Candidate Name Centre Number Candidate Number poi ZIMBABWE SCHOOL EXAMINATIONS COUNCIL General Certificate of Education Advanced Level CHEMISTRY 6031/2 PAPER 2 NOVEMBER 2020SESSION —_I hour 30 minutes Candidates answer on the question paper. ‘Additional materials: ‘Dat Booklet TIME | hour 30 minutcs INSTRUCTIONS TO CANDIDATES FOR EXAMINER’S USE Write your name, centre number and candidate number in the spaces at the top of this page. 1 Answer all questions. 2 Write your answers in the spaces provided on the question paper. 3 INFORMATION FOR CANDIDATES 4 The number of marks is given in brackets [ ] at the end of each question or part question. 5 \ 6 TOTAL ‘This question paper consists of 12 printed pages. Copyright: Zimbabave Seco! Examinations Council, N2020. eamscennan0 [Tarn over yo 2 inswer all questions @ @ Write a chemical equation to show how ammonia acts as a base, (i) State and explain the difference in the basicity of 1. ammonia and methylamine, 2 ammonia and phenylamine. 765) (©) @_—_Drawa dot and cross diagram to show the bonding in sulphur dioxide. sour namoq 3 For (Ut) State, with reasons, the shape of sulphur dioxide. ‘Use shape | reasons (5) [Total: 10] 2 @_—_@_ Name the material used for the electrodes in the electrolytic extraction of aluminium from its ore. (ii) Suggest any one safety risk associated with the electrolysis. 2 (b) Nickel is purified by electrolysis using a method similar to that for copper. (@® _Drawa diagram of the electrolytic cell that is used indicating the material used for each electrode and the electrolyte. (i) Describe the change in mass of the anode at the end of the purification. Bl a os wane [Turn over ti4 © 0 overall E® value for the reaction between (ii) State the change in oxidation state of the transition metal. OO 8 (@) Show, using E%, that silver cannot react with dilute acids. 2) [Total: 10) Fig. 3.1 shows a scl up for the preparation of ammonia in the laboratory. ammonium chloride and calcium hydroxide Fig. 3.1 (Construct a chemical equation for the formation of ammonia from a) - ‘ammonium chloride and calcium hydroxide. eosin N09(b) ay «tly @ a State the function of calcium oxide lumps. calcium Explain why concentrated sulphuric acid cannot repla oxide in this preparation. Explain the term eutrophication, Describe how farmers can limit the amount of nitrates entering water bodies. 603172 N2020 a1 (3) For Bxaraines’s ‘Use [Turn over6 (©) The apparatus shown in Fig, 3.2 was used to determine the enthalpy change of combustion of methanol, thermometer metal can draught shield stand spirit burner methanol Fig. 3.2 The measurements obtained were: volume of water in can = 200 cm? initial temperature of water = 24.0°C final temperature of water = 51.0°C initial mass of methanol = 13.06 g final mass of methanol = 12.02 g specific heat capacity of water = 4.18 jg~1K-1 @ Calculate the enthalpy change of combustion of methanol, a1 Nam0 fe@ a), @ @ The theoretical value for the enthal : ruethanl 713 Kia nwuPYSanes ofsombunion “ Explein why the experimental value in () is different from the theoretical value. ce oe ce (4) iar [Total: 10] Explain why propylamine is basic? oo ee ‘Table 4.1 shows dissociation constants of ammonia, dimethylamine and phenylamine, Table 4.1 ‘compound base dissociation constant Ky at 298K NH 1.8x1075 (Cib):NH 59x10 CétisNH2 42x10 Explain the trend in Ky values of the three ‘compounds. ee ee ee _ oT cosia N2070 [Turn over For Use) © Fig. 4.1 shows the structure of a polymer S. {——-yp Polymer $ 41 @ What type of polymerisation produces S, (i)_—_Draw the structures of monomers used to produce S. Suggest why the polymer $ is flexible. (5) Explain why carbonyl compounds do nat react with HCN in the presence of acids. ss —SMO (Total: 10]@ » Fig, 5.1 shows some of the reactions of 2-hydroxybenzaldehyde. CHO J OOccH, A on —action IL NaBH, ,warm in alkali cHO 2-hydroxybenzalhyde OH Br Br c Fig. 5.1 () Give the reagents and conditions for reaction 1. reayent(s) condition(s) (1) Give the structural formula of compound B. SS SO (i) Name the type of reaction that occurs in the formation of C SO 6031/2 62020 For ‘Use {Turn over) 10 (iy) Write a chemical equation for the formation of A. (¥) State the observation(s) for the formation of A. SSS (9 Explain why © __ benzene readily undergoes electrophilic substitution reaction unlike nitrobenzene, ee ee oe ee G@) methylbenzene is miscible in carbon tetrachloride but immiscible with water, ee ee ee ee [4] (Total: 10)n () Give any two applications of nanomaterials in medicine. 1 be ee i 2. TT (ii) State any two potential risks of using nanomaterials. 1 —— ee v ee eee ‘The ionisation of phenolpththalein indicator, Hin, may be represented as Hin = H+ In” colourless red (Explain why phenopththalein s colourless in acide solution, ere eel oe _ (i) The K, value for phenolphtbalein is 7.0x107!°moldm™? and the pH{ of the solution is 9.0. {in} Caleulate the ratio Faray 0312 N2020 (4 2) For ‘Usecc) n Explain why phenolphthalein is nota suitable indicator for the titration of hydrochloric acid and ammonia. [Total casi. s20%0 te (q 10) For UsTTT sc General Certifie, IL, EXAMINATIONS ‘ate of Education Advanced Ley, COUNCIL el MARKING SCHEME NOVEMBER 2020 SESSION 6031/2 CHEMISTRY2 ye i tnt aoW () 1 @ Oo wmstonnts / yayt &9 > phy i © pa proton acceptor = / w Gi) 1. Ammonia is less basic than methylamine; [h ® Cy/aky| group in methylamine has positive inductive effect/releases e~ to nitrogen atom making it more basic; - (1) fangs 2. phenylamine is less basic than ammonia; | ay lone pair of electrons on nitrogen atom on phenylamine is delocalized; ay ) (ii) benvv’-spap: : Sul oO seal nd Pal fg _ S| Loavege WHEMA 2 Paurs Ound 2 i ~ @ \ Lone pair ” is (@ (i) __graphite (both electrodes), — @ Lee > 6F-0F 0) (ii) Fluorine gas is toxic! i _ ae toxic fumes of Fx/CO; a(b) (c) @ @ (b) @ impure - pure nickel nickel ZF NiCh, INS One mark beth electrodes correct; ogi even wihuad: tale. One mark correct oleswaistes Label a (ii) mass decreases/becomes thinner, WW a @) [Bm +2e7>2Br- £° +1,07 Cr,03" + 14H* + 66" > 2Cr3* +7H,0 E° +133 Ww 133-107= +026, (A? *5Tadh a cat ell h candady, tine Me Corre Gi) +610 43 (decreases by 3; BR «) Bed Foy fo Bg BH 2 2g" = 0A fan () a) reaction is not feasible; ang old | 0), o (ii (ii) @ Ca(OH), + 2NFUCI > CaCh +220 +2NH; @ ae “ dying agen aw aboot walix , it is neutralized with the ammonia; /it reacts with ammonis(in an Scid-base reaction;) Tower yield of ammonia; io) excess nitrates causepilgal bloom/bloom of algae/AW when algae dies, batteria act on it; bacteria respires acrobically/uses up oxygen; aquatic life which uses dissolves oxygen dies;Or : of algae; excess nitrates cause algal bloom/bloom blocks sunlight from reacting aquatic plants, fut 2 photosynthesis of aquatic plants, i y, causing less dissolved oxygen/aquatic dies; Ap, (Any 3 points) i izer; ay Gi) adding/applying most economical amounts of frat, Japply fertilizer at the right time;(use of organic fuse of nanofertilisers; COP oth 1 © @) B= Vic. a0 = 200% 4,18 x27 = 22572 J; a) zasrall) azxaas7a ote a= 1,04 oe = ~695 kjmol™; (\) or —694,5 kmol-* Gi) loss of heatlpy convection/radiation/conduction; ) - (ly Jin complete combustion; Bhd Urcdahee man beomel (@) (nitrogen has a lone pair of ¢ etrons th enables wb K aueph (1 (@) CoH ) @__condensation/addition-elimination; (i)5 cl O° cl oO ® (iii) chains held together by weak vDw forces/no cross linkages between chains; ) (c) HCNis.a weak acid/HCN = H" + CN’, ay acids shift the equilibrium to the left hence no cyanide (CN*) to attack; (1) carboxyl carbon 5 @ i) _—_ Reagent - CHsCOCT wo bee mah MS Condition ~ reflux infalkaline solution{s479 besefo ie w (i) CH,OH Oho OH O- B (iii) electrophilic substitution oO Gv) CHO CHO 9 ll ou o—C¢, + CH,COCcl ——> IN cH, + HCL a) (v) white fumes af sweet smell; a6 (by (a) (b) (iy (i) (i) ai () any 6 nitro group is electron withdrawing (deactivating) a making the benzene ring less susceptible to electrophilic : attack; a ‘methylbenzene form van der waals interactions (l ) (hydrophobus) with CCld-hence it dissolves methylbenzene cannot ie hydrogen bonds with water thus » it does not dissolve in water ( artificial limbs; w drugs deliver ( cosmetics; sunsereen; Ruy a Ranoscnsors; Awe for djagnostics; a en GS) ie “Somer age. abt fen ’ y My toric, bioaccumulation; hr (on ot a gBigothe cavironmen; “LAY ( Censdoy oy.) @ Seal Feet pokeahat re? high (H*}; equilibrium shifts to the left: [more H/n molecules producing colourless soluti @ W @ Gutration of a strong acid with weak base: (1) a equivalent end point does not coincide with pil range over which phenophthalain changes colour/AW. ay