WAJA F5 Chemistry 2010 Chapter 1 : Rate of Reaction

ANSWER
Activity
1 speed , product
reactants , products
2 1. S 2. S 3. F 4. S 5. F
6. F 7. S 8. S 9. S 10. F
3 decrease , increase, increase, forming
Eq 1 : CaCO3 + 2HCl → CaCl2 + CO2 + H2O
Changes : - decrease in the mass of CaCO3
- increase in volume of CO2 released

Eq 2 : Na2S2O3 + H2SO4 → Na2SO4 + SO2 + S + H2O

Change : time taken for the yellow precipitate of sulphur formed

Eq 3 : 2H2O2 → 2H2O + O2
Change : increase in the volume of oxygen gas
4 4A 2(a) V4 ; V2 ; V3 - V2 ; 60 ; V3 - V2
240 120 60
2(c) V2 - V1
160 - 30
4B 1 Plot a graph
2 (i) Average rate of reaction , V = 86 = 28.67 cm3min-1
in the first 3 min t 3
(ii) V = V3 – V2 = 86 – 70 = 16
t = t3 – t2 = 3.0 – 2.0 = 1.0

Average rate of reaction , V = 16 = 16 cm3min-1

In the third min t 1.0

(iii) V = total volume of gas collected at 4.0 min (95 cm3)

t = time taken for the reaction to be complete = 4.0 min
Overall average rate of reaction , = V = 95 = 23.75 cm3min-1
t 4.0

(iv) Show a tangent at the 1 min of the graph

The instantaneous rate of reaction at 1 min
= gradient of the curve at 1 min
= Y2 – Y1 = 70 – 30 = 40 = 26.67 cm3min-1
X2 – X1 1.55 – 0.5 1.5
5 1 (a) (i) Average rate of reaction in the first 10 sec
= 20 = 2 cm3 s-1
10
(ii) Average rate of reaction in the first 30 sec
= 46 = 1.53 cm3 s-1
30
(iii) Overall average rate of reaction
= 50 = 1.25 cm3 s-1
40
(b) The rate of reaction decrease with time.
(c) This is because the concentration of

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WAJA F5 Chemistry 2010 Chapter 1 : Rate of Reaction

hydrochloric acid, HCl decreases. When there is no more hydrochloric acid,

HCl remaining, the reaction is complete and the rate of reaction is zero.
2 (a) the first 60 seconds = 29 - 17 = 12 = 0.4 cm3s-1
60 - 30 30
(b) the overall reaction = 36 = 0.3 cm3s-1
120
3 0.0036 g min-1
6 (a) The size of solid reactant/ Total surface area of solid reactant
(b) Temperature
(c) Concentration of reactant
(d) Presence of catalyst
(e) Pressure of gaseous reactant
7 1 √ Temperature
2 X
3 √ Concentration
4 √ Size of reactant
5 X
6 √ Presence of catalyst
7 √ Pressure
8 X
8 (i) CaCO3 + 2HCl → CaCl2 + CO2 + H2O
 Steeper
 Higher
 Larger/bigger, higher
(ii) Na2S2O3 + 2HCl → 2NaCl + S + H2O + SO2.
 Shorter
 The rate of reaction
 Higher , higher
(iii) 2H2O2 → O2 + 2H2O
 Steeper
 Higher
 Increase
(iv) Na2S2O3 + 2HCl → 2NaCl + S + H2O + SO2.
 Shorter
 The rate of reaction
 Higher , higher
9 1 low (-30 – 10oC) , active , toxic , lower.
high (25 – 40 oC) , more , lot of , higher
2 smaller , smaller , total surface area, higher
3 (i) ammonia , N2 + 3H2 ↔ 2NH3 , 450 – 550oC , 200 – 400 atm, iron
(ii) contact , 2SO2 + O2 ↔ 2SO3 , 450 oC , 1 atm , vanadium(V) oxide
10 1 (i) collision between particles
(ii) effective collisions
(iii) activation energy
2 (i) collide
(ii) product
(iii) effective , activation energy
3 Minimum
4 Reactant

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WAJA F5 Chemistry 2010 Chapter 1 : Rate of Reaction

11

Ea : Activation energy
Ea’ : Activation energy in the presence of catalyts
12 (i) total surface area , larger , increases , increase , higher
(ii) lower , incrases , higher
(iii) kinetic energy , faster , increase , more , increasing of , higher
(iv) increase , number , increases , increases , higher
13 1
Volume of hydrogen gas /cm3

C
B A

Time (s)
2
Volume of hydrogen gas /cm3

II I
III

15 20 55 Time (s)

14 1 (a) Zn + H2SO4 → ZnSO4 + H2

(b) Overall average rate of reaction = 210 = ……………. cms-1
150
(c) (i)
(ii) [Draw a tangent at 80 s] [Rate of reaction = gradient of the tangent]
(d) The decreasing of the mass of zinc used.

2 (i) higher , higher , higher , collision , increases , effective , higher.

(ii) higher , bigger.larger , collision, increases , effective , higher.

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WAJA F5 Chemistry 2010 Chapter 1 : Rate of Reaction