Materials A process flow diagram will be needed where materials of
construction can be noted. Amine corrosion only applies to equipment made of carbon or low alloy steel. Heat Stable Salt Concentration Determine the Heat Stable Salt content as a percent of the total solution. (Not HSS percent of total amine, see reference 3) Corrosion Coupon Corrosion Rate Corrosion coupons are typically found in the hot lean amine line or regenerator reboiler return line. Corrosion may show high in one system but low in another. Use a process flow diagram to identify all equipment in service conditions similar to each specific set of coupons. For example, if the coupons are in the lean amine line off the regenerator bottom and are showing more than 0.010 inches per year loss, then the following equipment may experience accelerated corrosion. The regenerator, the regenerator outlet piping, and any other equipment in the outlet piping up to the rich/lean exchanger where temperature of the lean amine is lowered. Velocity Fluid velocity will need to be calculated for the amine service lines in the plant. Experience indicates that a velocity over 6 feet per second can cause corrosion in the line, particularly at points of turbulence. Do not worry about amine pumps as they always have sufficient velocity and turbulence to cause amine corrosion, and are usually alloy. The industry standard prediction tool for CO2 corrosion is the nomogram by DeWaard-Lotz- Milliams from their 1991 NACE paper. It generally provides for a conservative, i.e. over estimation, of corrosion. The nomogram is presented below with permission of the National Association of Corrosion Engineers.