Topic-Equilibrium CBSE XI Date-21/02/2022

Max. Marks-25 ALL THE BEST Max. Time-1hr

1. Why carbon dioxide gas escapes out rapidly when soda water bottle is opened? [1]
2. State Le Chatelier Principle [1]
3. Write the conjugate acids for the following Bronsted bases? [1]
NH2− , HCOO− .
4. What is the change in Gibb’s Energy at equilibrium? [1]
5. Write any two condition to maximize yield of ammonia in Haber’s process. [1]
N2(g) + 3H2(g) →2NH3(g), ΔH= -46.2KJmol-1
6. At equilibrium the concentration of [N2 ] = 3 × 10−3 M , [O2 ] = 4.2 × 10−3 M and [NO] = 2.8 × 10−3 M in a
sealed vessel at 800 K. What will be K e for the reaction. N2 (g) + O2 (g) ⇌ 2NO(g) ? [2]
7. Calculate the pH of the 0.3 g of NaOH dissolved in water to give 200 mL of solution. [2]
8. The ionization constant of acetic acid is 1.74 × 10−5 . Calculate the degree of dissociation of acetic acid in its
0.05 M solution. Calculate the concentration of acetate ion in the solution and its 𝑝𝐻. [2]
9. For the following equilibrium, Kc= 6.3 × 1014 at 1000 K [2]
NO (g) + O3 (g) → NO2 (g) + O2 (g)
Both the forward and reverse reactions in the equilibrium are elementary bimolecular reactions. What is Kc, for
the reverse reaction?
10. Calculate the solubility of A2 X 3 in pure water, assuming that neither kind of ion reacts with water. The solubility
product of A2 X 3 , K sp = 1.1 × 10−23 . [2]
11. A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the
container is suddenly increased. [3]
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
12. The value of K c = 4.24 at 800 K for the reaction: [3]
CO(g) + H2 O(g) ⇌ CO2 (g) + H2 (g)
Calculate equilibrium concentrations of CO2 (g) , H2 (g), CO(g) and H2 O(g) at 800 K, if only 𝐶𝑂 and H2 O
are present initially at concentrations of 0.1 M each.
13. Find out the value of K c for each of the following equilibria from the value of K p : [4]
i) 2NOCl(g) ⇌ 2NO(g) + Cl2 (g) ; K p = 1.8 × 10−2 at 500 K
ii) CaCO3 (s) ⇌ CaO(s) + CO2 (g) ; K p = 167 at 1073 K

The End