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U$V,N Cnc,e,N)

T2 P- U - S= V a
T T

U G + TS-PV
G U+ PV-TS
61 n T,P,
3-9-24
HelmAa0t Polnioa Mununum Punuple

T HtBath
F U-TS
S 0AuL+hot

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UFUCS, V, N)
oul aU dSt JU

0 7 U -P SoV avaS
S OV

s )()
T
S
V
tablu o Thoume dunani s n

S I U A U )

Jaunbca
+

dnka aubayptums eoch uwnuh o hundantntal

nmstuttune uall
SESCU,V, N) barald hy a

S S

S SS = StS
&S CU, V, N)
1k tianatu to
KnOe UugyaU tom
S(U-S(U+A)|

S
Su u S
S u)
SU)

VBU U
oal
SCU- U) +S(UTAu)
Hotal
S totl
. cl a l
SlU Sy
ngt talule i
Dysam s
SCU-AU)+S (U+0 U)>8S (U)
ScUsU V,) t S CU+A, V, N)AS (u,VA)
TndittunbtalkmA

o U
AU-O
imit

Leca coconl

na

Cn

BCD BFE Cooba0 unalaod


Staule pod E
ABHEG
The Jundamertal
D Eauatun J he erlAhe
w u o a upeior dongertt
n
2Peblacsrg BcD EF B BHF
A
b EF ana OscaIoy stolte buct
"goaaA_ Uota0LL
laba SAalt ty cendluon u n

S-U-V auubapoes
S CU+ ou,V# AV, N*Sfu-AU, v-Bv ,N)
2 S V, N)

OV2
ouvN
- (3
y uav
ue belou
Th ebh@hy aNac eneuuhene
tongert plana

U Iv,N
- NCv c l a Apenie huat

apociby muut be t*
b

70
sv
f FCT, V, N)
VU(S, V.N)
E 7

0
T
V CT
1
T 2U S-F
OS T

u(x)EU
T=P Ur)EF

P Du x -a UCP)
P
Hene - UCP

ene, ha aum
Op Ox

Hlmha bokential dS-o ds 2o


Snae T
S entuopy
Ond cenue b
endunum
V p o t cula

(E L0
O T
40, 70 a maxm
KT 70

Cyo
Cp-Cy = Tu Cp-y 70 CeCy
KT
COnaqutnu o elaluduly hun us han
Wali unatabilib that a
har diagom a
hall mank e has
Pt VI
hanaie r

Wat

Phaae dagram

attnt haat TAS


(

o' 40 X
TIP,N TN

TT

7Te R AL

T 1e
T
G

Va

Ltial poind)
/py

N
A
AVO ArD Lical point)
AS 0

T
T

T
-H L uP

M
Panamagmuttc M O
Fememogretie M7O

T7Te
F
T
+1

CL
LS T[s s T
Co e Ten and the lapyen

P
A
A
T

Aand A coeuat Grd B and B uoNiad


o0eyhe ine phase Nanaition JSguur

cT
Te-TA
the cerdbien o uuuubuum,u
knsus
thad A and A OL in thun thei chemiaA
patunlia) must be eaalua ueT.

A A

A duL C t Aond B an wy lea


LHS

= du= SdT + oP
W-UA

-S' vaP
Mg M' du

dP AS
A

=TAS

OT TA

uhat w hane mastiy

oldbL s nigatme (ouy nwswal


Bud awotn,

d 40
dT

TAL A S
S S - S g SwSu 70
A L0
Vwa 2Via
Tu ekatng uy
W poanle

waud atid
cOslane ha
T

lhaae diagam He
Saud
HP

NOumal
Supt
ud Ca

AS -O SoHP om
uid b eto
x

y o
Kzo

P RT
- To

T
T T Ty

untale
FeH
thu pact FEH rd that
Oun aim
to upla ca
Tuo cO enialing phaOA
t upuu
a u = - S A T+ ud P
A

du df

P2Pe Aunle ota

VCP)
P z l s . 3 pos
L unalatle
Cad
M 10 heosR blw
N Gn /
wieh

P
M

pgLenboD àlaus
C has O u L

P
CP,T)=
N

D ia nd a toint o phae Danubèn.


tow dou low ui dhe aoint pork D

DO une
phase
Coeuan

M
A

AS Sp So

as du OS
OM KFD
senLashn

D h o a adO phasa
had
uo
Rilatuen
hem Cbbs Duhun

VCP) a P o

O= ceoP

Ana OM KO
Abea D FK D ceauu ctb
on
onau
Ara
Houul
ua

a uwnatalle part
JAgthaum
ushch has
Cunen
Ounen an
an
uhtabli pat au h hat
thi
ana t9 spa a
yo
ATa
cdttabid and
cSdituèn i s
thiy Manuul Eaus O
chos t h e dwo Paint D Cnd
h a d s touw you
how bla |ubarhuk h i ovginal
n d
OLnd thol's uil
t a l and that
the S n J h a t ào.
iothum
wothum e a untalule pat.
is q u n s t a l l e pat.
arnien thue
tuet
e et a pha

1+AT
7 AS d

OEFD

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