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FIITJEE – JEE (Main)

PHYSICS, CHEMISTRY & MATHEMATICS


SYNCHRO TEST– 8

Time Allotted: 3 Hours Maximum Marks: 300

 Do not open this Test Booklet until you are asked to do so.
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

Important Instructions:
A. General Instructions
1. Immediately fill in the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen. Use of
pencil is strictly prohibited.
2. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out
the Answer Sheet and fill in the particulars carefully.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 75 questions. The maximum marks are 300.
5. This question paper contains Three Parts.
6. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
7. Each Part has only one section: Section - A.
8. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough
work.
9. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in any
form, are not allowed.
10. Use Blue / Black Ball Point Pen only for writing particulars / marking responses on Side-1 and Side-2 of the
Answer Sheet. Use of pencil is strictly prohibited.
11. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone,
any electronic device, etc. except the Admit Card inside the examination hall / room.
12. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room / Hall. However, the candidates are allowed to take away this Test Booklet with them.
13. Do not fold or make any stray marks on the Answer Sheet.

B. Marking Scheme For All Three Parts.

(i) Section-A (01 – 20, 26 – 45, 51 – 70) contains 60 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong answer.

Section-A (21 – 25, 46 – 50, 71 – 75) contains 15 Numerical based questions, the answer of which
maybe positive or negative numbers or decimals and each question carries +4 marks for correct
answer. There is no negative marking.

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

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PART – I: PHYSICS
Section – A: Single Correct Answer Type

This section contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.

1. A body freely falling from rest has a velocity ‘v’ after falling through a height h. The distance
it has to fall down for its velocity to become double is
(A) 2h (B) 4h (C) 6h (D) 8h

2. A steel wire having a radius of 2.0 mm, carrying a load of 4 kg, is hanging from a ceiling.
Given that g = 3.1π ms−2 , what will be the tensile stress that would be developed in the
wire?
(A) 6.2 × 106 Nm−2 (B) 4.8 × 106 Nm−2 (C) 5.2 × 106 Nm−2 (D) 3.1× 106 Nm−2

3. A ball strikes a wall with a velocity at an angle θ with the normal to the wall surface and
rebounds from it at an angle β with the surface. Then:
(A) , if the wall is smooth
(B) if the wall is smooth, coefficient of restitution =

(C) if wall is smooth, coefficient of restitution


(D) none of the above

4. A uniform rod AB of mass m and length ℓ is at rest on a smooth horizontal surface. A


horizontal impulse P is applied to the end B perpendicular to the rod. The time taken by the
rod to turn through a right angle is

(A) (B) (C) (D)

5. A cubical box of side L is filled with a liquids of densities ρ. The liquid fills half the volume of
the vessel. Then the net force on any one vertical side wall of the vessel due to liquid is.
[Neglect atm pressure]
(A) (B) (C) (D)

6. A cylindrical vessel is filled with water upto height h. The vessel empties in time t sec. if the
water is now filled upto height ηh, the vessel will be emptied in time
(A) ηt sec (B) η2t sec (C) t sec (D) t/η sec

7. a1 1
In an interference experiment the ratio of amplitudes of coherent waves is = . The
a2 3
ratio of maximum and minimum intensities of fringes will be:
(A) 9 (B) 4 (C) 18 (D) 2

Space for rough work

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8. Two particles are in SHM in parallel straight lines close to each other. Amplitude A and
time period T of both the particles are equal. At t = 0, one particle is at displacement
and other at and they are approaching towards each other. After what
time will they cross each other?
(A) T/3 (B) T/4 (C) 5T/6 (D) T/6

9. A parallel plate capacitor has 1µF capacitance. One of its two plates is given + 2µC charge
and the other plate, +4µC charge. The potential difference developed across the capacitor
is:
(A) 3V (B) 1V (C) 5V (D) 2V

10. Two tuning forks A and B sounded together give 8 beats per second. With an air
resonance tube closed at one end, the two forks give resonance when the two air columns
are 32 cm and 33 cm respectively. What will be the frequencies of the two forks?
(A) 264 Hz, 256 Hz (B) 340 Hz, 358 Hz (C) 222 Hz, 300 Hz (D) 176 Hz, 184 Hz

11. A cell of internal resistance r drives current through an external resistance R. The power
delivered by the cell to the external resistance will be maximum when:
(A) R = 0.001 r (B) R = 1000 r (C) R = 2r (D) R = r

12. A certain charge ‘Q’ is divided into two parts, q and , such that when they are
placed at a separation ‘r’ apart, the coulombic repulsion between them is maximum. Then
the work done in reducing this distance to half its value, i.e., r/2 is
(A) (B) (C) (D)

13. A fully charged capacitor has a capacitance C. It is discharged through a small coil of
resistance wire embedded in a thermally insulated block of specific heat capacity s and
mass m. if the temperature of the block is raised by , the potential difference V across
the capacitance is
(A) (B) (C) (D)

14. A moving coil galvanometer has resistance 50 Ω and it indicates full deflection at 4mA
current. A voltmeter is made using this galvanometer and a 5 kΩ resistance. The maximum
voltage, that can be measured using this voltamenter, will be close to:
(A) 15 V (B) 20 V (C) 10 V (D) 40 V

15. Two infinitely long straight wires lie in the x – y plane along x and y axis, respectively. Each
wire carries a current , respectively, in positive direction of x and y axes. The locus of the
points, where the magnetic field is zero, is
(A) (B) (C) (D)
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16. An alternating voltage v ( t ) = 220 sin100 πt volt is applied to a purely resistive load of 50 Ω .
The time taken for the current to rise from half of the peak value of the peak value is:
(A) 2.2 ms (B) 3.3 ms (C) 5 ms (D) 7.2 ms

17. A concave mirror for face viewing has focal length of 0.4 m. The distance at which you hold
the mirror from your face in order to see your image upright with a magnification of 5 is:
(A) 0.16 m (B) 1.60 m (C) 0.24 m (D) 0.32 m

18. A monochromatic radiation of wavelength is incident on a stationary atom as a result of


which the wavelength of the photon after the collision becomes . The atom has De
Broglie’s wavelength and velocity in the direction of incident photon after collision. Then

(A) (B) (C) (D)

19. If a stationary electron gets annihilated due to the association with a stationary positron
(hypothetically), the wavelength of the resulting radiation will be (m0= rest mass of electron(
or positron) , c=speed of light )

(A) (B) (C) (D) none of these

20. Which of the following statement regarding semiconductors is correct?


(A) An n – type semiconductor is a negatively charged semiconductor
(B) Photodiodes are preferably used in reverse bias mode, as small changes in electron
and hole concentration are better detected in reverse bias mode
(C) The voltage – current variation graph for a diode has same units along positive and
negative direction of the axis depicting current
(D) Threshold voltage for a germanium based diode is more than that of silicon based
diode
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SECTION – A
(Numerical Answer Type)
This section contains 05 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).
40 16
21. The ratio of mass densities of nuclei of Ca and O is close to ______.

22. A lens has a power in air. Its new focal length (in m) if it is completely immersed in
water is? [Given aµw = 4/3 and aµg = 3/2]

  2πx  N
23. The electric field of light wave is given as E = 10−3 cos  −7
− 2π × 6 × 1014 t  xɵ . This
 5 × 10  C
light falls on a metal plate of work function 2eV. The stopping potential of the photo-
electrons is:

24. Consider the following data:


10 main scale division = 1 cm, 10 vernier division = 9 main scale division Zero of the
vernier scale is right of the zero marking of the main scale with 6 vernier divisions
coinciding with the main scale divisions and the actual reading for length measurement is
4.3 cm with 2 vernier divisions coinciding with main scale graduations. Then the actual
length (in cm) is

25. A gas has a density of kg/m3 and the velocity of the sound in it is 330 m/s under
standard conditions. Then the number of degrees of freedom the gas will have under
these conditions will be
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PART – II: CHEMISTRY


Section – A: Single Correct Answer Type

This section contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.

26 Number of moles of MnO4− required to oxidize one mole of ferrous oxalate completely in acidic medium
will be
(A) 0.6 moles (B) 0.4 moles (C) 7.5 moles (D) 0.2 moles

27. For the gas phase reaction, PCl5 ( g ) ⇌ PCl3 ( g ) + Cl2 ( g ) Which of the following conditions are correct?
(A) ∆H = 0 & ∆S < 0 (B) ∆H > 0 & ∆S > 0 (C) ∆H < 0 & ∆S < 0 (D) ∆H > 0 & ∆S < 0

28 K1 and K2 are equilibrium constant for reaction (i) and (ii)


1 1
N 2 ( g ) + O2 ( g ) ⇌ 2 NO ( g ) .......(i ) NO ( g ) ⇌ N 2 ( g ) + O2 ( g ) .......(ii ) then
2 2
2
 1  1
(D) K1 = ( K 2 )
0
(A) K1 =   (B) K1 = K 22 (C) K1 =
 K2  K2

29 When electrons are trapped into the crystalline anion vacancy, the defect is known as
(A) Schottky defect (B) Stoichiometric defect (C) Frenkel defect (D) F-centres

30 The specific conductance of a 0.1 N KCl solution at 23°C is 0.012 Ω−1 cm – . The resistance of cell
containing the solution at the same temperature was found to be 55 Ω . The cell constant will be
(A) 0.142cm −1 (B) 0.66cm −1 (C) 0.918cm−1 (D) 1.12cm−1

31 E ° Fe2+ / Fe = −0.441 V and E ° Fe3+ / Fe2+ = 0.771 V, The standard emf of the reaction Fe + 2 Fe3+ 
→ 3Fe 2+ will
be
(A) 0.111V (B) 0.330 V (C) 1.653 V (D) 1.212 V

32 In a first order reaction. A → B , if k is rate constant an initial concentration of the reactant A is 0.5 M,
Then the half life is
0693 log 2 log 2 ln2
(A) (B) (C) (D)
0.5k k k 0.5 k

33 Position of non-polar and polar parts in micelle is


(A) polar at outer surface but non-polar at inner surface
(B) distributed all over the surface
(C) polar at inner surface but non-polar at outer surface
(D) present in the surface only
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34 The ion that is iso electronic with CO is


(A) O2− (B) N 2+ (C) O2+ (D) CN −

35 Which of the following two are isostructural ?


(A) XeF2 & IF2− (B) NH3 & BF3 (C) CO22− & SO32− (D) PCl5 , & ICl5

36 Which of the following is most acidic


(A) N 2O5 (B) P2O5 (C) As2O5 (D) Sb2O5

37 Which of the following is an outer orbital complex and exhibits paramagnetic behaviour?
2+ 2+ 3+ 3+
(A)  Ni ( NH 3 )6  (B)  Zn ( NH 3 )6  (C) Cr ( NH 3 )6  (D) Co ( NH 3 )6 

38 → 2CuI ↓ + [ X ]
2Cu 2 + + 5I − 
[ X ] + 2S2O32− 
→ 3[Y ] + S 4O62 − ; X and Y are
(A) I 3− and I − (B) I 2 & I 3− (C) I 2 & I − (D) I 3− and I 2

39 Aluminium is extracted from alumina (Al2O3) by electrolysis of a molten mixture of


(A) Al2O3 + HF + NaAlF4 (B) Al2O3 + CaF2 + NaAlF4 (C) Al2O3 + Na3 AlF6 + CaF2 (D) Al2O3 + KF + Na3 AlF6

40

A ( predominantly) is

(A) (B) (C) (D)

41

The reaction
Which of the following compounds will be formed?

(A) (B)

(C) (D)

42 Which one of the following is not a common component of photochemical smog?


(A) Ozone (B) Acrolein (C) Peroxyacetyl nitrate (D) Chloroflurocarbon

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43 Which one of the following sets of monosaccharides forms sucrose?


(A) α D – Galactopyranose and α D glucopyranose
(B) α D glucopyranose and β -D Fructofuranose
(C) β -D glucopyranose and α -D Fructofuranos
(D) α -D glucopyranose and β -D fructopyranose
44 Nylon is an example of
(A) Polyester (B) polysaccharide (C) polyamide (D) Polythene
45 Which one of the following is employed as antihistamine
(A) Diphenyl hydramone (B) Norethindone (C) Omeprazole (D) Chloramphenicol

SECTION – A
(Numerical Answer Type)
This section contains 05 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).
46. What is the pH of 0.2 M CH3COONH4 solution?
[Given Ka of CH3COOH = Kb of NH4OH = 10–5]

47. How much heat is produced in calorie by heating one mole of an ideal gas at constant
3R
pressure from 10oC to 14oC? (CP of the gas = )
4

48. What is the rate constant k(in mol L–1s–1 unit) of a reaction which graph is given below:

20

15
t1/2
(in sec) 10

20 40 60 80
–1
Initial conc.(in mol L )

49. How many of the following compound(s) is/are more reactive than benzene towards
electrophilic bromination with Br2/Fe?
OH Cl NO2 CH3 C2H5 COCH3

, , , , ,

50. Heat
FeSO 4  → (P ) + SO 2 + SO3
How many atom(s) is/are present in one molecule of (P)?
space for rough work

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PART – III: MATHEMATICS


Section – A: Single Correct Answer Type

This section contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.

51. If n ∈ N > 1, then sum of real parts of roots of Z n = (Z + 1)n is equal to


n (n − 1)
(A) (B)
2 2
n (1 − n)
(C) − (D)
2 2

52. If a, b, c, c1, a1, e ∈ R , all are distinct and satisfy the relations a(b+c)2 +a1bc+e=0 and
a(b+c1 )2 +a1bc1 +e=0 , then
(A) a(c+c1 )=2(a+a1 )b (B) acc1 =e-ab 2
(C) a(c + c1 ) = (a + a1 )b (D) acc1 = e + ab2

53. ∑ r(
r =1
n
Cr −n Cr −1 ) is equal to

(A)2n+n+1 (B)2n -n+1


(C)n-2n+1 (D) n - 2n-1

 
54. Let a = ˆi + j, b = 2iˆ − k . The position vector of the point of intersection of the lines
       
r × a = b × a and r × b = a × b is
(A) 3iˆ + ˆj − kˆ (B) 3iˆ − ˆj + kˆ
(C) 3iˆ − ˆj − kˆ (D) none of these

  
55. a, b are two mutually perpendicular unit vectors and c is a unit vector that is inclined at
      
an angle θ to both a and b . If c = x1a + x 2 b + x 3 (a × b) , then
(A) x1 = x 2 + 1 (B) x 22 = − cosθ
(C) x 32 = 1 − 2x12 (D) x 22 = 1 − 2x 32

56. If f (x + f (y)) = f (x) + y, ∀x, y ∈ R and f (0) = 1, then value of f (7) is


(A) 1 (B) 7
(C) 6 (D) 8
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n −1
 r
57. a n = ∑  x +  , where [.] denote the greatest integer function, then the value of
r =0  n
a1 + a 2 + a 3 + ..... + a n
lim =
n →∞ n2
x
(A) x (B)
2
x
(C) (D) none of these
3

58. f(x)=[x2]-{x}2, where [.] and {.} denote the greatest integer function and fractional part
function respectively, is
(A) continuous at x = 1, -1 (B) continuous at x = -1 but not at x = 1
(C) continuous at x = 1 but not at x = -1 (D) discontinuous at x = 1 and x = -1

e −1/ x , x > 0


2

59. If f (x) =  , then f(x) is


 0 , x ≤ 0
(A) differentiable at x = 0
(B) continuous but not differentiable at x = 0
(C) discontinuous at x = 0
(D) none of these

60. Domain of definition of f’(x), where f(x)= maximum {x,1, x 2 }, ∀ x ∈ R , is


(A) R ~ {−1, 0,1} (B) R ~ {0,1}
(C) R ~ {−1, 0} (D) R ~ {−1,1}

ax + b dy d 3 y
61. y= , then 2. . 3 is equal to
cx + d dx dx
2
 d2 y  d2 y
(A)  2 
(B) 3.
 dx  dx 2
2
 d2 y 
(C) 3  2  (D) none of these.
 dx 

62. If the tangent to the curve xy+ax+by=0 at (1, 1) makes an angle tan-1(2) with x-axis, then
a+b
is equal to
ab
(A) 1/2 (B) – 1/2
(C) 1 (D) -1
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ab(a 2 − b 2 ) sin x.cos x  π


63. If a > b > 0, then maximum value of in x ∈  0,  is
a 2 sin 2 x + b 2 cos 2 x  2
a 2 − b2
(A) (B) 2(a 2 − b2 )
2
a 2 + b2
(C) (D) 2(a 2 + b2 )
2

ℓn 3
e x -1
64. ∫
− ℓn 3
ex +1
dx is equal to

4 2
(A) ℓn (B) ℓn
3 3
4 2
(C) 2.ℓn (D) 2.ℓn
3 3

65. The exhaustive set of values of ‘a’ such that x2 + ax +sin−1(x2 − 4x +5) + cos−1(x2 −4x +5) = 0 has at
least one solution is
 π  π
(A) −2 −  (B) −∞, −2 − 
 4  4
 π  π 
(C)  −∞, −2 −  (D) −2 − , −∞ 
 4  4 

66. If the side of a triangle ABC are in A.P.(order being a,b,c) and
2! 2! 1 8a
satisfy + + = , then cos A + cos B =
1!9! 3!7! 5!5! (2b)!
12 13
(A) (B)
7 7
11 10
(C) (D)
7 7

67. The combined equation of the straight lines that are obtained by reflecting the lines
y = x − 2 in the y-axis, is
(A) y2 + x 2 + 4x + 4 = 0 (B) y2 + x 2 − 4x + 4 = 0
(C) y2 − x 2 + 4x − 4 = 0 (D) y 2 − x 2 − 4x − 4 = 0
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68. Tangent drawn to x 2 + y2 = 25 at the point P(3,4) meets the circle x 2 + y2 = 81 at the points
A and B. If the tangents drawn to x2+y2=81 at the points A and B intersect at C, then co-
ordinates of ‘C’ are
 243 81   243 324 
(A)  ,  (B)  , 
 25 25   25 25 
 243 81 
(C)  ,  (D) none of these
 5 25 

69. If the circle x 2 + y2 + 2ax + 2by + c = 0 passes through exactly three quadrants and does not
pass through origin, then
(A) c > 0, a 2 > b2 (B) c < 0, a 2 + b 2 > 2c
(C) c(a 2 − c)(b2 − c) < 0 (D) c > 0, a 2 > c, b 2 > c

70. If it is raining, then I will not come. Its contrapositive is


(A)If I will come, then it is not raining (B)If I will not came, then it is raining
(C) If will not came then it is not raining (D) If I will come, then it is raining

SECTION – A
(Numerical Answer Type)
This section contains 05 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).

71. Total number of positive integral solutions of x1 + x2 + x3 = 24 and x12 + x22 = x32 is equal to

72. If S(n) denotes the sum of first ‘n’ terms of a certain A.P. with common difference 5,
then S(3n) =
S(2n) − S(n)

73. Sum of elements in the range of f(x)=[cos-1{x}], where [.] and {.} denote the greatest
integer function and fractional part function respectively, is equal to

3  A 5A 1 
74. If cos A = , then the value of the expression 32  sin .sin −  is equal to
4  2 2 4

75. P(t 2 , 2t), t ∈ ( 0,1] is an arbitrary point on y2 = 4x .’Q’ is the foot of perpendicular drawn from
focus ‘S’ to tangent drawn at ‘P’ Maximum area of triangle PQS is
Space for rough work

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