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    180170105035_Exp-10_CRE-2

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    6 views10 pages

    Exp-10 CRE-2

    Uploaded by

    ARROW FF
    Aeeghhgkk and all the best experience possible

    Copyright:

    © All Rights Reserved
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    of 10
    IeolFo 195935 [3170501 ~ Chemical Reaction Engineering! hemi! Engineering Department GEC Experiment No: 10 Date:07/09/2021 Mass Trai hor tion INTRODUCTION; Solid-liquid mass transfer plays an important role in some industrial operation: ‘occur with or without chemical reaction. In case dissolution is accompanied by solid-liquid reaction, it is desirable to know the enhancement in the rate of mass transfer due to simultaneous reaction and compare it with the enhancement predicted on the basis ofthe film and the boundary layer models, Here the system under study is dissolution of benzoic acid in aqueous NaOH solution. The dissolution of a sol solution accompanied with instantaneous chemical reaction can be expressed as: A+ npyB > Product ‘where A is the solid and B is the liquid phase reactant. Assuming the reaction to be instantaneous so that ‘A and B don't co-exist. The mechanism of solid dissolution involves: dissolution of A in liquid followed by its reaction with species B diffusing from the bulk liquid phase ata reaction plane. Ifthe film model is Xn, the enhancement factor, @ defined as the ratio of the solid liquid mass transfer ‘And for boundary layer model it rouncary OBJECTIVE: 1. To study the dissolution of benzoic acid in aqueous NaOH solution. 2. To compare the observed enhancement factor for mass transfer with those. predicted by film and boundary layer model. 3, Mass transfer with chemical reaction (solid Ti aqueous NaOH solution. SETUP DESCRIPTION: ‘The setup consists of a cylinder of benzoic acid mounted on a SS rod and with a D.C. motor. The ‘operational range of rotation is between 10 to 30 rpm. The cylinder is immersed in an aqueous solution of sodium hydroxide of known concentration in a 500 ml vessel filled to two-third its capacity. The position of the benzoic cylinder is so adjusted that the liquid level rises above the top surface by about the top surface by about 3 cm. The dimensions of the benzoic acid may be fixed at diameter 2 or 3 cm, length 5 to 77cm. the cylinder can be prepared by pouring molten benzoic acid in the mould of desired dimensions with 4 to 5 mm SS rod located in the center of the mould in a vertical position, Scanned with CamScanner (eotde 195°35 3170501 - Chemical Reaction Engineering! ‘chemical Engineering Department voeEC PROCEDURE: 1. Recoru the dimensions of the benzoic acid cylinder (0.4, length and od of ss rod) and then fix it in u vertical position with the D.C. motor, Fill the vessel with aqueous NaOH solution of known concentration upto 23rd of its ‘volume. Record the volume of aqueous NaOH solution added (wv). }. Start the water bath and fix the dissolution temperature, ambient upto $0 degree Celsius, 4, Fix the benzoic cylinder inside the vessel containing aqueous NaOH solution and start the motor at a fixed rotational speed N rpm. 5. Run the experiment for 10 minutes, 6. Stop the motor and remove benzoic acid cylinder and measure its dimensions again, 7. Mix thoroughly the contents of the vessel and analyse it for unreacted NaOH concentration by titration against standard HCI solution. & Measure the benzoic acid cylinder dimensions again. 9. Repeat steps | to 8 for different concentrations of aqucous NaOH solutions. 10. Repeat steps 1 10 8 using de-ionised water. This run may be carried for about 45 to 60 ‘minutes duration. During this period small samples should be withdrawn at regular intervals of 10 minutes and snalyzed for dissolved benzoic acid by titration against 0.02kmoV’m3 NaOH solution. CALCULATION: CASE 1: Mass Transfer With Chemical Reaction. BEFORE EXPERIMENT 1. Outer diameter of the benzoic acid cylinder = _3.3¢m Length of the benzoic acid eylinder = 4.9 em AFTER EXPERIMENT 1. Outer diameter of the benzoic acid cylinder =2,7em 2. Length of the benzoic acid cylinder = 3.7 em 3. Normality of HCL used for titration (NI) =.0.5.N 4. Volume of 0.5.N HCL used (V1) = 8.8m 5. Volume of NaOH taken (V2)=_10_m! Scanned with CamScanner [wolde 195935 3170501 ~Chemicol Reaction Engineering 11 ‘Chemical Engineering Department GEC Let the normality of unused NaOH in dissolution be Ns NiVi = N2V2 Nii V2 = 044 N The concentration of unused NaQH = 0.44 N ‘The rate of dissolution of benzoic acid = R. R=NyVolume of NaOH solution in tank = 1.10% 103 moVsec Let the average dimensions of benzoic acid cylinder be Day = 3 em Lay = 43 em Let rod diameter d 78 em Average surface area (AS) ™ As = WDaylay +2 G) (Dax? - ?) = 0.00537_n? Specific rate of dissolution R’ Mass Tr BEFORE EXPERIMENT 1, Outer diameter of the benzoie acid cylinder = 3.3m, 2. Length of the benzoic acid cylinder = 4,9 em AFTER EXPERIMENT 1. Outer diameter of the benzoic acid cylinder = 3.1 em 2. Length of the benzoic acid cylinder = 4.6m. 3. Normality of NAOH used for titration (N2) = osN 4, Volume of sample (VI}=_.2 mi 5. Volume of NaOH taken (V2) = _10_ml Scanned with CamScanner [eolae 195235 4317001 ~Chemicei Reecten Engineering! Chemical Engineering Department voEC Let the normality of unused NaOH in dissolution be Ns NiVi= N2V2 N2V2/V1 = 006 N ‘The concentration of unused B.A. = 0.06 _N ‘The rate of dissolution of benznic acid = R R=NV: =4.91x 10% molec Let the average dimensions of benzoic acid cylinder be Day = 32 em Lay=4.75 em Let SS rod diameter d= 0,78 em ‘Average surface area (AS) As = ®Deybav +2 (5) (Dey? ~ 2) Specific rate of dissolution RY Result: 1. Specific rate of dissolution for mass transfer with chemical reaction Rt = 2.0% 104 molim's 2. Specific rate of dissolution for mass transfer without chemical reaction RY = _2.81x 10 mol'm's Conclusion: Scanned with CamScanner {wolte 195935 3170501 ~ Chemical Reaction Engineering-II ‘Chemical Engineering Department VGeC Quiz: 1. Value of Henry's law constant H Increases with temperature V fi, Decreases with temperature i. Independent of temperature 2. The individual gas phase mass transfer co-efficient has the same unit as : i. Diffusivity ii, Molar concentration iii, Molar flux ,. None 3, Friction generated in separated boundary layer is called : i, Form friction’ ii, Skin friction Kwick friction iv. None 4, Friction generated in unseperated boundary layer is called : i, Form friction ii, Skin friction iii, Kwiek friction iv. None ‘5. law is applied Reynolds no. should be : Less than 1 Greater than 1 iii. Equal to 1V iv. None Scanned with CamScanner y RE-? I OO ——E——— eee a Soa was Mass trestle Lh and >] \\. twithowR Syesetion Jokjective ¥ TS teymine Hae = _] belo Dery panne dang ack tulthout reacllon ta _hets oyenens ys hen \ Observedion fables Moemaliky Volume of Volume oh Novmelidy oF HIT) HOLWAT paren @ oF NWEIOH Crm) ~\ o-5 ee) oGy Gleululion As per Nhe dubu Cotsne chemtal Zeuclisn ) CBenzote acid 4 caliurr Hyduoridd) VoWer diancley of The benzaic oad 1S Bede ico eng meee eee tee | Pete gylivder =4-9 oy Nhe dhe Ehpe Ymentd =) gules daweles & tLe Tenzote atit =2eey Y Lenyth of the henzote etd cy liter = Foy dhube why - averraye diameles of benzok ad Day pitD 23.3424 = 30w ee ie Scanned with CamScanner reorrres03s Gad Ley - Leb be gt3-# Wider a = Mew calarlate ue hose ity of tay Wy a Nev fz = My M8 Va jo (Me = pat wy} ewdecd to PM vol fit Od & mm. hy sf = ObYy a Go | = ool slyy Ze Comentidlion tv wists = oh “asl fs | 000 {= Je me> ol} + fipxe we see the ote yey of 95 fo 3 SOE Cm frobe of as golullov) at pe oic octet ie = jlo ae : | }to x1o & ec Scanned with CamScanner ’ Jasa\to\0 503 \AAA\\AAS. (Avera | fAvesaye syekice reg yo + D5 al = B14 vay G3 sot y 2 yp glh gshCe —G ary A zo. co5agre] 2" x -apecific dle of Jrcedlutron Riz Rizk i : Ae = lox | 9-02 53t [r= 2-0 054 Dl Result © A feapunt of Rwrouneet Meveilly Bivhie Pate ha benzete cxlt ee Oi Pa Arred Cr!) ts Ge O44 0.5 9.008% zanet LE without ale wie \_ Reaclion Copheus laften aude \y outer linwele vr af henzotc ariel = 2&C~9 2 jenath gt benzoic ccid cylinder = beng | phere fx periment dew \y oulesz — fitumeles: &_cyltwdes Zy lenghn ge Mee oylindo © =4-6 ot Scanned with CamScanner feo IFO 105099 = 0.06 = 0,06 = Lg isd rah.) Conees dss erhis a im ters (ms! a bee yo3 240\ ot 3) C ddacalubvon 6 Bewzate cued = 1 Ror z TS 2b) | KISS MOVs SAS Ps = M Dausla + 2[ SBI AN G6%

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