein proposed (Veiga et al., 2009) is fundamen- lines, water systems and tailing management, the CAPEX ranges
tally different from the process currently used by most entables, from US$ 20,000/tpd (for 200 tpd) to US$ 86,000/tpd (for 5 tpd). In
where no protocols of any kind are followed, resulting in poor comparison, the CAPEX calculated for the CICAN plants are much
safety measures for operators and irresponsible management of lower, ranging from US$ 5250/tpd for 2 tpd to US$ 13,000/tpd (for
tailings. In the mill-leaching process, the same small ball mills the 0.2 tpd).
entables use for amalgamation of the whole ore would be trans- Micro-miners would have to be eligible for government grants
formed into cyanidation tanks to leach gold from concentrates. or small business loans in order to have the financial wherewithal
Although this process involves technical expertise and some capi- necessary to acquire the CICAN equipment needed for each pro-
tal, it is much simpler to use than the classical cyanidation leaching duction level. For the purpose of this assessment, the loans would
in agitated tanks and more efficient than the vat-leaching (perco- be able to be amortized over a 5-year period at an interest rate of
lation) currently used by entables. 11%, which is the average interest rate in Colombia. The capital
In order to compare the feasibility of the CICAN techniques with payments are reflected in the cash-flows.
the entables, this study disregarded any taxes the micro-miners The CAPEX involved in taking the ores to entables to be pro-
would normally pay when selling their concentrates or gold. cessed by whole-ore amalgamation was estimated based on a fixed
Furthermore, the study used an inflation rate of 4.09% (Colombian nominal amount of US$ 500 per miner, which refers to sacks,
inflation in 2017), a nominal discount rate of 15.28% and an interest shovels, hammers, helmets and other materials needed to pack the
rate of 11% per year, which is typically used by Colombian banks. ore they have mined. It is important to emphasize that this amount
The time period used for the analysis was 5 years, which is the does not include expenditures related to mining activities, in order
amortization period of the investment (capital cost). to adequately compare with the capital costs associated with the
As the CICAN pieces of equipment are not enough to establish a CICAN process. After extraction of the material, the miners then
full processing plant, a crusher, static screens and a small ball mill pack the ore and take it to the entables (Table 2).
for mill-leaching cyanidation were also included as part of the
analysis.
4.3. Operating costs

4.2. Capital costs For the operating expenditures (OPEX) of miners using the
CICAN techniques, it was estimated an annual OPEX of US$ 4500 for
The capital cost (CAPEX) was estimated based on the local a processing plant of 0.2 tpd. This includes all expenses such as
manufacturing of CICAN pieces of equipment in Colombia, as well power, food, water, transportation, oil, etc. The data were obtained
as other equipment such as a jaw crusher, screens, cocos (small bill in Colombia, which result in an approximate cost of US$ 5/miner/
mills) for mill-leaching, etc., plus infrastructure. The estimated day for a 0.2 tpd plant. This cost does not includes salaries as the
CAPEX for each level of processing plant was calculated (Table 1). miners work in partnership to be rewarded with the gold they
This is an approximations as infrastructure costs can fluctuate extract. The number of miners per production rate used this 0.2 tpd
immensely. The CAPEX per tonne of ore processed per day usually plant, with 3 miners, as the Base Plant to scale up the number of
ranges from US$ 10,000 to US$ 20,000/tpd for artisanal processing miners for other production levels (see formula below). The
plants (Veiga et al., 2014b). For a conventional plant processing calculation used an adaptation of the “0.6 rule” formula devised by

Table 1
Capital cost (CAPEX) for micro-miners to process 0.2e2 tonnes of ore/day (tpd).

Capital Cost of Equipment (US$) Equipment Price Prod. Rate 0.2 tpd Prod. Rate 0.5 tpd Prod. Rate 1 tpd Prod. Rate 2 tpd

Jaw crusher or hammer mill 3000 3000 3000 3000


Static 7 mm screen 500 500
CICAN Chain mill 400 400 400 400 400
Static screen of 1 mm or trommel 500 500 500 500 500
CICAN shaking table for 0.2 tph 300 300 300 300 300
CICAN flotation cell 300 300 300
Large “coco” (100e200 kg/batch) for mill-leaching with cyanide 2000 2000
Other materials for cyanidation (activated carbon, oven, cooler, etc.) 1000 1000
Blow torch (propane) for gold smelting and crucibles 500 500
Infrastructure (fumehood, shed, electrical power, etc.) 1000 300 300 1000 2000
Others expenses 1100
TOTAL OF INITIAL CAPEX 2600 4500 5500 10500
CAPEX/tpd 13000 9000 5500 5250

Table 2
Initial Capital cost (CAPEX) for micro-miners processing ore at entables.

Production Rate (tpd) Number of Miners Initial Expenses per miner (US$) CAPEX - Total initial Investment (US$)

0.2 3 500 1500


0.5 5 500 2500
1 8 500 4000
2 12 500 6000
M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005 1001

Mular (1978) originally used for capital costs. 4.4. Gold selling price to cyanidation plants

This study considered that plants with production rates of 0.2,


 0:6
tpd of New Plant 0.5 and 1 tpd would have to sell the concentrates to large com-
Number of Miners in New Plant ¼
tpd Base Plant panies, since this reduces the CAPEX, OPEX and the bureaucracy
x Number of Mines in Base Plant (authorizations) required to use cyanide. In addition, the technical
knowledge needed to safely use cyanide requires a significant
The results of the number of miners were not rounded to amount of training, which would require more specialized workers.
calculate the OPEX of different processing production levels (New The concentrate price paid to micro-miners using CICAN tech-
Plants) using similar formula (Table 3). niques was compared with the amount of gold produced when
using entables, where the gold recovery is ~30%. The CICAN analysis
considered different gold recoveries and different ore grades (8, 15
 0:6
Number of Miner New Pkant and 25 g Au/t). While it was determined that all conditions for
OPEX New Plant ¼ micro-miners using CICAN techniques would be favorable and
Number of Miners Base Plant
profitable, in some cases miners processing ores in entables would
x OPEX Base Plant
make more money than at the poorest CICAN conditions. Therefore,
Although the annual OPEX of these small plants ranges from US$ the following formula was used to find the breakeven percentage of
75/tonne (for 0.2 tpd) to US$ 17/tonne (for 2 tpd), which is within gold content in the concentrates that would have to be paid in order
the range of conventional gold plants, the OPEX of very large con- to generate the same annual gross income for miners processing
ventional plants processing >30,000 tpd of gold ore can be as low as their ores in entables and those using CICAN techniques. The pro-
US$ 3 to 4/tonne (PBM, 2009). duction rate of 2 tpd was not included in this analysis, as the
When taking the ores to the entables, miners pay a small nom- concentrates, instead of being sold, would be processed with
inal fee (1000 Colombian pesos (CoP) or US$ 0.33) per 60e70 kg of cyanide.
ore processed, in addition to buying the mercury that they use
(800,000 CoP/kg or US$ 280/kg). According to the assessment of Breakeven % Au in Conc:
 
Garcia et al. (2015), which determined mercury losses from 20 cocos Gross Income when using entables
¼ x 100
in Antioquia, miners add on average 44.3 g (SD ¼ 11.6) of Hg per Gross Income when using CICAN
coco and lose 13.5 g (SD ¼ 5.9) of Hg per coco. Considering that they
only pay for the mercury that is lost, this represents US$ 3.78 per The results in Table 5 show that the breakeven percentage of
coco. gold in the concentrate needed to equalize the gross incomes from
The other operating cost (OPEX) that has to be considered is both situations varied between 35% and 60%. The lower the pro-
transportation of the ores to the entables. This was evaluated at duction rate and gold recovery, the higher the breakeven % Au in
15,000 CoP per 100 kg or US$ 54/tonne, which considered the cost the concentrate must be to overcome the money obtained when
of transportation by mules in Colombia. Another important point is processing the ore in entables. For example, in order to make the
that the miners stop mining one week per month to process their same profit as what they have using entables, miners with CICAN
ores by whole ore amalgamation at the entables. equipment processing 0.5 tpd of ore with 25 g Au/t and gold re-
The preliminary cost for processing ore in entables was esti- covery of 50% would have to sell their concentrates at a price above
mated at US$ 4 per day per micro-miner at a 0.2 tpd production 60% of the gold content in the concentrate. Therefore, for the pur-
rate. Therefore, the base operating cost was calculated at US$ 3,600, poses of this assessment, it was determined that buyers would
which included the estimated daily expenses (US$ 4), number of need to pay 65% of the gold content in the concentrate to micro-
miners (3), a 0.2 tpd production rate and 300 working days. The miners using the CICAN techniques. This number was then
“0.6 Rule” was also applied to establish the OPEX for other pro- applied in further steps of the feasibility study.
duction rates (Table 4).
4.5. NPV and IRR

The Net Present Value (NPV) and Internal Rate of Return (IRR)
Table 3
were calculated for the 4 production rates in order to compare
Annual operating expenditures (OPEX) for micro-miners using CICAN equipment.
different variables and conditions. All financial values are stated in
Production Rate Number of Annual Cost Annual OPEX/tonne United States Dollars (US$) and rounded off to the nearest dollar.
(tpd) Miners (US$) (US$/t)
The Net Present Value (NPV) is the difference between the
0.2 3.00 4500 75
0.5 5.20 6259 42
1 7.88 8032 27 Table 5
2 11.94 10309 17 Minimum selling price (% of gold content) of concentrates produced by CICAN
techniques.

Production Rate (tpd) Recovery Breakeven % of Au in the


Table 4 Concentrates
Annual operating expenditures (OPEX) for miners transporting and processing ore
in entables. 8 g/t 15 g/t 25 g/t

0.2 30% n/f n/f n/f


Production # of Miners Daily Expenses Annual Cost (US$)
50% 60% 60% 60%
Rate (tpd) per Miner (US$)
0.5 30% n/f n/f n/f
0.2 3 4 3600 50% 60% 60% 60%
0.5 5 3 5007 1 70% 43% 43% 43%
1 8 3 6426 85% 35% 35% 35%
2 12 2 8247
Note: n/f ¼ not feasible. It is always more profitable to process the ore in entables.
1002 M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005

present value of cash incomes and the present value of cash ex- over a period of 5 years. For a processing plant using CICAN tech-
penditures over 5 years. The Internal Rate of Return (IRR in %) is the niques to process 2 tpd at 25 g Au/t and 85% recovery, the NVP after
interest rate at which the net present value of the cash flow in 5 5 years of operation would be US$ 1.7 million with an IRR of 5049%
years equals zero, which evaluates the viability of the investment. or US$ 1 million more feasible than processing ores in entables
The NPV and IRR values were positive at almost all production using whole ore amalgamation and 30% gold recovery (Table 8). In
rates, due to affordable equipment prices and low operating costs in this particular case of high IRR (5049%) and high NVP (US$ 1.7
comparison with the CICAN techniques. The only situation that million), the initial capital (CAPEX) was very low, approximately
showed a negative NVP and IRR was the first one (0.2 tpd pro- US$ 6,000, with operating costs (OPEX) calculated at US$ 10,300.
duction rate, grade of 8 g/t, 30% recovery). This negative NPV means Considering the high grade of the ore (25 g/t) and high gold re-
that the present value of the costs exceeded the present value of the covery (85%), the robust return is not a surprise, due to the low
revenues at the assumed discount rate, which was due to the CAPEX and OPEX and more efficient processing.
CAPEX and OPEX of the miners operating their own processing
facility using the CICAN techniques. Above 50% of gold recovery, all
4.6. Cash flow analysis
of the 4 production rates showed similar to strong profitability,
which would be effective in enticing micro-miners to use the CICAN
For the purpose of this analysis, the following four different
techniques (Tables 6 and 7).
scenarios were selected to represent the economic outlook of the
When processing 0.5 tpd at a Au grade of 15 g/t and 50% Au
CICAN techniques for micro-miners. All scenarios used the gold
recovery, an NVP of US$ 74,522 and an IRR of 527% were obtained,
price of US$ 42.60/gram.
which shows very good profitability for the micro-miners’ invest-
ment. If 0.5 tpd of ore was processed in entables, the NVP would be
 Pessimistic scenario (0.2 tpd production rate, Au grade 8 g/t,
similar, with an estimated value of US$ 76,574 at the end of the 5-
50% Au recovery)
year period (Table 8). For miners using the CICAN techniques to
 Conservative scenario (0.5 tpd production rate, Au grade 15 g/t,
process 1 tpd of ore at a Au grade of 15 g/t and 85% recovery, the
50% Au recovery)
NVP would increase to US$ 315,693 with an IRR of 1754%. In
 Optimistic scenario (1 tpd production rate, Au grade 15 g/t, 85%
comparison, when miners use entables to process 1 tpd of ore at
Au recovery)
30% gold recovery, the NPV would be approximately US$ 166,000
 Full capacity scenario (2 tpd production rate, Au grade 25 g/t,
85% Au recovery)
Table 6
NPV of the operations using CICAN techniques (5 years of production). Although the pessimistic scenario has a negative NPV, but it is
still lucrative, generating US$ 1475 per year for a group of 3 micro-
Production Rate (tpd) Recovery NPV (US$)
miners using CICAN techniques and selling their concentrates at
8 g/t 15 g/t 25 g/t 65% of the gold content. At the conditions of this scenario, miners
0.2 30% 6539 5078 21674 would earn US$ 1.60 per day (Table 9), while from the entables they
50% 2312 21674 49333 would make US$ 2.80 per day (Table 10).
0.5 30% 3990 33032 74522
The conservative scenario showed good profits. The gross gold
50% 26117 74522 143671
1 70% 117927 253459 447076 revenue would be US$ 47,925 per year, generating a net income of
85% 151119 315693 550800 US$ 23,733. The total initial investment (CAPEX) for this scenario
2 70% 422757 839778 1435523 would be US$ 4500, while the annual OPEX is US$ 6259, resulting in
85% 524885 1031268 1754672 a total accumulated net income of US$ 118,665 after 5 years.
The cash flow for the optimistic scenario revealed strong

Table 7
IRR of the operations using CICAN techniques (5 years of production). Table 9
Net daily income per miner using CICAN techniques.
Production Rate (tpd) Recovery IRR (%)
Production Rate (tpd) Recovery Net Income (US$/miner/day)
8 g/t 15 g/t 25 g/t
8 g/t 15 g/t 25 g/t
0.2 30% n/f 85% 280%
50% 49% 280% 600% 0.2 30% 1.3 2.6 8.1
0.5 30% 49% 250% 527% 50% 1.6 8.1 17.3
50% 204% 527% 989% 0.5 30% 1.6 7.2 15.2
1 70% 674% 1414% 2471% 50% 5.9 15.2 28.5
85% 855% 1754% 3038% 1 70% 15.7 32.9 57.5
2 70% 1239% 2432% 4136% 85% 19.9 40.8 70.7
85% 1531% 2980% 5049% 2 70% 36.3 71.3 121.2
85% 44.9 87.3 148.0
Note: n/f ¼ not feasible.
Note: shaded cells indicate the studied cash flow scenarios.

Table 8
NVP of 5 years of operation of whole ore amalgamation in entables with 30% Au Table 10
recovery. Net daily income per miner using entables with 30% gold recovery.

Production Rate (tpd) NPV (US$) Production Rate (tpd) Net Income (US$/miner/day)

8 g/t 15 g/t 25 g/t 8 g/t 15 g/t 25 g/t

0.2 6939 24,811 50,343 0.2 2.8 8.8 17.3


0.5 31,893 76,574 140,403 0.5 6.6 15.2 27.5
1 76,732 166,093 293,753 1 10.3 21.6 37.8
2 170,795 349,519 604,838 2 14.8 29.8 51.2
M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005 1003

profits for the micro-miners using the CICAN techniques. The net would definitely represent a substantial reduction (>90%) in mer-
income would be almost 4 times higher than the conservative cury use in comparison to whole-ore amalgamation. While con-
scenario, generating a net income of US$ 96,464/year and a solid centrates can be further leached using cyanide, this step seems
NPV above US$ 315,000 after 5 years. somewhat advanced for some micro-miners.
Upon reaching the full capacity scenario with the CICAN While the CICAN project importantly introduces appropriate
techniques, the benefits for the micro-miners would be very robust and cost-effective equipment to eliminate the need for mercury use
and economically enticing. The net profitability of the operation by the artisanal gold micro-miners, thereby alleviating associated
would be US$ 500,000/year and more than US$ 2.5 million after 5 environmental and health impacts, this approach also encompasses
years. a sound pedagogical aspect employed to empower miners through
knowledge and increase their sense of self-esteem.
4.7. Daily income per miner Implementation of the CICAN techniques would be an excellent
technical and economical solution for micro-miners who produce
The daily incomes for each miner were calculated from the less than 2 tonnes per day of ore. They can do their own mercury-
annual net income of each cash flow scenario, divided by the free processing and either sell the concentrates to a cyanidation
number of workers at each production rate and the number of plant, or smelter or conduct their own cyanidation using small ball
working days in a year (300 days). If the income of the miners was mills or produce gold by direct smelting, if the concentrate grade is
split equally amongst the workers, the daily income per miner high enough. Upon implementation of the Colombian Law 1658 in
would start at $1.60 for those in the pessimistic scenario (0.2 tpd July 2018, which prohibits the use of mercury in artisanal and
production rate, 8 g Au/t, 50% gold recovery) and reach US$ 148 at small-scale mining, the entables will have to be converted into
the full capacity scenario (2 tpd, 25 g Au/t, 85% recovery) (Table 9). cyanidation centers, where gold concentrates can be processed.
The daily income per miner using the CICAN techniques was This conversion is not trivial, as entables are used to generating high
compared with the daily income per miner using the entables. The profits from the provision of amalgamation services to artisanal
miners processing ores in entables with 30% recovery would always miners, who receive ~30% of the gold in their ores and leave the
make more money than miners with the same gold recovery using tailings as payment, resulting in the successful extraction of addi-
CICAN equipment. Even miners processing 0.2 or 0.5 tpd with 50% tional residual gold. At any rate, enforcement on the prohibition of
recovery using CICAN equipment hardly they will make more whole-ore amalgamation is a crucial first step in the implementa-
money than when using entables. This is due to the very low pro- tion of any mercury-free solution.
duction level and miners using entables not having to invest in The concentrates generated by the micro-miners using CICAN
processing equipment and thereby having lower operating ex- techniques can be sold to local cyanidation plants at a fair price,
penses (compare Table 9 with 10). which depends on the production rate, gold grade and gold re-
covery of the ore. At a price of 65% of the gold content in a gravity
concentrate, the micro-miners can have reasonable to robust
5. Conclusion
profitability at a production rate higher than 0.2 tpd and 50% gold
recovery. For miners processing 0.5 tpd or less of ore, their re-
Although it is important to realize that the mercury problem in
coveries must be much higher than 50% to pay back the capital and
Colombia will not be solved solely by implementation of the CICAN
be more profitable than using mercury in entables.
approach, it certainly represents a good step towards reducing
The first step in implementation of the CICAN techniques as a
mercury releases. If miners or local shops could fabricate their own
business plan must involve educating local mechanical shops on
equipment, they would not need to process ores in the entables
how to build these pieces of equipment at low cost. The next step is
using cocos. Even if miners amalgamate only the concentrates, this

Fig. 5. Steps to implement a mercury-free gold processing scenario in Colombia.


1004 M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005

making sure that the mechanical shops are able to sell the CICAN- Colombia. Chemosphere 108, 183e189.
Drace, K., Kiefer, A.M., Veiga, M.M., 2016. Cyanidation of mercury-contaminated
designed equipment at affordable prices to the micro-miners. The
tailings: potential health effects and environmental justice. Current Environ.
last step involves providing the technological knowledge to Health Reports 3 (4), 443e449.
implement cyanidation techniques using small bill mills. However, El Espectador, 2018. Por regulacio  n, en 2017 cayo la produccion de oro en un 34%.
it is important to realize that these steps do not guarantee that the https://www.elespectador.com/economia/por-regulacion-en-2017-cayo-la-pro-
duccion-de-oro-en-un-34-articulo-739946.
miners or the entables will stop using mercury, unless they see Garcia, O., Veiga, M.M., Cordy, P., Suescún, O.E., Molina, J.M., Roeser, M., 2015.
economic advantages to do so. As solutions for micro-miners are Artisanal gold mining in Antioquia, Colombia: a successful case of mercury
not that simple, it is more preferable to work with larger groups of reduction. J. Clean. Prod. 90, 244e252.
Gibb, H., O'Leary, K.G., 2014. Mercury exposure and health impacts among in-
miners processing a higher volume of material, which will reduce dividuals in the artisanal and small-scale gold mining community: a compre-
the capital and operating costs. hensive review. Environ. Health Perspect. 122 (7), 667e672.
For any business plan to be successful, a permanent training Gonçalves, A.O., Marshall, B.G., Moreno-Chavez, J., Veiga, M.M., 2017. Mercury and
cyanide use at artisanal and small-scale gold processing centers in Zaruma-
center must be in place to provide technical assistance for the Portovelo, Southern Ecuador. J. Clean. Prod. 165, 836e845.
micro-miners when they need guidance and orientation. If not, Hentschel, T., Hruschka, F., Priester, M., 2002. Global Report on Artisanal & Small-
there is considerable risk that they will return to their familiar and scale Mining. Report to MMSD/IIED e International Institute of Environment
and Development, p. 67. http://pubs.iied.org/pdfs/G00723.pdf.
polluting methods of whole ore amalgamation. Commitment from Hilson, G., 2002. Small-scale mining and its socioeconomic impact in developing
Colombian educational institutions is critical for the success of any countries. Nat. Resour. Forum 26 (1), 3e13.
business plan to eliminate mercury use practiced by hundreds of Hilson, G., 2007. What is wrong with the global support facility for small-scale
mining? Prog. Dev. Stud. 7 (3), 235e249.
thousands of micro-miners. Fig. 5 outlines the steps on how a
Hilson, G., 2016. Farming, small-scale mining and rural livelihoods in Sub-Saharan
mercury-free action plan for micro-miners can be implemented in Africa: a critical overview. Extractive Ind. Soc. 3 (2), 547e563.
Colombia. Hinton, J.J., Veiga, M.M., Veiga, A.T.C., 2003. Clean artisanal gold mining: a utopian
In addition, as observed in the financial assessment, micro- approach? J. Clean. Prod. 11 (2), 99e115.
ICMI - International Cyanide Management Institute, 2018. Environmental & Health
credits as low as US$ 3000 would be sufficient enough for micro- Effects of Cyanide. https://www.cyanidecode.org/cyanide-facts/environmental-
miners to implement small CICAN processing plants, which they health-effects.
could then pay back in less than a year. However, one of the main Leja, J., 1982. Surface Chemistry of Froth Flotation. Springer Plenum Press, N.York,
p. 758.
hurdles to successful establishment of low-cost mercury-free gold Lins, F.F., Farid, L.H., 1992. Concentraça ~o gravítica. In: Lins, F.A.F. (Ed.), Aspectos
processing continues to be a lack of mineral titles for the artisanal Diversos da Garimpagem de Ouro, vol. 54. Pub CETEM/CNPq, Rio de Janeiro,
miners to work. This is a long-standing problem in Colombia pp. 31e51. Ser. Tecnologia Mineral. http://mineralis.cetem.gov.br/bitstream/
cetem/165/1/stm-54.pdf.
(Marshall and Veiga, 2017) and many other developing countries, Malm, O., Do rea, J.G., Barbosa, A.C., Pinto, F.N., Weihe, P., 2010. Sequential hair
which is related to unrealistic and impractical formalization ini- mercury in mothers and children from a traditional riverine population of the
tiatives, in combination with a weak State (Rochlin, 2018), that does Rio Tapajo s, Amazonia: seasonal changes. Environ. Res. 110 (7), 705e709.
Marrugo-Negrete, J., Benitez, L.N., Olivero-Verbel, J., 2008. Distribution of mercury
not guarantee fair distribution of lands to traditional artisanal in several environmental compartments in an aquatic ecosystem impacted by
mining communities. One way forward would be for large-scale gold mining in Northern Colombia. Arch. Environ. Contam. Toxicol. 55 (2),
gold mining companies, which typically have the legal rights to 305e316.
Marshall, B.G., Veiga, M.M., 2017. Formalization of artisanal miners: stop the train,
most of the mineral reserves in Colombia, to work on developing
we need to get off! Extractive Ind. Soc. 4, 300e303.
co-existence arrangements with micro-miners found on their McDaniels, J., Chouinard, R., Veiga, M.M., 2010. Appraising the Global Mercury
concessions. In addition to reducing conflict and eliminating the Project: an adaptive management approach to combating mercury pollution in
intrusion of illicit criminal organizations into the gold supply chain, small-scale gold mining. Int. J. Environ. Pollut. 41 (3/4), 242e258.
MME, Ministerio de Minas y Energia, 2016. Plan estrate gico sectorial para la
the implementation of CICAN techniques would eliminate the eliminacio n del uso del mercurio: la ruta hacia un beneficio sostenible del oro.
environmental and health impacts associated with mercury use June, 2016, p. 46. https://www.minminas.gov.co/documents/10180/0/
and serve as a viable profit-sharing strategy for legitimate PESþEliminaci%C3%B3nþMercurioþ%281%29.pdf/e2774fb2-e2a3-4229-8103-
2183e5a71e18.
stakeholders. Mular, A., 1978. Mineral processing equipment costs and preliminary capital cost
estimation. Canadian Inst. Min. Metall. Special 13, 166.
Olivero, J., Solano, B., 1998. Mercury in environmental samples from a waterbody
Acknowledgements contaminated by gold mining in Colombia, South America. Sci. Total Environ.
217, 83e89.
The contribution and guidance of Mrs. Corry van Gaal from PBM - Pacific Booker Minerals Inc, 2009. Morrison Copper/gold Project. Feasibility
Study. V. 4. Operating cost estimate (OPEX), Canada. http://www.pacificbooker.
Global Affairs Canada to elaborate the ideas of this article is fully com/pdf/736c%200652720100-REP-R0006-03%20Volume%204_final.pdf.
acknowledged and appreciated. The authors also express their Prospect Resources, 2018. CAPEX and OPEX. http://www.prospectresources.com.au/
gratitude to the Colombian SENA (Servicio Nacional de Aprendi- projects/arcadia-lithium-project/pre-feasibility-study/capex-opex.
Rochlin, J., 2018. Informal gold miners, security and development in Colombia:
zaje) and CICAN (Colleges and Institutes Canada) for their support charting the way forward. Extractive Ind. Soc. 5 (3), 330e339.
phane Labrecque, from
of the project. Mr. Marc Bertrand and Mr. Ste Rodríguez-Villamizar, L.A., Jaimes, D.C., Manqui nchez, L.H., 2015.
an-Tejos, A., Sa

CEGEP, miscamingue, Rouyn-Noranda, Que
l'Abitibi-Te bec are also Human mercury exposure and irregular menstrual cycles in relation to artisanal
gold mining in Colombia. Biomedica 35, 38e45.
acknowledged for their assistance in managing this project. Salazar-Camacho, C., Salas-Moreno, M., Marrugo-Madrida, S., Marrugo-Negrete, J.,
Díez, S., 2017. Dietary human exposure to mercury in two artisanal small-scale
gold mining communities of northwestern Colombia. Environ. Int. 107, 47e54.
References Schmidt, C.W., 2012. Quicksilver & Gold: mercury pollution from artisanal and
small-scale gold mining. Environ. Health Perspect. 120 (11), A424eA429.
Appel, P.W.U., Na-Oy, L., 2011. The borax method of gold extraction for small-scale Schumacher, E.F., 1973. Small Is Beautiful: a Study of Economics as if People Mat-
miners. J. Health Pollut. 2 (3), 5e10. tered. Publisher, Blond & Briggs, p. 288.
Bustamante, N., Danoucaras, N., McIntyre, N., Díaz-Martínez, J.C., Restrepo- Seccatore, J., Veiga, M.M., Origliasso, C., Marin, T., Tomi, 2014. An estimation of the
Baena, O.J., 2016. Review of improving the water management for the informal artisanal small-scale production of gold in the world. Sci. Total Environ. 496,
gold mining in Colombia. Rev. Facultad de Ingeniería, Universidad de Antioquia 662e667.
79, 174e184. Siegel, S., Veiga, M.M., 2010. The myth of alternative livelihoods: artisanal mining,
Cordy, P., Veiga, M.M., Salih, I., Al-Saadi, S., Console, S., Garcia, O., Mesa, L.A., gold, and poverty. Int. J. Environ. Pollut. 41 (3/4), 272e288.
Velasquez-Lopez, P.C., Roeser, M., 2011. Mercury contamination from artisanal Spiegel, S.J., 2012. Microfinance services, poverty and artisanal mineworkers in
gold mining in Antioquia, Colombia: the world's highest per capita mercury Africa: in search of measures for empowering vulnerable groups. J. Int. Dev. 24
pollution. Sci. Total Environ. 410, 154e160. (4), 485e517.
mez, A., 2014. Probabilistic meta-analysis
De Miguel, E., Clavijo, D., Ortega, M.F., Go Swenson, J.J., Carter, C.E., Domec, J.C., Delgado, C.I., 2011. Gold mining in the Peru-
of risk from the exposure to Hg in artisanal gold mining communities in vian Amazon: global prices, deforestation, and mercury imports. J. PLoS One.
M.M. Veiga et al. / Journal of Cleaner Production 205 (2018) 995e1005 1005

https://doi.org/10.1371/journal.pone.0018875. News 27 (1), 45e47.


Toledo, Z., Veiga, M.M., 2018. Locals' attitudes toward artisanal and large-scale Veiga, M.M., 2010. Antioquia, Colombia: the World's Most Polluted Place by Mer-
mining-a case study of Tambogrande, Peru. Extractive Ind. Soc. 5 (2), 327e334. cury: Impressions from Two Field Trips. Report to UNIDO. Bogota , Feb. 2010
Tschakert, P., 2009. Recognizing and nurturing artisanal mining as a viable liveli- trips. https://redjusticiaambientalcolombia.files.wordpress.com/2011/05/final_
hood. Resour. Pol. 34 (1e2), 24e31. revised_feb_2010_veiga_antioquia_field_trip_report.pdf.
UN COMTRADE, 2017. United Nations International Trade Statistics Database. Veiga, M.M., Nunes, D., Klein, B., Shandro, J.A., Velasquez, P.C., Sousa, R.N., 2009. Mill
Mercury imports to Colombia. HS280540. https://comtrade.un.org/data/. leaching: a viable substitute for mercury amalgamation in the artisanal gold
UNEP e United Nations Environment Programme, 2017. ASGM Partnership: mining sector? J. Clean. Prod. 17, 1373e1381.
Reducing Mercury in Artisanal and Small-scale Gold Mining (ASGM). http:// Veiga, M.M., Angeloci, G., Hitch, M., Velasquez-Lo  pez, P.C., 2014a. Processing centers
web.unep.org/chemicalsandwaste/global-mercury-partnership/reducing- in artisanal gold mining. J. Clean. Prod. 64, 535e544.
mercury-artisanal-and-small-scale-gold-mining-asgm. Veiga, M.M., Angeloci-Santos, G., Meech, J.A., 2014b. Review of barriers to reduce
UNEP, United Nations Environment Programme, 2018. Global Mercury Assessment mercury use in artisanal gold mining. Extractive Ind. Soc. 1 (2), 351e361.
2013: Sources, Emissions, Releases and Environmental Transport. Division of Vieira, R., 2006. Mercury-free gold mining technologies: possibilities for adoption in
Technology, Industry and Economics (DTIE), Geneva. https://wedocs.unep.org/ the Guianas. J. Clean. Prod. 14, 448e454.
bitstream/handle/20.500.11822/25462/GMA%202018-ReviewDraft_250518_ Wills, B.A., Finch, J., 2016. Wills' Mineral Processing Technology, eighth ed. Elsevier,
CLEAN_SEC.pdf?sequence¼1&isAllowed¼y. p. 498.
Universidad de Co  rdoba, 2015. Incidencia real de la mineria del carbon, del oro y del Wotruba, H., Weitka €mper, L., 2015. Technologies for Small Scale Primary Gold
uso del mercurio en la calidad ambiental con enfasis especial en el recurso Mining. CASM Asia Workshop. http://www.publiclandsforthepeople.org/wp-
hidrico - disen~ o de herramientas para la planeacion sectorial, p. 663. http:// content/uploads/2015/06/Technologies-for-Small-Scale-Primary-Gold-Mining-.
www.upme.gov.co/SeccionMineria_sp/Incidencia_real_de_la_mineria_sobre_ pdf.
recurso_hidrico.pdf. Zolnikov, T.R., Ramirez-Ortiz, D., 2018. A systematic review on the management and
Veiga, M.M., 2009. Artisanal gold mining: a trap of poverty and pollution. Geotech. treatment of mercury in artisanal gold mining. Sci. Total Environ. 633, 816e824.

You might also like