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SAFETY DATA SHEET

1. Identification
Product identifier Desi-Can
Other means of identification
SDS number 00410
Part Number 803-546
Recommended use Absorbent
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Supplier
Company name LECO Corporation
Address 3000 Lakeview Avenue
St. Joseph, MI 49085
United States
Telephone 269-983-5531
Website www.leco.com
E-mail info@leco.com
Emergency phone number Chemtrec: 800-424-9300
Chemtrec Int'l: 703-527-3887

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Sensitization, respiratory Category 1
Sensitization, skin Category 1
Carcinogenicity Category 1B
Reproductive toxicity Category 1B
Environmental hazards Hazardous to the aquatic environment, Category 2
long-term hazard
OSHA defined hazards Not classified.

Label elements

Signal word Danger


Hazard statement May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing
difficulties if inhaled. May damage fertility or the unborn child. May cause cancer. May damage
fertility. Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Do not handle until all safety precautions have been read and understood. Avoid breathing
dust/fume/gas/mist/vapors/spray. Use personal protective equipment as required. Avoid release
to the environment.
Response If on skin: Wash with plenty of water. If exposed or concerned: Get medical advice/attention.
Storage Store in a dry place. Store in a well-ventilated place. Keep container tightly closed.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

Material name: Desi-Can SDS US

SDS No. 00410 Version #: 02 Revision date: 08-25-2015 Issue date: 07-27-2015 1/8
3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Precipitated Silica 112926-00-8 50 - 100
(Silica-amorphous)
Cobalt dichloride 7646-79-9 <1
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Move to fresh air. Oxygen or artificial respiration if needed. Call a physician if symptoms develop or
persist.
Skin contact Wash off immediately with soap and plenty of water.
Eye contact Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Do not induce vomiting. Get medical attention if symptoms occur.
Most important Not available.
symptoms/effects, acute and
delayed
Indication of immediate Provide general supportive measures and treat symptomatically.
medical attention and special
treatment needed

5. Fire-fighting measures
Suitable extinguishing media Carbon dioxide (CO2). Powder. Water spray. Alcohol resistant foam.
Unsuitable extinguishing Not available.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters

6. Accidental release measures


Personal precautions, Ensure adequate ventilation. Wear appropriate protective equipment and clothing during clean-up.
protective equipment and
emergency procedures
Methods and materials for Sweep up or vacuum up spillage and collect in suitable container for disposal.
containment and cleaning up
Environmental precautions Avoid release to the environment.

7. Handling and storage


Precautions for safe handling Provide appropriate exhaust ventilation at places where dust is formed. Avoid breathing
dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Wear appropriate
personal protective equipment. Handle and open container with care. Wash thoroughly after
handling. Observe good industrial hygiene practices.
Conditions for safe storage, Store in tightly closed original container in a dry, cool and well-ventilated place.
including any incompatibilities

8. Exposure controls/personal protection


Occupational exposure limits
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components Type Value
Precipitated Silica TWA 0.8 mg/m3
(Silica-amorphous) (CAS
112926-00-8)
20 mppcf

Material name: Desi-Can SDS US

SDS No. 00410 Version #: 02 Revision date: 08-25-2015 Issue date: 07-27-2015 2/8
US. ACGIH Threshold Limit Values
Components Type Value
Cobalt dichloride (CAS TWA 0.02 mg/m3
7646-79-9)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Precipitated Silica TWA 6 mg/m3
(Silica-amorphous) (CAS
112926-00-8)
Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
Cobalt dichloride (CAS 15 µg/l Cobalt Urine *
7646-79-9)
1 µg/l Cobalt Blood *
* - For sampling details, please see the source document.
Appropriate engineering Provide adequate ventilation.
controls
Individual protection measures, such as personal protective equipment
Eye/face protection If contact is likely, safety glasses with side shields are recommended.

Skin protection
Hand protection Wear suitable gloves. Suitable gloves can be recommended by the glove supplier.
Other Not available.
Respiratory protection No personal respiratory protective equipment normally required. In case of insufficient ventilation,
wear suitable respiratory equipment.
Thermal hazards Not available.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Contaminated work clothing should not be allowed out of the
workplace.

9. Physical and chemical properties


Appearance
Physical state Solid.
Form Granular material in aluminum container.
Color Blue.
Odor Not available.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 3110 °F (1710 °C)
Initial boiling point and boiling 4046 °F (2230 °C)
range
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Material name: Desi-Can SDS US

SDS No. 00410 Version #: 02 Revision date: 08-25-2015 Issue date: 07-27-2015 3/8
Relative density Not available.
Solubility(ies)
Solubility (water) Insoluble
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 2.10 g/cm3
Explosive properties Not explosive.

10. Stability and reactivity


Reactivity Not available.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Not available.
reactions
Conditions to avoid Contact with incompatible materials. Moisture.
Incompatible materials Strong acids. Alkalis.
Hazardous decomposition Metal oxide fume.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation May cause allergy or asthma symptoms or breathing difficulties if inhaled. Prolonged inhalation
may be harmful.
Skin contact May cause an allergic skin reaction.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Not available.
Symptoms related to the Not available.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity May cause an allergic skin reaction.
Components Species Test Results
Cobalt dichloride (CAS 7646-79-9)
Acute
Oral
LD50 Guinea pig 55 mg/kg
Mouse 80 mg/kg
Rat 80 mg/kg
Precipitated Silica (Silica-amorphous) (CAS 112926-00-8)
Acute
Oral
LD50 Mouse > 15000 mg/kg
Rat > 22500 mg/kg

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Material name: Desi-Can SDS US

SDS No. 00410 Version #: 02 Revision date: 08-25-2015 Issue date: 07-27-2015 4/8
Skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity Not available.
Carcinogenicity
IARC Monographs. Overall Evaluation of Carcinogenicity
Precipitated Silica (Silica-amorphous) (CAS 3 Not classifiable as to carcinogenicity to humans.
112926-00-8)
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US. National Toxicology Program (NTP) Report on Carcinogens
Not available.
Reproductive toxicity May damage fertility.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not available.

12. Ecological information


Ecotoxicity
Components Species Test Results
Cobalt dichloride (CAS 7646-79-9)
Aquatic
Crustacea EC50 Water flea (Daphnia magna) 1.11 mg/l, 48 hours
Fish LC50 Rainbow trout,donaldson trout 0.569 - 3.474 mg/l, 96 hours
(Oncorhynchus mykiss)

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Not applicable.
products
Contaminated packaging Not applicable.

14. Transport information


DOT
UN number UN3077
UN proper shipping name Environmentally hazardous substances, solid, n.o.s.
Transport hazard class(es)
Class 9
Subsidiary risk -
Label(s) 9
Packing group III
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IATA
UN number UN3077
UN proper shipping name Environmentally hazardous substance, solid, n.o.s.
Transport hazard class(es)
Class 9
Subsidiary risk -
Material name: Desi-Can SDS US

SDS No. 00410 Version #: 02 Revision date: 08-25-2015 Issue date: 07-27-2015 5/8
Packing group III
ERG Code 9L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN3077
UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., MARINE POLLUTANT
Transport hazard class(es)
Class 9
Subsidiary risk -
Packing group III
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
DOT; IATA; IMDG

Marine pollutant

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Cobalt dichloride (CAS 7646-79-9) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

Material name: Desi-Can SDS US

SDS No. 00410 Version #: 02 Revision date: 08-25-2015 Issue date: 07-27-2015 6/8
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Cobalt dichloride (CAS 7646-79-9)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Cobalt dichloride (CAS 7646-79-9)
US. Massachusetts RTK - Substance List
Precipitated Silica (Silica-amorphous) (CAS 112926-00-8)
US. New Jersey Worker and Community Right-to-Know Act
Cobalt dichloride (CAS 7646-79-9)
Precipitated Silica (Silica-amorphous) (CAS 112926-00-8)
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
US. Rhode Island RTK
Cobalt dichloride (CAS 7646-79-9)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 07-27-2015
Revision date 08-25-2015
Version # 02
HMIS® ratings Health: 2*
Flammability: 0
Physical hazard: 0
"*" Represents a chronic hazard.
NFPA ratings Health: 2
Flammability: 0
Instability: 0

Material name: Desi-Can SDS US

SDS No. 00410 Version #: 02 Revision date: 08-25-2015 Issue date: 07-27-2015 7/8
Disclaimer Supplier cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user’s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information provided
in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date
of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not
be valid for such material used in combination with any other materials or in any process, unless
specified in the text.

Material name: Desi-Can SDS US

SDS No. 00410 Version #: 02 Revision date: 08-25-2015 Issue date: 07-27-2015 8/8

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