Lampiran Perhitungan

1. Volume tertier butil alkohol

Diketahui : ρ (CH3)3COH = 0,78 gram/mL
m CH3)3COH = 12,58 gram
Ditanyakan : V = …?
m
V=
ρ
12,58 gram
=
0,78 gram/ml
= 16,13 ml
2. Rendemen (%)
Diketahui : m (CH3)3COH = 12,58 gram
ρ (CH3)3COH = 0,78 gram/ml
V (CH3)3COH = 16,13 ml
V HCl = 42,5 ml
ρ HCl = 1,18 gram/ml
Mr HCl = 36,5 gram/mol
Mr (CH3)3CCl = 92,5 gram/mol
Mr (CH3)3COH= 74 gram/mol
Ditanyakan : % rendemen = …?
Penyelesaian : Massa HCl = V HCl x ρ HCl
= 42,5 ml x 1,18 gram/ml
= 50,15 gram
m HCl
Mol HCl =
Mr HCl
50,15 gram
=
36,5 gram/ml
= 1,37 mol

Mol (CH3)3 COH = 0,17 mol

(CH3)3COH(aq) + HCl(aq) (CH3)3CCl(aq) + H2O(l)
Mula-mula 0,17 mol 1,37 mol - -
Bereaksi 0,17 mol 0,17 mol 0,17 mol 0,17 mol
Sisa - 1,20 mol 0,17 mol 0,17 mol
Massa teori (CH3)3CCl = mol (CH3)3CClx Mr (CH3)3CCl
= 0,17 mol x 92,5 gram/mol
= 15,72 gram
= 18,72 mL
Massa praktek (CH3)3CCl = V (CH3)3CCl x ρ (CH3)3CCl
= 3 ml x 0,84 gram/mol
= 2,52 gram
massa praktek
% Rendemen = x 100 %
massa teori
2,52 gram
= X 100%
15,72 gram
= 16,03 %