Chapter 10 Practice Test Name MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) In liquids, the attractive intermolecular forces are A) strong enough to hold molecules relatively close together B) strong enough to keep the molecules confined to vibrating about their fixed lattice points ‘©)not strong enough to keep molecules from moving past each other D) very weak compared with kinetic energies of the molecules strong enough to hold molecules relatively close together but not strong enough to keep molecules from ‘moving past each other 2) Which statement is true about liquids but not true about solids? A) They flow and are compressible. B) They flow and are highly ordered. © they flow and are not compressible D) They assume both the volume and the shape oftheir containers. E) They are highly ordered and not compressible. 3) Which one ofthe following exhibits dipole-dipole attra. Axor B)Cly OC D)BCls Syvers planar loner Lee tegen planar 4) Based on molecular mass and dipole moment ofthe five compounds in the table below, which should have the highest boiling point? cigs patie Paemeceuas be Substance Propane, CH3CH3CHs Dimethylether, CH3OCH3 13 Methylchlorde, CHCl 19 Acetakichyde, CH3CHO 27 Acetonitrile, CH3CN 39 A) CHaCHCH mass ane eladvely Simstan Qaren pe alae differance C) CH3OCH3 at, D) CHC! B) CH3CHO.5) The principal source of the difference in the normal boiling points of ICI (97°C; molecular mass 162 amu) and Br2 (57°C; molecular mass 160 amu) is. i A) hydrogen bonding dipole-dipole interactions ©) London-dispersion forces D) both hydrogen-bonding and dipole-dipole interactions ae vernee™ ” 6) Draw a diagram showing how the hydrogen bonding facilitates the formation of dimers of acetic acid. £ id ) both dipole-dipole interactions and London dispersion forces weno o' ESSAY. Write your answer in the space provided or on a separate sheet of paper. MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 7) The intermolecular force(s) responsible for the fact that CH has the lowest boiling point in the set (CH, Siig, GeHg, Sng is/are. ‘A) mainly hydrogen bonding but also dipole-dipole interactions B) dipole-dipole interactions C) hydrogen bonding D) mainly London-dispersion forces but also dipole-dipole interactions, London dispersion forces 8) Of the following substances, only _has London dispersion forces as the only intermolecular force A) NH3 (8)kr Ons D) CH3OH E)HCI9) Which one of the following substances will have hydrogen bonding as one of its intermolecular forces? EH must be bonded fo OF Ly has nore mass and mere eleckons. ) Tee dbi'smrore polarizable “This causesit to have more LOF. 10) Which one of the following should have the lowest boiling point? A) SiH B)PH3 C)HCI D)H20 E) HS ‘Aen eslen. Pyramidal ‘ent font ESSAY. Write Yost answer in the space provided or on a separate sheet of paper. } 11) The boiling point of carbon tetrachloride (CCl) is higher than that of chloroform (CHCI3). Since chloroform is polar and carbon tetrachloride is not, consideration of dipole-dipole forces would predict that chloroform ‘would have the higher boiling point. Flow can we account for the observed order of the boiling points? MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question, 12) Of the following, has the highest boiling point. A) B) Hp Ba D)Nz B02 ost he" most planivable 3Ave om Large pecai si eee 13) In which of the following molecules is hydrogen bonding likely to be the most significant component ofthe total intermolecular forces? A) CsH10H B)COz (CHOH D)CHy E) CgHygNHg ‘non polon net mach non palon 14) Cz Hg molecules are held together by dispersion forces B) ion-ion interactions hydrogen bonding 1D) dipole-dipole interactions E) ion-dipole interactions 13) isthe energy required to expand the surface area of a liquid by a unit amount of area, A) Meniscus Gane ©) Capillary action D) Viscosity B) Volatility 16) Which statements about viscosity are true? (i). Viscosity increases as temperature decreases, (ii) Viscosity increases as molecular weight increases. (iil) Viscosity increases as intermolecular forces increase, A) (only B) (ii) and (ii) ©) (and (ii) D)none @a 17) The shape ofa liquids meniscus is determined by A) the type of material the container is made of B) the volume of the liquid the relative magnitudes of coh container D) the amount of hydrogen bonding in the liquid ) the viscosity of the liquid forces in the liquid and adhesive forces between the liquid and its 18) The direct conversion of a solid toa gas is called ‘A) vaporization ——_B) condensation) fusion Q@oubtimation __£) boiling 19) The substance with the largest heat of vaporization is A) Bry B)Q Och @e. . Br most polanzehle 20) Of the following, is an exothermic process. A) melting B) subliming ) boiling Oren B) All of the above are exothermic.Ke Soya s 2.78 males yee 21) The heat of fusion of water is 6.01 kJ/mol. The heat capacity of liq water is 75.2 A + K. The conversion of 50.0 gof ice at 0.00°C to liquid water at 22.0°C requires Kotheat aya Bem, LUT UT es B) 0.469 Teme # @©us (are mX76.2HmalwXard)2 4.6007 1D) 38x 102 23k F) Insufficient data are given. SHORT ANSWER. Write the word or phrase that est completes each statement or answers the question, ‘Soo Sh retain Im 22) Explain why heats of vaporization are greater than heats of fusion. 3g IME axe broken MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. Heat added (J) 23) The heating curve shown was generated by measuring the heal flow and temperature for a solid as it was heated. The slope of the ‘segment corresponds to the heat capacity of the liquid of the substance. A)AB B)BC cD D)DE —)EF 24) ‘The heating curve shown was generated by measuring the heat flow and temperature of a solid as it was heated, The heat flow into the sample in the segment will yield the value of the Hyap of this, substance. A)AB B)BC ow @ve EEE 25) The phase changes B-> C and D+ Bare not associated with temperature increases because the heat energy is used up to ‘A) increase the density of the sample B) break intramolecular bonds increase distances between molecules 1D) rearrange atoms within molecules E) increase the velocity of moleculesCSSH2.0ME)_—torT bss fel, SOS S10 7 Goes )eLiniod cues add abt GsisS@.0XB) acto issex teh, BIT 35.0 er 26) How much energy (Kj) is required to convert a 15.3 ice cube at ~50°C to water vapor at 180°C? +s B) 90x 103 O56 pu 227 27) 110044 ofheat are added 100155 gice cube at -5.00C, what willbe the resulting sate and temperature of he water? Tel gree CisseXrorXs)> aS heat 10.0— 102 — Sige LTE Wg ete, baler ig ak (gh et 7 5:18 Y1eTs liss\quel6r) bT27a.5°. Qinwia TOC BY iquid, 139°C) vapor, 103°C ——D) solid, 485°C) vapor, 134°C 28) A volatile liquid is one that A) is highly hydrogen-bonded B) is highly flammable readily evaporates ) is highly viscous ae A ) ishighly cohesive We on" “ we 2) OF te following, isthe mest volatile A)ccly B)CR4 Ocenia D) CBrg @Ocu 30) In general, the vapor pressure of a substance increases as. increases. A) molecular weight B) hydrogen bonding ©) viscosity D) surface tension temperature 31) Volatility and vapor pressure are A) not related 3) both independent of temperature © the same thing aireetty proportional toone another 7) inversely proportional to one another Ja long-range repeating pattern of atoms, molecules, or ions B) atoms, molecules, or ions that are close together ) no orderly structure 1D) much larger atoms, molecules, or ions B) appreciable intermolecular attractive forces 32) ou solids differ from amorphous solids in that crystalline solids have33) The type(s) of solid(s) that are characterized by low melting point, softness, and low electrical conduction is/are solids, A) both ionic and molecular B) ionic ©) metallic D) covalent-network molecular 34) A solid has a very high melting point, great hardness, and poor electrical conduction. This is a(n) solid. A) metallic and covalent network B) metallic Qoovatent network D) molecular Bionic €& but ckdoesdeseribe this also! — Need more info! 35) The fluorocarbon C2CI3F3 has a normal boiling point of 47.6 C. The specific heats of C2CI3F3 (I) and CCIgF3 (g) are 0.91 J/g-K and 0.67 J/g-K, respectively. The heat of vaporization of the compound is 27.49 k}/mol. The heat required to convert 50.0 g of the compound from the liquid at 5.0°C to the gas at 75.°C is WL A) 38.20 B) 31.31 27.55 1D) 1.07 x 104 E) 29.07 7s (60.X%. ANaa.0) = 14HeT > Ler Wedd 50q , esl Tunes a UBT (ogra) 2 3T— 012 119 eT