Chem 3111 quiz 1

1. A solution was prepared by dissolving 6.34 g of KCl• MgCl2 • 6H2O (277.85 g/mol) in
sufficient water to give 2.000 L. (K: 39.1 g/mol). Calculate the following. You should
write your final results with correct significant figures.
(a) the molar analytical concentration of KCl • MgCl2 in this solution.
2+
(b) the molar concentration of Mg .

(c) the molar concentration of Cl-.

(d) the weight/volume percentage of KCl• MgCl2 • 6H2O

(e) the number of millimoles of CI- in 25.0 mL of this solution.

(f) ppm K+.

(g) pMg for the solution.

(h) pCl for the solution.

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 2. Exactly 75.00 mL of a 0.3333 M solution of Na2SO3 was treated with 150.0 mL of
0.3912 M HClO4 and boiled to remove the SO2 formed.

Na2SO3 + 2 HClO4 à 2NaClO4 + H2O +SO2

(a) What was the mass in grams of SO2 that was evolved?

(b) What was the concentration of the unreacted reagent (Na2SO3 or HClO4) after the
reaction was complete?

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