SOAL LATIHAN KESETIMBANGAN KIMIA

1. Untuk reaksi NH3 ↔ ½ N2 + 3/2 H2 Kc = 5,2 x 10-5 pada 298 K. Berapakah nilai Kp pada 298 K
untuk reaksi: N2 + 3H2 ↔ 2NH3

2. Senyawa ClF3 disiapkan melalui 2 tahap reaksi fluorinasi gas klor sebagai berikut

(i) Cl2(g) + F2(g)  ClF(g)

(ii) ClF(g) + F2(g)  ClF3(g)

Seimbangkan masing-masing reaksi diatas dan tuliskan reaksi overallnya! Buktikan bahwa Kc overall
sama dengan hasil kali Kc masing-masing tahap reaksi

3. Calculate Kp for the following reaction

a. PCl3(g) + Cl2(g)  PCl5(g) Kc = 1,67 (at 500 K)

b. N2O4(g)  2NO2(g); Kc = 6,1 x 10-3 (298 K)

c. N2(g) + 3H2(g)  2NH3(g) Kc = 2,4 x 10-3 (at 1000 K).

d. CaCO3(s)  CaO(s) + CO2(g) Kc = 2,1 x 10-4 (at 1000 K)

4. Untuk reaksi N2O4(g)  2NO2(g), ∆Ho = +61,5 kJ/mol dan Kp = 0,113 pada 298K

Berapa nilai Kp pada 0oC? (1,2x10-2). Pada suhu berapa nilai Kp = 1,00

5. A precipitate of AgCl has been prepared in the laboratory and is about to be washed free of
impurities. The concentration of Ag+ in saturated solution of AgCl is 1.35 x 10-5M. to avoid losing this
much Ag+ in the washing, the experimenter washes the precipitate with 1 M NaCl. How many moles
per liter of Ag+ will be lost in this case?

6. Silver acetate is quite a bit more soluble than silver chloride. The Ksp of silver acetate is 2.3 x 10-3.
What should be the concentration of NaC2H3O2 solution keep the silver ion concentration down to
1.0 x 10-3?