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PART A
UNIT 3
(8 Hours)
Classification of soils
Introduction:
Soil classification is the arrangement of soils into different groups such that the soils
in a particular group have similar behaviour. As there are a wide variety of soils covering
earth, it is desirable to systematize or classify the soils into broad groups of similar
behaviour.
For general engineering purposes, soils may be classified by the following systems
The size of individual particles has an important influence on the behaviour of soils. It is
a general practice to classify the soils into four broad groups, namely, gravel, sand, silt
size and clay size.
Note:
While classifying the fine-grained soils on the basis of particle size, it is a good practice
to write silt size and clay size and not just silt and clay. In general usage, the term silt and
clay are used to denote the soils that exhibit plasticity and cohesion over a wide range of
water content. The soil with clay-size particles may not exhibit the properties associated
with clays. For eg. Rockflour has the particles of the size of the clay particles, but does
not possess plasticity. It is classified as clay-size and not just clay in the particle size
classification systems.
i) U.S. Bureau of Soil and Public Road Administration (PRA) System Classification
This is one of the earliest classification systems developed in 1895 by the U.S.
Bureau of soils.
(ii) International Classification System:
This system was proposed for general use at the international Soils Congress held at
Washington in 1927. This was known as the Swedish Classification system before it was
adopted as International system.
In this system, an additional term Mo (Majla) has been used for soil particles in the
size range between sand and silt
2. Textural Classification:
The visual appearance of a soil is called its texture. The texture depends upon the
particle size, shape of particles and gradation of particles and gradation of particles. The
textural classification incorporates only the particle size. Here, the term texture is used to
express the percentage of the three constituents of soils, namely, sand, silt and clay.
According to the textural classification system, the percentages of sand (size 0.05 to
2.0 mm), silt (size 0.005 to 0.05 mm) and clay (size less tan 0.005 mm) are plotted along
the three sides of an equilateral triangle. The equilateral triangle is divided into 10 zones,
each zone gives a type of soil. The soil can be classified by determining the zone in
which it lies. A key is given that indicates the directions in which the lines are to be
drawn to locate the point.
For e.g. If a soil contains 30 % sand, 20 % silt and 50 % clay, it is shown by point P in
the figure. The point falls in the zone labeled clay. Therefore, the soil is classified as clay.
The textural classification system is useful for classifying soils consisting of different
constituents. The system assumes that the soil does not contain particles larger than 2-mm
size. However, if the soil contains a certain percentage of soil particles larger than 2 mm,
a correction is required in which the sum of the percentages of sand, silt and clay is
increased to 100 %. For e.g. if a soil contains 20 % particles of size larger than 2-mm
size, the actual sum of the percentages of sand, silt and clay particles is 80 %. Let these
be respectively 12, 24, and 44 %. The corrected percentages would be obtained by
multiplying with a factor of 100/80. Therefore, the corrected percentages are 15, 30 and
55 %. The textural classification of the soil would be done based on these corrected
percentages.
Q 1. How are soils classified based on the Indian Standards Classification. List the salient
features of this classification.
Q 2. What is plasticity chart? Explain how it is useful for classification of fine-grained soils
Indian Standard Soil Classification system is in many respects similar to the Unified
system. However, there is one basic difference in the classification of fine-grained soils.
The fine-grained soils in this system are sub-dived into three categories of low, medium
and high compressibility instead of two categories of low and high compressibility in
Unified soil classification system.
Peat - 1 group
Coarse-Grained Soils:
The classification of coarse-grained soils is done on the basis of their grain and gradation
characteristics as illustrated in Table, when the fines (75 µm) present in them are less
than 5 % by weight. Coarse-grained soils are sub-dived into gravel and sand. The soil is
termed gravel (G) when more than 50 % of coarse fraction (>75 µm) is retained on 4.75
mm IS sieve, and termed sand (S) if more than 50 % of coarse fraction is smaller than
4.75 mm IS sieve. These are further sub-divided as given in Table into 8 groups.
Coarse-grained soils which contain more than 12 % fines (< 75 µm) are classified as
GM or SM if fines are silty in character (meaning, the limits plot below the A-line on the
plasticity chart). On the other hand they are classified as GC or SC if the fines are clayey
in character (meaning the limits plot above the A-line on the plasticity chart).
Fine-grained Soils:
The fine-grained soils are classified on the basis of their plasticity characteristics using
the I.S Plasticity chart shown in Fig.
The fine-grained soils are further divided into three sub-divisions depending upon the
values of the liquid limit:
a) Silts and clays of low compressibility – These soils have a liquid limit less than 35 %
(represented by a symbol L)
b) Silts and clays of medium compressibility – These soils have a liquid limit > 35 %
but < 50 % ( represented by a symbol I)
c) Silts and clays of high compressibility – These soils have a liquid limit > 35 %
(represented by a symbol H)
Fine-grained soils are further sub-divided, as given in table in 9 groups.
Boundary Classifications:
Sometimes, it is not possible to classify to classify a soil into any one of 18 groups
discussed above. A soil may possess characteristics of two groups, either in particle
distribution or in plasticity. For such cases, boundary classifications occur and dual
symbols are used.
(i) Boundary classifications within gravel or sand groups can occur. The following
classification are common
GW-GP, GM-GC, GW-GM, GW-GC, GP-GM,
(ii) Boundary classifications can occur between the gravel and sand groups such as
GW-SW, GP-SP, GM-SM, and GC-SC
Note: The rule for correct classification is to favour the non-plastic classification.
For eg. A gravel with 10 % fines, Cu = 20 and Cc = 2 and IP= 6 will be classified as GW –
GM, and not GW – GC.
(i) If the limits plot in the hatched zone on the plasticity chart, i.e., IP between 4 and
7, the soil has a group symbol CL – ML.
(ii) If the position of the soil on the plasticity chart falls close to the A-line, dual
symbol is used, such as CI – MI , CH – MH
(iii) If the liquid limit is very close to 35 % or 50 %, dual symbols are used, such as
ML – MI, MI – MH, CL – CI, CI – CH, OL – OI, OI – OH.
c) Boundary classification between coarse-grained and fine-grained soils:
Dual symbols can also be used when the soils have about equal percentage of coarse –
grained and fine – grained fractions. The possible dual symbols in this case are GM –
ML, GM – MI, GM – MH, GC – CL, GC – CI, GC – CH,
A step-by-step procedure for classifying the soils as per IS: 1498 –1970 is illustrated
below:
Dispersion Test
A few other miscellaneous identification tests are as follows:
Organic content and colour:
Fresh, wet organic soils usually have a distinctive odour of decomposed organic
matter, which can be easily detected on heating. Another distinctive feature of such soils is
the dark colour.
Acid test:
This test, using dilute HCl, is primarily for checking the presence of calcium
carbonate. For soils with a high value of dry strength, a strong reaction may indicate the
presence of calcium carbonate as cementing material rather than colloidal clay.
Shine test:
When a lump of dry or slightly moist soil is cut with a knife, a shiny surface is
imparted to the soil if it is highly plastic clay, while a dull surface may indicate silt or clay of
low plasticity.
CLAY MIERALOGY AND SOIL STUCTURE
Clay Minerals:
The Crystalline minerals whose surface activity is high are called clay minerals.
The behavior of the fine grained soils depends to a large extent on the nature and
characteristics of the minerals present.
Clay Mineralogy is the science dealing with the structure of the clay minerals on
microscopic, molecular and atomic scale. It also includes the study of the mineralogical
composition and electrical properties of the clay particles.
Primary Valence bonds hold together the atoms of molecule. These are of two types
1. Ionic Bond
2. Covalent Bond.
Ionic Bond:
In an atom the electrons carrying a negative charge revolve about the nucleus. Some
elements have an excess or a deficiency of the electrons in the outer shell one atom joins
another atom by adding some of the electrons to its outer shell or by losing some of electrons
from its outer shell.
The atom which loses an electron becomes a positive ion (Cation) and that which gains as
electron becomes a negative ion (anion).
Covalent Bond:
This type of bond develops between two atoms by sharing of electrons in their outer shell.
Two atoms, each lacking one electron, may combine by sharing of pair of electrons.
In other words, a covalent bond occurs when there is sharing of electrons by atoms of like
valence. The covalent bond occurs generally in elements of negative valences or in non-
electrolytes, such as carbon (A non electrolytes does not form ions).
Primary valence bonds are very strong. These bonds do not break in normal soil engineering
applications. Therefore, primary valance bonds are not much relevance in soil engineering.
Hydrogen Bond:
The hydrogen bond has only one electron. The number of electrons required to fill the first
shell is 2. The atom can be considered either as a cation (with one excess electron) or an
anion( with one electron deficiency). The bond between the hydrogen cation(H+) and anions
of two atoms of another element is called Hydrogen Bond.
E.g.: H2O
Hydrogen bond is considerably weaker than primary valence bond. However, it is fairly
strong and cannot be broken during normal soil engineering problems.
Secondary Valence Bonds:
Secondary valence bonds are intermolecular bonds which develop between atoms in one
molecule to atoms in another molecule. A molecule is electrically neutral. i.e., it has no
charge. However the construction of the molecule may be such that centres of the negative
and positive charges do not exactly coincide. The molecule may behave like a bar magnet,
with two electrical dipoles. Consequently, an electrical moment is developed inside the
molecule; A molecule with such a structure is called a dipole. In nature, two dipolar
molecules orient themselves in such a way that net attraction occurs. The attractive forces so
developed are known as Vander waal Forces. (after Vander Waal who postulated the
existence of a common attractive forces between molecules of all matters in 1873)
Vanderwaal forces also develop between the surface of two parallel particles of clay mineral,
separated by water. The magnitude of the forces depends upon the distance between the clay
particles, structure of the minerals and the characteristics of water.
The secondary valence bonds are relatively weak and are easily broken. The vander waal
forces play an important part in the behavior of clayey soils.
Van der Waal
Basic structural units of clay minerals or primary building blocks of clay minerals.
1. Tetrahedral Unit
2. Octahedral Unit.
1. Tetrahedral Unit:
4+
A tetrahedral unit consists of a silicon atom (Si ). Surrounded by four oxygen
atoms( O 2-), forming a shape of a tetrahedron. Oxygen atoms are at the tips of the
tetrahedron, whereas the silicon atom is at the centre. There is a net negative charge
of 4. An individual tetrahedron unit cannot exist in nature.
Tetrahedral Unit
A number of tetrahedron unit combine to form a sheet. Each oxygen at the base is shared by
two tetrahedra. A silica sheet is formed by tetrahedral units. Due to this sharing of oxygen
atom at the base, the negative charge per tetrahedra at the base is three and two at the tip and
4 positive charges due to silica atom at the centre, leaving a net negative charge of one per
tetrahedron.
Figure below gives a simple representation of silica sheet, commonly used in clay minerals.
2. Octahedral Unit:
It consists of six hydroxyles (OH-) forming a configuration of an octahedron and
having one aluminium atom at the centre. As the aluminum (Al +3) has three positive
charges, an octahedral unit has 3 negative charges. Because of net negative charges,
an octahedral unit cannot exist in isolation.
Octahedral Unit
Several octahedral units combine to form a gibbsite sheet. Figure shows a gibbsite sheet
formed by four octahedral units. The sheet is electrically neutral.
CLAY MINERALS:
1. Kaolinite Mineral:
Kaolinite is the most common mineral of the kaolinite group of minerals. Its basic
structural unit consists of alumina sheet (G) combined with a silica sheet (S) . Tips of
the silica sheet and one base of the alumina sheet form a common interface. The total
thickness of the structural unit is about 7 Angstron (Å), ehere one Å = 10 -10 m or 10 -7
mm. The kaolinite minral is formed by stacking, one over the other, several such
basic structural units.
Fig shows two such units.
The Structural units join together by hydrogen bond, which develops between the
oxygen of silica sheet and the hydroxyles of alumina sheet. As the bond is fairly
strong, the mineral is stable. Moreover, water cannot easily enter between the
structural units. So, expansion or swelling will not take place.
The kaolinite mineral is electrically neutral. However, in the presence of water, some
hydroxyl ions dissociate and lose hydrogen and leave the crystal with a small residual
negative charge. The flat surfaces of the mineral attract positive ions (cations) and
water.
The kaolinite minerals generally have a hexagonal shape in plan, with the side of the
hexagon being 0.5 to 1.0 micron, The thickness of the mineral is about 0.05 micron,
The specific surface area is about – 15m2/g.
Eg: China Clay.
2. Halloysite:
It is a clay mineral which has the same basic structure as kaolinite, but in which the
successive structural units are more randomly packed and are separated by a single
molecular layer if water. The properties of halloysite depend upon this water layer. If
the water layer is removed by drying , the properties of the mineral drastically
change.
Halloysite particles are tubular in shape, in contrast to the platy shape of kaolinite
particles. The soils containing halloysite have a very low mass density.
3. Montmorillonite:
Montmorillonite is the most common mineral of the montmorillonite group of
minerals. The basic structural unit consists of an alumina sheet sandwiched between
two silica sheets, Successive structurak units are stacked one over another, like leaves
of a book. Fig shows two such structural units. The thickness of each structural unit is
about 10Å.
The two successive structural units are joined together by a link between oxygen ions
of the two silica sheets. The link is due to natural attraction for the cations in the
intervening space and due to Vander Waal force. The negatively charged surfaces of
the silica sheet attract water in the space between structural units. This results in
expansion of the mineral. It may also cause dissociation of the mineral into individual
structural units of thickness 10Å. The soil containing a large amount of mineral
montmorillonite exhibits high shrinkage and high swelling characteristics. The water
in the intervening space can be removed by heating to 2000 - 3000C.
4. Illite Mineral:
Illite is the main mineral of the illite group. The basic structural unit is similar to that
of the mineral montmorillonite. However, the mineral has properties different from
montmorillonite due to following reasons.
a. There is always a substantial amount of isomorphous substitution of silicon by
aluminium in silica sheet. Consequently, the mineral has a larger negative charge
than that in montmorillonite.
b. The link between different structural units is through non-exchangeable potassium
(K+) and not through water. This bonds the units more firmly than in
montmorillonite.
c. The lattice of illite is stronger than that of montmorillonite and is therefore less
susceptible to change.
d. Illite swells less than montmorillonite. However, selling is more than in kaolinite.
e. The space between different structural units is much smaller than in
montmorillonite, as the potassium ion just fit between the silica sheet surfaces.
Scanning Electron Microscopic view of - Illite
The properties of the mineral illite are some intermediate between that of kaolinite
and montmorillonite.
The lateral dimensions of the mineral are the same as that of montmorillonite mineral are
the same as that of montmorillonite mineral, equal to 0.1µ to 0.5µ. However, the thickness
is much greater than that of montmorillonite and is between 0.005µ and 0.05µ. The specific
surface is about 80m2/g.
The particles of clay carry net negative electric charge on its surface. The net
negative charge may be due to one of the following reasons:
The magnitude of the electrical charge depends on the surface area of the particle.
It is very high in small particles, such as colloids, which have very large surface
area. A soil attracts the cations in the environment to neutralize the negative
charge. The phenomenon is known as adsorption.
The cations attracted to the negatively charged surface of the soil particles are not
strongly attached. These cations can be replaced by other ions and are, therefore known as
exchangeable ions. The phenomenon of replacement of cations is called cation exchange or
base exchange.
The net negative charge on the mineral which can be satisfied by exchangeable
cations is termed cation exchange capacity (CEC) or base exchange capacity (BEC).
The faces of clay minerals carry a net negative charge because of which the clay
particles attract cations in presence of moisture and reach an electrical balanced equilibrium.
These cations in turn, attract particles with negative charges and water dipoles. The cations
attracted to a clay mineral surface also try to move away from the surface because of their
thermal energy. The net effect of the forces due to attraction and that due to repulsion is that
the forces of attraction decrease exponentially with an increase in distance from the clay
particles surface. It is believed that immediately surrounding the particle, there is a thin, very
tightly held layer about 10Å thick. Beyond this thickness there is a second layer, in which
water is mobile. This second layer extends to the limit of attraction. The layer the clay
particle surface to the limit of attraction is known as diffuse double layer.
Diffuse Double Layer
In other words, base exchange capacity is the capacity of the clay particles to change the
cation adsorbed on the surface.
BEC is expresses in terms of the total number of positive charges adsorbed per 100g of soil.
It is measured in milliequivalent (meq), which is equal to 6 X 1020 electronic charges. (Thus,
one meq per 100g means that 100 g of material can exchange 6 X 1020 electronic charges if
the exchangeable ions are univalent, such as Na+. However, it is the exchangeable ions are
divalent, such as Ca2+, 100g of material will replace 3 X 1020 calcium ions)
Cation Adsorption
The Base Exchange Capacity of clay depends upon the pH value of the water in the
environment. If the water is acidic (pH < 7), the BEC is reduced. Some cations are more
strongly adsorbed than others. The adsorbed cations commonly found in soils, arranged in a
series in terms of their affinity for attraction are as follows:
+3
For e.g.,: Al cations are more strongly attracted than Ca2+ cations. Thus Al 3+
ions can
replace Ca2+ ions. Likewise Ca2+ ions can replace Na+ ions.
Adsorbed Water:
The water held by electro-chemical forces existing on the soil surface is known as adsorbed
water. As the adsorbed water is under the influence of electrical forces, its properties are
different from normal water. It is much more viscous, and its surface tension is also greater.
It is heavier than normal water. The boiling point is higher, but the freezing point is lower
than that of the normal water.
The thickness of adsorbed water layer is usually about 10 to 15Å. This water imparts
plasticity characteristics to soils.
Soil Structure:
The geometrical arrangement of soil particles with respect to one another in a soil mass is
known as soil structure.
Engineering properties and the behavior of both coarse grained and fine grained soils depend
upon the soil structure.
Cohesionless soils, such as gravel and sand, are composed of bulky grains in which
the gravitational forces are more predominant than surface forces. When deposition of
these soils occurs, the particles settle under gravitational forces and take an
equilibrium position on deposition. Each particle is in contact with those surrounding
it. The soil structure so formed is known as single grained structure.
It is possible for sine sands or silts to get deposited such that the particles when
settling develop a particle to particle contact that bridges over large voids in that soil
mass. The particle wedge between one another into a stable condition and form a
skeleton like an arch to carry the weight of the overlying material. The structure so
formed is known as honey comb structure. This structure usually develops when the
particle size is between 0.0002mm and 0.02mm.
Honey-comb structure occurs in soils having small granular particles which
have cohesion because of their fineness. The particles are held in position by mutual
attraction due to cohesion. The particles, however, do not possess plasticity
characteristics associated with clayey soils.
c. Flocculated Structure:
Flocculated structure occurs in clays. The clay particles have large surface area and,
therefore, the electrical forces are important in such soils. The clay particles have a
negative charge on the surface and a positive charge on the edges. Inter particle
contact develops between the positively charged edges and the negatively charged
faces. This results in a flocculated structure.
Flocculent structure is formed when there is a net attractive force between
particles.
When clay particles settle in water, deposits formed have a flocculated structure. The
degree if flocculation of a clay deposit depends upon the type and concentration of
clay particles , and the presence of salts in water. Clays settling out in a salt water
solution have a more flocculent structure than clays settling out in a fresh water
solution. Salt water acts as an electrolyte and reduces the repulsive forces between the
particles.
In general, the soils in a flocculated structure have a low compressibility, a high
permeability and high shear strength.
Scanning Electron Micrograph showing flocculated structure
d. Dispersed structure.
Dispersed structure develops in clays that have been remoulded. The particles
develop more or less a parallel orientation. Clay deposits with flocculant structure
when transported to other places by nature or man get remoulded. Remoulding
converts the edge to face orientation to face to face orientation. The dispersed
structure is formed in nature when there is a net repulsive force between particles.
The soils in dispersed structure generally have a low shear strength, high
compressibility and low permeability.
It is defined as
S = Surface Area/ Weight of soil
Expressed in m2/g