M.Phil. Test Fall 2012 Analytical(20) 1. Choose the correct answer. 1 Plants look green du to the absorption of |. Green ight i.8lu i.Red light. v.Yellow light 2.Contre of distribution is given by |.iMiean liMode ii Average Ww.Standard deviation 3. Concentration change during tration is measured by \.Conductometry i-Voltametry li. Coloumetry Wv. Polarography 4. By increasing temperature concentration LLinereases i, Decreases il, Unchanged iv.Random 5. To20.8M CH,COOH Solution enough CHsCOONa is added to make i 0.2M wrt sal The ka is 1.8*10* Calculate PH, 6. Theawear KINO is 530mm Calculate is E, LS3Ki/mol i —erg/mo!_i.80Kca/mot 7. The curve which measures value from -- to 400s called LGuassiancurve ii. — 8.KjC140, iscolored (Yellow duc to |. Chargetransferi.n-r transition i 9. orbital s sensitive towards | Strength of igand i.strength of met ti 20. 1n Raman the most intense line is |. Stokeline ii Anti-stoke line fil Rayleigh line v.None of the above41, Select only Raman active 1.c0 1,.CO,I.CHC vc 32.Amino acids are separated by | Partition chromatography i.Columnchromatography i 113.Chromatography was discovered by----- scientist L.Frefich i.Aussian tiLAmerican iv 16. The key and lack mechanism is applied in 1. Size exclusion i 415. The chromatography which employ liquid as both stationary and mabite phase LPL HLTLC HRLGC Ww 16 A solution has a cone of 0.2 and volume is 250ml to it S40! solvent is added what isthe cone of new solution. 17.0 compound has By what isitS Pn |.6000n i 500% Wy 1g.the reaction of HEI and NaOH take place in Lao” fag m.20%w. {19 test is performed when standard deviation values are same l.bifferent imatching i 20.In Flame photometry which lamp is used LCL i iNone of the above 2 igher frequency is associated with 1.50cm'* :S00em” fi500dem ' i.50000em"* 2, Write formulas. 1. Speeific resistance 2. Specific conductance 3. Molar conductancefit Mn®? + S:0¥* + 10 2 10.Write the isolobal fragments of the following. (CoM (Co)sFe 11.The bond distance of Bry is 2.09.The bond distance of Ir, is 3.4A2 Caleulate radi of lodine. 12.Draw and label the MO diagram for NO. 13.Caleulate bond order. 114.Write the point groups and symmetry elements of the following. iSicls far, 15.Draw structures by using VESPR theory. isk, flick, 16:The yas for & compound is 9380AP.Caleulate A, 17.Complete and balance the reaction, roMg® ot 2Heta AP” ob? re Peto uuX? 42 18.CalculateZaq for the d electron of Zn. Goon Luck Recommended books : ‘+ Fundamentals of analytical chemistry by Skoog and west ‘+ Instrumental analysis by Skoog and west ‘+ Analytical chemistry by G.D cristian ‘+ Analytical chemistry by D.C Haris © Coordination chemistry by Basalo + Environmental chemistry by Anetkumar4. Ostwald's law 5.Cell constant 6.K0 3, Draw graphs. Paws. HY Piivs. oH Tvs. ca” Tus. ka Ts. Pla Precisionvs. Accuracy Inorganic (20) 41. Write IUPAC names. 1ayC0, 1040 ‘uxaletch i. (Co (0) iuFe (CO), 2.The gu for compound is 2600em" Caeulat Bo Whats the magnetic behavior ofthis on rite two examples of ambidentate ligand 441n ABAG type which type of atic or packings formes. 5 Caleuate CFS ford? system for bath oh and Td system, 6.caleulate spin of Fe'"ion by spin only formula “L.whFeati¢ autopyrolysie2Give two examples Give two examples of sosters. iatance and complete the reactions UURHOHOT, 22 iN{CO(EDTA]? + [Fe(CN)eI__y