DAYANANDA SAGAR COLLEGE OF ENGINEERING

Accredited by National Assessment & Accreditation Council (NAAC) with ’A’ Grade
(AnAutonomousInstitutionaffiliatedtoVisvesvarayaTechnologicalUniversity,Belagavi& ISO 9001:2015
Certified)

DEPARTMENT OF CHEMISTRY
Question Bank 2019-20

UNIT 2: ELECTROCHEMICAL CELLS AND BATTERY TECHNOLOGY

1. Define single electrode potential and explain its origin.

2. Generate Nernst equation for single electrode potential.
3. Solve for the electrode potential of copper when it is in contact with 0.5 M CuSO 4
solution at 298 K, given Eo value of copper as 0.34 V.
4. Solve for the standard electrode potential of Zn2+/Zn if the electrode potential at 25 oC is -
0.76 V, when [Zn2+] = 0.73 M.

5. Solve for the emf of a cell constructed by coupling a zinc electrode dipped in 0.5 M
ZnSO4 and a nickel electrode dipped in 0.05M NiSO4. Write the cell representation
and cell reaction, given the standard reduction potential of Zn and Ni as -0.76 V and -
0.25 V respectively.
6. Solve for the emf of the following cell at 298 K; Ni/ Ni 2+ (0.01M) // Cu2+ (0.5M) / Cu.
The standard reduction potentials of Ni and Cu are -0.25 V and 0.34V respectively. Write
the electrodes reaction.
7. Classify the six different types of electrode with examples for each.

8. Describe the construction and working of calomel electrode with a neat diagram.
9. Summarize the demerits of standard hydrogen electrode.
10. List the applications and advantages of calomel electrode.
11. Determine the standard electrode potential of copper using a saturated calomel electrode
as reference.
12. Describe the construction and working of glass electrode with a neat diagram.
13. Describe the determination of pH of a solution using glass electrode.
14. Define: (a) ion selective electrode (b) concentration cell
15. Discuss the concept of electrolyte concentration cell.
16. A concentration cell is constructed by immersing two iron electrodes in 0.01M and 0.1M
FeSO4 solutions. Represent the cell and solve for the emf of the cell at 298 K.
17. The emf of the cell Ag / AgNO3 (0.0093 M) // AgNO3(X) / Ag is 0.086 V at 25 °C. Solve
for the value of X.
18. Solve for the emf of the following concentration cell: Zn /Zn 2+(0.025 M) // Zn2+(0.15
M) /Zn at 298 K.
19. Emf of the cell Ag / AgNO3 (C1) // AgNO3 (C2 = 0.2 M) / Ag is 0.8 V. Solve for C1.
20. Classify the three different types of batteries with description.
21. Analyse the criteria for selection of lithium as anode.
22. Appraise the construction, working and applications of Li ion battery.
23. Elaborate the recycling of Li-ion battery.
24. Define fuels cells. Formulate the construction and working of hydrogen-oxygen fuel cell.
25. List the limitations and advantages of fuel cells.
26. Distinguish between battery and fuel cell.
27. Illustrate the electrochemical reduction of CO2 into value added products.