Ao + hv ⇌ A*

r1 = d[A*]/dt = fa - k 2[A*][A]-k 3[A*]=0

[A*] = fa/ (k 2[A]+k 3)

fa = -d[hv]/dt
Io
fa = (1-e−alC )
I N ohv
H2 + Cl2 2HCl

d [ A 2 ] / dt
GA =
fa
105
IoA - IA
Cl2 2Cl*
Cl* + H2 HCl + H

H + Cl2 HCl + Cl*

R5 = k5 [A]2

k 2 [ A] f a k5[ A] 2

+
k 4 k 2 [ A]+ k 3 k 4
k4 ❑
2
k5 [ A ]
[A2] =
k4

d[A2]/dt = k 2[A*][A]-k 4[A2]

k 2 [ A ] fa
- k [A2]
k 2 [ A ]+ k 3 4

k 4[A2][A]

r = k 2 [ A] - k 4 [A ]
2
fa k 2 [ A ]+k 3 fa