Supplementary material

Instantaneous characterization of edible vegetable oils via triacylglycerols fingerprint by Atmospheric Solids Analysis Probe
(ASAP) mass spectrometry

Jessica S. Pizzo1, Victor H. M. Cruz1, Patricia D. S. Santos,1 Geovane R. Silva1, Patrícia Souza1, Luciana P. Manin1, Oscar O. Santos1,
Jesuí V. Visentainer1*

1
Department of Chemistry, State University of Maringá (UEM), Maringá, Paraná 87020-900, Brazil.
2
Post-graduate Program in Food Science, State University of Maringá (UEM), Maringá, Paraná 87020-900, Brazil
*jesuivv@gmail.com
Table S1. Fatty acid composition and lipids nutritional quality indices of sunflower, soybean, coconut and sweet almond oils samples.

Fatty acid composition (%)

Fatt Soybean Oil Sunflower Oil Coconut Oil Sweet Almond Oil
y
Co Co  Co Co
Acid SB1 SB2 SB3 SB4 SB5 SF1 SF2 SF3 SF4 SF5 CN1 CN2 CN3 CN4 CN5 SA1 SA2 SA3 SA4 SA5
dex dex dex dex
4.6-
 N  N 4.60±0. 4.63±0. 4.68±0. 4.78±0. 4.73±0.
8:0 ND ND ND ND ND ND ND ND ND ND 10. ND ND ND ND ND ND
D D 02D 01D 05 C 02 A 02B
0

 N  N 5.0- 5.38±0. 5.92±0. 5.98±0. 6.01±0. 5.48±0.

10:0 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
D D 8.0 03E 05C 05 B 00 A 02D
45.
 N  N
1- 46.23± 46.91± 46.71± 48.54± 48.47±
12:0 D- ND ND ND ND ND D- ND ND ND ND ND ND ND ND ND ND ND
53. 0.02C 0.07B 0.03 B 0.01 A 0.02A
0.1 0.1
2
16.
ND ND ND
0.06±0. 0.14±0. 0.08±0. 0.16±0. 0.07±0 0.05±0. 0.07±0 0.07±0 0.06±0 0.05±0. 8- 20.98± 21.00± 21.03± 17.63± 21.05± 0.10±0. 0.06±0. 0.05±0. 0.05±0. 0.05±0.
14:0 - - -
00C 02A 00B 00 A .00B 00C .00 A .00 A .00B 00C 21. 0.04A 0.08 A 0.00A 0.02B 0.03A 00A 01B 01B 05 B 00B
0.2 0.2 0.1
0
8.0
5.0 4.0
- 10.76± 13.15± 12.14± 12.39± 12.01± 5.62±0. 5.38±0 6.16±0 6.17±0 5.91±0. 7.5- 9.66±0. 8.22±0. 8.17±0. 9.16±0. 8.16±0. 5.37±0. 6.44±0. 6.26±0. 6.34±0. 6.59±0.
16:0 - -
13. 0.01E 0.00 A 0.00 C 0.01 B 0.01 D 01 C .02 C .00 A .01 A 01B 10. 01A 04C 04 D 03 B 01 D 06E 02 B 02 D 02 C 04 A
7.6 9.0
5 2
16:1 0.09±0. 0.16±0. 0.13±0. 0.18±0. 0.13±0 0.08±0. 0.07±0 0.10±0 0.09±0 0.12±0. 0.32±0. 0.34±0. 0.32±0. 0.69±0. 0.48±0.
ND ND ND ND ND ND
n-7 00 D 01 B 00 C 00 A .00 C ND 00 A .00 B .01 A .00 A 03 A 0.2 01 C 02 C 03 C 02 A 02 B
-
- ND -
0.2
16:1 0.3   0.8
  ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
n-9

ND ND  N ND
0.09±0. 0.09±0. 0.09±0. 0.09±0. 0.10±0 0.05±0.
17:0 - - ND ND ND ND ND D ND ND ND ND ND - ND ND ND ND
00B 00 B 00 B 01 B .00 A 01 A
0.1 0.2 0.2
ND ND  N ND
0.06±0. 0.07±0. 0.06±0. 0.06±0. 0.07±0 0.09±0. 0.09±0. 0.09±0. 0.07±0. 0.08±0.
17:1 - - ND ND ND ND ND D ND ND ND ND ND -
00 A 00 A 00 A 00 A .00 A 00 A 00 A 00 A 05 B 00 AB
0.1 0.1 0.2
2.0 2.7 ND
3.73±0. 3.86±0. 3.20±0. 4.04±0. 3.14±0 3.62±0. 3.51±0 3.55±0 3.59±0 3.38±0. 2.0- 3.84±0. 4.00±0. 3.92±0. 3.27±0. 3.99±0. 1.23±0. 1.18±0. 1.06±0. 1.12±0. 1.32±0.
18:0 - - -
02 C 01 B 01 D 01 A .02E 02 A .00 B .00 C .01 A 01 C 4.0 01C 04 A 04 B 01D 00 A 11AB 04 B 03 C 04BC 06 A
5.4 6.5 3.0

18:1 21.22± 27.65± 24.00± 28.31± 24.59± 26.54± 33.50± 29.56± 29.39± 39.46± 7.85±0. 7.76±0. 7.71±0. 8.14±0. 6.65±0. 67.40± 62.07± 62.01± 61.64± 69.02±
n-9 0.01E 0.01 B 0.02 D 0.00 A 0.02 C 14. 0.00E 0.04 B 0.01 C 0.01 D 0.02 A 01 B 05 C 03C 01 A 03 D 62. 0.15 B 0.06C 0.03C 0.00 D 0.07 A
5.0-
17- 0- 0-
10.
30 39. 76.
18:1 1.56±0. 1.84±0. 1.57±0. 1.75±0. 1.51±0 0.55±0. 0.56±0 0.67±0 0.72±0 0.55±0. 0 0.15±0. 0.05±0. 0.12±0. 0.13±0. 0.11±0. 0.05±0. 0.06±0. 0.05±0. 0.05±0. 0.05±0.
4 0
n-7 01C 00 A 02 C 01 B .01 D 01 C .05 C .00 B .00 A 01 C 00 A 00 C 01 B 00 B 00 B 00 A 01 A 00 A 07 A 00 A
48. 48. 20.
18:2 0- 55.75± 48.00± 51.96± 48.00± 51.40± 3- 62.11± 55.75± 58.72± 58.54± 49.33± 1.0- 1.11±0. 1.39±0. 1.51±0. 2.09±0. 1.10±0. 0- 25.33± 29.62± 30.06± 29.88± 22.27±
n-6 59. 0.00A 0.02 D 0.04 B 0.01D 0.02 C 74. 0.03A 0.02 C 0.01 B 0.01 B 0.03 D 2.5 04 D 00 C 00 B 01A 00 D 30. 0.05D 0.07B 0.03A 0.00C 0.04E
0 0 0
18:3 6.16±0. 4.47±0. 6.26±0. 4.43±0. 6.42±0 0.23±0. 0.23±0 0.26±0 0.23±0 0.22±0. 0.14±0. 0.07±0. 0.12±0. 0.12±0. 0.20±0. 0.06±0. 0.06±0. 0.05±0. 0.05±0. 0.08±0.
n-3 4.5 01 C 02 D 00 B 01 D .01 A 00 B .00 B .00 A .00 B 00 C 00 B 00 D 00 C 00 C 03 A 01 B 00 B 00 B 00 B 00 A
ND ND
- ND
- -
11. -0.2
18:3 0.23±0. 0.22±0. 0.19±0. 0.19±0. 0.17±0 0.3 0.07±0. 0.5 0.05±0. 0.07±0. 0.05±0. 0.05±0. 0.05±0.
0 ND ND ND ND ND ND ND ND ND
n-6 00A 00 A 01 B 00 B .00 C 00 A 03 A 05 A 00 A 00 A 00 A

0.1 0.1 ND
0.14±0. 0.18±0. 0.15±0. 0.19±0. 0.19±0 0.22±0. 0.19±0 0.19±0 0.25±0 0.19±0. ND 0.06±0. 0.05±0. 0.05±0. 0.07±0. 0.06±0.
20:0 - - - ND ND ND ND ND
00 C 00 B 00 C 00 A .00 A 00 B .00C .00C .01 A 00C -0.2 00 A 00 A 00 A 00 A 00 A
0.6 1.5 0.5
 ND 0.3 ND
0.14±0. 0.17±0. 0.17±0. 0.23±0. 0.18±0 0.79±0. 0.75±0 0.80±0 0.78±0 0.71±0.
22:0 - - ND ND ND ND ND ND - ND ND ND ND ND
00 C 00 B 00 B 00 A .00 B 00 B .01 D .00 A .01 C 01E
0.7 1.5 0.2
 N ND  N ND
0.18±0. 0.08±0.
24:0 D- ND ND ND ND ND - ND ND ND D ND ND ND ND ND - ND ND ND ND ND
00 A 02 B
0.5 0.5 0.2
∑SF 14.92± 17.60± 15.83± 17.09± 15.70± 10.48± 9.89±0 10.77± 10.85± 10.32± 90.75± 90.73± 90.54± 89.46± 91.88± 6.70±0. 7.76±0. 7.37±0. 7.56±0. 7.97±0.
A 0.03E 0.01A 0.01C 0.01 B 0.01 D 0.02 C .01 E 0.01 B 0.02 A 0.03D 0.04D 0.04 B 0.01 A 0.02 C 0.05 C 20 E 05 B 04 D 08 C 06 A

∑M 22.94± 29.72± 25.77± 30.29± 26.31± 27.17± 34.13± 30.33± 30.20± 40.12± 8.00±0. 7.81±0. 7.83±0. 8.26±0. 6.76±0. 67.86± 61.58± 62.50± 62.46± 69.63±
UFA 0.02E 0.03 B 0.03 D 0.00 A 0.01 C 0.01E 0.02 B 0.01 C 0.01 D 0.00 A 01 A 04 C 01 C 01 B 03 C 0.15 B 0.04C 0.03 C 0.06 C 0.06 A

∑PU 62.14± 52.69± 58.40± 52.62± 57.99± 62.35± 55.90± 58.82± 59.07± 47.33± 1.25±0. 1.46±0. 1.63±0. 2.21±0. 1.30±0. 25.44± 30.66± 30.14± 29.98± 22.40±
FA 0.01 A 0.01 D 0.04 B 0.01E 0.02 C 0.02 A 0.02 D 0.01 C 0.01 B 0.03E 04 C 00 B 00 D 01 C 03 A 0.06 D 0.02 A 0.02 B 0.08 C 0.04E
6.16±0. 4.47±0. 6.26±0. 4.43±0. 6.42±0 0.23±0. 0.23±0 0.26±0 0.23±0 0.22±0. 0.14±0. 0.07±0. 0.12±0. 0.12±0. 0.20±0. 0.06±0. 0.13±0. 0.05±0. 0.05±0. 0.08±0.
∑n-3 01 02 00 01 .01 00 .00 .00 .00 00 00 00 00 00 03 03 02 00 00 03
55.98± 48.22± 52.14± 48.19± 51.57± 62.11± 55.75± 58.64± 58.72± 49.33± 1.11±0. 1.39±0. 1.51±0. 2.09±0. 1.10±0. 25.38± 30.54± 30.09± 29.93± 22.32±
∑n-6 0.00 0.02 0.04 0.00 0.02 0.03 0.02 0.01 0.01 0.03 04 00 00 01 00 0.09 0.03 0.03 0.07 0.04
0.13±0. 0.17±0. 0.15±0. 0.16±0. 0.15±0 0.07±0. 0.06±0 0.07±0 0.07±0 0.07±0. 8.21±0. 7.61±0. 8.02±0. 7.19±0. 9.63±0. 0.06±0. 0.07±0. 0.07±0. 0.07±0. 0.07±0.
IA 00 00 00 00 .00 00 .00 .00 .00 00 02 01 05 01 05 00 00 00 00 00
0.19±0. 0.27±0. 0.22±0. 0.25±0. 0.21±0 0.13±0. 0.12±0 0.14±0 0.14±0 0.13±0. 6.83±0. 6.59±0. 6.48±0. 5.39±0. 7.04±0. 0.14±0. 0.17±0. 0.16±0. 0.16±0. 0.17±0.
IT 00 00 00 00 .00 00 .00 .00 .00 00 02 01 06 01 16 00 00 00 00 00
Means ± standard deviations (n = 3). Different letters within a row of same oil variety indicate significant differences of means (p ≤ 0.05). Fatty acids: Caprylic acid (8:0), Capric acid (10:0),
Lauric acid (12:0), Myristic acid (14:0), Palmitic acid (16:0), Palmitoleic acid (16:1n-7), Margaric acid (17:0), Heptadecenoic acid (17:1), Stearic acid (18:0), Oleic acid (18:1n-9), Vaccenic
acid (18:1n-7), Linoleic acid (18:2n.6), α-Linolenic acid (18:3n-3), Gamma-linolenic acid (18:3n-6), Arachidic acid (20:0), Behenic acid (22:0), and Lignoceric acid (24:0). IA: index of
atherogenicity; IT: index of thrombogenicity; n-6: omega-6 fatty acids; n-3: omega-3 fatty acids; SFA: saturated fatty acids; MUFA: monounsaturated fatty acids; PUFA: polyunsaturated fatty
acids; ∑ summation; SB: soybean oil; SF: sunflower oil; CN: coconut oil; SA: sweet almond oil. ND: non detectable, defined as ≤.0.05%; nd: not stablished by Codex.
Table S2. Relative abundances of the main triacylglycerols identified in soybean, coconut, sunflower and sweet almond oils.
ASAP ESI-MS TAG composition (%)
ASAP
Main CN/ m/z m/z
m/z CN CN CN CN CN
TAGa DB [TAG+H]+ [TAG+NH4] SB1 SB2 SB3 SB4 SB5 SF1 SF2 SF3 SF4 SF5 SA1 SA2 SA3 SA4 SA5
[TAG•]+ 1 2 3 4 5
+
CyLaLa 32:0 582 583 600 NP NP NP NP NP NP NP NP NP NP 3.63 3.76 3.87 4.29 4.10 NP NP NP NP NP
CLaLa 34:0 610 611 628 NP NP NP NP NP NP NP NP NP NP 4.26 4.82 4.94 5.37 4.80 NP NP NP NP NP
CyMLa 34:0 610 611 628 NP NP NP NP NP NP NP NP NP NP 3.30 3.37 3.48 3.12 3.55 NP NP NP NP NP
639 12.1 12.7 12.8 14.4 14.1
LaLaLa 36:0 638 656 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP
5 8 1 6 0
CMLa 36:0 638 639 656 NP NP NP NP NP NP NP NP NP NP 3.87 4.32 4.44 3.89 4.15 NP NP NP NP NP
CyLaP 36:0 638 639 656 NP NP NP NP NP NP NP NP NP NP 1.52 1.32 1.36 1.63 1.39 NP NP NP NP NP
CyLaO 38:1 664 665 682 NP NP NP NP NP NP NP NP NP NP 1.23 1.24 1.28 1.43 1.13 NP NP NP NP NP
667 16.5 17.1 17.2 15.7 18.3
LaMLa 38:0 666 684 NP NP NP NP NP NP NP NP NP NP NP NP NP NP NP
7 7 8 4 1
CLaP 38:0 666 667 684 NP NP NP NP NP NP NP NP NP NP 1.79 1.69 1.73 2.04 1.62 NP NP NP NP NP
COLa 40:1 692 693 710 NP NP NP NP NP NP NP NP NP NP 1.44 1.58 1.63 1.79 1.33 NP NP NP NP NP
PLaLa 40:0 694 695 712 NP NP NP NP NP NP NP NP NP NP 7.65 6.71 6.75 8.23 7.15 NP NP NP NP NP
LaMM 40:0 694 695 712 NP NP NP NP NP NP NP NP NP NP 7.53 7.69 7.77 5.71 7.93 NP NP NP NP NP
719 <1.0 <1.0
LaLLa 42:2 718 736 NP NP NP NP NP NP NP NP NP NP 1.15 1.24 1.88 NP NP NP NP NP
0 0
LaOLa 42:1 720 721 738 NP NP NP NP NP NP NP NP NP NP 6.16 6.30 6.33 7.24 5.84 NP NP NP NP NP
PMLa 42:0 722 723 740 NP NP NP NP NP NP NP NP NP NP 6.96 6.01 6.07 5.97 6.19 NP NP NP NP NP
SLaLa 42:0 722 723 740 NP NP NP NP NP NP NP NP NP NP 3.00 3.27 3.21 2.95 3.49 NP NP NP NP NP
723 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
MMM 42:0 722 740 <1.00 <1.00 <1.00 <1.00 1.07 1.17 1.17 1.14 <1.00
0 0 0 0 0 0 0 0 0 0 0
747 <1.0 <1.0 <1.0 <1.0
LaLM 44:2 746 764 NP NP NP NP NP NP NP NP NP NP 1.36 NP NP NP NP NP
0 0 0 0
LaOM 44:1 748 749 766 NP NP NP NP NP NP NP NP NP NP 5.60 5.64 5.70 5.26 5.06 NP NP NP NP NP
SMLa 44:0 750 751 768 NP NP NP NP NP NP NP NP NP NP 2.73 2.93 2.89 2.14 3.02 NP NP NP NP NP
PLaP 44:0 750 751 768 NP NP NP NP NP NP NP NP NP NP 1.61 1.17 1.19 1.56 1.21 NP NP NP NP NP
751 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
PMM 44:0 750 768 <1.00 <1.00 <1.00 <1.00 1.56 1.34 1.37 1.34 <1.00
0 0 0 0 0 0 0 0 0 0 0
POLa 46:1 776 777 794 NP NP NP NP NP NP NP NP NP NP 2.58 2.20 2.23 2.75 1.98 NP NP NP NP NP
777 <1.0 <1.0
MOM 46:1 776 794 NP NP NP NP NP NP NP NP NP NP 1.27 1.26 1.28 NP NP NP NP NP
0 0
779 <1.0 <1.0
SLaP 46:0 778 796 NP NP NP NP NP NP NP NP NP NP 1.26 1.14 1.18 NP NP NP NP NP
0 0
803 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
LaOO 48:2 802 820 <1.00 <1.00 <1.00 <1.00 1.21 <1.00
0 0 0 0 0 0 0 0 0 0 0 0 0 0
805 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
POM 48:1 804 822 <1.00 <1.00 <1.00 <1.00 1.35 1.16 <1.00
0 0 0 0 0 0 0 0 0 0 0 0 0
831 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
PLP 50:2 830 848 2.16 2.78 2.50 2.44 2.44 <1.00 <1.00 <1.00 <1.00
0 0 0 0 0 0 0 0 0 0 0
833 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
POP 50:1 832 850 1.61 1.15 1.44 1.17 <1.00 <1.00 <1.00 <1.00 0.93
0 0 0 0 0 0 0 0 0 0 0
PLnL 52:5 852 853 870 4.50 1.89 2.61 1.73 2.61 <1.00 <1.0 <1.00 <1.0 <1.00 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.00 <1.0 <1.0 <1.0
 0 0 0 0 0 0 0 0 0 0 0
855 10.0 10.4 <1.0 <1.0 <1.0 <1.0 <1.0
PLL 52:4 854 872 11.24 10.75 9.43 7.09 5.36 6.91 7.03 4.67 1.08 1.76 1.75 1.79 1.02
8 7 0 0 0 0 0
855 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
PLnO 52:4 854 872 1.10 1.20 1.02 1.25 <1.00 <1.00 <1.00 <1.00
0 0 0 0 0 0 0 0 0 0 0 0
857 11.6 11.1 10.0 <1.0 <1.0 <1.0 <1.0 <1.0
PLO 52:3 856 874 8.54 9.92 6.05 6.45 6.96 7.05 7.50 5.73 7.37 7.20 7.34 6.31
6 1 2 0 0 0 0 0
859 <1.0 <1.0 <1.0 <1.0 <1.0
POO 52:2 858 876 1.62 3.37 2.29 3.28 2.40 1.29 1.94 1.75 1.77 3.01 7.63 7.71 7.42 7.53 9.76
0 0 0 0 0
859 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
SLP 52:2 858 876 1.49 1.64 1.32 1.58 1.26 <1.00 <1.00 <1.00 <1.00
0 0 0 0 0 0 0 0 0 0 0
877 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
LLnL 54:7 876 894 6.52 3.44 5.60 3.35 5.58 <1.00 <1.00 <1.00 <1.00
0 0 0 0 0 0 0 0 0 0 0
879 12.1 12.1 14.9 18.7 22.1 <1.0 <1.0 <1.0 <1.0 <1.0
LLL 54:6 878 896 19.55 15.40 26.21 22.12 12.98 1.68 2.71 2.83 2.84 1.15
9 7 5 9 3 0 0 0 0 0
879 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
OLnL 54:6 878 896 4.95 3.97 5.17 3.95 5.34 <1.00 <1.00 <1.00 <1.00
0 0 0 0 0 0 0 0 0 0 0
881 21.1 21.5 21.4 33.9 33.3 <1.0 <1.0 <1.0 <1.0 <1.0 13.4 17.4 17.4 10.6
OLL 54:5 880 898 22.28 31.33 33.55 33.41 31.27 17.03
5 2 6 0 1 0 0 0 0 0 2 8 7 6
881 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
VLL 54:5 880 898 1.58 1.37 1.42 1.37 1.31 <1.00 <1.00 <1.00 <1.00
0 0 0 0 0 0 0 0 0 0 0
879 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
OLnO 54:5 880 898 1.15 1.19 1.63 1.28 <1.00 <1.00 <1.00 <1.00
0 0 0 0 0 0 0 0 0 0 0 0
883 12.2 12.6 10.2 20.3 16.7 <1.0 <1.0 <1.0 <1.0 <1.0 35.7 36.0 35.8 32.9
OLO 54:4 882 900 8.46 9.84 14.32 16.82 25.10 35.68
3 9 7 9 1 0 0 0 0 0 5 1 8 9
883 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
SLL 54:4 882 900 3.88 2.98 2.84 3.04 2.70 4.56 3.54 4.08 4.08 2.69 <1.00
0 0 0 0 0 0 0 0 0
883 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
VLO 54:4 882 900 1.20 1.59 1.32 1.61 1.25 <1.00 <1.00 <1.00 <1.00
0 0 0 0 0 0 0 0 0 0 0
885 <1.0 <1.0 <1.0 <1.0 <1.0
SLO 54:3 884 902 2.96 3.44 2.62 3.59 2.59 3.89 4.26 4.10 4.09 4.32 1.27 1.38 1.28 1.28 1.24
0 0 0 0 0
885 <1.0 <1.0 <1.0 <1.0 <1.0 31.7 24.7 24.5 34.0
OOO 54:3 884 902 1.07 2.36 1.51 2.49 1.64 2.04 4.09 2.82 2.80 6.72 24.91
0 0 0 0 0 4 2 6 2
887 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
SOO 54:2 886 904 <1.00 1.06 <1.00 1.28 1.03 1.03 1.73 1.70 1.45 1.32 1.32 1.92
0 0 0 0 0 0 0 0
TAG: Triacyglycerol. NP: fatty acid is not present in oil composition according to Table S1. aFatty acid abbreviations: Caprylic acid (8:0), Capric acid (10:0), Lauric acid (12:0), Myristic acid
(14:0), Palmitic acid (16:0), Stearic acid (18:0), Oleic acid (18:1n-9), Linoleic acid (18:2n.6), and α-Linolenic acid (18:3n-3). SB: soybean oil; SF: sunflower oil; CN: coconut oil; SA: sweet
almond oil.

Figure S1. Representative full scan ASAP-MS data of five different lots of sweet almond oil.

Figure S2. Representative full scan ASAP-MS data of five different lots of sunflower oil.
Figure S3. Representative full scan ASAP-MS data of five different lots of soybean oil.

Figure S4. Representative full scan ASAP-MS data of five different lots of coconut oil.
Figure S5. Representative full scan ESI(+)-MS data of five different lots of sweet almond oil.
Figure S6. Representative full scan ESI(+)-MS data of five different lots of sunflower oil.
Figure S7. Representative full scan ESI(+)-MS data of five different lots of soybean oil.
Figure S8. Representative full scan ESI(+)-MS data of five different lots of coconut oil.