500700
Department of Petroleum Engineering
DETERMINATION OF RESIDUAL GAS SATURATION AND
GAS-WATER RELATIVE PERMEABILITY IN
WATER-DRIVEN GAS RESERVOIRS
Henny Mulyadi
‘This thesis is presented as part of the requirements for the award of the degree of
Doctor of Philosophy
of the
Curtin University of Technology
July 2002ABSTRACT
The research on Determination of Residual Gas Saturation and Gas-Water Relative
Permeability in Water-Driven Gus Reservoirs is divided into four stages: literature
research, core-flooding experiments, development and application of a new
technique for reservoir simulation. Overall, all stages have been completed
successfully with several breakthroughs in the areas of Special Core Analysis
(SCAL), reservoir engineering and reservoir simulation technology.
Initially, a literature research was conducted to survey all available core analysis
techniques and their individual characteristics. The survey revealed that there are
several core analysis techniques for measuring residual gas saturation (Sgr) and
hence, the lack of a commonly agreed method for measuring Sgr. The often-used
core analysis techniques are steady-state displacement, co-current imbibition,
centrifuge and counter-current imbibition. In this research, all centrifuge tests were
y of replacing gas
with a ‘model fluid’ to minimise errors due to gas compressibility. Furthermore, Sgr
performed with a decane-brine system to investigate the possil
is a function of testing temperature and pressure, types of fluid, wettability, viscosity,
flow rate and overburden pressure. Consequently, large uncertainties are associated
with measured Sgr and the recoverable gas reserves for water-driven gas reservoirs.
Due to the lack of a common method for measuring Sgr, the first important step is to
clarify which is the most representative core analysis technique for measuring Sgr. In
Stage 2 of the research, core analysis experiments were performed with uniform
fluids and ambient temperature. In the core flooding experiments, four different sets
of core plugs from various gas reservoirs were selected to cover a wide range of
permeability and porosity. Finally, all measured Sgr from the various common core
analysis techniques were compared. The evidence suggested that steady-state
displacement and co-current imbibition tests are the most representative techniques
for reservoir application. Steady-state displacement also yields the complete relative
permeability (RP) data but it requires long stabilisation times and is costly.In the third stage, a new technique was successfully developed for determining both
Sgr and gas-water RP data. The new method consists of an initial co-current
imbibition experiment followed by the newly developed correlation (Mulyadi, Amin
and Kennaird correlation). Co-current imbibition is used to measure the end-point
data, for example, initial water saturation (Swi) and Sgr. The MAK correlation was
developed to extend the co-current imbibition test by generating gas-water relative
permeability data. Unlike previous correlations, MAK correlation is unique because
it incorporates and exhibits the formation properties, reservoir conditions and fluid
properties (for example, permeability, porosity, interfacial tension and gas density) to
generate the RP curves. The accuracy and applicability of MAK correlations were
investigated with several sets of gas-water RP data measured by steady-state
displacement tests for various gas reservoirs in Australia, New Zealand, South-East
Asia and U.S.A. The MAK correlation proved superior to previously developed
correlations to demonstrate its robustness.
‘The purpose of the final stage was to aggressively pursue the possibility of advancing
the application of the new technique beyond special core analysis (SCAL). As MAK
correlation is successful in describing gas water RP in a core plug scale, it is possible
to extend its application to describe the overall reservoir flow behaviour. This
investigation was achieved by implementing MAK correlation into a 3-D reservoir
simulator (MoReS) and performing simulations on a producing field. The simulation
studies were divided into two categories: pre and post upscaled application.
‘The case studies were performed on two X gas-condensate fields: X1 (post upscaled)
and X2 (pre upscaled) fields. Since MAK correlation was developed for gas-water
systems, several modifications were required to account for the effect of the
additional phase (oil) on gas and water RP in gas-condensate systems. In this case,
oil RP data was generated by Corey’s equations. Five different case studies were
performed to investigate the individual and combination effect of implementing
MAK correlation, alternative Swi and Sgr correlations and refining porosity and
permeability clustering. Moreover, MAK correlation has proven to be effective as an
approximation technique for cell by cell simulation to advance reservoir simulation
technology.BIOGRAPHY OF THE AUTHOR
Henny Mulyadi completed a Bachelor of Engineering (Chemical) degree with
Honours at Curtin University of Technology between 1995 and 1998. As an
undergraduate, she received several awards including 1" Prize Asia-Pacific Society
of Petroleum (SPE) Undergraduate Research and 2"! Prize Intemational SPE
Undergraduate Research. Furthermore, she was also awarded 1" and 2 Prize for
Asia Pacific and Intemational SPE Doctorate Research respectively. All awards are
attached in Appendix A.
She received a scholarship to conduct this research for her Doctorate of Philosophy
at Curtin University of Technology. The research is sponsored by ExxonMobil,
Chevron, Core Laboratories, Fletcher Challenge (NZ) and Woodside. She is
currently working as a Reservoir Engineer at ChevronTexaco Australia Pty Ltd.
Papers written in support of this thesis are given below and details of each
publication are included in Appendix A:
SPE #71523: Practical Approach to Determine Residual Gas Saturation and Gas-
water Relative Permeability In Water-Driven Gas Reservoir.
SPE #64710: Measurement of Residual Gas Saturation in Water-Driven Gas
Reservoir ~ Comparison of the Various Core Analysis Techniques.
MH#576H: Sequestration of Supercritical CO2 in Deep Brine Formation.
SPE# 68733: A New Approach to 3D Reservoir Simulation — Effect of Interfacial
Tension on Improving Oil Recovery.ACKNOWLEDGEMENTS
I would like to express my appreciation by thanking the following people and
organisations for their generous support and advice during this research:
My supervisor, Professor Robert Amin and Anthony F. Kennaird for their
continuous support and generosity;
Professor Ashok Khurana for initiating this research;
Professor A. Firoozabadi, Dr T. Tang and Ross Jahanian at the Reservoir
Engineering Research Institute (RERI) in California, U.S.A;
Professor Raj Rajeswaran and all staff at the Petroleum Engineering
Department of Curtin University of Technology.
Special thanks to the following sponsoring companies and their respective
representatives;
.
Woodside — Goos G. Bakker, David Steer and Dr Tom L. Mason;
Core Laboratories — Anthony F. Kennaird;
West Australian Petroleum (WAPET) — Erik Van Der Steen and Danny Van
Nispen;
Fletcher Challenge — Ian. Palmer; and
ExxonMobil.
‘Their detailed comments, advice, compliments and criticisms have added significant
value to the completeness of this research. Finally, I would like to acknowledge my
family for their tremendous support and understanding which is received with the
warmest thoughts and respect at all times.NOMENCLATURE
ABBREVIATIONS
D Darcy
FZI Flow-zone-indicator
Gp ‘Cumulative gas production
HU Hydraulic Unit
IFT Interfacial tension
Ka ‘Absolute gas permeability
Korw _Oil relative permeability in the presence of water
Krg Gas relative permeability
Krog _Oil relative permeability in the presence of gas
Krw _ Water relative permeability
Np Cumulative oil production
Pe Capilllary pressure
PV Pore volume
Q Production rate
RP Relative permeability
RQI Reservoir-quality-index
Sg Gas saturation
Sgi Initial gas saturation
Ser Residual gas saturation
Sorg Residual oil saturation in the presence of gas
Sorw Residual oil saturation in the presence of water
Sw Water saturation
Swi Initial water saturation
Wp Cumulative water production
SUBSCRIPTS
e Effective
g Gas
° Oil
r Residual
w WaterTABLE OF CONTENTS
ABSTRACT
BIOGRAPHY OF THE AUTHOR
ACKNOWLEDGEMENTS
NOMENCLATURE
ABBREVIATIONS
‘SUBSCRIPTS
LIST OF APPENDICES
LIST OF TABLES
LIST OF FIGURES
CHAPTER 1: INTRODUCTION
1.1 Background
1.2 Motivation and significance of this work
1.2.1 Motivation
1.2.2 Objectives
1.2.3 Significance
1.3 Thesis Outline
CHAPTER 2: HisTORICAL OVERVIEW
2.1 Pertinent Research
2.2 Available Core Analysis Techniques
2.2.1 Steady-State Displacement
2.2.2 Centrifuge Technique
2.2.3. Co Current Imbibition
2.2.4 Counter Current Imbibition
2.3 Factors Influencing Sgr Measurements
2.3.1 Effect of Core Dimensions
vw
ey a
ee ce
10
u
13
132.3.2 Effect of Porosity and Permeability 14
2.3.3 The Effect of Wettability 15,
2.3.4 Effect of Overburden Pressure 15
2.3.5 Effect of Temperature 16
2.3.6 — Effect of Interfacial Tension and Density 17
2.3.7 Effect of Viscosity 17
2.3.8 Effect of Flow Rates 19
2.3.9 Effect of Pressure Gradient 2
2.3.10 The Effect of Gas Type (Compositions) 21
CHAPTER 3: EXPERIMENTAL TESTS 24
3.1 Objectives 25
3.2. Rock and Fluid Properties 25
3.3. Core Plugs and Composite Core Arrangement 26
33.1 Hydraulic Units (HU) 26
3.3.2 Huppler Calculations 21
3.4 Steady-State Displacement 28
3.4.1 Set-Up 28
33.2 Procedures 28
3.4 Co-current Imbibition 31
34.1 Set-Up 31
3.4.2 Procedures 31
3.5 Counter-Current Imbibition 31
35.1 Set-Up 31
3.5.2 Procedures 32
3.6 Decane-Brine Centrifuge 33
3.6.1 Set-Up 33
3.6.2 Procedures 34
3.7 Discussions 36
CHAPTER 4: THE NEW PRACTICAL DETERMINATION OF SGR AND GAS-WATER
RELATIVE PERMEABILITY 414.1 Proposed Strategy 41
4.2 New Technique 42
43 Laboratory Experiments 43
43.1 Co-current Imbibition 43
432 Interfacial Tension (IFT) 43
44 Generating Gas-Water Relative Permeability 44
(CHAPTER 5: COMPARISON BETWEEN NEW AND STEADY-STATE DISPLACEMENT
TECHNIQUES 46
5.1 Case Study Source 46
5.2 Current Experimental Study 47
5.3. Generic Data 49
5.3.1 SPE Publications 49
5.4 Discussions 33
CHAPTER 6: COMPARISON BETWEEN NEW AND PREVIOUS CORRELATIONS 54
6.1 Other Correlations
6.2 Discussions 56
g
CHAPTER 7: RELATIONSHIPS BETWEEN PETROPHYSICAL PROPERTIES AND SGR
60
7.1 Background 60
7.2. Sgr Correlations 60
7.3 Discussions 61
(CHAPTER 8: APPLYING MAK CORRELATIONS TO NON-HYDROCARBON-BRINE.
SysTEeMS 67
8.1 Background 67
8.2 MAK Correlations at Reservoir Conditions 67
8.3 MAK Correlation for Non-Hydrocarbon-Brine Systems
8.3.1 Background
38
va84
83.2 Experimental Set-Up
Discussions
CHAPTER 9: APPLICATION OF THE NEW TECHNIQUE FOR RESERVOIR
91
92
9.4
95
9.6
SIMULATION
Background
MoReS Simulator
General Application
9.4.1 — Implementation Options
94.2 Cell-By-Cell
9.4.3 Clustering of Cells
Possible discontinuity
Automating MAK Correlations in Reservoir Simulator (MoReS)
69
10
2
3
14
14
14
15
78
82
CHAPTER 10: APPLYING MAK CORRELATIONS TO Gas CONDENSATE SYSTEMS
10.1
10.2
103
10.5
10.6
Objectives
Original Field Model Assumptions
10.2.1 No Condensate Dropout in Reservoir
10.2.2 Formation Properties
10.2.3 Relative Permeability
APPLYING MAK Correlations FoR GAS-CONDENSATESsystems
10.3.1 Assumptions
10.3.2 Modification of Krw for Three-Phase Systems
10.3.3 Modifying Krg for Three-Phase Systems
Reservoir simulation with MAK correlations
Post-Upscaled Application
10.6.1 General Note
10.6.2 Case Study One
10.6.3 Case Study Two
10.6.4 Case Study Three
10.6.5 Case Study Four
88
88
89
89
90
1
92
92
93
94
96
98
98
99
109
107
11610.7 Pre-Upscaled Application
CHAPTER 11: ConcLusions & RECOMMENDATIONS
11.1 Conclusions and Key Findings
11.1.1 Summary of Research
11.12 Key Findings
11.2 Recommendations
REFERENCES
125
133
133
133
134
139
140LIST OF APPENDICES
Appendix A
Appendix B
Appendix C
Appendix D
AWARDS & PUBLICATIONS
‘(CORE FLOODING EXPERIMENTAL RESULTS
COMPARISON OF GAS-WATER RP MODELLING BETWEEN MAK
CORRELATION AND STEADY STATE TEST
PERMEABILITY AND POROSITY CLUSTERING CALCULATIONS
xiLIST OF TABLES
Table 2.1
Table 3.1
Table 3.2
‘Table 3.3
Table 3.4
Table 5.1
Table 8.1
Table 8.2
Table 83
Table 8.4
Table 9.1
Table 9.2
Table 9.3
Table 9.4
Table 9.5
Table 10.1
Table 10.2
Table 10.3
‘Table 10.4
‘Table 10.5
Table 10.6
‘Table 10.7
Table 10.8
ADVANTAGES AND DISADVANTAGES OF THE VARIOUS CORE ANALYSIS
‘TECHNIQUES
CORE PROPERTIES
‘TesTED ComPostre CORE PROPERTIES
EFFECT OF TYPE OF IMBIBING FLUID ON MEASURED SGR BY COUNTER
CURRENT IMBIBITION
SUMMARY OF CORE ANALYSIS EXPERIMENTS
INTERFACIAL TENSION (IFT) MEASUREMENTS FOR BRINE-METHANE
SYSTEM AT AMBIENT CONDITIONS
CORE PLUG PROPERTIES
INTERFACIAL TENSION MEASUREMENTS AT RESERVOIR CONDITIONS
GAS DENSITY MEASUREMENTS AT RESERVOIR CONDITIONS
GAS VISCOSITY MEASUREMENTS AT RESERVOIR CONDITIONS
MEMORY STORAGE REQUIREMENT FOR CELL-BY-CELL,
IMPLEMENTATION
ORIGINAL PERMEABILITY CLASS FOR X.
PERMEABILITY CLASSES
POROSITY CLASSES
‘PERMEABILITY AND POROSITY MATRICES
CALCULATED CORRELATIONS’ EXPONENTS FROM ESTIMATED PORE SIZE
DISTRIBUTION (A)
SUMMARY AND COMPARISON FOR CASE STUDY ONE
‘SUMMARY OF RESULTS FoR CASE STUDY TWO.
SUMMARY OF RESULTS FOR CASE STUDY THREE
PERMEABILITY CLUSTERING SCHEMES
POROSITY CLUSTERING SCHEMES
‘SUMMARY OF RESULTS FROM CASE STUDY FOUR
SUMMARY OF RESULTS FROM CASE STUDY FIVE,
xtLIST OF FIGURES
Figure 3.1
Figure 3.2
Figure 3.3
Figure 3.4
Figure 5.1
Figure 5.2
Figure 5.3
Figure 5.4
Figure 5.5
Figure 5.6
Figure5.7
Figure 5.8
Figure 6.1
Figure 6.2
FIGURE 6.3
Figure 6.4
Figure 7.1
Figure 7.2
Figure 73
Figure7.4
STEADY STATE DISPLACEMENT SET UP
COUNTER CURRENT IMBIBITION
DECANE-BRINE CENTRIFUGE SYSTEM
COMPARISON OF MEASURED SGR BY THE VARIOUS CORE ANALYSIS
TECHNIQUES
COMPARISON OF GAS-WATER RP DATA BETWEEN STEADY-STATE
EXPERIMENTAL AND MAK CORRELATIONS (CASE 1)
COMPARISON OF GAS-WATER RP DATA BETWEEN STEADY-STATE
EXPERIMENTAL AND MAK CORRELATIONS (CASE 2)
COMPARISON OF GAS-WATER RP DATA BETWEEN STEADY-STATE
EXPERIMENTAL AND MAK CORRELATIONS (CASE 3)
COMPARISON OF GAS-WATER RP DATA BETWEEN STEADY-STATE
EXPERIMENTAL AND MAK CORRELATIONS (CASE 4)
COMPARISON OF GAS-WATER RP DATA BETWEEN STEADY-STATE
EXPERIMENTAL AND MAK CORRELATIONS (CASE 5)
‘COMPARISON OF GAS-WATER RP DATA BETWEEN STEADY-STATE
EXPERIMENTAL AND MAK CORRELATIONS (CASE 6)
COMPARISON OF GAS-WATER RP DATA BETWEEN STEADY-STATE
EXPERIMENTAL AND MAK CORRELATIONS (CASE 7)
COMPARISON OF GAS-WATER RP DATA BETWEEN STEADY-STATE
EXPERIMENTAL AND MAK CORRELATIONS (CASE 8)
COMPARISON BETWEEN VARIOUS CORRELATIONS AND LABORATORY
STEADY-STATE DISPLACEMENT TESTS (CASE 1)
COMPARISON BETWEEN VARIOUS CORRELATIONS AND LABORATORY
‘STEADY-STATE DISPLACEMENT TESTS (CASE 2)
COMPARISON BETWEEN VARIOUS CORRELATIONS AND LABORATORY
STEADY-STATE DISPLACEMENT TESTS (CASE 3)
COMPARISON BETWEEN VARIOUS CORRELATIONS AND LABORATORY
STEADY-STATE DISPLACEMENT TESTS (CASE 4)
RESIDUAL GAS SATURATION VS WATER PERMEABILITY
INITIAL WATER SATURATION AS A FUNCTION OF AIR PERMEABILITY
RESIDUAL GAS SATURATION AS A FUNCTION OF ABSOLUTE AIR
PERMEABILITY
‘RESIDUAL GAS SATURATION AS A FUNCTION OF INITIAL GAS SATURATION
xhFigure 7.5
Figure 7.6
Figure 8.1
Figure 8.2
Figure 9.1
Figure 9.2
Figure 93
Figure 9.4
Figure 9.5
Figure 9.64
Figure 9.68
Figure 9.7
Figure 10.1
Figure 10.2
Figure 103
Figure 10.4
Figure 10.5
Figure 10.64,
Figure 10.68
Figure 10.6C
Figure 10.6D
RESIDUAL GAS SATURATION AS A FUNCTION OF POROSITY
EFFECT OF FLOW RATE ON RESIDUAL GAS SATURATION
SIMULATION WITH MAK CORRELATIONS AT VARIOUS RESERVOIR
Conpitions
COMPARISON BETWEEN THE EXPERIMENTAL AND SIMULATED
SUPERCRITICAL CO2-WATER RPC AT VARIOUS INTERFACIAL-TENSION
SCENARIOS
RATE OF CHANGE OF WATER RELATIVE PERMEABILITY WITH RESPECT
TO AIR PERMEABILITY (DKRW/DKA) WITH CONSTANT POROSITY (PHI)
AND INITIAL WATER SATURATION (SW1)
RATE OF CHANGE OF WATER RELATIVE PERMEABILITY WITH RESPECT
‘TO POROSITY (PHI) AT CONSTANT INITIAL WATER SATURATION (SW!)
RATE OF GAS RELATIVE PERMEABILITY CHANGES WITH RESPECT TO
PERMEABILITY (KA) WITH CONSTANT INITIAL WATER SATURATION (SWI)
OVERVIEW OF COMPLETE ROUTINES FOR IMPLEMENTING MAK
‘CORRELATIONS IN MORES
DETERMINATION OF MAK CORRELATIONS EXPONENTS
GENERATING WATER-OIL (WOIJ) RELATIVE PERMEABILITY DATA
(GENERATING WATER-OIL (WOIJ) RELATIVE PERMEABILITY DATA (CONT)
GENERATING GAS-OIL (GOI4) RELATIVE PERMEABILITY DATA
(COMPARISON OF VARIOUS CORRELATIONS IN MORES TO ESTIMATE SCG,
SORW AND SORG
WATER OIL SysTEMS
MOVABLE OM. SATURATION IN WATER-OIL SYSTEMS
Gas OIL Systems
MOVABLE OIL SATURATION IN GaS-O1L SYSTEMS DISTRIBUTION (4)
(CAPILLARY PRESSURE (PC) VS WATER SATURATION (SW) FOR 0