CH.RAGHAVA RAO, MAHADEVA PU COLLEGE.

Ph: 7411224133
Subject: Chemistry New model paper-2 Max. marks: 70M

Part – A i) Answer any ten of the following 10 X 1 = 10M

1. what are farbenzenter centre?

2. Name the law behind CO2 gas in soft drinks under what type of solution
3. Ornament gold containing copper is an example for what type of solution
4. Which gas is evolved at cathode during the electrolysis of an aqueous solution of NaCl
5. What happens to the half life period of a first order reaction if the initial concentration of the reactants is
increased
6. What are emulsions?
7. Out of physisorption and chemisorptions which one has higher enthalpy of adsorption
8. Nickel is refined by using which process?
9. XeF6 + 3H2O → ___ + 6HF. Write the formula of the product
10. What is the common oxidation state shown by lanthanoids?
11. Name the reagent used for dehydration of haloalkanes to alkenes
12. C6H5 – O – CH3 + HI → ______ + CH3OH
13. Write the name of reaction in which carbonyl compounds are converted into alkanes?
14. Give example for thermosetting polymers?
15. What are antibiotics?

Part- B Answer any five of the following. 5 X 2 = 10M

16. Write the difference between n-type and p-type semiconductors
17. Write the favourable conditions for dissolved gas in liquid?
18. Write the anode and cathode reactions carried in leclanche cell
19. Explain H2-O2 fuel cell
20. Explain the leaching process for extraction of gold
21. Why noble gases are chemically inert?
22. Explain friedal crafts alkylaton of chlorobenzene?
23. What is Explain diazotization? Write the reacton?
24. What is the role of following chemicals in food i) saccharin ii)sodium benzoate
25. What are antifertility drugs give an example

Part – C answer any five of the following 5 X 3 = 15M

26. In the extraction of Aluminium by electrolysis
i) give the composition of electrolyte used ii) overall cell reaction iii) role of crolyte
27. Write the balanced chemical equation with condition involved in manufacture of nitric acid by ostwald’s process
28. Complete the following equation i) PbS + 4O3→ PbSO4 +__
ii) Cu +2 H2SO4 ----→ CuSO4 + ______ + 2H2O
iii) Cl2 + 2H2O + SO2 --→ ____ + 2 HCl
29. A)how is chlorine prepared using KMnO4 b) why is I2 less reactive than ICl
30. A)calculate the spin only magnetic moment of Fe2+ b) why Sc3+ is are colorless but Cr3+ are coloured
31. Write the balanced equations in the manufacture of K2Cr2O7
32. What are interstitial compounds and write the properties of interstitial compounds?
33. With the help of V.B theory explain hybridization, geometry and magnetic property of [CoF6]3-
CH.RAGHAVA RAO, MAHADEVA PU COLLEGE. Ph: 7411224133
34. A) write any two postulates of Werner theorys of co ordination compounds b) write the IUPAC name of
[Pt(NH3)3(H2O)Cl2]
35. A) Write the fac and mer isomer structure for [Co(NH3)3(NO2)3] isomer. B) what are metal carbonyls?

Part – D iv) answer any three of the following 3 X 5 = 15M

36. A)calculate the packing effiency in a BCC b) silver forms a CCP lattice. The edge length of its unit cell is 408.6pm
calculate the density of silver ( atomic mass of silver is 108g.mol-1)
37. A)5.8g of a non volatile solute was dissolved in 100g od carbon disulphide. The vapour pressure of the solution
was found to be 190 mm.of Hg. Calculate the molar mass of the solute given the vapour pressure of pure CS2 is
195mm of Hg (molar mass CS2 is 76g.mol-1) b) mention any two differences between ideal and non ideal
solutions
38. A) state faradays first law of electrolysis. Write its mathematical form using usual notations b) state
kohlrausch law c) write the overall cell reaction takinf place in Daniel cell
39. A) write the Arrhenius equation and explain the terms in it? B) Calcute the half life time for a first order reacton
if rate constant is 0.0693 sec-1?
40. A)derive the integrated rate equations for the rate constant of a zero order reaction b) draw a graph o
fpotential energy vs reaction coordinating showing the effect of a catalyst on activation energy
41. A)Mention any three differences between lyophilic and lyophobic colloids b)what is heterogencous
catalysis?Give an example

v) Answer any four of the following 4 X 5 = 20M

42. A)Explain the mechanism of SnI reaction taking 2-bromo-2 methyl propane (t-butty bromide) B)Explain wurtz-
Fitting reaction c)Write the general formal of Griganard reagent.
43. A)How is phenol manufactured by cumene process? B)Among alcohols and phenols which one is more acidic
and why?
44. A) Explain Kolbes reaction B) explin the mechanism involved in dehydration of ethanol into ethene
45. A)Explain aldol condensation by using ethanal B)How is benzamide obtained from benzoic acid?
46. A) write the IUPAC name of CH3-CH2-CH2-COOH b) write the reaction of preparation of benzamide from
benzoic acid? C) why benzoic acid not participate in friedal crafts reactions?
47. A)Explain Carbyl aqmine reaction B)What is the action of bromine water on Benzenamic (aniline)at room temp
c)The pkb values of Ammonia methanamine and Benzenamine (anline) are 4,75,3,38 & 9.38 respectively
.Arrange them in the increasing order of their basic strength
48. A)How do you show that glucose contains a linear chain of six carbon atoms.
B)What are essential amino acids?is glyeine an essential amino acid?
C)Write the general formula of Zwitter ionic form of an amino acid.
49. A) write the Haworth structure of maltose B) which vitamin can increase blood cloting time C) explain
denaturation of proteins?
50. A)Explain addition polymerization with an example.b)Name the monomers used in the manufacture of Nylon-
6.6 c)Write the partial structure of Neoprene