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Lai Van Duy, Nguyen Van Duy, Chu Manh Hung, Nguyen Duc Hoa,
Nguyen Quang Dich
PII: S2352-4928(20)32456-9
DOI: https://doi.org/10.1016/j.mtcomm.2020.101445
Reference: MTCOMM 101445
Please cite this article as: Van Duy L, Van Duy N, Hung CM, Hoa ND, Dich NQ, Urea
mediated synthesis and acetone-sensing properties of ultrathin porous ZnO nanoplates,
Materials Today Communications (2020), doi: https://doi.org/10.1016/j.mtcomm.2020.101445
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ZnO nanoplates
Lai Van Duy1, Nguyen Van Duy1*, Chu Manh Hung1, Nguyen Duc Hoa1,
1
International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology,
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No. 1, Dai Co Viet, Hai Ba Trung, Hanoi, Vietnam;
2
Institute for Control Engineering and Automation, Hanoi University of Science and Technology (HUST), 1-
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Daicoviet, Hanoi, Vietnam
Highlights
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Ultrathin porous ZnO nanoplates were synthesized for acetone gas sensor
The ZnO nanoplate has a pore size of 2.5 nm and a thickness of 15 nm
The sensor showed excellent acetone sensing performance with detection limit
of 45 ppb
The sensor is suitable for diabetes diagnosing via breath analysis
Abstract
Facile synthesis of advanced porous nanomaterials for enhanced gas sensing performance has gained increasing
interest. Here, we report our study on the preparation of ultrathin porous ZnO nanoplates by a urea mediated
hydrothermal method for acetone gas-sensor application. The synthesized ZnO nanomaterials were nanoplates
with a porous structure, high crystallinity, and ultrathin thickness of approximately 15 nm. The gas-sensing
characteristics of the ultrathin porous ZnO nanoplates were studied at 350–450 °C. The sensor showed the highest
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response to acetone among the tested gases (methanol, ethanol, acetone, toluene and ammonia); the response to
2.5 ppm acetone was 1.8. The sensor also showed a low 45 ppb detection limit with excellent stability and
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selectivity at 450 °C. The acetone-sensing mechanism of the ultrathin porous ZnO nanoplates was also discussed.
Overall, the findings indicated that the ultrathin porous ZnO nanoplates were excellent materials for sensing
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applications (e.g., breath analysis) of volatile organic compounds.
Exhaled breath contains around 500 various volatile organic compounds (VOCs) [1,2] but their
concentrations are different depending on the human health condition [3]. The sources of VOCs in exhaled breath
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can be endogenous or exogenous [4], such as a metabolic deficiency, a pathological disorder [5], cellular
destruction or human body inflammation [6]. Monitoring the VOCs in exhaled breath is an instant method for non-
invasive medical diagnoses [3,6] because the presence of some VOCs can be considered biomarkers for a disease
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[7]. It was reported that differences in the concentration of exhaled VOCs can serve as a fingerprint for specific
diseases [4], including diabetes and kidney failure [3]. Recently, acetone has been used as an effective biomarker
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in diagnosing diabetes [8] because its concentration in the exhaled breath of a diabetic patient is higher than that
in healthy people. The detection limit of an acetone sensor for exhaled breath analysis is 1.8 ppm [9]. Therefore,
many attempts have been made to develop a highly sensitive acetone gas sensor [10].
Resistive gas sensors present possibilities for disease diagnosis because they have some advantages, such as
small size, low cost, portability, robustness, high responses and real-time monitoring [4,11]. Different metal oxides
[12] were prepared for VOC gas sensor applications [13–17]. Zinc oxide (ZnO) [18], an n-type semiconductor has
been widely used as a gas sensing material thanks to its simple synthesis and high response to various gases [19].
Attempts have focused on synthesising different ZnO nanostructures for VOC sensors [8,19–27]. Nanomaterials
with a porous structure were prepared for gas-sensing applications [28] because they can promote the diffusion
path to enhance the adsorbed quantity of target gas molecules [29]. The porous structure also possesses high
activity in surface chemical reactions and, thus, provides high gas sensitivity [30]. Therefore, gas sensors fabricated
with a porous morphology are expected to exhibit high response with reduced response and recovery times [31].
Two-dimensional (2D) ZnO nanomaterials have also proven to have a good sensing performance because of their
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increased proportion of exposed active planes [32,33]. In addition, decorating the surface of sensing materials with
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noble metal particles could also improve the sensitivity of ZnO nanostructures [34]. The ZnO nanostructures can
be easily prepared by co-precipitation, sol-gel, electrospinning and hydrothermal methods [35,36]. For example,
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the 2D ZnO nanostructures could be prepared using a hydrothermal method with low-cost equipment compared to
thermal evaporation [37]. ZnO nanosheets doped with Sn were prepared by a hydrothermal method [38], where
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the synthesized ZnO nanosheets have a dense structure with a 20 nm thickness. The response (Ra/Rg) value to 200
ppm acetone at 320 °C was approximately 5.6. Recently, porous ZnO nanoplates with large pores were prepared
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for ethanol detection [19]. However, the ZnO plates were large, i.e., approximately 5 µm in size, with a thickness
of approximately 100 nm, leading to a low sensor response. Therefore, an easy, less toxic, scalable synthesis
method for preparing ultrathin porous ZnO nanoplates remains challenging. In addition, the acetone sensing
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Here, we report our study on the urea mediated synthesis of ultrathin porous ZnO nanoplates for acetone gas
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sensor application. The ultrathin porous ZnO nanoplates were synthesized by a facile hydrothermal method and
subsequent annealing process. Urea was used as a mediating agent to control the pH and porosity and the less toxic
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bioreagent zinc sulfate was used as a Zn2+ precursor. Ultrathin porous ZnO nanoplates exhibited superior
sensitivity to acetone with excellent stability and are suitable for application in diabetes diagnosis.
2. Experimental
The reagents used in this study included zinc sulfate heptahydrate (ZnSO4·7H2O), urea (CH4N2O) and
deionized water. The analytical grade reagents were used as received. The hydrothermal method was used to
prepare ultrathin porous ZnO nanoplates [33,34]. Briefly, a mixture of 0.28 g ZnSO4·7H2O and 1.2 g CH4N2O was
dissolved in 50 mL deionized water at room temperature by magnetic steering. The pH of the solution was adjusted
to 5 by further stirring for 15 min. This solution was poured into a 100 mL Teflon-lined stainless-steel autoclave
[19]. After capping, the autoclave was loaded in an electric oven for hydrothermal material growth at 220 °C for
24 h. The electric oven was then turned off and left to cool to room temperature naturally. The white precipitate
was washed with a mixture of deionized water and ethanol to remove the unreacted reagents. The hydrothermal
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product was centrifuged at 4000 rpm for 20 min to collect the precipitate. After drying at 60 °C for 24 h, the final
product was annealed for 2 h in air at 600 °C. The synthesized materials were characterized by some advanced
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techniques [39], such as SEM & EDS (JEOL 7600F), XRD (Advance D8, Bruker) and HRTEM (JEM2100).
Optical properties were studied by Photoluminescence (PL) and Raman spectroscopy measurements.
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The sensors were prepared using a thick film technique, as reported in ref. [39]. Briefly, the ZnO nanoplates
were dispersed in N-vinylpyrrolidone solution using an ultrasonic bath. The colloidal solution was then cast onto
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Pt-interdigitated electrodes to form the sensors. The gas-sensing properties were measured at different
temperatures using a home-made system [40]. During gas sensing measurement, the resistance of the sensor was
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measured while the tested gas was introduced. The sensor response was defined as S=Ra/Rg, where Ra and Rg are
The morphologies of the product observed by SEM images (Figure 1[A–B]) display the ultrathin porous
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structure of the ZnO nanoplates. Numerous randomly oriented nanoplates, micrometres in width and length, were
found. The top surface and the edges of the ZnO nanoplates can be seen in Figure 1[A]. However, the nanoplates
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were very thin (Figure 1[B]), approximately 15 nm. We could not see the porous structure of the nanoplates
because of the low-resolution SEM image. The thickness of the porous ZnO nanoplates (15 nm) prepared in our
study was far less than that of the porous ZnO nanoflakes (~70 nm) [30]. This is an advantage because it is
comparable with the Debye length (~20 nm) of ZnO, thus it was expected to show high gas sensitivity [41]. The
mechanism for the formation of the porous ZnO nanoplates can be explained as follows. When dissolved in water,
the zinc sulphate heptahydrate formed the Zn2+ ions. During hydrothermal treatment at high temperature, the
CH4N2O decomposed into NH4OH and HNCO. Thus, the (OH)− group reacted with Zn2+ ions to form Zn(OH)2
flakes. The flakes grew with hydrothermal treatment and then decomposed into ZnO and generated the ultrathin
porous nanosheet structure. The crystal structure of the ZnO nanoplates was investigated by XRD and is shown in
Figure 1(C). The XRD pattern of synthesized materials matched the standard spectrum of ZnO (JCPDS card No.
36-1451) with the hexagonal structure. No impurity peak was observed, indicating the single phase of the ZnO
nanoplates [42]. The average crystalline size of ZnO crystals was approximately 10 nm, which was much smaller
than the size of the nanoplates. This result confirmed that the ultrathin porous ZnO nanoplate was polycrystalline.
The composition of the ultrathin porous ZnO nanoplates was studied by EDS (Figure 1[D]), which showed
evidence of Zn and O. The nanoplates were of high quality without any detectable impurities. The content of O
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and Zn was 53.56 and 46.44 at.%, respectively. This composition was approximate to the stoichiometry of ZnO,
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confirming that a high-quality material was obtained [43].
porous ZnO nanoplates (Figure 2). Figure 2(A) shows a TEM image of the ZnO nanoplates, which indicates that
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the nanoplates were not uniform but highly porous. Some aggregated tiny particles can also be observed in the
HRTEM image, possibly due to fracture of the material during sampling by ultrasonication. Many large pores can
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be easily observed in the nanoplates, confirming the porous structure of the material [44]. The porous structure of
the nanoplates was more evident in the higher magnification HRTEM (Figure 2[B]). The inset of Figure 2(B) is a
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cross-sectional HRTEM image of the synthesized ZnO nanoplates, which reveals that the nanoplates have an
average thickness of 15 nm. The surface of the nanoplates was not as flat as that of the single crystal but rough
due to the formation of nanopores. The HRTEM image of the corresponding area of the nanoplate shown in
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Figure 2(C) shows the high crystallinity of the nanoplate where the lattice fringes were visible. However, the
orientation of the lattice fringes was different, suggesting that the nanoplate was composed of different
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nanocrystals. Figure 2(D) displays the enlarged HRTEM image, which shows clear lattice fringes with an
interspacing of 0.52 nm. The distance between lattice fringes is consistent with the gap between (0001) planes of
hexagonal ZnO. This result indicated that the synthesized nanoplate was not a single crystal but polycrystalline
with different orientations of the nanocrystals. However, the preferred growth orientation of the nanocrystals was
[0001] direction [33,45]. This is advantageous because ZnO crystal with exposed facets of {0001} could enhance
The porosity and specific surface area of the ultrathin porous ZnO nanoplates were determined by BET
measurement [33]. The isotherm nitrogen adsorption/desorption (Figure 3[A]) displays the characteristics of type
IV porous materials [47]. There are two peaks at approximately 2.5 and 100 nm in the pore-size distribution of the
ZnO nanoplates (inset of Figure 3[A]). The first pore (2.5 nm) was attributed to the nanopores inside the
nanoplates, whereas the second pore (100 nm) was formed by the interspaces between the ZnO nanoplates. The
BET surface area of the ultrathin porous ZnO nanoplates was 74.976 m2/g, which was higher than that of the ZnO
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nest-like architecture (63.46 m2/g) [46] and precipitated ZnO nanosheets (23.88 m2/g) [33]. The large BET surface
area with many pores of the ZnO nanoplates was advantageous for enhancing gas sensitivity [48].
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The PL spectrum of the ultrathin porous ZnO nanoplates (Figure 3(B)) displays a small peak at 325 nm,
assigned to the helium–cadmium (He-Cd) excitation laser. In addition, there are two emission peaks centred at
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approximately 389 nm and 650 nm. The near-band-edge emission in the UV region is ascribed to the band-to-band
of ZnO nanocrystals (3.188 eV). The broad emission centred at 650 nm was deconvoluted into three peaks at 526,
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600, and 695 nm. The presence of visible peaks was ascribed to defects in the ZnO nanoplate structure. The peak
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at 526 nm was attributed to OZn, whereas yellow (600 nm), and orange (695 nm) emissions result from oxygen
interstitials [49,50]. Herein, the large amount of oxygen interstitials in ZnO is expected to yield a higher sensor
response [42].
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In addition to the PL data, the Raman spectrum of the porous ZnO nanoplates was also studied, and the
data is shown in Figure 3(C). Three peaks can be observed at 150, 385, and 1060 cm−1, which correspond to the
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optical phonon 2E2(L), A1(TO), and A1(TO)+ E2L modes of hexagonal ZnO, respectively [51]. The 2E2L mode at
approximately 150 cm−1 is the strongest, indicating a high level of defects relating to the Zn sublattice vibration
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[52]. The present of multi-phonon scattering modes at 385 and 1060 cm−1 in our result is similar to that reported
in ref. [53].
methanol, toluene and NH3 gases at temperatures ranging from 350 to 450 °C. Figure 4(A) displays the transient
response versus time of the sensor to acetone (50–125 ppm) measured at different working temperatures. The base
resistance of the sensor in air decreased from 11 k to about 10 k with increasing temperature from 350 to 450
°C. This was caused by the thermal energy, which activates the electrons from the donor levels to the conduction
band and decreases the based resistance of ZnO. At a given temperature, the sensor resistance rapidly decreased
upon exposure to acetone, and reached the saturation value within a minute, indicating the fast response speed.
The result is consistent with recent reports on the acetone sensing behaviour of ZnO, where the decrease of sensor
resistance upon exposure to acetone was ascribed to the reducing behaviour of acetone and the n-type
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semiconducting properties of ZnO. After stopping the flow of acetone and refreshing with air, the sensor resistance
recovered to the initial value, confirming the good recovery characteristics of the sensor. Figure 4(B) depicts the
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dependence of sensor response (Ra/Rg) as a function of acetone concentration at all measured temperatures. At a
given measured acetone concentration, the sensor response was maximal at a working temperature of 450 °C in
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the measured range. A decrease in working temperature leads to a decrease in sensor response. For example, the
response value to 50 ppm acetone is 11.64 at 450 °C but it is only 7.8 at 350 °C. This means that the reaction
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between acetone molecules and the surface of porous ZnO nanoplates required high activation energy. Our result
is consistent with the report by Wongrat et. al [54], where ZnO nanowires exhibited the maximum response to
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acetone at a working temperature of 425 °C. Herein, at the working temperature of 450 °C, the sensor response
increased nearly linearly from 11.64 to 20 with increasing acetone concentration from 50 to 125 ppm. The porous
ZnO nanoplates prepared in our study exhibited a better acetone sensing performance than that of Sn-doped ZnO
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ultrathin nanosheets [38]. Comparing with recent reports on acetone sensors, the sensitivity of the ultrathin porous
ZnO nanoplates was very high compared to Sn-doped ZnO ultrathin nanosheets, which exhibited a response of
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5.55 for 200 ppm acetone at 320 °C [38], porous 1% Au@ZnO nanoplates, which exhibited a response of 32 for
100 ppm acetone at 400 °C [34], coral-like ZnO, which exhibited a response of 12 for 100 ppm acetone at 360 °C
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[45], and the nest-like ZnO architecture, which exhibited a response of 11 for 1000 ppm acetone at 105 °C [46].
The response and recovery times of the sensor were calculated from the transient resistance versus time
when the flow was switched from air to gas and back to air. Figure 4(C) shows the response and recovery time of
the sensor measured at 450 °C. At a low acetone concentration of 50 ppm, the response and recovery time of the
sensor was 23 and 637 s, respectively. However, the response time decreased to 7 s and recovery increased to 550
s when the acetone concentration increased from 50 to 125 ppm. The recovery time was much longer than the
response time, possibly due to the strong interaction between acetone molecules and the surface of ZnO. The long
recovery time was also caused by the large volume of the test chamber, which required a long time to refresh the
chamber. The decrease of response time with increased acetone concentration can be explained as follows. When
increasing the acetone concentration, more acetone molecules can come to adsorb on the surface of ZnO and
rapidly occupy the adsorption sites. Because the number of available adsorption sites on the surface of the sensing
layer is fixed at a given working temperature, increasing the acetone concentration leads to reduced response time
[55]. By contrast, the recovery time of the sensor increased with an increase of acetone concentration because at
the dynamic equilibrium condition, the number of acetone molecules adsorbed on the surface of the sensing layer
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is high with high concentration; thus more adsorbed molecules require a longer time to desorb. With an increase
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of working temperature, the response time and recovery time of the sensor decreased (data not shown). The
recovery time decreased with increased working temperature due to the rapid acetone desorption with the
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acceleration of thermal energy. Despite the long recovery time of the sensor, the device still exhibited 100%
recovery characteristics, where the sensor resistance recovered to the base resistance after refreshing the chamber.
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This result confirmed the physical adsorption of acetone molecules on the surface of ZnO, thus enabling the
We also tested the response of the sensor to low acetone concentrations of subppm levels to apply it in
diabetes diagnosis [56]. Figure 5[A] shows the dynamic sensing response of the ultrathin porous ZnO nanoplates
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to 2.510 ppm acetone at 450 °C. The sensor could detect acetone at low concentrations down to 2.5 ppm. The
sensor response increased from 1.8 to 2.0 with an increase of acetone concentration from 2.5 to 10 ppm
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(Figure 5[B]). The response increased as the acetone concentration increased, with a slope of 0.022. We calculated
the lower detection limit of the sensor to be about 45 ppb [56], which is lower than the threshold concentration
(180 ppb) of acetone in breath analysis, indicating the potential application of the sensor for diagnosing diabetes
mellitus. Stability and selectivity are essential aspects of practical applications. Figure 5[C] showed ten pulse
exposures of the sensor to 125 ppm acetone at 450 °C. A negligible response reduction was observed after the test,
indicating the good stability of the sensor. This is the result of the high crystallinity of the ZnO nanoplates. The
selectivity of the ultrathin porous ZnO nanoplate sensor to acetone, ethanol, methanol, NH3 and toluene was tested
at 450 °C. Figure 5(D) shows the response values to different gases, including acetone, ethanol, methanol, NH3
and toluene. The sensor presented the best sensitivity to acetone, followed by ethanol and methanol; the response
values were 20, 9.0 and 4.0, respectively. The sensor presented a negligible response to NH3 and toluene gases.
Those data confirmed that the sensor had good stability and selectivity for detecting acetone at sub-ppm
concentrations.
Humidity was also present in the exhaled breath; thus, we tested the response of the sensor to 125 ppm
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acetone in different values of relative humidity (RH), as shown in Figure 6. Figure 6(A) demonstrates that the RH
significantly influenced the base resistance of the sensor and its response. At an operating temperature of 450 °C,
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the base resistance was 10, 19 and 36 k for 10, 60 and 80% RH, respectively. The base resistance of the sensor
shifted to higher values with an increase of RH in the measured range, indicating that the adsorbed water molecule
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donated free electrons to the conduction band of ZnO to increase the base resistance. However, the presence of
humidity seems not to influence the response time and recovery time of the sensor, where the sensor exhibited
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100% recovery in different RH values. Figure 6(B) showed the response values of the sensor measured at different
RH. The response value to 125 ppm acetone was 20, 13.6, and 11.86 in 10, 60 and 80% RH, respectively. The
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humidity in exhaled breath is relatively high, about 80–90%. The ambient humidity influenced the acetone
response, but at high humidities of 60%–80% RH, the variation in acetone response was ignorable. Therefore, the
We compared the acetone sensing response of the ultrathin porous ZnO sensor with other materials, as
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shown in Table 1. The ultrathin porous ZnO nanoplates exhibited better acetone gas-sensing properties than those
of 0.5 wt% Co-doped ZnO nanofibers, porous ZnO/ZnCo2O4 hollow spheres, Ag-ZnO NCs, GO/ZnO-NR/GO,
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ZnO rods, CuO nanosheets, nanoporous TiO2 and Co3O4 crossed nanosheets. However, its performance is less
than that of the WO3-C3N4 nanosheet. The sensing performance was believed to be dependent on the materials,
their morphology and composition. The ultrathin porous ZnO nanoplates have a large specific surface area (74.976
m2/g), ultrathin thickness (15 nm) and large pore size (2.5 nm), thus possessed a high response value. The porous
ZnO nanoplates exhibited a higher sensitivity of 20/125 ppm, compared the pure ZnO rods with 4.5/100 ppm.
However, the ultrathin porous ZnO nanoplates required a high operating temperature of 450 °C, compared with
the 300 °C of the ZnO rods. This means the ultrathin porous ZnO nanoplates consume more energy for device
operation, thus limiting its potential application in portable sensing systems. However, such parameters can be
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GO/ZnO-NR/GO 200 12.52 450 [58]
Density functional theory calculation [64] pointed out that upon exposure to acetone vapour at
approximately 430 °C, the pre-adsorbed oxygen species (O−, O2−) were dissociated from the surface of ZnO and
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replaced by acetone molecules. In addition, the calculation also found that the oxygen extracted more electrons
from the surface than acetone. Thus, the gas sensing mechanism of the ZnO nanoplates can be explained by the
band bending model, in which interaction between the analytic gas molecules and the surface of the sensitive
material modulates the electron-depleted region of the ZnO crystals and leads to the change in resistance of the
sensor [56]. Figure 7 shows a proposed gas sensing mechanism of the ultrathin porous ZnO nanosheets. The sensor
was tested in the air as a reference; thus, the oxygen in ambient air played an important role in the gas sensing
mechanism because, during measurement in air, oxygen molecules were adsorbed on the surface of the ZnO
The adsorbed oxygen species extract electrons from the conduction of ZnO to form a thick depletion
region on the surface of the ZnO nanoplate (Figure 7[A]). Due to the thin thickness of the ZnO nanoplates with
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many pores, the oxygen adsorbed and depleted the total surface of the ZnO nanoplates, and thus, the sensor has
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high base resistance in air. Upon introduction of acetone, the acetone molecules reacted with the preabsorbed
oxygen species and released electrons back to the conduction band of ZnO [46], as described by Equations (5–6):
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CH3COCH3(gas) + 8O−(ads) → 3CO2 + 3H2O + 8e−
as shown in Figure 7(B). As a result, the exposure to acetone gas decreases the sensor resistance compared to the
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base value. Not only is there a significant change in the depleted region to maximize the sensing performance, but
the porous structure of the ZnO nanoplates also enables the effective diffusion of the gas molecules to enhance the
response speed. As a result, the ultrathin porous ZnO nanoplates exhibited remarkably high sensitivity [19]. The
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high sensitivity of the sensor obtained in this study is comparable with that of graphene–Ag loaded ZnO
nanocomposites, which showed a response of 83 for 1000 ppm acetone at 175 °C [66].
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4. Conclusion
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In conclusion, the ultrathin porous ZnO nanoplates were prepared for acetone gas sensing by an
environmentally friendly hydrothermal method without using any surfactant or organic solvent. The prepared ZnO
materials possess a nanoplate morphology with a porous structure and thin thickness of approximately 15 nm. The
sensor fabricated from the ultrathin porous ZnO nanoplates exhibits high sensitivity, selectivity and stability to
low-acetone concentrations (2.5–125 ppm) at a working temperature of 450 °C. The response to 2.5 ppm acetone
is approximately 1.82, which is superior to other reported acetone sensors. The detection limit of the sensor to
acetone at 450 °C is 45 ppb, which is lower than the threshold limit concentration of acetone in diagnosing diabetes
through breath analysis. This result indicates that the ultrathin porous ZnO nanoplates are potential materials for
achieving excellent acetone-sensing performance with detection at the ppb level, enabling application in breath
analysis.
Novelty statement:
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High performance acetone gas sensor is potential for application in diabetes diagnose via
exhaled breath analysis. Here, we used a urea mediated hydrothermal method to synthesize
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ultrathin porous ZnO nanoplates. The synthesized ZnO nanoplate has a pore size of 2.5 nm and
a thickness of 15 nm, which showed excellent acetone sensing performance with detection limit
of 45 ppb.
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Declaration of interests
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The authors declare that they have no known competing financial interests or
personal relationships that could have appeared to influence the work reported in
this paper.
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Acknowledgement
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This work was funded by the Vietnam National Foundation for Science and Technology Development
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Figure caption:
Figure 1. SEM images (A–B), XRD patterns (C), and EDS analysis (D) of the ultrathin porous ZnO nanoplates.
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Figure 2. (A, B) Low- and (C, D) high-magnification TEM images of the ultrathin porous ZnO nanoplates. Inset
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450 °C: (A) transient resistance vs. time, (B) the dependence of response on acetone concentrations, (C) response
concentration, (C) stability of the ZnO sensor to acetone, (D) selectivity of the sensor.
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Figure 6. Dynamic resistance curves (A), the response (B) of the sensor to 125 ppm acetone with different relative
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Figure 7. Proposed gas-sensing mechanism: (A) ultrathin porous ZnO nanoplates in air; (B) ultrathin porous ZnO
nanoplates in acetone
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