Hass fx CN») A iving foree Nase Transfer ! Nas CHte) Cor) concft For gases Na: Re Caca) = ky (sya) = ku C BPa) t Fox_ttquccls C4 Na = & Cam) = kx (ate) RS nits of tre, ; fe] Re —» mot [ime areata) ~ Ro —» rol [time area) CAPa> 7 Ly mot fine area) (0yn) " a Ry ~> nol [ time) (aren) (bGq) ¢ LL eg not | Cede) (aurea) Lota) 7 I a — Scanned with CamScannerbk’ = rp ky = Pap & ERT ERT Uig- Phase: _, = Pap ky > Cong & & gb ~—Hass_Fanster Resistance He p — ~ y NN a > Molecular Theortu for convective _ _—s Mase Transfer —_— © Specific t» Simple Caces ®_Simpucfcen Assumptions I @ No direct Beem untabitity _ = for_vlouty —| Scanned with CamScanner_ | Dimendon te Num bere = _ bos Conyivective 7 Mass flux frr motecutar deff tov _—* i thrown a stag. media ot teucchneu U unde DE, oy _ 1 a Re Bfy Cos Let ean) BP a “Shs het Pet 2 kel [é 7 Can e Pas com | 2 ke a L-> characteristic Length Se = 4 _ wv C Pas Pas Re = eve A Stu = Sh = Rh = & Ac mo] Stanton Num ber _ Red CD 7 are k fo = (Stu) (se: sh Ltetburn factor fo +l Re csc) mS Mm mM Scanned with CamScanner_______||_ Assumptions +________— a =| MT eccure by purely — _moteuuar Acffustorn Mase far cs flows, Mase transfer, “from a sod surface a fu eng | | | | | | | | LOTTI y at the through a_ stagnant _ftuuid xfer | phase boundary Beyond. the _fclun, the fucd is _ weth mined — Ce= tap) - _ At steady stale NatNg = 0 CFlux & low, mase transfer occurs at Low cone-) (5 t lp F andi Lt ite } r pty From Fick's 2" aww, lg eta he : | Get o = et So peu eRe —— LMT occurs here) ky t be - oe 2 ta,s Ri ye - Gye é _—— veLt Nat kt hi Oe eas : da = (Ge- Gs) oy ot g Nae = Pap Cina - 1) 6 ke = Dap 8 - = Scanned with CamScannerare ae | Gr same peated ot tanat oa thas Pas —_ Q- Gp = t- ege = Gre = Ge Oa iin Na (42 = Pap Coxe _- Ge) ne 5 Na Ct) Le — Na, a= —_ te 7 —] a aor —| = [rnp C tae - Cow —— Ate I a vel f Not wf ted ~—| ps ——__—— ips ute of Pag re inst: at k= Cas) NL —— SS a] Scanned with CamScanner—||_ Surface Renewat Theory. [me © Covi - Ged S -* Surface Renucal Rate __ vee at kt St | Bourne account for. neg profete- Liendany— Moyer fee (Sh = #lRe, so) Shu = ki % = 0-332 (Rew? (6e)"% Pre 4 Chav = Kyaw & > 0664 (Re)* Cse) = np _ elm Theor kab Penetration Theory Ke & BY Surface Renewat Theory ke a p> Boundary ayer Theory ke pile tye Shs ft a | ea Re Se = : a 4. ~ =. = Sty, Se B= Sh = 9-03 fe Z ve Re a 1 ” Reynololt Analogy _ -_ Applicable for (omunar Flow, Sex Prot Stu = #2 - : 7 py turbulent Ho 0-6 « Sc 42500 _ 076 = Pe <0 _ Scanned with CamScanner_4 — ee = |__Anatogies _ Ctonde'tions ) —~ ce |_ Phy sicae properitces Shout be const- A _-7) —No—mass__or energy is procuced. inthe system _ E _2 Xeh profiles anavegous ers oe |_fer_single sphere pee te we = — | Sh = Shot c Re™ Se” ; _ _ She —* _Shereend Number at very tow Re. ee Sh= 2+ d-3 Re?S se°3* CFrom Ht) | Procedure © be fouowed @ | Match the situation | @ Hare process erde- Parameters C Se, Red © | Rnd suctable cwrretations @| 3 no corretation is _avaitable_ look for analogy: (use anatogeus torrelation from HT) © —If_not_available then finally use Boundary —layer theory —__ | a ——__| ~—_| - ~~] ~~ ~— Scanned with CamScanner€q- between two phaser means, ho net_trane. of solute from one phace to ether: At op, chemveat quat: Titerphasce Hass Transfer potential of two phases are For _a@ system at aq: the —D-F ts zero Rooutt's 1aw For an ideal gas -Uiq- or vapour iq _cystem zm aq PP exertat 4 wR of colute. Tr by se ste, Mole fraction of solute 4 A uqued Henrys low : ven solute Scanned with CamScannerww! : hey B27 flxae) mass transfer occurs | Btnary ett, Non reactive Ft = tequecet system. There te 4 “}—F Oxy) =a > Snterface. Act: #2 4cU0 theory Tue profile - ——_ “ab . te Scanned with CamScannerOA win be transported $0 | Mechanism. - m_butk to interfo,, A_witt be transported from interface _to . |_ AL mass transfer resistance oCcurs tn the ———_| thin, film near the finterfaces Absorption. 7 = Na-2 hy Cym= ye? = Ra (t,-%ap Ry Cyan yid = bu (ag -mty) | by | Stepping ye = gad Ciry-%) . a — S 7 ——_ Say ue | key ey Scanned with CamScannerie = Thobvidual -gou_- phase UTR = Individual tig phar HTR be __ Fractional Resistance offered by gas prow = (ee ‘Ly == Fractional mass transfer raistan. by Wy- pose L = ken m == | TKy 7 Tomes oe | I - i —————_—— Scanned with CamScannerat section O Gig = Rate of flow of Gt, Gs on_soute free _basce 42% G- Rate of flow of G - — at ony secttor Li= Rate of output of Lat see @ ——___“s = Rate of flow of L on solute free basic _% - Hote fraction of solute mb X= Mo vats of sotute tn Lb - (onsidering env. O : ——_Tetat_vrote of tnmput of solute + bs Xo + Ge Total va 6F output of souucte = Is X ¢ GY ! Gs(¥-Y,)= lsCx-%2) -@ Considering ew © i Gelty-42) = te CxX,-x2) O_— Operating Une ts - oo —-n+ re Scanned with CamScannerSteady state (o-Current Mt Env tt Gs l%4- Y= Us Cx - m4) _fny 2: Gs OM) = bs 64 =x) sty te Yeo ayy ee Step = = *5/ Ge Stage wise Operation Ee] [EG ye ican | a: By i ond) ana | Une 2 Ata s - Fake Ws be a= (N22 An ne cw - eC 4) a Tt fone Cr) for > te ew ee ‘dn Gs Ne Yar — Ctsor pion? U,- Bake Scanned with CamScannerPs ey for stripping : _ /oNe wag { (gezene nary |. Kes - Yer ft nosy =, = bs Cw -%) a o ~ Stage wise unter curren Scanned with CamScannerCry statlizatcorm - — __ Seperation of sods in sock form from ao ___ eal: —— : ” : _-4 ee ; a —— — ___|| + Greatton _of —» Bath of crystat, __,_ Gr7»wth_of _ | Supersate Nucleation. _ Cry stots ® - f @ —| ~ | @_cen Corystal size a pistribution) O, Creation of Supersaturation e-c* = & Cdegree co? | C-c* —e Extent of con =| Process can be done by «noting or by evaporation >| Adolition of soume 6r solwent mary shift —_____ the eA- crerve @ || Bertn of crystats _Rate of generation of crystats of zero st; Eze Bo_ Char- Length of crystal > ¢ Bo = w% A CNV) As ba & aerate cic ve ROE Scanned with CamScannerHeterogeneous ___ storage Action of. or pol Sepa, __Heterogeneous = ony: Seeds Csmast fone ) are added to fasciutarte of Crystals for__ primary nucleation ery stat ste $ \o A be ra exp F- BRT Tu tc 3 ia _ Gin), “4 Bo = & Mrs ¥ Hase of sucpension - ne2 Cf nothy rc mentioned _ ung eS — 4 Scanned with CamScanner_—®)_Trans fer of sot, Lute mo lector sy from. bulk to top of surface a —t (Pr rnass_of eryctad a __t Ame = Re Ae Ce-ct) ae | dm = ke A Co - cD ae Ko = ' Snore me = Yee = &e Ome = ki Ae Ce-c*) Qe at A CHR) = mK Ae Ce-c*) at duos oe (tac* rs “ see. du = x’s at Gs k's = _ te 7 a jn qenerae, Ge KS Scanned with CamScannerNe ¢ ae oN He Coble Ot tow oe —Grystal growth ic inclependent of eryetag > ——|8ize_t, ce hk’ és tnelependent of — dy = 0 , ak it ® | Crystat size Distribution a i —— B Molt) -» Crystal size distribution of vaniching mall size- —. helt) = ub [4 coy Rot Lao > Be a 7 Nu) v ca > =e _ 2 Nr: f no db Aa = frcwr4, ude ‘ ta rn 4 2 a ve +f nit) ¢, Bae a = Le. Me = Velo = & fou holt z Scanned with CamScanner—T 4 a staleezer — — ae ase “ ~~ — | Degree of supersaturation tobe maintained a . oe | Nucleation _¢.Suerry contaéning fine cryctats) — | ~ sil | = Batch. cont: MsHeR _ __» : _ ————— >; ONined tturry mixed 7 z tat: remover) 7 Evaporative 7 toons, Cry statizer uystattzer | dw = ? & = 6-e* = const 7 ee > Ee 7 | At _t=0 a My > NOL. be 7 Le tee) ore M = Nd 276 d Cve My) = = Abe i Cov = 3NOUe ar ao Hw at | L>Gttle Crt t=) | — See —__] Nw te i | Cc dv = ante ore 4 Se - | ole Hw J ee NS , 2 + Gia ‘ “ s time | Lp 4° paten, < Scanned with CamScannergé- c-c 2 c -! a es c= ce cstid = £(1) CstID Since ch & a tn of temp: de = fer) cstI at __ at ot _ vat = aH, {1s t&e ¥. Ga — lt HGS bs fe __ a —_ _ Scanned with CamScannere Steady state * No eryck abs tn Seek * Wet mirek + bh eu appiccable pect at No: of erystats with size L in_loD = No of crystals with size b out (F sent) at) + No: of crystals grown tp size _+ nto v AL oO: to size Lest nerar vee eo na) seb = nC vee —- netsh) VAL a at On soWwen | = ho EAs oe : ne) tc) op ( ~ ott) = Bo = _ a = a ep tz) nto) _ He = f nm CL? a ol. Ce ee Scanned with CamScannerScanned with CamScanner