1. The TUPAC name of the compound shown below is: 8 The TUPAC name of the following compound is: t co » (sea 20) cme (naan 6aeyelor ee ty Berge 2 Nee (b) 6-bromo-2-chlorocyclohexene (@) bicycio [2.2.0] hexane (6) 3-bromo-I-chlorocyclohexene 9, The TUPAC name of the compound (@ |-bromo-3-chlorocyelohexene (CH, ), CHCH=CH—CHOH—CH, is 2. ‘The IUPAC name of C,H,COCI is: (2) benzoyl chloride (@) S-methythex-3-en-2-01 () benzene chloroketone (©) 2-methythex3- (© Sey 2ney pete (©) H,O=C(CH )CH,CH, Br 7. ‘The IUPAC pane ofthe compornd oe H,C=CH. ‘CH CH—CH, is: (@ CH —C(CH, J=CHCH,Br CH, C,H, OH (@) 3-cthyl-4-methyiliex-5-en-2-o1 (b) 3-methyl-4-ethythex-I-en-5-ol (©) 3ethyl-2-hydroxy-4-methylhex-S-ene (@) none of the above Date: 9910672020 ‘Exam: Class XT Organic Chemistry, page-t|4.Which of the following will have a meso-isomer also? (@) 23Dichlorobutane (©) 2Chlorobutane {6} 23Dichloropentane (@) 2Hhydroxy propanoic acid 18.Which of the folowing molecules will not show optical activity? Hy "Son H @ HO. HC H,C—CH~CD, © Hyc—pHt-cH, cH, a 16, Pick out the correct statements: @ ita compound bas no asymmetic carbon atom, i is always achiral. (Gi) if'a compound has just one asymmetric carbon atom, it is chiral (ii) a compound has more than one asymmetic carbon axoms, it may or may not be chiral (2) (9, Gi) and (i) are correct (©) () and (i) only are correct (ec) (i) and (iit) only are correct @) only (ii) is correct (©) only (iis correct 17, The chirality of the compound r His ud Sa @R (eS @z OE 18, Different structures generated due to reaction about C—C axis of an organie molecule, are examples for: (a) geometrical isomerism (b) optical isomerism (©) conformational isomerism (@ structural isomerism 19.The number of Reometrical isomers in (CH, CH—=CHCH,CH—CHy is: (@) two (b) three ©) four © five Date : 09/06/2020 20-The total number of isomers in CjH,Cly is: @) two OD &) three (c) four O @ five sion my sec de es net emer ea fa) 2 O ws 6 O@s 2. Betis ts fe nn nag cH’ be, (a) 28,38 OD @) 25,35 (c) 2R, 38 O (d) 283k 23, The absolute configuration of HO,C OH wo Kon“ it @) SR OD wss ORR O@Rs 24, CyHg that can form cis-rans geometrical isomers and also has eileen, is: @ = 0 wa 1 () none of these (c) both of these '. Which of the following is chiral? (>) CHyCH,CHCH,CH, f" (© CICH=CHCH,CH,CH, (@) HO=C=CHCH,CH, 1 26, Ofthe isomeric hexanes, the isomer that give the minimum snd maximum number of monochloro derivatives are respectively: (@) 23-2>3>4 () 4>9>251 (©) 2>1>3>4 ( 2>3>1>4 ‘Which ofthe following hydrocarbons has the lowest dipole moment? HC CH, ® = < # H ©) CHC=C—CH, (© CH,CH,C=CH (@ H,C=CH—CmrcH, 32. Which ofthe following acids has the smallest dissociation constant? (@) CH,CHFCOOH () FCH,CH,COOH (© BICH,CH,COOH —_(@) CHCHBrCOOF Hye fH —Cay +B 9 12+ He D Oh 23, Identify the structure ofthe major product © Bcf Fo D CH, () H,C—CH—C—CH, rt © yee ata, D CH 3M. (@ HycH fon cH, ‘34.|dentify the correct order of boiling points of the following, compounds CH,CH,CH,CH,OH, CH,CH,CH,CHO, oO Q CH,CH,CH,COOH, @ (a) 1>2>3 (b) 3>1>2 () 1>3>2 @3>2<1 35, Among the following, the molecule with highest dipole ‘moment is: Date 09/06/2020 @ CHC ©) CHCl, (© CHC, @ cc 36-Which of the following represents the given mole of hybridization sp? 5p?-sp-sp from let to right? (®) HxC—CH—C=CH () HO=C—c=cH (©) Hy,C—CH=CH—CHy, (@) H,C=CHCH=CH, 37 Which of the following pK, values, represents the stron- gest acid ? @ 10% (&) 10% (© 0 (@ 107 38. Which of the following orders regarding relative stability of fre radicals i correct? @ 3<2<1 @ #>P>1 @ e223 @ Pore 139, Which ofthe following isthe strongest base? 2 @ ) ' : H 40. Which of the following is least reactive in a nucleophilic substinution reaction? @ (CH;),C—C1 © CH,CH,CL 41-In the compound given below: HN. ti o Yo @ ro the comet onder of acidity of the - postions (1), (P)and (2) @ @> C0) © ®>@>e) (®) CH, =CHCL (@ CH, ~CHCH,CL ©) >) @ @ M7 Q>@ Exam: Class XI Organic Chemistry, Page-342, Which of the following reagents, when heated with ethyl ‘hori, forms etiylene? (@) Aqueous KOH {b) ZaHCl ‘3, © Alcoholic KOH (a) 1 Ozonolyss products of an olefin are OHC—CHO and ONC—CH, —-CHl,--CHO, the olefin i: @ 0) © oO © oO 4 t] 44. What is formed when calcium carbide reacts with heavy water? (@ C.D, @) cap, (© Cap,0 (@ cD, 45. A molecule (X) has (i) four sigma bonds formed by ibe ‘overlap of sp? and s orbitals; (i) one sigma bond formed by sp? and sp? orbitals and (i) one t-bond formed by p, and 1, otbitals. Which ofthe following is 2 @ GH ©) GAC © GHC, (@ Cal > CH=CH, MH, ‘RCH,CH; Gison ‘This reaction is called as: (a) Fischer-Siper reaction (b) Clemmensen reduction (©) Birch reduction (@) Amat-Fistert synthesis $1 CH,CH=CH, + NOCI—> P een te adc: (@) CH; — a () CH, a TE ice NO i cca a NO a 48. Identify °B” in the following reaction: Ast AICls @ Ph— Cp H,C—cH, + HC] PENS , (4)4 29 , eaHsoHt +H () CH ©) Gli, (©) GHC (@ GH,OH 49. Prod the product ‘C” obtained inthe following reaction of 1-butyne: . Date: 0910672020 si. 53 5 CH, CH, C==CH + HCI— @) 24 ©) 1 | (8) CH,CH,—CH—CH,C1 1 I 2 ae ee a © ct Ecc a 1 I (@ CH,CH,CH,—C—-H a | CaCy + HO 4) 22°, HCOOH, 9 is: @ CH 0 © Gh © GH, 1D @ cxoH, In the reactions oy atest pom SM, (4) i (A) and (B) are geomettical isomers. Then: (@ Aiscis and Bis rans (b) Ais trans and B is cis (©) A and B are cis (@ A and B are rans - The reagent(s) for the following conversion, islee: BRK, {@) alcoholic KOH (©) alcoholic KOH followed by NaN, (©) aqueous KOH followed by NaNH, @ ZvCH,0n ‘The compound ++ wb (@) allyne, amine (b) alkene, " amine (© alkene, 3 amine (alkyne, 2 amine Identify the product(s) in the following reaction: H,0,/08 3CH CH=CH, (x) 20/8", Product(s) + HsBOs (0) CH,CH,CH,OH (©) CH,CH,CHO (© CH,CHO+ CHO (@) CH, CHORLH, (@CH,CH,OH+CH,OH ‘Exam: Class XI Organie Chemistry, Page-458.The best method for the conversion of an alcohol into an alkyl chloride is by treating the sleohol with: (@ PC, (©) SOC, in presence of pyridine © Pel; (6) dey HEI in presence of antydrous ZnCl, 6, Which of the following on heating with aqueous KOH produces acetaldehyde? (@ Ca,coct ©) CHCHACL (© CHCICH,CI (@ CHyCHCl, Consider the following reaction: CyHgCl+ Agen OHO, (major) 57, Which one of the following statements is tue for X? (@) It givos propionic acid on byarotysis (©) Iehas an ester function (6) Ithas a nitrogen linked to ety carbon @) It has a cyanide group 58. An organic compound on heating with CuO produces CO, but no water. The organic compound may be: (@) chloroform () ety entoride (©) methane (@) carbon tetrachloride 58, Which one of the following does not undergo iodoform reaction? (@) Secondary butyl alcobot () 80 propyl alcohol (©) Diethyl ketone (@ Esty! alcohol 60. An ethereal solution of alkyl halide is heated wit metal. The reaction is known as (@) Frankland’s reaction (b) Sandmeyer’s reaction (©) Wurtz-Fittig reaction (4) Wurtz reaction 61. For the following reaction, B (OME E10 (6) ©, (a) HO product [4] is: ‘@ [coor coon ° o pt< op sodium uw ‘82 Which of the following is the least reactive towards smleophile? (@) CHsCH,CL © CHC © H,C=CH—-CH,CL—@ GE,CL ( cHCHKCHCH, Date: 09/06/2020 6. or. . Methyl bromide reels with AgF to give methyl fluoride and ‘AgBr. This reaction is called: (@) Finkelstein reaction (b) Fitug reaction (©) Swans reaction (8) Wares reaction (©) Wartz-Fttig reaction ‘Chemical formula of phosgene is: (@ Coa, (6) Ca0cly (©) Caco; @ coc In the following reaction, CH PAN le ere ‘The major product obtained is CH:Br Hy Br o Hy CH Br @ Br 11 3dibrofhopropane reacts with zine and Nal, the product obtained () propene (©) propane ©) cyclopropane (@) hexane ‘Chronic chloroform exposure may cause damage to liver. and kidney, due to the formation of (@) phosgene (©) methyl chloride (©) phosphoryl chloride ‘The correct order of reactivity of the halides, ethyl chloride (D, 80-propy! chloride (1) and benzyl chloride (IH) in S 1 reactions is: (b) methylene chloride (@) carbon tetrachloride (@ m>m>1 () I> um (© > I> @ imu (@ W>1> 11 The order of rate of hydrolysis of alkyl halides 1°, 2”, 3° and CH, by the S 52 pathway is (a) > 2>3°>CH,X — (b) CH X>3°> > 18 OCHA > P>3 | 3>2>1°>CHX ‘Exam: Class XI Organic Chemistry, Page-5