\2ms Date

Practice IB Bxam: Topic 1 Quantitative Chemistry

1. Al and
The relativemolecularmassof aluminiumchloride is 267 and its compositionby massis 20.3%o
79.7%chlorine.Determinethe empiricaland molecularformulasof aluminium chloride.

;;/ o/; i,a.!3

; ffi;; o::)si;iiJ//

'g;V;;,'ie / F;ia/1 :t
no/al
,
ft.tg ft/"/s= 26:rfr*t1s*2fi)=/s3.ttJ

(Total4 marks)

2. Sodiurnreactswith water as follows.

2Na(s)+ 2H2O(l)- 2NaOH(aq)+ Hz(g)

(Total 3 marks)
3. An organic compound,A, containingonly the elementscarbon,hydrogenand oxygerrwas analysed.

(a) A was found to contain54.57oC and 9.17oHby mass,the remainderbeingoxygen.Determine

the empiricalformulaof the compound. % O
@

(3)

(b) A 0.230g sam , when vaporized,had a volumeof 0.0785A*iat 95'C and 102 kPa.
Determinet

fu't
(3)

(c) Determinethe molecularformulaof A usingyour answersfrom pafts(a) and (b).

ne/+ r/Fl!' . F ?rto Q= t(tl,:t) *ry(1,f0* /(:6a = ??.o;

/7= 87,8

( 1)
(Total7 marks)
4. An organiccompoundA contains62.07oby massof carbon,24.1o/o
by massof nitrogen,the remainder
beinghydrogen.

(i) Determinethe percentageby massof hydrogenand the empirical formula of A.

(3)

(ii) Define the term relativemolecularTass.

(2)

(iii) The relativernolecularmassof A is 116.Determinethe molecularformulaof A.

( l)
(Tot al6 m ar ks)
 Propaneand oxygenreactaccordingto the following equation.

C:Hs(g)+ 5Oz(g)- 3COz(B)+ 4H2O(g)

Calculatethe volume of carbondioxide and water vapourproducedand the volume of oxygen

when20.0drn3of propane
remaiuilu{, reactswith 120.0dmi of oxygen.All gasvolumesaremeasured
iffi" arrd
temperature presiure.
. : ,n %l::: !
. . . . . . . . . ' . . . . . . ......' ............' .........g d n 3 eaL./,.@
t?J-,s.
Aog-Jnlc'irr m= .

/ Ao,o-/o0. = leo.dn"oL
fZemoir?,trr
6.

"4^/e

bJt (Tot al3 m ar ks)

i; 4 tfu" ifl /,y'ett4€ '

 C*lfY o*
7. (i) Crocetinconsistsof the elementscarbon,hydrogenand oxygen.Determinethe empiricalfomula
of crocetin,if 1.00g of crocetinforms 2.68 g of carbondioxideand 0.657g of water when it
undergoescompletecombustion.

C*zceAn * o?-* CQt *rfza

a.!rfr r, J
o:6_

;;'i,i; e%
*;;:$:,i;;,;:,,;i;;i; """"""/"'?ti/ - -""""""""4"
' :":":"'tt':' o:o72/ mo/ r /;":iN'q:
rnat't fr= ":" : -''=: . ' . / r r . l/ . . . . :;. , .d. d ? s6q h
. . .... . . . . . . . . . . . v
o

(ii) Determinethe molecularformulaof crocetingiventhat 0.300rnoleof crocetinhasa massof 98.5 g

mo/a /*t:l! 9F CrlaO 7 sta':pt {O:1D*zao =f,fl.//q

U

n=ffi= L/ (2)
(TotalS marks)

-,ff;*^,ry(+ho)+
 A solutioncontainingammoniarequires25.0 cml of 0. 100rnol dm-3hydrochloricacid to reachthe

#ij n://uftt =rto/t*?/

1i; Writean equaiidl-or tlte reactionof ammoniawith hydroclrloric
acid

) 4rl e/ ( l)

(ii) Calculatethe amount(in rnol) of hydrochloricacid atrdammoniathat react.

i;/tv/; i";///4

(2)

(\--Calculate the massof ammoniain the solution.

O,MXftm9l,ffi
(2)
&rrl (Total5 marks)

273llAnd
3.8%nitrogenand46.2%carbonby massQAt
theempiricalfoffila of R.
lo+sg ofA occupies462cn3.Determine
molar massof the compoutrdattddetermineits molecularstructure.

t*lo/ lU '-

rno/ C=
...............8
"'/.;r''.cu./...
tryol 4 / /q
/4)?trrct :
3. fr

*4;

2*to/t*ttt.r! ?N= /3.o/ /--/q' O/ = 7& a z7 (Tot al3 m a

7 /= =?- ffi,rirAe'q+@ 6