| “ ‘The clin which the ftlowing eation eur: 2Fe™(ag) + 2 (ag) —> 2Re™(aq) + 1,68) nas Eq = 0236 V at 298 K. Calculate the standard Gibbs energy and the equilibrium constant ofthe cell reaction. Ans. Fe" 426 —+ 2Fe" of 21" — + 26° “Thus forthe given cll reaction, n= 8:0" = nF Eg =~2 96500 0.236 J mo! = — 45548 ] mol! = 48.58 kJ mol! 4,0°=- 2303 RT og K, 4G eT es — 45.55 KI mot ‘THOSRT ~ 303% 8.314% 10 KF K" mk meee K, Antilog 0.983) =9616 «107 G7. Why dos the conductivity of soliton decrease with ditution? ‘Ams Condctviy of soliton isthe conductance of ons ee i sf i in uit Volume ofthe sohition, On di Sonne as er eit vole estes So, thconcty ase ete Slition Oncaea alu of water 208K = Phir) * Noo] +s +A D-Pibas +AR5 5) + Noa ~ A. he molar conduetivity of 0.025 mat isolation and disocition constant, ven 41) = 49.6 em? mol and 2 "(COO Ans. AZ (HCOOH) = 2} * Cateutate te Is degree of rf tors, 18540825 en? mo AS = 46S em? mol" (GiHCOOH === HCOO + HY Initial conc. emol Lt 0 0 Cone. at equilibrium = ¢(1 a) ca cw ca. co. 0.025 x (0.114)? e(l-a) I-a 1-0.114 =3.67 x 104Calculate the standard cell potentials of galvanic cell in which the following reactions take, (@ 2Cr(s)+3Cd?* (ag) — 2Cr** (aq) +3Ca(s) (i) Fe® (aq)+ Ag’ (aq) — Fe" (aq) + Ag(s) Given: Ee3+/cp =— 0-74 Vs Eear/ca =~ 0-40 vy, EX g/g = 080 Vs Ee /pet = O77 V ¥ Calculate A,G° and equilibrium constant of the reactions. == 0.40 V—(- 0.74 V) =+0.34V | Ans. FP.ar = Feanose ~ Psnode =n FE. =~ 6 mol 96500 C mol! * 0.34 V 196860 C V mol" = -196860 J mol” =-196.86 kJ mol = 2,303 RT log K. 196860 = — 2.303 x 8.314 x 298 log Ke or log K,= 34.5014 K, = Antilog 34.5014 = 3.192 x 10 * 4 = + 0.80 V — 0.77 V =+ 0.03 V n FE”, = — (1mol) X (96500 C mol) x (0.03V) =~ 2895 CV mol =~ 2895 J mot"! =~ 2.895 kJ mol A,G? = - 2.303 RT log Ke = 2895 =~ 2.303 x 8.314 x 298 x log Ke or log K, = 0.5074 or K, = Antilog (0.5074) = 3.22 wee — ‘Oitireettten eet eterna Gi) Fe(s)| Fe (0.001 MM) If HCL Mp | Hg) (bar) | Puts) (Gi Sos) | Sn (0.050 Nf |] H* (0.020 ND | Hg) (1 bar) | PAs) POI Iac eae ne Fragen O14 Vs Bangg 4 LOB Y. ep Otmmdns |. upeoeeaee ey soi, [Mg*) Nemst equation: : am ier 271 0m955-268 "> (@) Cetteation rer tt RP Nermeqution: Egy Et ~ 2052 yg le] ww? 05,102 | cera a (3) 0.44+00887 (Gi) Cat reaction: Sa 2H" — Sa +H n= 2 Neto: ag Fag 22g (6) Cet reaction: ems equ 2031 pg. ano) 0597) = 108-0208-— 12819 Assan hf plex Fret ow sven mprsiton Sout Px [H,0 (1 bar) | (0.03 M) || Be (0.01 MD | Bex | PUpomine conductivity and motar conductivity for the solution ofan electrolyte. Discuss their variation with concentration. 00 Ans. Referto Basie Concepts Points and 10 for dition, fe Variation of Conduetivity and Molar Conductivity with 2 Concentration: Condusiviy always. decreases with the & decrees in concentration both for weak andstongelectolyies. 2.20 “Thisis Decne the number fons per unit volume thatcary the tare na soluton dees on ian The confocyof Tenson a ny tan nce tr ceean ooo Sai volume of ston kept btesn fo pau eles ‘Tin tae of row ssn nd dance oot ng This lear fom he aon Ae (th Aan ae unity nth port uns inmotem ‘Molar conductivity ofa solution ata given concentration isthe conductance ofthe volume V of solution containing one mole of electrolyte kept between two eect ‘with the area of cross section A and distance of unit length. Therefore, eA ae Since I= 1 and A = V (volume containing I mole of electrolyte) y= Molar conductivity increases with the derease in concentration. This is because the total volume, Ve solution containing one mole of electrolyte also increases. It has been found that decrease in x ond ‘oF soaton is more than compensated by increase in is volume. ‘The conductivity of 0.20 M solution of KCL at 298 Ki 0.0248 S cm" Calculate its molar condctivi 1000 em?» 1 020mol 124.8 em? mor ce ing 0.001 M KCI solution at 298 K is 1500 ©. What is ‘if conductivity of 0.001 M KCI solution at 298 K is 0.146 x 10" S em"? 1 Resistance (R) ¥ =0.146% 10° S em", R= 15000 0.146 10° em ‘Ans. Conductivity (s) = % Cel constant 1 ag * Cell constant 146 x 10 Sen Cell constant % 1500.2 = 219 x 10° em 0.219 emtHow much charge is required for the following reduction: OG Totton to mel atCocu? Gi) 1.mol of MnO; to Mn**? Ans. ()) AP + 36° — AL (Quantity of charge required for reduction of 1 mol of AI* 2 (Quantity of charge required for reduction of | mol of Cx i) in; — ain? Oxidation number of Mn changes from +7 to +2: Quantity of charge required = SF = 5 x 96500 C = 482500 C OGG ow mach ceiiy interme Faratty brcquea opens © 200 gf Ca from molten CaCl? @ 40.0 gf At from molten A1,0,? Ams @ Ca 4 26 — Ca As. 40 8 of Ca, require electric 20g ofCa » requis eleicy = 22 “a ecticity 40 wi, ADP + 3° — al As Umolof A ie 27 got Area cescy 3 F 40 got Alwit oie eoity = 2s 4aer low much electricity is required in coulomb for the oxidation of © 1 mol of H,0 to 0, i) 1 mol of FeO to Fe,0,2 ( The electrode reaction for 1 mol ofH, Wo — 24+ L oye2e ‘Quantity of electricity required (id) The eleceode reaction is given as Ans. te 2F oR 2 For the oxidation of 2 moles of FeO, required charge For the oxidation ! mole of FeO, required charge = | F = 96500 €solution of Ni(NO,); i clectrolysed between platinam electrodes using a current of $ amperes for 40 minutes. What mass of Niis deposited atthe cathode? Tense (r) 20181 Quantity of electricity passe ‘A) x 20 60's) = 6000 C ‘The clectode eation i: NP* + 26” —+ Ni 2596500 C deposit Ni= 58.7 @ oro wit postin SEs cogs fre ect sand contig saan of 7280, MANO a C80, rap Jen nse Ay core ote assed hgh te oa ‘Medea of Ww ong caret hw! Wht mao eoppetsod steer dpe ‘csr Da st Ans. Ag+ © —— Ag 10 got At epi 96500€ 1.45 g of Ag willbe deposited by 210956 | TO LsOy TATE, cits 2 os 249800 teat = 6354 cutee ty 125562 558555 x a6 adore Ze 4 te Tn 2496800 tea’ =653§ 53 Za deposited by 1295.6C= 55S x 12956 1A tne reaction between the following is sing the andar letrade potentials given below, rei eases {0 Fe" ap) and Cag) (i Aen) ana Cu ii) Fe and Br (aq) iv), Ag(s) and Fe" (ag), (©) Br; (aq) and Fe (ag) (ivnstandard electrode pote Fine SHV, Een +034¥, = seat noe Freya 11090, Egg 080s Fyre ‘Ans. A reaction feasible if eam ofthe cell ection is posi (0) Fea) + (ag) — Fea) + 77 V 0.54 V =0.23 V (feasible) Age) +Cu— ng) +0409) sing Far = 080-024 V = 046 V ease). (0) FO* an BF (aq) — Fea) F 032 (not feasible). Bay 0.7 V—1.09)Gi). ABO) + Fe (ag) — Ag” log) + Fe (ay), Elgy= 0.77 V ~0.80 V=~0.03 V (not feasible). © bein : Ans, () Electrolysis Atcathode: As Ag* ions have lower discharge potential than ions. Therefore, Ag* ions Avanode: (i) Electrolysis of aqueous solution of AgNO, with platinum electrodes: ‘Ateathode: As given in pat (0). At anode: Aveathode: H +e" —+ HH +H Hy Atanode: 1,00) — Lo, + 24° + 26 “Thus, Ha is herated at the cathe and Os athe anode. (Gr) letra 0 = sor ‘At cathode: Ca?" ions wil be reduce in preerenee to Hons Cu 426 cu ‘Atande: CT ions wil be oxidise in preference to ON" ions or —aee, a+a—a, Hence, Cu will be deposited onthe ealhode and Cl, will be liberated tthe anode. E2q= 109 V0.7 O18) Predict te products of electrolysis oft @ Anaqueous solution of AgNO, with silver electrodes. (Gi) An aqueous solution of AgNO, with platinum electrodes. Gi) A ditute solution of H,SO, with platinum electrodes. (>) An aqueous solution of CuCl, with platinum electrodes. Electrolysis of dilate H;S0, with platinum electrodes: + Fe™ (aq) —- Br + Fe, following: yi is of aqueous solution of AgNO, with silver electrodes: ABNO\s) —+ Ag*(ay) + NOj(a9) 40 = H+oIr ‘will be deposited as Ag in peoference to H* ons. [As Ag anode is atacked by NO} ions, Ag ofthe anode wil dissolve to form, Ag” ions in the solution, Ag) — Astiag) + ‘As anode is not attackable, out of OH” and NO; ions, OH ions have lower. Potential, Hence, OH" ions willbe discharged in preference to NO; ions, which ecompose 10 give out O; 1,00 — Lo, + 2H" + 2 H,S0, — 2H" + soe 10 = H+ or0. In the button cells widely used in watches and other devices, the following reaction takes place: Zn(s) + Ag,O(s) + H,0() —— Zn**(aq) + 2Ag(s) + 20H (aq) Determine £° and A,G° for the reaction, Given, Zn ‘Zn + 26°, E? = + 0.76 V5 Ag,0 +H,0+2& ——> 2Ag+ 2087, E"Ans, At anode: Zn Zn + 267 Atcathode: — Ag,0 +H,0+2e° —— 2Ag + 20H" Zn + Ag,O +H,0 ——+ Zn +2Ag + 20H” Een = Eeahode — = Exe /ng— Ezat* zn Egy = 0.34 V ~(- 0.76 V) = 1.10 V AG NF Egy 0 = 2 2 x 96500 x 1.10 2.123 x 10° Jmoland write the correet option(s) inthe following questions, Which cel will measure standard eecrode potenti copper electrode? (a) P)| Hy (8.0.1 ban] Haq, 1M). |] Cu (ag, IND} Cw ©) PU} G1 bat) |HNGQ, 1M) |] Cu (aq, 290] Cu (©) POH, (G1 ba) [G9 1M) | ]C* fay, IMD] Ou (@ PA] Ha (G1 ba) | "(09.0.1 NOL Cu (ag, 1M Cu A hypothetical electrochemical ellis shown below: ‘ATAGAD IL B'GMD |B ‘The emf measured is $0.20 V. The cll reactions @ AtBY atte Mte AB te [A device that converts energy of combustion of letra energy is known ase (@) dynamo INCERT Exemplar) (bye cll reaction cannot be predicted Os +B— Ase fuels like hydrogen and methane diretly into ) Nica ct (@)slecrlsic cell i. The lference between the electrode potentials of two electrodes wien no current is drawn through (© futectt the cell is called : INCERT Exemplar] (4) Cell potential (6) Collen (6) Potential diterence (@) Cen voltage ‘Which of the following statement isnot correct about an inert electrode ina cell? [NCERT Exemplar} (@) Ie doesnot paticipate i thecal rection (©) lt provides surface either for oxidation or for eduction reaction, (6) tprovides surface for conduction of electrons. (@) le provides surface for redox reat Charge arvied by 1 mole of electrons is (@) 6.023 x 10” coulomb () 9.65 x 10" coulomb (6 16%:10" coulomb (@) 628 x:10” coulomb - Standard electrode potential for San" coupe is 4.15 V and that forthe CP"/Cr couple is~0.74V. The two couple in their standard states are connceted to make cell The cell potential! will be: @ sisv (0897 © wr8v @s0v ‘Which on of the flowing always teu about the spontaneous cl econ In galvanic (0) F2y>0,86"<0,0>K, (0) Big 0,40" <0,0K, (0) £i4>0,80"> 0,0> 8, (Bay 0,86" <0,0 Feat 1. Which ofthe statements about solutions of electrolytes isnot correct? {@), Condvctvity of soltion depends upon size of fos. (@) Conductivity depends upon viscosity of solution. (Conductivity does not depend upon solvation of fons present in solution, {@) Conductivity of solution increases with temperature ‘cing the data given below ind out the strongest reducing agent, Beer /or"tV Fajr 136¥ SIV Bbpn jeg OAV wor ce ton the order of reducing power is INCERT Ex Fimo; @a ‘Using the data given in Q- 12 find out in which opt (@ cer 0,18) *4H (ag) +4e~ 96 icenr Even) — 8,0 tap +26 in 2805 (00)(a) Indilute sulphuric acid solution, hydrogen will be reduced at cathode. (®) Inconcentrated sulphuric acid solution, water will be oxidised at anode. (©) Indilute sulphutie acid solution, water will be oxidised at anode, (d) Indilute sulphuric acid solution, SO}~ ion will be oxidised to tetrathionate at anode. iInswers \ 7) 2. (a) 3.0 4.) 5a) 6. (b) 7. (6) 8 @) 9.(2) — 10.(0) 1. (©) 12. () 13. (6) 14. (@) 15. (c) 16. (©) 7.(0) 18. (d) 19. (b),() 20. (a), (c)sertion-Reason Questions, folowing quesions statement of serton old by astatoent of reason i ive, Choa the correct tof the following choices. Me seon and reeton bah are coret statement and rear is ore explanation fraser to) tuertion and reason bach re correc statements bt reason i not correct explanation for ssn. {e)_sserton correct latement but reason is wrong statement. ay Assertion i wrong statement but reason is correct satement, 1. Awertion (A) + Cusess reactive than hydrogen. Foray is negative. Bsa shoud have a positive vale fo the elo funtion, Fann Su!(aq) + 26°, B= +151 ‘Construct the redox equation from the standard potential of the cell and predict if the reactant favoured or product favoured. [CBSE (Al) 2009; De Ans. At anode (S5"* (aa) Sua) + 2615 Atcathode: _[MnOj(aq) + 8H"(a9) +e Mn®* (aq) + 44,0 ()] x2 Cell reaction: 2MnOsag) + SSH (aa) + 16H" Caa) 2M (ag) + SSH Cag) + Bh SiV-015V ‘As cll potentials positive therfore the reaction is product favoured. 3) Determine te raies oer comin fa 6 fr the long esto Ni(s) +249" (ag) —+ NP* (ag) +2Ag(0), £2 = 108 V (1 F=96500 C mot") [CHSE Del ‘Ans. Ni(s)*2A8" (ag) — Ni" (ag) + 2049 B= 1.08 V Het, Jog k.~ 999 Bean 2 log K, agp 108 39.5932 alg 39.5932 = 3.919 10" 39210" AG" =~ WE Ly AG? = 2 16500 1.05 = 202680) = 202.65 kd‘Themolar conductivity of a 1,5 M solution tre 7 ae meee ofan electrolytes found the 138.9 Sem? mo! Caleulate po 000 [CBSE (AN) 2012) Ans. he AXxM “1000 38.95 em?mol" X15 mol >! yoo 208455 em uy) The conductivity of 0.20 M solution of KCI at 298 K is 0.025 $ em”, Caleulate its molar conductivity. ge AO. 25S 100 on 2 ot! eee ns Ta = 1258 em mot (2) oe ‘many moles of mercury wil be produced by electrolysing 1.0 M HNO,), solution with @ current of 200A for 3 hours? [ese (ap 20101 ms Mas of mercury produced a the cathode, ere MEL ma 2x1 x10 ML = Mamerx2ax360x60e 4, ; 296500 C mol” * MM BrOll9xM s o119xMg Me mor No.of moles of mercury produced = 119 mol QB, The chemistry of corrosion of iron is essentilly an electrochemical phenomenon. Explain the reactions occuring during the corrosion of iron inthe atmosphere. CBSE Dethi 2011) According to electrochemical theory of rusting the impure ton surface behaves like small electrochemical cell the presence of water containing disolved oxygen or carbon doxie. In this cell pure rea acts as node and impure ion surface ac a5 cathode, Moisture having dissolved CO, oO; acta an elec ‘The reactions are given below. Atanode: Fe —— Fe* 4 26% Ehnjp, =-044V Atathodes Ans. vel = ait + to, +26 HO: Eire *123V Overall reaction fe aitsto, — Fe" 140; Aya} ‘The Fe ins are fuer oxidised by atmospheric oxygen 10 Fe" ons, which comes ut in the form of raed frie onde (rs) are + Lo, +210 — FeO; + 4H FeO, + aH0 — FeO) s8,0 (Rus) fs) cate the degre of saan) of cet cd ls maar conduct (A) 2848 Sem Given y= 249.65 cn? mol" and Neyo) 7409S" ort, (cBSE Deni 2017) 48 Necony™ Nancooy* iy (40 39.6) Sen? mat 390.5 Sem? moi 3905Sem* nol"17.) The following curve is obtained when molar conductivity (A,) is plotted against the square root of concentration, ¢"” for two electrolytes A and B. ( How do you account for the increase in the molar conductivity of the electrolyte A on dilution? (i As seen from the graph, the value of limiting ‘molar conductivity (A%,) for electrolyte B cannot be obtained graphically. How can this value be obtained? [CBSE Sample Paper 2016) (@ As seen from the graph, electrolyte ‘A’ isa strong electrolyte which is ionised almost completely in solutions. For strong electrolyte “A the number of fons does not increase appreciably on dilution and only mobility of ions increases due to docrease in {nteionic attraction. Therefore, molar conductivity increases lite as shown in graph bya straight Gi) Limiting molar conductivity (A%,) for weak electrolyte “B' can be obtained by using Kohlrausch of independent migration of ions which says that limiting molar conductivity of an electrolytes to the sum of the individual conibution ofthe cation and anion ofthe electrolyte. Q.18 When a current of 0.75 is passed through a CuSO, solution for 25 min, 0.369 gof copper is de at the cathode. Calculate the atomie mass of copper. he Wezxlxe Ans. 0.15 225% Seog 075% 25% 60 M=633 w/mol [At what pif of HCI so (44 = molar mass of copper) hydrogen gas electrode show electrode potential of 0.118 V2 Hs Ans Wt + = —‘ow many molecules of chlorine should be deposited from molten sodium chloride in one minute ‘current of300 milllampere? " com fe 123,034: nian aa4ne0e rer — Ci, + 2 2% 96500 C deposit Cl = 1 mol wa epost Cx BOLIC 6.022 102 8c wil deposit Chy= HPI EE SORE cas mo = 5.616 10" molecules Calculate A,G* and log K.for the following reaction: [ens 2019 so41)) Ca*(ag) + Znls) — Zn*(ag) + Cais) EXyeyg2 = 0403 V Give Ejvan® 0768 Cf" (0g) + 246) — 20°C) + C00) ee, Fla Foote Foes Fees foa~ Ea fen 0403 V =(0783 V) 0360V Bg = 02360; A,G = WPS, =2 96500 mol 0.36 V 69480 CV mot" CrOs(ag) + 6H" + be" — Cr(s) + 311,0 Caleutate how many grams of chromium wil be eletroplated by 24,000 coulombs. Hove long wil it lake to eleetroplate 15 g chromium using 12.5 A current? [Atomie mass of Cr = 52 mor, 1 F= 96500 C mot) Ans: 6596500 C deposit Cr= 52g se 2410 wit estore gStEg n.000C= 288 5 gotcrsdepnedy 308006 rela 1SgotCreequire= ger eh 167019 Time for which the current is passed = "953‘One half-cell in a voltaic cell is constructed from a silver wire dipped in silver nitrate solution of unknown concentration. The other half-cell consists of a zinc electrode in a 0.10 M solution ‘A voltage of 1.48 V is measured for this cell. Use this information to calculate the ‘concentration of silver fons in the solution. = +080) [CBSE (F) 2010) Given: 3.2/9, #076 V, Erge/ag ‘ns. Electrochemical cell Za(s)|2a°* (0.10 M) |] As* (Cone) | Ag) Fat BB BaF 20.80 V — (0.763) = 1.563 V Wetnow tat, a at Fg 2 ng EF tAg'] 0.0591 {0.10} 148 = 1.563 - 2052 pg UL 2 Fag (010) 0083 bo a = Tas = 28087 {0.10} o 1020. nitog 28087 = 6837 (As'] tar = 222 sss 104 [ag’] = 1.287 x 107M 6 strip of nickel metal is placed in a 1 molar solution of Ni(NO,), and a strip of silver metal is laced ina t-molar solution of AgNOy- An electrochemical cll is created when the two solutions are ‘connected by a salt bridge and the two steips are connected by wires to voltmeter. () Weite the balanced equation for the overall reaction occurring in the cel and ealeulate the cell Potential, (2 Cateuate the cell potential, at 25°C forthe cll the inital concentration of Ni(NO) i 0.100 ‘molar and the Inia concentration of ARNO, is 1.00 mola. (ES jg #098 Vis Be /yg = 080 Vlog 10" [CBSE (F) 2012)© Atanode: Ni NI 426 Atcathode: —(agh + e —— Ag]x2 Cell reaction: Ni+2Ag" —> Ni*+2Ag Feet = Eatate ~ Etoate = Exe ne Enh 080 V- 025 v) = 10s 209 yg i Euan = By aan? oo [ag'] » Eeay= 1.05 V, [Ni] =0.1 M, [Ag"] = 059 | (0.1) Feat = 1.05 v ~ 9959 jog C1). cl 2 8 (pe Eouy = 1.05V ~ 0.0295 tog 107 (Er) mesa ran at acm eM No ton ti o ‘5.55 x 10° ohm. Calculate its resisti Here, n N lameter 1 cm and length 50 em is {ys conductivity and molar conductivity. [CBSE (42) 2012] : 4 (Len) = 07856: - sn Ans. A= x= 5.55 x 10° ohm x 0.785 cm? ~~ $0.em Resistivity, p= A= 4 87.135 ohmem Condcvig, c=! 1 = 7.135 ohm am ~ 00148 S em 1000 _ 0.01148 em“ x 100m? [-! Molar Conductivity, A,,=<* onsmol 229. 6 S em® morEstimate the minimum potential difference needed to reduce Al,0, at 500°C. The free energy change for the decomposition reaction 2,0, — {Al + 0,k9a = 95500 Cot, viors niojant* +20) —+ 21+ 20,8 2 4 2,0, — tars Onna} ‘4,6 = 960 x 1000 = 9600003 Now, FE 4,6 __-se0000 2.487 V mF ~ 4x 96500 Minimum potential difference needed to reduce Al,O, is 2.487 V. L. The emf ofa cell corresponding to the reaction. ‘Za(s)+ 2H (aq) —+ Zn®*(0.1 M) +H (gy 1 atm) i 0.28 volt at 25°C. ‘Write the half-cell reactions and calculate the pH ofthe solution at the hydrogen electrode, Pag = O6Vs Ein, 20 (ors) Half-el reactions: Zn — Tal 426 2H +26 — Hy Ze oi — Zn + Hy a 0.0591 (28° a ee a 91 jog tl = (Bef, Eten) 2? ‘= [0 - (-0.76)] - 0.02955 [log 107-2 log (H")] 028 2076 0.02955 (14204) pli ==log (9) 2pll-1= 16244 pl =8.62 1: molar conductivities at infinite dilution, ealeulate 157.607 em? mo! From the fll 5 for NH,OH. ‘Ny for Ba(OH), 1 for BaCh = 240.6 0° em? mot! ‘AY, for NH,CIit 291 K, the molar condecth ation of NH,Cl, NaOH and NaCl are 129.8, 217.4 x 108.9 Sem" mot respectively. Ifthe molar conductivity af centinormal solution of NHOH is 9.33 $ em? mot", what isthe percentage dissociation of NH,OH at this difution? Also ealeulate the dissociation constant of NH,OH. (Wwors} ‘ns. Here, we are given [AS foe NH,C1= 1298S om? mol! A, for NAOH = 217.48 em? mot! {Ny forNaCI = 108.9 S cm? mot! By Koblrausch's law, 1 for NHOH = Rio: +R = AS OVH,C1) + AQ (NaOH) ~ Ag ONC) = [129.8 + 217.4~ 108.9} Sem? mol"! or Percentage dissociation = 0,0392 100 = 3.92% Calculation of dissociation constant HOH == NH} + OIF Initial cone, ¢ 0.0 Equilibrium cone. ¢= cor cao cet Ia) caxcar ca Kea) 1-8 Substituting, c= 0.01 N= 0.01 M, and a = 0.0392, we get (0.01) (0.0392)* Weeet, Ke 00392 10x 3.92*107)? = 0.9608 1.509 x 10°MY) Vetine the robowing terms: eee (a) Limiting molar conductivity (6) Fuel cell (@ fssne of a conductivity cell filled with 0.1 mol L™' KCI solution is 100. If the resistance of Ahe same cell when filled with 0.02 mol L~! KCI solution is 520 Q, calculate the conductivity and molar conductivity of 0.02 mol L“' KCI solution. The conductivity of 0.1 mol L~' KCI solutions 1.29 x 107 Oem. @ @ The molar conductivity when concentration approaches to zero is called limiting molar conductivit (b) A fuel cell is a device which converts energy produced during the combustion of fuels like hydrogen, methane, methyl alcohol etc. directly into electrical energy. One such successful fuel cell is hydrogen-oxygen fuel cell. i) For 0.1 mol L™ KCI solution, .29 x 10°? 2"! em, Resistance, R = 100.2 Conductivity, x Conductivity x resistance 29x 107 O°! em"! x 100.2 = 1.29 em" Cell constant For 0.02 mol L™ solution, 1.29 em"! Resistance = 520 Q, Cell constant Cell constant Conductivity. «= “Resistance Molar conductivity, Ay, as _ 0.00248 2" em! « 1000 em! LE 0.02 mol 124.071 em? morti State two advantages of Hy-O: fuel cll over ordinary cll ) Sliver is clectrodeposted on a metalic vessel of total surface area 500 em by passing acu = of 05 amp fortwo hours. Calitate the thickness of silver deposited. [Given: Deny of siver= 18 gen, Atomic mas of sles = 108 am, F = 9650 Cnet Advantages of fue cll (@) Nisa pollaion-fve deviee since no harmful products are formed. (@) Is offcincy is about 75% whichis considerably higher than conventional cells. (6) tis a continuous source of energy if he supply of gases is maintained. (ny Ta © fen 211 0 23360064098 105 gem” Let the thickness of silver deposited be xem. ¥ Veaxx of ant 3837 9387. 5.67 10cm, © Weite the cel reaction and caeulate the ean of the folowing cell at 298 K: SaKs) | Sa? (0.004 MH” (0.020 M0 | Hale) (1 bar) | Pts) Given: Egg = 014) (Give reasons: («) On the basis of £* values, O; gas should be Hberated at anode but itis Cl gas which erated in the letras of aqueous NaCl (6) Conduetivity of CHCOOH decreases on dilation, Am.) Atanoe Sn —= Sai + 2e Atcathode: HT +e —~ Lay px (Cell reaction: Sn + 21" ——~ Sn + Thy Elsa ™ Esse Finate * Ein, ~ Beg 20.00 V (0.141) =0,18¥ [Se] 107 Ms IIE} 2 102M w= Subsituig tese values in the Nernst equation for above cel react 005 180") atl We get Me pe Ee 0059, 4x10" ag ES oF Ey 1400295 og 10 Foy 01400-00295 « 0.1108 ¥ {W) (a) On account of ovepotenta of onygen (©) AS munber of ions pe lame that cary the cure in the solation decreases on ditaen