> Tomes: Unusecroff— pa5y, bh ry 2.9 Molecular shape: stereoisomerism ‘Aa tomers on of eer pce that have th omposton (onc orl) bt have dite nto ela (cm rane) or ret ‘Newockenel forme, nme exh lent peal ‘nijr chen operon a this section we lcs steric. Examples art taken frou both p- and lock chenisy. Othe Spe of ‘Howriam aredoeibd in Seton 203. two spent theresa fraul andthe same on county, ba ae patil sangeet ‘ltecar ats rouge tout otal stom oa doue ‘ond thn the compounaaze teroone Stroitame fll nto sro casos, dazereotomars nd mantomarr. Diaseriomers azeseeisomecs tht fare not misorinages of one anos. Buuntlmers are —eenaomers tht are mizoriaages of ome apoe. ‘his scton, we sall eal be concened with daseco- ‘noma, We eam to enatomar ia Sectons 43 and 208 Square planar species ‘na square planar spces cha [IC oe PCL” 2.20), ‘hefour stoma ae oqileat Sly, in PC(PME (G31 ie only one paibeeangeectof ths groups round thr square plans PT) tee. (The we of aos ‘ori to dept bonds i cooriaton compounds i ie ‘sed in Sete 7.1) Siuare pan pie of he era fms XY oF ‘ary posen cand rnecass. Octahedral species “Thee ce wo pt of taresiomecan ascate wit oct ‘dele. a EGY, the X groups may be meal orton a8 hows for [Sa Mey?” (234 ead 23 i te 50 ate erate of [NEh{SaF (Med, the aie pre- Peat athe rome tone! Palos ee at vice aan am 1 an octahedral spe bas the. geaseal forme OGY, then the X groups (nd also the Y grow) may tb aringed #0 a1 dane one fice ofthe ocabedra ‘ormay ein plane that als contin the central tom E (Figure 2.17), Tote stereosomers re abled fe (il, land mer (oesdonal)reapestivy. In PCAIPCSFS POUR, ean eta otf ad mei Gotan 23. Slee]: F 71S mR fete tome aan =n = = roam oe Fig. 2.17 Tioga ofthe ama fan merismes. For ‘Sey the ceed tam ot oma. =P‘Avett pce containing wo ena ops og of ‘ype GY) may poe tread eau arto thse groupe. Aa octincal pai conn tee ‘ete rope (eg of ype EXGY;) my pots fac end ‘Trigonal bipyramidal species. {a gona bipyramidal EX, tee are tno ope of X ams ‘sual and equatorial Theat the post of seeo- ‘omen when more thin oat type of saben is stich to the cata stom. Ion pefacaztoay, (CO), is tigoal ad when o "Ph, Wo sereouomen ae posible dependog on whether (he PP and it ail (2.38 or egntorally (2.39), ex a0) For tignal bipyremidtl EY), te sereisomers (2.401024) are poste copending oa the reaive positons of te X atoms. Str factors may diate which Somer it prefered fora given aces a in te sade srure of PIF, the F toms copy the to al i, end the large laters reside inthe egutoi plane Chapter 2+ Further reacing $5 Double bonds Incontrast to single (0) bond where ie rotaton i == ‘aly ese, rotation about «double bond is teow ory proves, The pesencs af «doable bond may tere {ore lad to sercizomian aria observed for NyPy Each N atom esti alone pur as well forming ene [NGF sagle bond and en N=N double bond. Struc 2S and 14 show the row and cvaomers! rspecinly ot, € Further reading Atkin nd J. de Pus (000 As’ Pysl Chey, is ea, Oxford Uaivrty Pray, Onfrd Tet ge ‘nd wetted backgoued a pyoeal emity ‘J.Banet (0) Smeure anf Bonding, RSC Pabiiting, lnk — An sen tt ld et bond soar etal snd VSEPR hese, RS, Giese ond 1. Haga (W91) The PSEPR Motel of Melecar Gromer, Allyn abd Bacon, Boson ~ A txt @ ns gona bipranlpece,sarstomci et enue of the presen of en aad epi ts High coordination numbers ‘Toe preeoce of axial and equatorial te in a pentegoatl Dipyreida molec leads t rector in Se ‘manner to that in a tigonal hpyranial species Ia a ‘que antprismatic molecule EX;, each X wom it ‘eatin (Figure 2.19. Once to or moe diferent sons or groups ace present, eg, EXYs, staisomers are poss De. As an eters, daw oat tbe four poses for square sntprimmatio EGY;, pr DW, Saith (008) Jaen of Chana! Fda, Yo 6 ~All ete tof echang as) td spinor coupling on bod mrp. (MGI, Winer (986) Chemie! Bond, Oxford Univesity ‘Press, Oxo Ths pane fr fat yar underrasaes sprouts shielding ron tammy ~