Dé THI THU MINH HQA S030 KY THI TOT NGHIEP TRUNG HQC PHO THONG NAM 2021 (Bé thi co 04 trang) Bai thi: KHOA HQC TY’ NHIEN Mén thi thanh phan: HOA HOC Thin gian lim bai: 50 phit khang ké thot gian pha dé Ho, ten thi la = 23; Mg = 24; Al= 27; S = 137. ‘hit nao sau day thude loai disaccarit? A. Fructoza. B. Glucozo. C. Tinh bot. D. Saccarozo. (Céu 42: Khi thay phan hodn todn tripanmitin trong dung dich NaOH dur thi thu duge glixerol va mudi X. Céng thite ciia X la A.CiHisCOONa. —_B. Crp COONa. C. C1sHa,COONa. D. CisHsCOONa. (Cu 43: Thinh phin cha yéu cia khi thién nbién “8 A. CoH, B. CH. CGH. DCH. ‘Cfiu 44: Syc khi CO> dur vao dung dich X, thu duye két tia. Dung dich X chira chat nao? A. NaAll B. NaOH. C.HCL. D. Al(NO:)s im loai nio sau diy khéng tan duge trong H2SOs loaing? B.Cu, C.Fe. D.AL 5: Céng thite phan tir cia sit(IM) clorua la A. Fex(SO.)s. B.FeCh, CFeCh. D.FeSOs. Cfu 47: To nao sau day thude loai to thién nhién’? A. To capron. B, To axetat. To tim. D. To nitron (Cu 48: Kim loai nao sau day ¢6 tinh khir manh rh A.Cu. B.Fe CAg D.AL Jun nuée cimg lau ngay trong 4m nude xuat hign mét lép cn. Thanh phan chinh cua lép cin 46 A. Ca0. B.CaCOs, C.CaCk, D. Na:COs ‘Cu 50: Hop chit Gly-Ala-Val-Gly c6 miy lién két peptit? AL. B.3, Gl D.4. (Céu 51: Kim loai ctom khéng phan img duge véi ALP B. AgNOs (dd) CHCl loding nong, §—_D, NaOH de néng. ‘Cfiu 52: Natri cacbonat li héa chat quan trong trong c6ng nghigp thay tinh, b6t gift, pham nhudm, gidy, sgi,... Cong thie cia natri eacbonat li ‘A. NaHCOs, B, NaxCOs. C.NaNOs. D. NaCl. ‘CAu $3: Dung dich nao sau day Ikhéng hoa tan duge Als? A. HINOs, B. NaOH C.HCL. D. NaNOs, diéu kign thich hgp, phan img ciia K vii chat nao sau day tao thanh oxit? B.Ch. CO D. #20. : Saccarozo (Ci:H2:011) phan tg duge vai chat nao tgo thanh dung dich e6 mau xanh thm? A. O21"). B. Cu(OH) C. AgNOMINES (t*). D. Fh (, Ni). Cau 5 A. Metylamin. B. Phenylamin, C. Dimetylamin, Jung dich amin nao sau day tao két tua tring véi dung dich Br:?O diéu kign thuong, chat X 6 thé khi, tan rat it trong nude, khong duy tri sur chay va su hé hip. 6 trang thai long, X ding dé bio quin méu, Phan tirX c6 lign két ba. Cong thite ciia X Ta A.NO>. B.NO. CNEL. D.N2. Céu 58: X, Y la hai cacbohidrat. X, ¥ déu kh6ng bj oxi héa boi AgNOVNEb. Khi thay phan hodn toan X hode Y trong mi trudng axit déu thu duge mot chat hiru co Z duy nhét. X, Y lan lugt la: ‘A, saccarozo va fructozo. B. xenlulozo va glucozo. C. tinh bot va saccarozo. D. tinh bot va xenlulozo. ‘Cfu 59: Cho céc chat sau: alanin, etylamoni axetat, ala-gly, etyl aminoaxetat, So chat phin img duge voi dung dich HCI va dung dich NaOH 1a AL2. BI C3. D.4. Cu 60: Phat biéu nio sau day khdng ding? A, Amilozo c6 mach khong phan nbn, B. Poli(vinyl clorua) e6 tinh dan hdi C. Cao su buna — N 1a polime ting hop. D.. Poli(phenol — fomandehit) durgc digu ché bing phan tg tring ngung. Cau 61: Este nio sau day tée dung v6i dung dich NaOH thu duye natri metaerylat? A. CH)COOGHHs. B, CH»=CHCOOCH3. C. CH>=C(CH:)COOCHS. D. CHsCOOCH3. (Céu 62: Hoa tan m gam Al trong dung dich HNOs du, thu durge 3,36 lit khi NO (dkte) duy nhit. G ata m fa A138, B.8,1, 27. D.4,05. Céu 63: Dét chay hodn toan amin don chéte X, thu durge durge 4,48 lit COs va 1,12 lit No, Céc thé tich khi do 6 dktc. Céng thie etia X 1a A, CoHsNEb. B. CsHoNE, C. GH:NEb. D. CHaNEb. (Cfiu 64: Cho day cdc chat: Phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S6 chit trong day khi thiy phan trong dung dich NaOH (dur), dun néng sinh ra ancol i ALS. B.2. C4, D.3. (Cu 65: Khong khi trong phong thi nghigm bj nhiém bin boi khi Cls. Dé Khir de, c6 thé xit vao khong. hi dung dich nao sau day? H3S0; loang, BNE. C. NaCl D. HCL Cu 66: Khi cacbonic chiém 0,03% thé tich khong khi, Muén t3o 500 gam tinh b6t thi edn bao Khdng khi (dkte) dé cung cdp dit CO» cho phan img quang hgp? A. 1402666 li B, 1382716 lit. ©. 1482600 lit D. 1382600 lit. Cfiu 67: Cho cic chiit sau day: NaxCOs, CO2, BaCOs, NaCl, Ba(HCOs)s. Dung dich Ca(OH): tie dung duge véi bao nhiéu chat? ALS. B.2. 4. D.3. Céu 68: Cho 18 gam hdn hgp X gdm RoCOs vi NaHCOs (s6 mol bing nhau) vao dung dich chira HCI dur, sau khi cae phan img két thic thu duoc 4.48 lit CO> (6 dktc). Mat khdc, nung 9 gam X dén khéi Itong khong d6i thu durge m gam chat rin, Gia tri ca m ki A.2,65. B. 7.45. C345. D625 (Cu 69: Xa phéng hod hoan toan 0,1 mol mét este no, don chite bing 26 gam dung dich MOH 28% (M li kim logi kiém), roi tién hanh chung cat sin phim thu durge 26,12 gam chat long X va 12,88 gam chat rin Khan Y. ét chy hoan toan chit rin Y, thu duge HO, V lit CO: (dkte) va 8,97 gam mot mudi duy nhat, Gia tricia V li A. 5,600. B. 14,224 C.5,264. D. 6,160.Céu 70: Héa tan hoan toan 8 gam hén hop X gim FeS va FeS2 trong V ml dung dich HNOs 2M, thu durge khi NO va dung dich Y, Dé tée dung hét cic chit trong Y 250 ml dung dich Ba(OH) IM. Két ta tgo thinh dem nung trong khong khi dén khéi Iuong khong déi thu duge 32,03 gam chit rin Z. Gi tri cia V 1a A290. B.270, C400. D.345, Caw 71: Cho cée phat biéu sau: . . (a) Khi hidro héa hodn toan chat béo long la triolein (xite tée Ni, t’) ri dé ngudi, thu duge chat béo rin Li tristearin (b) Trong phan tir xenlulozo, méi gée glucozo e6 ba nhém -OH. {c) Cho Cu(OH)> vao dung dich long tring trimg thay xuat hign mau vang. (@) Phenol (CéHsOH) va anilin déu phan img véi nude brom tao két tua. (@) Da sé cic polime khéng tan trong cc dung méi thong thing. 6 phat biéu diing 1a ALS. B.2. C3 D4 (Céu 72: Hon hop X gém axit oleic va triglixerit Y. Dat chiy hoan todn 0,2 mol X can vira dit 10,6 mol 2, thu drge CO2 va 126 gam H20. Mat kde, cho 0,12 mol X téc dung véi dung dich NaOH vita da, dun nnéng, thu duge glixerol va m gam hén hop gém natri oleat va natri stearat. Gif tri ciia m li A, 60,80. B. 1220. €. 73,08. D. 36,48. ‘Cfiu 73: Cho cae phat biéu sau: (a) Hén hgp Al va BaO (ti 18 mol twong img la 1:1) tan hodn toan trong nude du. (b), Cho tir tir dung dich NaHSOs dén dur vao dung dich Ba(AlO2)s, thay xuat hign két ti phan két tia bi hda tan. (©) Suc 2a mol CO) vao dung dich hén hyp chia ¢ mol NaOH va 0,5a mol Ba(OH)2 thu duge két tia, (@) Phén chua duge sit dung lim mém nude cig cé tinh eting vinb cit. (e) Dung dich hén hop FeSO. va HeSO. cé thé lim mat mau dung dich KMnOs. (g) Trong xir ly nude cimg, c6 thé diing cc vat liu polime c6 kha nang trao d6i cation. 'S6 phat biéu ding la 6. B.3, (Cau 74: Cho cée so dé chuyén héa theo ding ti I mot: E (C,H,,0,)+2NaOH 9X, +X, +X, X, +2HCL— Y +2NaCl sau dé mot X, +0, 228 57+1,0 Zt X, EE 1CH,,0,) 41,0 Biét chat E la este mach ho. Cho cdc phat biéu sau: (a) Hgp chat E ¢6 hai déng phan edu tao. (b) Khéi lugng phan tir etia X: 18.160, (c) Trong phan tir Y, s6 nguyén tir oxi gap 2 lan sé nguyén tir hidro, (d) Hop chat T cé hai déng phan cau tao, (c) Chat Z e6 thé duge tgo than tir CHsOH chi bing 1 phan tmg hia hoe. $6 phat bigu ding la Ad B.2. 3. D.4. Céu 75: Hin hop E gém chit X (CsHioN2Os) va chat Y (C7HisN3Os), trong d6 X 1a mudi ca axit da chire, Y 1 tripeptit. Cho 27,2 gam E tic dung véi dung djch NaOH dur, dun néng thu durge 0,1 mol hén hgp 2 Khi, Mat khée 27,2 gam E phan img véi dung dich HCI thu duge m gam chat hitu co. Gia tri cla m 8 A. 39,350. B. 34,850. ©. 44,525. D. 42,725‘C4u 76: Hoa tan hét 11,02 gam hén hgp X gm FeCOs, Fe(NOs)2 va Al vao dung dich Y chita KNOs vva 0,4 mol HCI, thu duge dung dich Z va 2,688 lit (dkte) khi T gom CO, Ha va NO (c6 ti 1g mol tong img la 5 : 2: 5). Dung dich Z phan img duge t6i da véi 0.45 mol NaOH. Néu cho Z tie dung vi dung dich AgNOs dur thi thu duge m gam két tia. Biét cdc phan tig xay ra hodn toan va NO la san pham khir duy nhat ciia N’* trong cic phan img trén. Gid trjctia m la A, 59,02. B. 63,88. C.68,74. D. 64.96. (C4u 77: Tién hinh thi nghiém phan img tring guong cia glucozo theo ede bude sau day: ~ Budéc 1: Rita sach Sng nghigm thay tinh bing céch cho vao mot it kiém, dun néng nhe, tring déu, sau 45 6 di va trang Iai éng nghigm bing nude cit. = Bude 2: Nhé vo dng nghiém trén | ml dung dich AgNOs 1%, sau d6 thém timg gigt NH, trong éng nghigm xuat hién két tia nu xém cua bac hidroxit, nho tiép vai gigt dung dich NHs dén khi két tua tan het. - Buse 3: Thém tigp 1 ml dung dich glucozo 1%, dun néng nhe trén ngon lita dén cén mot thi gian thdy thanh dng nghigm sing béng nhwr gong. Cho cae phat biéu sau: (a) Trong phan img trén, glucozo da bi oxi héa béi dung dich AgNOWNHs. (b) Trong bude 2, khi nh6 tiép dung dich NHs vio, két tia néu xém cia bac hidroxit bj héa tan do tao thanh phite bac [Ag(NH)2 : (©) Trong bude 3, dé két tia bac nhanh bam vio thanh éng nghigm ta phai ludn bic déu hén hop phan img. “ie G bude 1, vai trd cla NaOH Ia dé Lim sach bé mat éng nghiém. 86 phat biéu ding la ALL Be 3. D.2. (Cau 78: Hon hyp X wom Na, Ba, NaoO va BaO. Hoa tan hodn wan 131,4 gan X vay nude, thu duye 6,72 lit khi He (dktc) va dung dich Y, trong 46 ¢6 123,12 gam Ba(OH)2. Hap thy hodn todn 40,32 lit khi CO2 (dkte) vio Y, thu durge m gam ket tia. Gia tri cha m la AL 141.84, B. 131,52. €. 236,40, D. 94,56. in hop E gém ba este mach ho, déu co ban lién két pi (x) trong phan tt, trong dé c6 mét este don chife la este cia axit metaerylic va hai este hai chute 1a déng phan ciia nhau. Dét chdy hon ton 12,22 gam E bing O2, thu duge 0,37 mol HzO. Mat khac, cho 0,36 mol E phan tmg vira dit véi 234 ml dung dich NaOH 2,5M, thu duoc hén hop X gém céc mudi cia cae axit cacboxylic Khdng no, c cling sO nguyén tir cacbon trong phan tir, hai ancol khdng no, don chite ¢6 khdi leng m; gam vi mt ancol no, don chite o6 khdi lugng m, gam. Ti If m, : m, c6 gid tr] gin nit v6i gid tr] ndo sau day? ALA. B. 27. Cul D.2, Cfu 80: Hon hop X gdm phenyl axetat, metyl benzoat, etyl axetat, diphenyl oxalat va glixerol triaxetat, Thay phan hoan toan 44,28 gam X trong dung dich NaOH (dur, dun néng), c6 0.5 mol NaOH phan img, thu durge m gam hén hop mudi va 13,08 gam hdn hp Y gim eée ancol. Cho toan bé Y tie dung voi Na dur, thu durge 2,688 lit Hs. Gia tri ctia m la A, 48,86 gam, B. 59,78 gam. C.51,02 gam. D. 46,7 gam, HET———