PERCUBAAN SPM PERLIS Telegram @soalanpercubaanspm ANSWER PAPER 1 TRIAL SPM 2020 1 A a D 4 A 2 € 22 B a2 B 3 ic 23 D B D 4 D 24 B a A 5 D 25 ic 5 c 6 A 26 B 46 c 7 A 27 B a A 8 A 28 c B Cc 9 c 29 A 9 D 10 A 30 B 50 Cc i B 31 B 12 iC 32 D B D 33 B iu D 34 B 15 B 35 ic 16 A 36 ic 17 D 37 D 18 B 38 D 19 B 39 A 20 e 40 A ANALISIS Acll B:12 Cid D:13 Scanned with CamScannerPEPERIKSAAN PERCUBAAN SPM PERLIS 2020 CHEMISTRY 4541/2 Paper 2 Answer: Mark @ Water 7 Gi) jum Chloride 7 (b) | @ aa 1 Gi) [Toa juplet electrons arrangement 1 (c) |G) | Jonic bond, 1 Gi) [Ton @ 1 @/@ |287 T @ ii) TOTAL| 9 Low melting point // exist as orn temperature // low boiling, 1 point // dissolve in water // sas yanic solvent Scanned with CamScanner2. | (@) | Atoms of same element that have same number of protons but different number of neutrons 1 (6) To detect the leakage of underground pipe// 1 tect the blood clot in blood capillary @ a Number of elcctron | Number of neutron Isote L Bilangan elektron | _Bilangan neutron ‘Sodium-23 yA 8 2 Notrium-23 1 Sodium 24 3 wom 24 Y 1 (a) |) ] The heat energy absorbed by particle’ i 1 Use to overcome the forces attraction bet cles 1 Oy Temperature /°C > Suhy /°C % Freezing point Takat beku Telegram @soalanpercubaanspm Time/s Masa/s Corect title and unit | 1 Correct shape of curve | 1 mark freezing ponit | 1 TOTAL | 9 Scanned with CamScannerQuestion Answer Mark number 3] @ [@_| Ester T (ii)_| Propyl butanoate 1 @)_[@) | Esterification 1 (ii)_| Butanoic acid 1 iii) | CsHhOH + CsH}COOH — CsHsCOOCH = H20 correct chemical formulae for reactant and product [Im] | 2 @ balanced equation [1m] (ce) 9 ©BOH + 502+ 3CO2 + 41:0 // 2c: 902 + 6CO2 + 8H0 ct chemical formulae for reactant and product {1m] 2 balanced equation [Im] @ HOH H-c-C-C-H) 1 HHH HH H 1 | 1 H-C-C-C-H > H OHH - Total 10 Question _ Mark Number Answer 4 |) (i)_| period 2 I Gi) _| alkali metal 1 ii) |T"_ Telegram @soalanpercubaanspm ©) (| more reactive (ii) atomic size for Qis bigger force of attraction between nucleus and electron for atom Q is I weaker © |@ [4Na+O:> 2NaO correct chemical formulae for reactant and produet [Im] | 2 balanced equation [1m] (ii) | mol Na 2.3/23=0.1 [Im] from the equation 4 mol Na: 1 mol O> 3 if 0.1 mol Na: 0,025 mol O» [1 m] mass O» = 0.025 x 32 =0.8 g [1 m] TOTAL 10. Scanned with CamScannerQuestion Mark Number Answer 3] @) sitively charged fon T (b)| @) II) iodide / Plumbum (Il) iodida T yellow precipitate will dissolve when heated 1 Gi) selon eit will form again when it is cooled 1 i) [Pom + b> Telegram @soalanpercubaanspm correct chemical formulae for reactant and product [1m] | 7 balanced equation {1m} (iv) _ | from the equation 1 mol Pbl> if 0.0002 epson mol Pbk: (1 m] 2 mass Pl = 0.0001 x 46° oe Um) () zine ion / Zn** oY 1 @ T. add excess sodium hydroxide so to the industrial waste T water 1 2. blue precipitate formed OR 1. add excess ammonia solution into the inutol ste water 2. dark blue solution formed Sy TOTAL | 11 Scanned with CamScanner@ "To reduce heat lost to surrounding/ Polystyrene is a good insulator of heat ) + SO” >PDSOs (5050) x 4.2 x (32.0— 28.0) J// 16801 1.68 without unit) Wi Nupibepof mole of lead ion Gy tam 1001 Yy oR Number of mole of Os, ion n= 05x50 i 1000 7 0. 1,0 mol PbSO4 precipitate produce > oy 1680 “ 0.025 0.025 =- 672003 mol! // - 67.2 KI mot" Heat of precipitation = AH = -67.2 kI mot" (r: without unit) @ @ Heat of combustion is heat released when I mol of alcohol/fuel is burnt in excess oxygen ww Range between 3320-3340 KI Wo ‘Lnumber of carbon atom increases 2. more carbon dioxide and water are formed 3, more heat released during bond formation TOTAL i Scanned with CamScannera Question ‘Answer Mark umber @ ‘Set I: In dry state, hydroxide ions in solid sodium hydroxide are 7 arranged orderly at fixed position. Dry solid sodium hydroxide does not show alkaline properties. 1 Ob Set I: When moist red litmus paper is used/ water is present, sodium hydroxide ionises in water to produce free moving hydroxide ions. 1 Sodium hydroxide shows alkaline properties. 1 i) im hydroxide is strong alkali but ammonia is weak alkali, 1 1m hydroxide ionises completely in water but ammonia ionises paftilly in water. 1 si \droxide produces high concentration of hydroxide ions but ammoriigprpdices low concentration of hydroxide ions 1 “The higheFthe concentration of hydroxide ions, the higher the pH 1 value. (2 © /@ | Diluion T 0.1x¥=0.02 «280 1 Volume = 50 em! 1 Gi) _| pH value is lower than 1 T Concentration of hydroxi eases, 1 ‘The lower the concentration ide ions, the lower the pH 1 value Gil) | Neutralisation 1 HpSO, + 2NaOH — NasSO, + 2H20 correct chemical formul yctant and product (1m] | 1 lanced equation [1m] | 1 Calculation: Number of mote of NaoHt = 292%25 1 0,995 Ce > ‘i 2 mol of NaOH reacts with 1 mol of H2SO // 0.0005 mol of NaOH reacts with 0.00025 mol of H»SOs Concentration of HaSOy = 29002521000 sot an 70,01 mo 25 1 OR Telegram @soalanpercubaanspm M,x25_1 002x252 i M, = 0.01 mol dm? Total | 20 Scanned with CamScannerMark ber Answer ) | @ | f oxidation number for magnesium is +2 T 2. oxidation number for ferum is +3 1 oO 1. MgCl is magnesium chloride / magnesium klorida 1 2. Fe:Osis iron(ID) oxide / ferum (ID oksida 1 o [fedox/oxidation and reduction 1 Fy ial Y is copper T Zis zine 1 1 20 correct chemical formulae reactant & product {1m} | 2 balanced equation{ 1m] © | @ | hmeal Riss Calg T 2. metal S is M 1 Set 3. tron rutcorrode ~ C) 1 “tanked 1 5. Fe* is formed 1 enone © 7. Iron is oxidized 7) 1 a 2D, 8. Iron does not rust 1 9. Iron is less electropositive than S g. 1 10. Presence of OH 1 11, 0: + TO + 4e > 40H" Q 1 12, Metal S is oxidized & 1 max 8 TOTAL | 20 Scanned with CamScanner7. Question ‘Answer Mark Number 9, = Y: (Name of any metal situated above Cu in the 1 electrochemical series) = Z: (Name of any acid) 1 ‘Sample answer: Y: Magnesium // Zinc // Aluminium [Reject: Sodium // Potassium} 4 Hydrochloric acid // Sulphuric acid // Nitric acid 9 Accept: weak acid] Telegram @soalanpercubaanspm . equation: Coi ula of reactants and 1 p are 1 Sample ak) Me+2HCI— yg He wo o Gi) | Experiment 1 Average Rate of Reaction 10 = 3.0cm’s! 1 Experiment I o 1 Average Rate of Reaction = 30/2 Y emis! [With correct unit] j wad Git) . = Rate of reaction in Experiment I is higher than Exper 1 = The size of metal Y in Experiment | is smaller than ro) Experiment II// The total surface area of metal Y in Experiment I larger than Experiment IT >» 1 = Frequency of collision between hydrogen ions and atoms of Y in Experiment I is higher than in Experiment II i = Frequency of effective collision (between the particles) in Experiment I is higher than in Experiment IT 1 Scanned with CamScanner(b) ‘Temperature: 1, (20 — 100) em? of (0.1 ~ 1.0) mol dm? sodium thiosulphate solution is measured 2. Sodium thiopsulphate solution is then poured into a conical flask The initial temperature of sodium thiosulphate is recorded ‘The conical flask is placed on the top of a piece of white paper marked with “X” 5.0 cm of (0.1 ~ 1.0) mol dm? hydrochloric acid is measured ie hydrochloric acid is poured quickly into the conical flask spwatch is started immediately 8 nical flask is swirled throughout the experiment 9. taken for the mark “X” to disappear from sight is recor 10.The ex} ant is repeated using sodium thiosulphate solution solution at 3: wr and 50°C. 1, (25-50) cm’ of (0.1-1.0) mol wo lrochloric acid is measured and poured into a coni 2 About 5.0 g of zine granules is weigh. A 3. A burette is filled with water and inverted ig Mpasin containing water %, 4 The water level in the burette is adjusted to 50 cl 7 The granulated zinc is added into the conical flask Immediately the conical flask is closed and connect it M OR delivery tube to the burette 7. The stopwatch is started. 8. The conical flask is shaken steadily. 9. 1 Record volume of hydrogen gas every 30 seconds interval. 0.The experiment is repeated by adding 5 em? of copper(I) sulphate solution into the reactants mixture. ol OR TOTAL Scanned with CamScanner10 10. | (@) | -Cleaning agent Y is more effective than cleaning agent X T Cleaning agent Y do not form scum in hard water , so it can remove oily stain 1 Cleaning agent X form scum in hard water and cannot remove oily stain 1 Calcium ions and magnesium ions in hard water react with cleaning agent X to form 1 Qecumivtite precipitate ) bronze OR Pobrass 1 Zs Qebronze 1 . J alloy PI // | Brass / alloy Q./| is harder than it cooper / pure metal 1 . ence of different sizes of stanum/zinc atoms disrupts the ordely arre it of atoms in cooper / pure metal © These 1e atomic layers of atoms in alloys is harder to slide over one br another c yY ii contain same si ms. © The layer of eee pure metal easily slide one another because it @ S In? 1 kg weight Orie Ake ball uli compel a EE blok kupl Om diagram | 1 yelled diagram | 1 Procedure: 1. A steel ball is attached to the surface of the copper block using cello 1 2. A weight with a mass of | kg is hung at a height of 50 cm above the ste 1 3. The weight is then dropped on the steel ball, 1 4, The diameter of the dent on the surface of the copper block is measured and 1 recorded. 1 5. Steps 1 to 4 are repeated for two times at different places on the copper block & Tecan Goan ng eliscursnaewOIMcEoeucaS. | copper block. Scanned with CamScanner11 @ Type of ‘Diameter of dent (em) | Average diameter of dent (em) material 7)? 73 Jenis bahan Copper a fa | w= alem@aal Ta i 3 a bebah 7b : 2, . Conclusion [Bronze / alloy Ke) 3s / alloy Ql is harder than coppery 7 Telegram @soalanpefcibaanspm ‘TOTAL | 20 Scanned with CamScannerPEPERIKSAAN PERCUBAAN SPM PERLIS TAHUN 2020 SP. SKEMA KIMIA KERTAS 3 (4541/3) Qu Rubric Score num 1@) cord all readings accurately with unit.) 3 rt Set Il: 16 Set II: 2.4 v4) [Able to record all re ura eo without unit, oF able to record any two readings 2 correctly with unit, oF ms all readings accurately in two decimal places without unit.) Sample answer : Set 1: 0.7/0.70 Set IT: 1.6 / 1.60 Set II: 2.4/2.40 [Able to record at least one reading correctly.] > 1 No response or wrong response ¥e) 0 ‘Question Rubric Score number 1(b) _ | {Able to state the three variables correctly.) 3 Sample answer : Responding variable : Potential difference//Voltmeter reading “» Fixed variable : Type of electrolyte//Metal X Able to state any two variables correctly. 2 [Able to state any one variable correctly.) 1 No response or wrong response o Scanned with CamScanner‘Question Rubric Score number YEA _| tabieto state te relationship berween the manipulated variable and the responding variable | 3 “Ee and state the direction correctly] Q Sample answer urther the distance between two metas in electrochemical series, the voltmeter reading comes higher. Able fo ute the relationship between the manipulated variable and the responding variable | 2 without a 1 Sample ans “The distance bet metals in electrochemical series influences changes the voltmeter reading. O Sample answer : S Different metal has a different voltage) No response or wrong response 9 % 0 ‘Question Rubric uo Score ‘number g * 1(@) | {Able to give the operational definition forthe construction of el mical series 3 correctly with the following aspects (1) What should be done ) (ID) What should be observed > Sample answer ; Telegram @soalanpercubaanspm ‘When two different metals are dipped into an electrolyte, the voltmeter gives a ae reading shows that the further the distance between two metals. SD Able to give the operational definition for the construction of electrochemical series incompletely with any (one) aspects either (1) or (ID) Sample answer : ‘Two different metals are dipped into an electrolyte/the voltmeter gives a higher reading shows thatthe further the distance between two metals Able to give an idea of operational definition for the construction of electrochemical series.) | 1 Sample answer : The voltmeter gives a reading No response or wrong response 0 Scanned with CamScannerRubric Score 1 (e) (Gp tAble to arrange the four metals correctly. | 1 symbol) wer t magnesium, (accept symbol [Able to ota ‘metals in sequence correctly.] Sample answer : X, ti Tin, zine, bs [Able to arrange any two metals We correctly] (accept symbol) Sample answer : S Stn Fan De sn, mapeiom % i % Question number Q Rubric “Oy ‘Score 1 ani) Sample answer : The size of metal X increases//hicker. [Able to state the size change of metal X less correctly. | Sample answer : ‘The size of metal X changes [Able to give an idea of any observation] Sample answer : No response or wrong response Scanned with CamScannerQuestion Rubric ‘Score number 1 (9G) _ | [Able to make inference correctly. 3 “ Sample answer : ;pper(Il) ion receive electron/discharge to form copper atom. iin se corey] 2 Sample aor ‘atom formed. Copper(Il), Sample answer : Magnesium dissolved No response or wrong response o Question wit Score number 1 (Citi) | [Able to state the relationship between the change in the si strode with time 3 correetly.] Telegram @soalanpercubaanspm ra santa Sar mere gucci %, és correctly. [Able to state the relationship between the change in the size of X electrode with Ge 5 2 Sample answer : Telegram @soalanpercubaanspm The size of X electrode directly proportional with time. [Able to give an idea of size of X electrode.) 1 Sample answer : The size of X electrode changes. No response or wrong response 0 Scanned with CamScannerQuestion Rubric ‘Score [Able to predict the voltage produced accurately.] Telegram @soalanpercubaanspm Qeowiee twp te voage produced es ncurtely. 2 Sample 18 [Any value betw Answer : Less than 2.4 No response or wrong response Oo > 0 Question Rubric 2, Score number 1(h) | [Able to achieve all the following aspects correctly = (i). Balance the half equation at zinc electrode. ii) Balance the half equation at metal X electrode. (ii) Write the overall ionic equation.] Answer: At zine electrode : Zn —» Zn®* + 2e At metal X electrode : X* + 2e—+ X Overall ionic equation : Zn + X2*—+ Zn?" +X [Able to achieve any two aspects correctly. [Able to achieve any one aspect correctly.] 1 No response or wrong response 0 Scanned with CamScannerQuestion Rubric ‘Score number wy, [Able to classify all the four metals correctly.) 3 Answer : dL which are more Metal which are Tess oo than copper clectropositive than copper Tr Silver Tin Gold [Able to clas three metals correctly.) 2 [Able to classify any Is correctly. //Classify inversely 1 0 No response or wrong respons @ Scanned with CamScannerQuestion Rubric ‘Score number 4, [Able to give the problem statement correctly,] 3 ple answer : Telegram @soalanpercubaanspm yw does when iron in contact with magnesium, rusting of iron inhibit? / jowdoes when iron in contact with copper, rusting of iron increase? // wi 1¢ effect of other metal on the rusting of iron? [Able to gi roblem statement less correctly] 2 Sample answer » To investigate the rusting of iron when in contact with more electropositive metal. / To investigate the ef ting of iron when in contact with less electropositive metal. [Able to give an idea of the prdblenp-statement.] 1 Sample answer : @ Does rusting occurs when iron in suit bape metal? Question Rubrie ‘Score number 206) 3 [Able to state all the variables correctly.) co api sarer: O Manpulated arable 9. ‘Magnesium and copper // Type of metals in contact with iron, Rusting of iron // formation of blue spot/colouration. Fixed variable {ron nails //jelly/agar-agar solution // electrolyte // temperature // potassium hexacyanoferrate(III) solution. [Able co state any two variables correctly.] 2 [Able to state any one variable correctly.] 1 No response or wrong response 0 Scanned with CamScannerQuestion number Rubric ‘Score 20) a. [Able to state the relationship between the manipulated variable and the responding variable correctly and with direction.| ‘Sample answer : en iron in contact with magnesium, rusting of iron inhibit // en iron in contact with copper, rusting of iron increase oF [Able relationship between the manipulated variable and the responding variable correctly and/sejthout direction. ] rusting occurs. Sample anever ‘When iron in contfep%yith, metal, iron does not rust. // When iron in contact with metal, [Abe tov nie of he pos Sample answer : The presence of metal effect rusting Ay No response or wrong response 0 ‘Question number ‘Score 2@ [Able to list all the materials and apparatus correctly] A ‘Sample answer Q ect cai, gli ion, exper ioen wn hh hexacyanoferrate(II) and phenolphthalein indicator, sand paper. Apparatus : Test-tubes/boiling tubes, test tube rack 9. [Able to give a list the following materials and apparatus. Sample answer Materials : Iron nail, magnesium, copper, jelly solution, potassium hexacyanoferrate (IID). Apparatus : Test-tubes//boiling tubes, test tube rack. [Able to give an idea of materials and apparatus.] Sample answer Materials Iron nail, magnesium/copper. Apparatus : Boiling tube / beaker / any suitable container. No response or wrong response Scanned with CamScanner(Question Rubric ‘Score number [Able to state all steps in the procedure correctly.] 3 ple answer : Jon nails, magnesium ribbon and copper strip are cleaned with sand paper. Both iron nails is coiled with different metal. he icon nails are put into two different test tubes. 4. (hgMnixture of jelly solutions, potassium hexacyanoferrate (II1) and phenolphthalein i is poured into the test tubes. 3. The 2 left aside for one day. 6. Any ol are recorded. [Able to state the ho and 6) 2 aur wamsa ana 7 Oo 1 No response or wrong response @ Ds 0 ‘Question Rubi ‘Score number 2() | [Able to tabulate the data with the following aspects :] 2 1, Correct titles Os 2. Complete list of metals ys Sample answer : Q Pairs of metal Observation Tron + magnesium Iron + copper Telegram @soalanpercubaanspm As [Able to tabulate the data but incomplete.] ‘Sample answer : Tron + magnesium Iron + copper No response or wrong response Scanned with CamScanner