-•’-üμ¿¢√®Ωç 18 -¢Ë’ 2011 Ñ-Ø√-úø’ £j«-ü¿®√-¶«-ü˛ 2

EAMCET - 2011 MODEL GRAND TEST

4) Identical
1) iii only iii ´÷vûª¢Ë’ C6H12 Å®·-ûË A, B, C & D ©’ ´®Ω’-Ææí¬
2) ii and iii only ii ´’Jߪ· iii ´÷vûª¢Ë’ 1) Calcium heptanedioate, cyclohexanol,
È®çúø÷ äéπ üΔEéÀ
cyclohexanone, lodocyclohexane
3) iii and iv only iii ´’Jߪ· iv ´÷vûª¢Ë’
äéπöÀ Ææ´÷†ç
153. The products in
4) i and iv only i ´’Jߪ· iv ´÷vûª¢Ë’ é¬L{ߪ’ç £«Ê°d-Ø˛-úø-ßÁ÷-ö¸, ÂÆjéÓx-£«-éπq-ØÓ™¸, ÂÆjéÓx- the following reaction
141. Assertion (A): NCl3 hydrolyses easily £«-éπq-ØÓ-Ø˛ & ÅßÁ÷úÓ ÂÆjéÓx-£«-ÍéqØ˛ Ç Ææ¢Ë’t-∞¡-†ç™ Ææ©p¥®˝ ßÁ·éπ\ ¨»ûªç?
2) Calcium heptanedioate, cyclohexanone,
éÀçC ®Ω≤ƒ-ߪ’† Ωu™ véÀߪ÷-ï-Ø√u©’ 1) 20 2) 50 3) 14 4) 80
NCl3
HI 373K
ï© N¨Ïx-≠æù îÁçü¿’-ûª’ç-C. 157. The compound whose 0.1M solution has
Cyclohexanol, lodocyclohexane (CH3)3C-O-CH3 + con ⎯→ products
Reason (R): Electronegativity of Nitrogen
pH < 7 are
and Chlorine are same é¬L{ߪ’ç £«Ê°d-Ø˛-úø-ßÁ÷-ö¸, ÂÆjéÓx-£«-éπq-ØÓ-Ø˛, ÂÆjéÓx- í¬úμø véÀߪ÷-ï-Ø√u©’
£«-éπq-ØÓ™¸ & ÅßÁ÷úÓ ÂÆjéÓx-£«-ÍéqØ˛ 0.1 M í¬úμøûª éπ-L-T† éÀçC à vüΔ´ùç pH < 7
ØÁjvö-ïØ˛ ®Ω’ù N-ü¿’u-üΔ-ûªt-éπûª éÓxJ-Ø˛èπ◊ Ææ´÷†ç
3) Calcium hexanedioate, Cyclohexanone, Öç-ô’ç-C
1) Both A and R are true, and R is correct
Cyclohexanol, Iodocyclohexane a) Potassium oxalate §Òö«-≠œßª’ç Çéπq-™‰ö¸
explanation of A
b) Ammonium chloride Ç¢Á÷-Eߪ’ç éÓxÈ®jú˛
A ´’Jߪ· R ©’ ߪ’üΔ-®Ωnç, ´’Jߪ· R Å-ØËC é¬L{ߪ’ç £«ÍéqØ˛ -úøßÁ÷ö¸, ÂÆjéÓx-£«-éπq-ØÓ-Ø˛, ÂÆjéÓx-
£«éπq-ØÓ™¸ & ÅßÁ÷úÓ ÂÆjéÓx-£«-ÍéqØ˛ NH3 c) Ammonium sulphate Å¢Á÷-Eߪ’ç Æ晉p¥ö¸
A
154. Phenol ⎯⎯⎯⎯⎯→
èπ◊ ÆæÈ®j-† N´-®Ωù
4) Calciumhexanediote, Cyclohexanol, ZnCl2 300°C d) Sodium acetate
2) Both A and R are true, and R is not the
≤ÚúÕߪ’ç áÆœ-õ‰ö¸
Cyclohexanone, Iodocyclohexane CH3COCl HNO3 H2O 1) a, b 2) a, d 3) a, b, d 4) b, c
correct explanation of A
A ⎯⎯⎯⎯→ B ⎯⎯⎯→ C ⎯⎯→ 158. One litre of 1M CuSO4 solution is electrol-
A ´’Jߪ· R ©’ ߪ’üΔ-®Ωnç. é¬-F, R Å-ØËC é¬L{ߪ’ç £«ÍéqØ˛ -úøßÁ÷ö¸, ÂÆjéÓx-£«-éπq-ØÓ™¸, ÂÆjéÓx- H2SO4

A èπ◊ ÆæÈ®j-† N´-®Ω-ù- é¬ü¿’ £«-éπq-ØÓØ˛ & ÅßÁ÷úÓ ÂÆjéÓx-£«-ÍéqØ˛ D. The compound D is ysed. After passage of 2F of charge the
148 The equation for Langmuir adsorption molarity of CuSO4 will (Neglect the
3) A is true but R is false
. NH3
isotherm ⎯⎯⎯⎯⎯→ change in volume of solution)
A Å-ØËC ߪ’üΔ-®Ωn¢Ë’ é¬F, R ߪ’üΔ-®Ωnç é¬ü¿’ °∂œØÓ™¸ ZnCl2 300°C
4) A is false but R is true
™«çí˚´- ‚®˝ ßÁ·éπ\ Ææ¢÷Á ≥- Úgv- íû∫ √ Í®ë« ÆæO’-éπ®- Ωùç äéπ Mô®Ω’ 1M CuSO4 vüΔ´-ù«Eo 2F Ç¢Ë-¨»Eo
CH3COCl HNO3 H2O
x 1 x bP A ⎯⎯⎯⎯→ B ⎯⎯⎯→ C ⎯⎯→ D.
Ö°æ-ßÁ÷-Tç* Nü¿’uû˝ N¨Ïx-≠æù îËÆœ† ûª®Ω’-¢√ûª Ç
A Å-ØËC ߪ’üΔ-®Ωnç é¬ü¿’. é¬F, R ߪ’üΔ-®Ωnç 1) log ⎯⎯ = log K + ⎯ log P 2) ⎯ = ⎯⎯ H2SO4 vüΔ´ùç ßÁ·éπ\ ¢Á·™«-Jöà (vüΔ´ùç °∂æ’† °æJ-
m n m a
142. Compounds obtained when bleaching Ééπ\-úø D Å-ØËC? ´÷-ùç™ ´÷®Ω’p í∫ùÀç-îª-ü¿-T-çC é¬ü¿’)
powder is decomposed in presence of x aP x KP
3) ⎯⎯ = ⎯⎯⎯ 4) ⎯ = ⎯⎯⎯ NH2
- M M
cobalt chloride m 1 + bP m 1+bP NH2 NH2
+
NH3 , Cl 1) 1M 2) ⎯ 3) ⎯ 4) Zero
2 4
Hx*çí˚ §˘úø®- ˝†’ éÓ¶«™¸f éÓxÈ®új ˛
Ææ´’-éπ~ç™ NßÁ÷í∫ç îÁçCÊÆh à®Ωpú- Ë Ææ¢’Ë t-∞¡Ø- √©’ 149. The enthalpy of formation of N2O and NO
2) Ca(ClO3)2, CaCl2 2) CaCl2,O2 are 82 and 90 KJ/mol. The enthalpy of
SO3H
3) CaO3, Cl2 4) Ca(ClO3)2, CaCO3 reaction 2N2O(g) + O2(g)) → 4NO(g) is NO2
NO2

143. Glucose does not react with N2O ´’Jߪ·NO © ßÁ·éπ\ Ææç¨Ïx-≠æ-éÓ-≥ƒg©’ 155. Match the following
82 ´’Jߪ· 90 éÀ.ñ˜/-¢Á÷™¸ Å®·-ûË éÀç-C-¢√-öÀ-E ïûª-°æ-®Ω-îªçúÕ
2N2O(g) + O2(g) → 4NO(g)
í∫÷xéÓñ¸ -üËçûÓ îª®Ωu ï®Ω-°æü¿’?
1) C6H5NHNH2 2) NH2OH
ßÁ·éπ\ Óu≠ægç
List-I List-II
1) 8 KJ 2) 16 KJ 3) 88 KJ 4) 196 KJ
3) HCN 4) NaHSO3 1) MnO/300°C A) Preparation of
150. Equimolar concentration of H2 and I2 are
144. Which of the following statements are cor- acetaldehyde from
heated to equilibrium in a 2 lit flask, at
rect éÀç-C-¢√-öÀ-™ ÆæÈ®j† ¢√uêu©’ ethanoyl chloride
equilibrium the rate constants of forward
I) Cationic polymerisation initiators are °j ÆæO’-éπ-®Ω-ù«--™x Z àC?
and backward reactions are equal. What Éü∑¿-ØÓ-®·™¸ éÓxÈ®jú˛ †’ç-*
AlCl3, SnCl4
is the % of initial concentration of H2
é¬ô-ߪ÷-Eé˙ §ƒL-´’-K-éπ-®Ωù áÆœ-ö«-Lf-£j«ú˛ ûªßª÷K
AlCl3, SnCl4
reacted at equilibrium
v§ƒ®Ωç-¶μº-鬩’ 2) H2/Pd-BaSO4 B) Hydration of Alkynes
II) Anionic polymerisation initiators are
2 M. §ƒxÆˇ\™ Ææ´’ ¢Á÷™«®˝ í¬úμøûª -Ö-†o H2
R -Li, KNH2 Ç™„j \-Ø˛© £j«vúË-≠æØ˛
´’Jߪ· I2 ©†’ ¢ËúÕ -îË-¨»®Ω’. Ææ´’-û√-ÆœnA ´ü¿l C) Catalyst used in the
R -Li, KNH2 PdCl2
3) ⎯⎯ →
Åߪ÷E- é˙ §ƒL-´’-Ké- π®- Ωù v§ƒ®Ωç¶- ºμ é- ¬©’ A®Óí¬N’, °æ¤®Ó-í¬N’ √u Æœn®√ç-鬩’ Ææ´÷†ç
III) Percentage fo sulphur in abonite is preparation of ace-
Å®·-ûË, Ææ´’-û√-ÆœnA ´ü¿l Ωu §ÒçC† H2 ßÁ·éπ\ CuCl2 H+
60%-65% tone from acetic acid
v§ƒ®Ωç¶μº í¬úμøûª ¨»ûªç áçûª?
á¶-ØÁj-ö¸™ 60]–65] ´®Ωèπ◊ Ææ©p¥®˝ Öçúø’†’ 1) 33% 2) 66% 3) 50% 4) 40% áÆœ-öÀé˙ Ç´’xç †’ç-* áÆœ-
IV) 1, 4 - Linkages of natural rubber was 151. Choose the correct statements
öØ˛ ûªßª÷-KéÀ ÖvûËp-®Ωéπç
determined by ozonolysis experiment 160. Identify the correct statements
éÀç-C-¢√-öÀ-™ ÆæÈ®j† ¢√uêu-©’ 4) 1% D) Hydroxylation of
Ææ£æ«ï ®Ω•s®˝-™ 1, 4 – •ç-üμ¿Ø√-©†’ ãñ- HgSO4/H2SO4 Alkene ÆæÈ®j-† ¢√êu-©†’ í∫’Jhç-îªçúÕ.
i) Ozone is diamagnetic molecule
Ø√LÆœÆˇ v°æßÁ÷í∫ç E®√l¥-Jç--*çC. 60°C ÇM\-Ø˛© £j«vú≈-éÀq-™‰-≠æØ˛ I) Chloramphenical is broadsectrum
1) All are correct
ãñØ˛ úøߪ÷-´÷-í∫o-öÀé˙ Åù’´¤ Antibiotic
Å-Fo ÆæÈ®j-†N ii) Ozone decolourises organic colouring E) Hydration of Alkenes
2) I & II only I & II ´÷vûª¢Ë’ éÓx®Ωç °∂œE-鬙¸ v¶«ú˛ ÂÆpéπ¢Z ˛’ -ߪ÷çöà •--ßÁ÷öÀé˙
matter by reduction
3) II, III & IV only II, III & IV ´÷vûª¢Ë’
ÇM\-Ø˛© ï©-N-¨Ïx-≠æù II) Omeprazole is antacid
ãñØ˛ ®Ωçí∫’ -Ö-†o éπ®Ωs† Ææ¢Ë’t-∞¡-Ø√-©†’ éπ~ߪ’-
4) I, II & IV only I, II & IV ´÷vûª¢Ë’ éπ®Ωùç üΔy®√ N´®Ωgç -îËÆæ’hç-C The correct match is ÆæÈ®j-† -ñ -úÕç°æ¤ ã¢˛’-v°æ-ñ ™¸ Å-ØËC áçö«-Æœú˛
145. The complex Fe (CO)x follows EAN rule, III) Aspartame is an example of polypeptide
iii) Hypo reacts with Cl2 (moist) giving 1) 1-C, 2-E, 3-A, 4-D 2) 1-C, 2-A, 3-E, 4-B
then the value of x is NaCl, S, HCl, SO2
á≤ƒp-®Ωdç Å-ØËC §ƒL-°-°kd-ú˛èπ◊ ÖüΔ-£æ«-®Ωù
3) 1-A, 2-C, 3-B, 4-E 4) 1-B, 2-E, 3-C, 4-A
Fe (CO)xÆæçéÀx-≠dçæ EAN Eߪ’-´÷Eo §ƒöÀÆæ’hç-C. IV) Sulpha diazine is anti biotic
£j«§Ú ûË´’ éπL-T† Cl2 ûÓ îª®Ωu §ÒçC NaCl, 156. 0.04g of organic compound containing
x S, HCl, SO2
Æ晫p¥ úøߪ’-@Ø˛ äéπ -ߪ÷çöà •--ßÁ÷öÀé˙
sulphur produces 0.233 g of BaSO4 per-
Å®·-ûË N©’´ ©†’ ÉÆæ’hç-C
1) 2 2) 3 3) 4 4) 5 1) I and II only I ´’Jߪ· II ´÷vûª¢Ë’
iv) S reacts with F2 to give SF6 centage of sulphur in the compound is
146. The freezing point of water is depressed 2) I, II, III only I, II, III ´÷vûª¢Ë’
F2
ûÓ îª®Ωu §ÒçC SF6 -†’ -ÉÆæ’hç-C Ææ©p¥®˝ -éπ-L-T Ö-†o 0.04 ví¬´·©’ äéπ éπ®Ωs†
by 0.037°C in a 0.01 M NaCl solution. The 3) II & IV only II ´’Jߪ· IV ´÷vûª¢Ë’
Ææ©p¥®˝
1) i only i ´÷vûª¢Ë’ Ææ¢Ë’t-∞¡-†ç 0.233 ví¬´·© BaSO4 †’ ÉÆæ’hç-C.
freezing point of 0.02 M solution of 4) I, II, and IV only I, II ´’Jߪ· IV ´÷vûª¢Ë’
sucrose in °C is 2) i and iv only i ´’Jߪ· iv ´÷vûª¢Ë’
3) i, ii and iv only i, ii ´’Jߪ· iv ´÷vûª¢Ë’ KEY PHYSICS
0.01 M NaCl vüΔ´-ùç™ FöÀ °∂æ’F-¶μº-´† ≤ƒn†
81. 2 82. 1 83. 2 84. 2 85. 1 86. 3 87. 1 88. 4
E´’oûª0.037°C Å®·-ûË 0.02M Ææ’véÓñ¸ vüΔ´ù 4) All are correct Å-Fo ÆæÈ®j† ¢√uêu©’ BOTANY
89. 3 90. 1 91. 2 92. 4 93. 4 94. 4 95. 1 96. 4
°∂æ’F-¶μº-´† ≤ƒn†ç E´’oûª °C ©™ 152. Consider the following representations 1. 4 2.4 3. 3 4. 2 5. 1 6. 1 7. 4 8. 1 9. 1 10. 4
97. 2 98. 2 99. 2 100. 1 101. 2 102. 4 103. 4
1) -0.0370 2) -0.0185 3) -0.0740 4) -0.185 Ñ éÀçC ®Ω÷§ƒ©’ ¢ËöÀéÀ îÁçü¿’-û√®·? 11. 2 12. 2 13. 3 14. 3 15. 3 16. 4 17. 3 18. 1
CH3 CH3 104. 3 105. 2 106. 2 107. 2 108. 1 109. 1 110.
147. Preparation of cyclohexane by a wisli- 19. 3 20. 3 21. 4 22. 4 23. 2 24. 3 25. 3 26. 4
2 111. 4 112. 3 113. 2 114. 3 115. 2 116. 3 117.
cenus method is represented as follows 27. 3 28. 3 29. 4 30. 4 31. 2 32. 2 33. 2 34. 3
2 118. 2 119. 4 120. 1
NÆœx-ÂÆ-†Æˇ °æü¿l¥A üΔy®√ ÂÆjéÓx-£«-ÍéqØ˛ ûªßª÷-KE H Br F H 35. 2 36. 2 37. 2 38. 4 39. 3 40. 2
CHEMISTRY
ZOOLOGY
121. 2 122. 1 123. 2 124. 1 125. 1 126. 2 127. 2
éÀçCNüμ¿çí¬ Ææ÷*ç-î√®Ω’.
distillation Na/EtOH HI Zn+HCl F Br 41. 1 42. 4 43. 4 44. 4 45. 3 46. 2 47. 1 48. 1
A⎯⎯⎯⎯→B ⎯⎯⎯⎯→C →D ⎯⎯⎯→ They are 128. 1 129. 1 130. 1 131. 4 132. 4 133. 4 134. 2
1) Enantiomers 49. 3 50. 2 51. 1 52. 1 53. 1 54. 3 55. 2 56. 4 135. 3 136. 3 137. 3 138. 1 139. 2 140. 2 141. 2
C6H12 what are A, B, C & D respectively áØ√-E{-ßÁ÷-¢Á’-®˝©’
57. 4 58. 4 59. 4 60. 2 61. 4 62. 1 63. 1 64. 4 142. 2 143. 4 144. 4 145. 4 146. 1 147. 2 148. 3
Na/EtOH HI Zn+HCl 2) Diastereomers
65. 4 66. 2 67. 3 68. 3 69. 4 70. 2 71. 1 72. 4 149. 4 150. 1 151. 2 152. 4 153. 3 154. 2 155. 2
ÊÆyü¿†ç úøߪ÷-Æ‘d-J-ßÁ÷-¢Á’-®˝©’
A⎯⎯⎯⎯→B ⎯⎯⎯⎯→C →D ⎯⎯⎯→ 3) Cis-Transisomers ÆœÆˇ–-vö«-Ø˛q -â-≤Ú--´’®Ω’x 73. 2 74. 1 75. 4 76. 3 77. 3 78. 4 79. 4 80. 2 156. 4 157. 4 158. 4 159. 3 160. 4