SK 015, Chemistry Unit, KMK PRA PSPM SET 1

UNIT KIMIA
KOLEJ MATRIKULASI KEDAH

PRA PSPM
SEMESTER 1, 2021 /2022
SET 1

CHEMISTRY
SK 015
SK 015, Chemistry Unit, KMK PRA PSPM SET 1

TABLE OF RELATIVE ATOMIC MASSES

Element Symbol Proton number Relative atomic mass
Aluminum Al 13 27.0
Silver Ag 47 107.9
Argon Ar 18 40.0
Arsenic As 33 74.9
Gold Au 79 197.0
Barium Ba 56 137.3
Beryllium Be 4 9.0
Bismuth Bi 83 208.0
Boron B 5 10.8
Bromine Br 35 79.9
Iron Fe 26 55.9
Fluorine F 9 19.0
Phosphorus P 15 31.0
Helium He 2 4.0
Mercury Hg 80 200.6
Hydrogen H 1 1.0
Iodine I 53 126.9
Cadmium Cd 48 112.4
Potassium K 19 39.1
Calcium Ca 20 40.1
Carbon C 6 12.0
Chlorine Cl 17 35.5
Cobalt Co 27 58.9
Cerium Ce 58 140.1
Krypton Kr 36 83.8
Chromium Cr 24 52.0
Copper Cu 29 63.6
Lithium Li 3 6.9
Magnesium Mg 12 24.3
Manganese Mn 25 54.9
Sodium Na 11 23.0
Neon Ne 10 20.2
Nickel Ni 28 58.7
Nitrogen N 7 14.0
Oxygen O 8 16.0
Platinum Pt 78 195.1
Lead Pb 82 207.2
Protactinium Pa 91 231.0
Radium Ra 88 226.0
Radon Rn 86 222.0
Rubidium Rb 37 85.5
Selenium Se 34 79.0
Cerium Ce 58 140.1
Cesium Cs 55 132.9
Silicon Si 14 28.1
Scandium Sc 21 45.0
Tin Sn 50 118.7
Antimony Sb 51 121.8
Strontium Sr 38 87.6
Sulphur S 16 32.1
Uranium U 92 238.0
Tungsten W 74 183.9
Zinc Zn 30 65.4
SK 015, Chemistry Unit, KMK PRA PSPM SET 1

LIST OF SELECTED CONSTANT VALUES

Ionization constant for water at 25C Kw = 1.0  10−14 mol2 dm−6

Molar volume of gases Vm = 22.4 dm3 mol−1 at STP

= 24 dm3 mol−1 at room condition (25 C, 1
atm)

Speed of light in a vacuum c = 3.0  108 m s−1

Specific heat of water = 4.18 kJ kg−1 K−1

= 4.18 J g−1 K−1
= 4.18 J g−1 C−1

Avogadro’s number NA = 6.021023 mol−1

Faraday constant F = 96500 C mol−1

Planck constant h = 6.6310−34 J s

= 6.6310−34 Kg m2 s-1

Rydberg constant RH = 1.097  107 m−1

= 2.18  10−18 J

Molar of gases constant

= 0.08206 L atm mol−1 K−1

Density of water  = 1 g cm−3

Freezing point of water = 0.00 C

= 273.15 K

Vapour pressure of water at 25C P H2O = 23.76 torr

UNIT AND CONV ERSION FACTOR

VOLUME 1L = 1 dm3
1 mL = 1 cm3

ENERGY 1 J = 1 kg m2 s−2 = 1 N m = 1  107 erg

1 calorie = 4.184 J
1eV molecule−1 = 96.7 kJ mol−1

JPRESSURE 1 atm = 760 mmHg = 760 torr = 101 325 Pa = 101 325 N m-2

TEMPERATURE 0C = 273.15 K

OTHERS 1 faraday (F) = 96 500 Coulomb

1 newton (N) = 1 kg m s−2
SK 015, Chemistry Unit, KMK PRA PSPM SET 1

1. Lithium has two naturally occurring 7. A 25.0 mL potassium oxalate, K2C2O4

isotopes, 6Li and 7Li, with isotopic masses solution is titrated with 50.0 mL of
of 6.0151amu and 7.0160 amu potassium permanganate, KMnO4 with
respectively. The atomic mass of lithium is concentration 0.42 M solution in acidic
6.9409 amu. What is percentage medium according to the following
abundance of 6Li? equation:

A. 92.5 C. 14.3 2MnO4- + 5C2O42-+ 16H+ 2Mn2+ + 10CO2

+ 8 H2O
B. 85.7 D. 7.5
Calculate the concentration of K2C2O4
solution used in the titration
2. Calculate the concentration by mass A. 1.3 M C. 2.1 M
percentage (%w/w) of 14.9g of sodium
chloride in 94.1g of water. B. 1.6 M D. 2.5 M

A. 6.3% C. 15.8% 8. Calculate the mole fraction of CuCl2 in a

solution by dissolving 0.30 mol CuCl2 in
B. 13.7% D. 86.3% 100 g of water.
3. The composition of oxalic acid is 2.27 % H, A. 0. 50 C. 1.5
26.65 % carbon and 71.08 % oxygen. The
molar mass of oxalic acid is 90 g/mol. B. 0.080 D. 0.051
What is its molecular formula?
9. How much energy would be released as an
A. CHO C. C2H2O4 electron of a hydrogen atom moves from n
= 4 to n = 3?
B. C2H4O2 D. CH3O
A. 1.53 x 10-17 J
4. Calculate the mole fraction of benzene
(C6H6) in a solution of 46.8 g benzene and B. 1.74 x 10-19 J
36.8 g of toluene (C7H8)
C. 2.18 x 10-18 J
A. 0.4 C. 0.7
D. 1.06 x 10-19 J
B. 0.6 D. 0.5
10. According to the Bohr model for hydrogen
5. Balance the following redox reaction in atom, the energy required to excite an
acidic solution. electron from n= 2 to n= 3 is _______the
energy required to excite an electron from
ClO4-(aq) + SO32- SO42-(aq)+Cl-(aq) n=1 to n= 2.
The sum of coefficients is A. equal to
A. 5 C. 12 B. less than
B. 6 D. 10 C. greater than
6. A sulphuric acid solution contains 66.0% D. greater than or equal to
H2SO4 by weight and has a density of 1.58
g/mL. How many moles of the acid are 11. Select the velence electronic configuration
present in 1.00 L of the solution? that violates the Hund’s Rule for an atom
in its ground state.
A. 10.64 C. 9.05
2s 2p
C. 1.02 D. 0.67 A.

B.
SK 015, Chemistry Unit, KMK PRA PSPM SET 1

17. Which of the following compound has the

highest boiling point.
C.
A. CCI4 C. CH4
D.
B. CBr4 D. CF4
12. The electronic configuration of a cation
M5+ is 1s2 2s2 2p6 3s2 3p6. What would be 18. Which of the following species has the
the electronic configuration for M? shortest nitrogen to nitrogen bond?

A. 1s2 2s2 2p6 3s2 3p1 A. N2 C. N2O

B. 1s2 2s2 2p6 3s2 3p5 B. N2O4 D. N2H4

C. 1s2 2s2 2p6 3s2 3p6 3d5 19. What are the types of hybridization for a,
b and c in the given molecule below?
D. 1s2 2s2 2p6 3s2 3p6 3d3 4s2
(b)
13. The molecule BF3 is an example of a H
molecule that
H - N -C - C=O
A. Obeys the octet rule H H OH
(c )
(a)
B. has an expanded octet

C. Has an incomplete octet A. sp2, sp2, sp3 C. sp, sp2, sp3

D. has odd number of electrons B. sp, sp3, sp3d D. sp3, sp3, sp2

14. What is the type of hybridisation for the 20. A 3.0 L vessel is filled with 12.85 g of a
central atom of SO32-? gas mixture at 300C. The gas mixture
consisted of 80% w/w of argon and 20%
A. sp C. sp3 w/w of nitrogen gas.

B. sp2 D. sp3d Calculate the total pressure of gasses

15 Based on VSEPR theory, predict the A. 3.35 atm C. 2.10 atm

shape of IBr4+ ion.
B. 2.89 atm D. 3.89 atm
A. Distorted tetrahedral
21. Calculate the total pressure exerted by a
B. Tetrahedral mixture of 16g of N2 and 12 g of O2 in a
3.0 L vessel at 250C.
C. Trigonal pyramidal
A. 8.2 atm C. 7.70 atm
D. Square planar
B. 6.70 atm D. 7.25 atm

22. A 2 dm3 glass vessel at T0C contains

16. The forces of attraction between hydrogen Helium gas at 1/4P while a 3 dm3 glass
molecules are vessel at the same temperature contains
oxygen at 1/2P. When both vessels are
A. Covalent bond joined and the gases are completely
mixed, what is the partial pressure of the
B. hydrogen bonds
oxygen gas?
C. London forces
A. 3/10P C. 3/20P
D. dipole-dipole forces
B. 4/5P D. 5/4P
SK 015, Chemistry Unit, KMK PRA PSPM SET 1

23. Equilibrium constant, Kp, for the the pH of the solution was 4.93. Calculate
equilibrium the Ka value for HX.

BeH6 (g) + 4BF3 (g) 6HBF2 (g) A. 1.37 x 10-10 C. 1.17 x 10-5

is 2.94 at 296K. What is the value of B. 6.85 x 10-9 D. 5.85 x 10-4

equilibrium constant, Kc for this
equilibrium at the same temperature? 27. Calculate the pH of a 0.02M solution of
Ca(OH)2 at 25oC
A. 0.121 mol L-1 C. 71.4 mol L-1
A. 0.04 C. 1.69
B. 8.26 mol L-1 D. 2.94 mol L-1
B. 1.40 D. 12.6
24. The formation of Sulphur trioxide gas SO3
is given as: 28. Choose the CORRECT statement
regarding buffer solutions
2SO2(g) + O2(g) 2SO3(g)
A. A buffer capacity is the pH of a buffer
Initially, 2 mol of Sulphur dioxide gas, SO2 after mixing an acid and base pair in
and 1 mol of oxygen gas, O2 is placed in limited amount.
1.0 L flask. At equilibrium, 57% of oxygen
was completely reacted. Calculate the B. A buffer made from strong acid and
percentage of Sulphur trioxide, SO3 at strong base is normally able to resist
equilibrium. changes in pH better.

A. 50.5% C. 75% C. A buffer solution made from NH3 and

NH4CI pair will have pH in the acid
B. 46.9% D. 63% range.

25. The graph below shows the effect of D. A buffer is characterized by its pH, and
temperature, T on the equilibrium constant, its buffer capacity upon the addition of
Kp fpr the reaction small amounts of strong acid or strong
base.
X (g) + Y (g) Z(g)
29. If the molar solubility of PbBr2 is 0.01mol
Kp
L-1, what is the solubility constant, Ksp?

A. 4.0 x 10-6 mol3 L-3

B. 4.0 x 10-6 mol2 L-2

C. 3.0 x 10-6 mol3 L-3

1/T
0
D. 1.0 x 10-6 mol3 L-3
Which of the following statements about
30. Choose the CORRECT statement(s)
the reaction is true
regarding 0.0010M NH3 solution. [Kb NH3
A. The forward reaction is endothermic. = 1.8 x 10-5]

B. The forward reaction is exothermic A. The concentration of NH4+ is

4.24 x 10-4 M
C. At high temperature, the amount of Z
in the equilibrium mixture decreases. B. The concentration of H+ is
7.46 x 10-11 M
D. At higher Temperature, Kp increase. C. pOH of the solution is 10.13

26. An aqueous solution of a weak acid, HX, D. pH of the solution is 3.8

is prepared by dissolving 0.020 mol of HX
in water to yield 1.0L of solution. At 25.0oC, END OF QUESTION PAPER.
SK 015, Chemistry Unit, KMK PRA PSPM SET 1