KANHA MAKHAN MILLENNIUM SCHOOL

UT-2 EXAMINATION (2021-22)

SUBJECT- CHEMISTRY (043)
CLASS – 12
Time: 2 Hours M.M-50
General Instructions:-
 All questions are compulsory.
 There are five sections in Paper.
 Section A contains One Word Question (1 to 10) and Fill in the Blanks (11 to 20).Each Question
Carry One Mark.
 Section B contains Match the column and One Case Study Based Question. Each Question Carry
One Mark.
 Section C Contains two question of two marks each.
 Section D Contains two question of three marks each.
 Section E contains two questions. Each question carries five marks.
 There is no overall choice. Only Internal Choice is there.
______________________________________________________________________________________
Section – A
One word question:-
1) What type of aldehyde undergo Aldol Condensation?
2) Rearrange the following compounds in the increasing order of their boiling points
CH3 — CHO, CH3 — CH2 — OH, CH3 — CH2— CH3
3) Name the reagents used in the following reactions :

4) What is Tollen’s reagent?

5) Write the structure of the product formed in the following reaction :

6) Write IUPAC name of the complex [Co(en)2(H20)(CN)]2+

7) Write down the formula of: Tetraamineaquachloridocobalt(III) chloride.
8) What are Strong field Ligands?
9) Complete the following reactions:
(i) CH3CH2NH2 + CHCl3 + alc. KOH →
10) Why is ethylamine soluble in water whereas aniline is not?
Fill in the Blanks:-
11) The ligand NH2CH2CH2NH2 is ______________________ ligand.
12) A coordinate bond is formed by an arrow from ________________to ________________.
13) The oxidation state of Fe in [Fe(CN)6]3- ___________________
14) Cannizaro’s reaction is not given by _______________.
15) Pentan-2-one can be distinguished from Pentan-3-one by _______________________ test.
16) The pKa of acetic acid is ________________________ than that of phenol.
17) ____________ acid obtained from red ants gives silver mirror with Tollen’s reagent test.
18) –OCH3 _________________ the basic character of amines.
19) __________________ don’t react with Hinsberg Reagent.
20) CH3CH2NH2 has ___________________ boiling point than (CH3)2NH.
Section – B
21) Match the Column:-
Column A Column B
a) Cinnamaldehyde Rhodium
b) Wilkanson Catalyst 3-Phenylprop-2-enal
c) Acetophenone Cobalt
d) Vitamin B12 Zwitter Ion
e) Sulphanilic Acid 1-Phenylethanone

22) Case Study :-

Amines are classified as primary, secondary and tertiary amines. Primary amines cannot be obtained by
ammonolysis of alkyl halide because we will get mixture of 1°, 2° and 3° amines. Cyanides on reduction gives
primary amines where as isocyanides on reduction gives secondary amines. Nitro Compounds on reduction also
gives primary amines. Primary amines react with CHCl3 and KOH to form foul smelling isocyanide. They react
with HNO3 and liberate N2 amine form yellow oily compounds with HNO2 and salt formed with C6H5SO2Cl, is
insoluble in KOH. 3° amines form salt soluble in water with HNO2 but does not react with C6H5SO2Cl .

(i) Why is an alkylamine more basic than ammonia?

(ii) Why Aniline does not undergo Friedel-Crafts reaction.
(iii) What is Hinsberg reagent?
(iv) Write IUPAC name of the following compound: (CH3CH2)2NCH3
(v) How may methyl bromide be preferentially converted to methyl isocyanide?

Section-C
23) Write the equations involved in the following reactions:
(i) Wolff-Kishner Reduction
(ii)Etard reaction
OR
Write the reactions involved in the following reactions:
(i) Clemmensenreduction
(ii) Cannizzaro reaction
3+
24) Explain why [Co(NH3)6] is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex.
(At.no. Co = 27, Ni = 28)
 Section-D
25) Predict the products of the following reactions:

26) In the following cases rearrange the compounds as directed :

(i) In an increasing order of basic strength :
C6H5NH2, C6H5 N(CH3)2, (C2H5)2NH and CH3NH2
(ii) In a decreasing order of basic strength :
Aniline, p-nitroaniline and p-toluidine
(iii) In an increasing order of pKb values :
C2H5NH2, C6H5 NHCH3, (C2H5)2NH and C6H5NH2
OR
State reasons for the following:
(i) pKb value for aniline is more than that for methylamine.
(ii) Ethylamine is soluble in water whereas aniline is not soluble in water.
(iii) Primary amines have higher boiling points than tertiary amines.
Section-E
27)(a) Give chemical tests to distinguish between
(i) Propanal and Propanone, (ii) Benzaldehyde and Acetophenone.
(b) How would you obtain
(i) But-2-enal from Ethanal, (ii) Butanoic acid from Butanol,
(iii) Benzoic acid from Ethylbenzene?
OR

(a) Give chemical tests to distinguish between the following pairs of compounds :
(i) Ethanal and Propanal (ii) Phenol and Benzoic acid
(b) How will you bring about the following conversions?
(i) Benzoic acid to benzaldehyde (ii) Ethanal to but-2-enal (iii) Propanone to propene
Give complete reaction in each case

28) (a) For the complex [Fe(CN)6]3- write the hybridization type, magnetic character and spin nature of the
complex. (At. number: Fe = 26).
(b) Write the IUPAC name of the following:
(i) [Co(NH3)6]Cl3
(ii) [NiCl4]2-