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    32 views128 pages

    Hjsdfasvfa 2022

    Uploaded by

    Bala Ji G

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    errs Asmeciy ora : CYPG/2022 rai 2022 sar — 1 Gasudued (YpBeoe WHLKugLY4s Spb) 10) sare) : peng) wee Cay] [Quongs wA4Quakrear : 300 Garésgsg ubostsgqrar Apesam .oPlanyacer suanorets Uyssoib % pala aBpainrad L id earsdengau, Cota Gsm igaisde 15 MO nsenies opérargrs a niaenks aupiusriiGih Be ea ety ge re pee Soe See ee eee Suspect oaths Carey Gp tdes GObG opened ren wp ee etre a eceiees l@rudlésad. cdar Alemnésand eownen wAC@uensér Qancim_eau. 4. HE G_OLW LiPe; caren se leat gy Gind gpanauild Aser emoggcra Oi she fuser reps lig Cap oa eaceeees erQpBemLrgl. ee eee ae 5. Beogsnd gen e_secr Winsg opssensreMainergnd eisai cuprsscU@id. Sees sang 2erefi res Garippinas Geusirges si fleyengescr den pgienees, (EmL DOES Fag culpaciue (Harare. 6. HeargAgneu —— (Question Booklet Number) flen_ggrrafler 5580 ogetee mong eno ‘eouels —ubgrom et aeecera Betonci Gace, sBorspoptecu caterer en ure SLE seaplane Ge Goes! po fardon Saeg ees a gers Ghtenpianoe 7. ong © odes O) sous gy ps ter dew ae Ook oe seats axbongs (D) @enousatled lumen Blancos Asay Qe tig cle a me Giang eons Sapuie ohare Sia ox Gone net epee wenhtee ea Henao Slo ggnafi @ilsgieam ceo “ers Sle. weBnce Sadud AMUGAGMOD. crigunBgnnd, oo Csorcas SCr GO Beeee Sao. Bhar ps San ig gage Ooh pie oe 8. fm amp enesae senapestn im 3005 Bisson ming. Cpta; Coho Obs — eg Seen eee eee Bini 9. RO ur eyed Soenmaea (Oat 2.¢raT LibsitisopeT Ler sperma mrtg oes ache SLAB Pol peer pe hres 10. snanég) Dariaaligih aisle eine eos. Ai Ralety Cideuwi. slain setamwnag SEUNS pans Ostaraens spt PLaKsmsserse 2crams CpfiPib car sPlapssuu ENGLISH VERSION OF THE ABOVE INSTRUCTIONS ARE — ON THE BACKSIDE OF THIS BOOKLET & {Turn over SPACE FOR ROUGH WORK CYPG/2022 2 In the given phase diagram at constant pressure, the degree of freedom at point ‘x’ is x 100% Ag 100% Pb (A) three WT wo (C) one ©) zero (BE) Answer not known Que AsnGsscucQerer Peowner spss Geren st awjursHia, Usrafl ‘x’ Wer «553 ULL Sle cratenflésens créer? = 100% Ag 100% Pb A) yan B) Qran@ © aenp O) waQuo (E) Bear Asfuciedrena 3 CYPG/2022 [Turn over 2. In the reaction N,04,, = 2NO2@) , N20, is 20% dissociated at 298 K and 2 atm pressure. The percentage of dissociation at 1 atm will be @) 10 28 (© 40 () 98 (BE) Answer not known N20, 2NOo() corp aflenemusie NO, 298 K Gaiciusflenanuder 2 aueflingon_o 2198855 20% Aepam Hpy sald 1 acl veme oisssdo A@sam_uyb sgohgib (A) 10 to SBS (©) 40 “ @) 98 (BE) lor Qgfuddaa 3. Consider the following equilibrium at 298.15K 14N, +340 NH, - The value of K, for the equilibrium is : AF® = change in free energy AF =-3980 cal. 298.15 K. (A) 2.917 3.98 @) IH 226.1 @) 1.98 (E) Answer not known Spsred Quss evflmau 298.15K -© YNy, +36Hy, = NHy, é Quss soflmater K, Wer oScurengi ogi? AF® = change in free energy AF° =—3980 cal. 298.15 K. (A) 2.917 (B) 3.98 (©) 826.1 @) 1.98 (E) Aer Qpfucioea CYPG/2022 4 & 4, In the following green reaction, Cr CH. ag. KMn0, Cy COOH ee ey 2 Toluene : Benzoie acid ss (> 85% yield) YH Crown ether (B) Dimethyl ether (©) Diethyl ether (D) Dipropyl ether (E) Answer not known ~ Exicin_ User Slerom9e, or CH. a4 KMnO, Cr cooH eee AL nguesen : QuaiGems ouland (285% Qupg) (A) Syay6r apt B) @Lavsde rst (CE) @ assia rsir QD) av YGyneue Feit (B) Aer AgiflueAeoenes 5. Barium Sulphide exhibits (A) Fluorescence MF Phosphorescence (©) Bio-luminescence (D) Chemiluminescence (E) Answer not known Gumlud soau® B GanGsAngy. (A) 2LGenafiga B) Aspnes (C) 219 gofige QM) Gad) gafligse (B) er Qsfuciaere w 5 CYPG/2022 [Turn over 6. Which one of the following is act as a Photosensitiser? (A) Tungsten @) Platinum (© Silver WF Mercury (E) Answer not known Epscr_aphe ag gall canta’ quins QouduGdpgs? (A) Lrieiveer (B) Germ wend © adr @) ungroo () Gear Asfudeome : 7. The Stern-Volmer equation for fluorescence quenching is given as [el] fs. hQ yh ~ (eee OF iy eer [al $0 _ Wii Lia } i Ped pace eg te i. (E) Answer not known ahGd sérow safiughsrer ovGLér — gawiler sflumer FLOSTLIM tg. Cer seins. : [2] 9.0 kQ Gp0 _ hy (A) ——=1+)———+—_ ‘B) —_—_— Oe pe) Oi yamat ha [a] tro $0 _ hy } op. peer © Geahn Oe eres (E) Alar A@sfluddca CYPG/2022 6 & 8. The value of activation energy E, can be obtained by plotting (A) logK against T (@) K against T WM logK against 4, @) log Ye against 4, (E) Answer not known Bariey Gard a ppe Eq Wer nsitieou Beuamp aeypursse SHlugser Epard Qupambd (A) logK afigns T ®) K afigns T © Wek afore Yp @) log Yq afar Vp ©) ior Asfluchidera 9. The rate constants of a first order reaction at 400 K and 200 K are 0.04 and 0.02 s-}, respectively. Then its energy of activation (Z,) is (Given : R=8.314 JK“mol”) (A) 2000 J mol P2300 J molt (C) 2500 J mol (@) 1900 J mol (E) Answer not known 400 K wagid 200 K 2yAu Qaiiplnmsciie Cpe ans AenenGas winpdlecr apy 0.04 st ppd 0.02 s* colle Hania appaas sandAQs. Gsn@ésastUi Loe : amy wn = 8.314 JK" mol”) (A) 2000 J mol (B) 2300 J mol (© 2500 J mol (@) 1900 J mol (E) lar Agfucileoeme & 7 CYPG/2022 [Turn over 10. The study of chemical kinetics can provide information about which of the following? (@ Rates of chemical reactions Gi) Reaction mechanisms Gii) Factors that influence rate of chemical reactions (A) @ and (ii) (B) @ and iii) (C) Gi) and (iii) LF ©, Gi) ana Gi) (E) Answer not known Cah MerenCasudud Spar apner obO5 55 s20mad QanGadlenng) 2 @) MenanuMer Gausid Gi) Aeoen aparann Gil) Amanda Cusgeg unde snpenfsdr A) @ wppw Gi) (B) (@ wpguo Gi) (© Gi) wppu Gii) ©) ©), G) wogw Gi) (BE) Ben. AgifuscSlereney CYPG/2022 8 & Bye 12. Glucose on reduction with NaBH, to form (A) Pentane-2, 4-diol (B) _Hexane -1, 6-diol G7 Suditol () Mannitol (E) Answer not known G@psGsram NaBH, Gran gOsab Qstagrd Aotugs (A) QuenGér -2, 4-ewined (B) GanéCoven -1, 6— oud (6) enm9cind @) wreaficine ©) dar Qsfuddma In Hammett’s equation the substituent constant ‘c’ is more positive. When? ‘The electron withdrawing power of the substituent is greater. (B) The electron withdrawing power of the substituent is lesser. (©) The electron releasing power of the substituent is greater. (D) The electron releasing power of the substituent is lesser. (E) Answer not known. Gano. sverige otiGungg (6) UPSCO wnpldAuver ws sss Cpr ALY eusns BH Ed? (A) UASLO AsrEAWer cos qren suigcan sPswrs QHseqb umeps B) LAS AsrgAer cose qrer surscrn Gopans QGesSb Aum (CC) us Asr@Huver crs qner Qachic Gs serow sslsors QGsqd Qumwas DO) LPSLO AgngeAver crosoner GauaMU GS sorow Gopans QGsGb Qumepas E) dar Asfiucilde@s 9 CYPG/2022 [Turn over 18. Cannizaro reaction takes place in this type of aldehyde (A) formaldehyde (B) formaldehyde and acetaldehyde (©)_ benzaldehyde formaldehyde and benzaldehyde (E) Answer not known Asn Ossie Geror YoymanGsale séralenCyr Aenea eGUuGUon (A) umiioréqgcran@ B) uniordaqgoan® vpgd HLtdgman (C) Quererdyman® OD) urtordyean@ wpm Qucrerdyoan® E) Par Agfludsa ; 14. The product obtained in Perkin reaction from bonmeldehye is WI C,H; -CH=CH-COOH (B) C,H;-CH=CH-CHO (©) CH, - CH = CH- COOH @) CH, - CH = CH-CHO (E) Answer not known ace Aad Aucrerdymengd QGsgi Se sGb Heer Herer Qunger si (A) C,H;-CH=CH-COOH (8) C,H;-CH=CH-CHO (©) CH; -CH = CH-COOH @) CH, -CH = CH-CHO © ar Asfiusioss CYPG/2022 10 & 15. Which one is the product of the following reaction? @ @) © wr © Cc : qa) ov? (2) HCl [__)—coocn, > CH, - CH, Los COCOOH [>= coon Answer not known Epacin clnender Heer Guinea «rg1? (A) @) © @) ©) : S (1) 0 : gees (2) HCl ‘0 Lo CH, - CH, “7 Cocoon — COOH Aen Opfiussflerene n CYPG/2022 [Turn over 16. The hybridization of OCR, anion is sp? ®) dsp? () sp ©) sp? () Answer not known Scr, Hume Derssociwinssed (A) sp? (B) dsp? (©) sp (D) sp? (E) Alar Qs flusiaoere 17. The correct order of bond polarity is (A), C-F>C-0=C-NC-O>C-N>C+C (©) C+FC-0=C-NC-0>C-N>C-C @ C-F Moy > M* > M* PF M* > MO} > M™ > MO; (©) Mo} > M* > M* > Mo} (D) Mo; > M* > Mo# > M* (E) Answer not known BSyMaA Swelsciler enema 2 Ganga cssAer Bn als (A) MO; > Moy > M™ > M“* (8) M* > MO? > M* > Mo; (©) Moy > M* > M* > MO; (@) MO; >M* > Moe > M* © dar @sfludeoma In actinides, the degree of complex formation for the ions M**,M**,MO3* and MO} decreases in the order \O7 M* > Moz >M*>MO3 — (B) M* > M** > MO} > MO} (©) M*>M*>MO;>MO3 @) M** >M* > MO} > Mo} (BE) Answer not known BymarOschd, M*,M*,MO3 wppib MO} Su: suefisciiar o\enemrayé Gsiod aang dfsb Gepu aflmsurengy (4) M*>MO3*>M*>MO; (@B) M* > M* > MO#* > MO} (© M*>M*>MO;>MO2 —(D) M** > M* > MO; > MO2* (E) Ale Agfiueilaane CYPG/2022 38 we 62. Which of the following M* Lanthanide ion have maximum magnetic moments in (BM)? (A) Pr® (B) Sm** (C) Ga* iP Dy* (E) Answer not known Epsscn_ M* onfsmer® suwefsdla sPeucs sibs AGuUp Aper Qsreim_ cmusell «rg? (A) Pr* (B) Sm* (© Ga @) Dy* (B) Aer Gpfucoae 63. Choose the correct order of reducing strengths of lanthanide +2 ions (A) Sm* > Eu” > Yb** QF 8m" > Yb™ > Eu” (©) Yb* > Eu* > Sm* () Bu > Yb" >Sm* (E) Answer not known anbsme® +2 suailsatie eOSGo Aperacflen sfluren aiflenscous Gstb0s (A) Sm > Eu® > Yb** (B) Sm* > Yb* > Eu (©) Yb* > Eu* >Sm* (@) Eu* > Yb* > Sm* () Aor sfucoeme & 39 CYPG/2022 [Turn over 64. [Co(NH,),}" is more stable than [Co(NH,),P*. Since (A) Co** (a”) has much higher value of CFSE GF Co* (4*) has much higher value of CFSE (©) Both Co** and Co* have the same value of CFSE @) Co** (d*) has lower value of CFSE (E) Answer not known [Co(NH,),P* ow ef. [Co(NH,),P* 8s fmaciys serano eumiubggs. Taree A) Co®* (d”) 28s CFSE wf iy Garam gy (B) Co* (a) xfs CFSE wfitiyé Ganon gy ©) Co** npg Co** @rar@Gw o ora; CFSE wslsyse6r Aereior_gy D) Co** (d°) seopee CFSE wAcys Garang CE) Aer QgAuchose CYPGi2022 40 & 65. 66. Correct statement on the colours of the solutions of the complex ions [Ni(H,0), P* and [Ni(CN),}° is (A) [Ni(H,0),P* is colourless and [Ni(CN), > is green 97 INi(CN),} is colourless and [Ni(H,0),}** is green (C) Both are green in colour ©) Both are colourless (E) Answer not known [Ni(H,0),P* wp» [Ni(CN),P° sinara, swofisoficr sesedsafien Bows e5ésrer sfuiman sido (A) [Ni(,0),F* sooppe opp [Ni(CN),P users Spwrerug ®) [NiCN),P Sowp0s opp [Ni(H,0),F* veers Poereruss CO) QrarGw users fpm@snein_oe OD) QranOd sowdowa E) lar Asfiucdee Which of the following complex ion is Low spin and diamagnetic? (A) [CoF.}* (B) [Mn(CN), or [Rh(NH;), P* ©) [Co(NH,),* (E) Answer not known Epascir. Soca, swellseld crneu smp spbA wpprd Lwranbss serenw Gasreim_snes? (A) [oF ®) [Ma(cn),P° (© [Ra(NH;),* ©) [Co(NHs),/* () Aer AgfucAdcra 41 CYPG/2022 [Turn over 67. Match the following : Compound (a) CsCuCly () KCuCl, (© NH, CdCl; @ ®° © @ 2:98 2 1 Ouse @) 3 2 (©) Answer not known Qungggis > Gamo (@) CsCuCl, ) KCuCl, (©) NH, CdCl, @ © © W223. 71 Qe 1g (Oe 88 as @) 3.241 ©) Aer @sfiucido@me CYPG/2022 Co-ordination Number/nature of bond 6/C1, -(Cu,Cl,)-Cl, — double chain (distorted octahedral) 4/-Cl-(CuCl,)-Cl - chain 6/double chains, undistorted Doane, creit/sen0014 6/C1, -(Cu,Cly)—Cly — @reer studio Fp ereirap 4/-Cl-(CuCl,)- Cl — sided 6/ Qytoor siASsdr, Eqrengy 42 we 68. Which of the following obeys Sidgwick’s EAN rule? (A) [Fe(CN),]*" B) [Co(CNe]* (© [Ni(CN),)" PF [CulCN),]” (E) Answer not known Aeraunacraupmer i gailsder EAN Hew Gerugiegy ogi? (A) [Fe(CN)6]* (B) [Co(CN)g]* (©) INi(CN),)> ) [Cu(CN),]* ©) dlr @sfuddae 69. The isomerism involved in the complex pair [pt(NH;),Cl,]Br, and [pt(NH3),4Br,JCl, is 97 Tonisation isomerism (B) Hydrated isomerism (C) Coordination isomerism (@) Linkage isomerism (E) Answer not known [pt(NH,),Cl,JBr, wig [pt(NH;),Br,JCl, c@id simera Catwnisalle FOUL Oerar wnp Busi A) swetwinés ompSud B) septisnGanpp wnppurd (CC) smareunés wm bud QD) Qeamtny wonpfuw ©) Ber Asfucidoara e 43 CYPG/2022 [Turn over 70. The ESR spectrum of naphthalene radical anion consists of (A) @®) ©) we () 10 lines 15 lines 20 lines 25 lines Answer not known prigéer sel opty aA suefluder ESR siya Apwramavle asgsener CanGadr SrewliuGid (A) @®) © @) @) 10 Gsn@ser 15 Gen@aer 20 Gan@acr 25 Gan@aer Aer Aguchdrara 71. 2-D NMR spectra have intensity axis. a @) © @) (@) 2,1 a4 4,1 5,1 Answer not known 2-D NMR slyemiscies <21bers(@5Lb 2 draren. (A) () © @) ® CYPG/2022 2,1 3,1 4,1 5,1 Aor Asfuceera frequency axes and OPiGadr sss@nb, a xflay 44 & 72. 73. The’ molecular ion peak in aromatic compounds is relatively much intense due to the presence of ——————— electron system. @ o On © n (@) Both o and z. (E) Answer not known CprCntgcr CsiomsAd Cosmp Wahl psigar Gepla sissors QeiUsE arpemb sf 2éren or @&L gen g1om011L4 A o () 2 On (D) o & 7b Gathg Oouug ©) ar Asfiucaaa ‘The Infra-red spectrum of carbon-di-oxide molecule consists of two bands at 2350cm~! and 667cm™’. These bands are due to Yr Asymmetric stretching and bending vibrations respectively (B) Symmetric stretching and bending vibrations respectively (C) Symmetric stretching and Asymmetric stretching respectively (D) Appearing due to two types of bending vibrations (E) Answer not known smiiét-oo-ysnsQ epadenfler siséaiiy lpvorrercudler 2350cm™) wpm 667em™ y8u sao censcld cpsOsdr cpepGw asain Csnerpdérper? (A). waptu srenougp SCA oppId amerse sArajscfemne B) yanGu Srewuydror $A ppd awargd mPraysefenns (CC) repGu Sienoujsror LA wood Sreoowpp BLA D) QranG Agionen amare PitaysoMennd Gprenp Sennen ©) Aer AgfucAdrene 45 CYPG/2022 [Turn over 74. 75. In IR spectroscopy resonance effect of a double bond in an amide will (A) displaced to higher wave number PF displaced to lower wave number (©) will not affect the position of signal @) will not allow to Record spectra (E) Answer not known assay Soormaoralie gsdlensa, Aencra, sm0G-& eXdrar QoL DeemiIa Aegisgibd Benaray A) sPavren sine cengné6 wombmd B) Gapainen Kno creireniss ompgnd ©) aps Aercrmauyd opuGseng) ©) Spvreevcrefleu Qwss seo opuGsgd ) Alar Agflualana The value of wave function can be (A) Positive (B) Positive and zero (C)_ Positive and negative only WA Positive, negative and zero (BE) Answer not known Boos AswdumT er WAY wUg BGssomd? (A) Gpinap wSuIe Boqsseombd B) Gotwoep opm Ugurs QGssamd (©) pina opmid «Siroap oI Qwssamd D) Gpnoep, «Slop wpond ysuuors ep seomd ©) Aer AsAuciasme CYPG/2022 46 we 76. 77. ‘The important factor which determines the rate of absorption of energy in NMR by a nucleus is WH spin-lattice relaxation (B) Spin-Spin relaxation (©) Fermi resonance @) Spin-Spin coupling () Answer not known 2OMssG smbs erefesa, Hovrmavld mood oAeeiGerns Sinorefls@d (su anger (A) sbappal - ume sarita CB) spay - sbappél saritay (©) Gums o1alensay (D) spapdA - sbayppA Qenanay (BE) ler pfuciaee The mass spectrum of Benzaldehyde exhibits the most intense peak at mie (A) 75 (B) 76 Im () 78 (E) Answer not known Qucrsrayoanyer Cungeman0 Apormauvle ss Gsfleyen sigus sO Gareénp m/e -er Alt (A) 75 (B) 76 © 77 () 78 (©) Alar Asfuciaaa 47 CYPG/2022 {Turn over 78. Calculation of the vibrational frequency of a bond with reasonable accuracy as at \ My Ms a + al pee (By as Gemecmy Hm + amas) 1 Oe Emam Km, aatcas) ot k ae | (E) Answer not known 9G Goremider oPiag AtGocinnan Spssdn Asm mac UveiGss semsE_ambd oe Eee) ® ht) 2 Gamera) @ rim) (B) Aer. @psfiuscSierenco CYPG/2022 48 s 79. Calculate the number of vibrational degrees of freedom for benzene (A) 18 @® 12 I 30 @) 36 (E) Answer not known QucrSgiésren 14. 5Usteyssrer SLig.érenw Tana: sims (A) 18 @® 12 (C) 30 @) 36 (E) Alor Asfudoame 80. In corrosion galvanizing is the process of coating iron object with YF Gine @) © @) Gadollinium Gallium Indium (E) Answer not known asifloneng8led snroamendia Geuagrannile QgGdaer Bs WeuGags @& @) © @) ®) As aGurdlefund emu Dora usid Hen Gg fussidrena 49 CYPG/2022 [Turn over 81. The Debye-Huckel Onsagar’s equation for a solvent at given temperature is A) An =A, +(A+BA;,) VE ®) A, =A, +(AA;, +B)VE ©) An =A_-(A-BA;,) VC PP n= Bin (A+ BA VE (E) Answer not known 2G GONICL senqiuTgM“sS, GAIILL GariiplmoIEa you-shsse senensit sémin@ ——————- a6. @ A,=M, +(A+BA,)VC (B) An =An + (AA, + B)VC ©) Ag =A, -(A- BA’, ) VO @) An =A, -(A+BA;,) VC €) ar @sfuddaa CYPG/2022 50 es 82. The equivalent conductances at infinite dilution of NH,Cl, OH™ and Cl- are 130, 174 and 66 ohm™! cm” egqvt."! respectively 20°C. Predict the equivalent conductance of NH,OH at infinite dilution at 20°C using Koblrausch’s law (A) 370 ohm™ cm? eqvt.? (B) 110 ohm™ cm? eqvt.? MF 238 ohm™ cm?® eqvt.* (D) 22 ohm! cm? eqvt.* (E) Answer not known eumbupp $785 HlerauIe 20°C —d NH,Cl, OH” wpgib Cl” Qarausatler sumer sig) Apensér cpepGu 130, 174 wom 66 ohm” cm? eqvt.* ew. 20°C-& agbudp Sigs fleoauler NH,OH-er sora agg) Speon Candyray APUG soir_H (A) 370 ohm cm? eqvt.* (B) 110 ohm™ cm? eqvt.* (C) 238 ohm cm? eqvt.* (@) 22 ohm” cm? eqvt.* ) dar Asfuda@e 51 CYPG/2022 [Turn over 83. The standard reduction potentials of Pb?* and Ag* respectively are — 0.13 V and + 0.80 V. What is the E’ for the following overall cell reaction? Pb+2Ag* > Pb?* + 2Ag @ 0.67 V PI 0.93 © 147V @) 173V () Answer not known Pb** wom Ag* @mascier ALL gGss Deronysstiscr apenp@u — 0.13 V wopprd + 0.80 V. Dereugid apgp Wlesrsa cSlenanuIer E° crevrar? Pb +2Ag* > Pb + 2Ag (A) @) © @) ©) CYPG/2022 0.67 V 0.93 V 147V 1.73.V Aor Agflueldena 52 z 84, La,, Ba,, CuO, behaved as a super conducting material at 85. temperature. (A) 10K (®) 10K © 80K wT ® AsueuGapgy. @ @) © @) ®© At 0°K, covalent solids like @) @®) 35K Answer not known GatuiGerauIe La,;Ba;;Cu0, Bes Hers. sSuirs 10K 110K 80K 35K Har Agsflucildena do not conduct electricity. Copper Zinc JO Germanium @) 103)) Aluminium Answer not known OK Garuigloavle ssciMercorcry serocs Qungsetter ——————— lear Bomeovs s_ssrg. (A) ®) © @) ©) pri sisspreib Gegtoreusd rgBleflust Har Asfuclrena 53 CYPG/2022 {Turn over 86. 87. ‘The number of Schottky defects in a crystal is (A) n=-N exp(-E/2 kT) (B) n=N exp(E/2 kT) SF n=N exp(-E/2 kT) (D) n=N exp(-E/kT) (©) Answer not known 2G Uys6A 2 crot Lagr A Genpun@safler crerashlsens (A) n=-N exp(-E/2 kT) (B) n=N exp(E/2 kT) (C) n=N exp(-E/2 kT) @) n=N exp(-E/kT) E) Aw Qsfucilo@ma The Miller indices of the planes are intersect in the crystallographic axes at the distances (2a, 3b, 2c) and (2a, 2b, 2c) are (A) (232) and (220) (B) (233) and (101) (323) and (110) (@) (832) and (010) (E) Answer not known Qa, 3b, 2c) wigid (2a, 2b, 2c) Agrmoaisdr Aare uplisluosens Goins HSiT_NSSIUOL sors sled oan mG Mdoit Elem _qadt wrencs? (A) 232) wop (220) (B) (233) pp» (101) (©) (823) wpgnb (110) (D) (832) wppw (010) (B) Ber AgAucteorse CYPG/2022 54 & 88, Match List I with List II using the codes given below: List I List II (a) Brage’s reflection 1. 0.74 (packing efficiency) (») HCP 2, Intrinsic semiconductor (c) Cubic 3 As2d (@) Thermistor 4, Four C; axis @ ® © @ yea: Wl Se aed (pet: 22574 3 rs 1 4 2 (Ml as 22 8. (©) Answer not known utqwe Tere utiqud IT eens Qungsgs ucigwie I utqwe IT (a) Agnsdlén Sloss 1. 0.74 (packing efficiency) (b) Qané AD 2. CeriAhs esac sr © ays Sy A590 @ QsimHewit 4, preng Cy sip 185 (yee to a @ 1: 2 #38 (ys 1 4 8 Gy i 2 8 ) Aer Agilucherenre &S 55 CYPG/2022 [Turn over 89. Fill in the blank : NO, Br | | The IUPAC name of jC -C-CH, -C-CHsg is | | O:Hs C,Hs (A) 3-Nitro-3, 5-dimethyl-5-bromoheptane PF 3-Bromo-3, 5~dimethyl-5-nitroheptane (© 2, 4-Diethyl-2-nitro-4-bromopentane ) 2, 4-Diethyl-2-bromo-4- nitropentane (E) Answer not known Apays + NO, Br ! | HC -C-CH, -C-CH, @ser IUPAC Quust ! I GH, AG.b (A) 3-eope Gyn—B, 5c Qing Gla!-5—1 Cyn Con@emiGLer (B) 3-yGqrGior—3, 5a Qs Ho—5—enpp Con@anesGen (©) 2, 4-enr_ ei So—2-enp! Gpr—41 Syn ion uid Ler (D) 2, 4- mors Seo-2-YSqnGion—A— pe Cyn @uierLer ©) Bar agsAwcerera CYPG/2022 56 90. The shape of IF; molecule is YP" Pentagonal bipyramidal (B) Trigonal bipyramidal (©) Square bipyramidal @) Pyramidal (E) Answer not known TF, eposenfler ugar sentir} (A) gaGsrer OG INA B) psCarasr QG INO ©) 87 OG Indo ©) GnAG (BE) Ao. Agusan 91. The bond angle of O-S-0 in sulphite ion (803) is (a) 108° SP 106° (© 120° @) 95° (©) Answer not known séoenuit. qweuder (502) 2crer O-S-O Bena Canemorengs: (A) 108° (B) 106° © 120° @) 95° (E) Alor Asfiusiloee & 87 CYPG/2022 [Turn over 92. Match the following : (a) Nido compound 1, = Bsby (®) Arachnocompound 2. — [BsHs © Closo compound 3. BsHy @ ® © Qs 2s Qot a2 (3 rs 1 2 (E) Answer not known Epsdr_apan Gungsgis : (a) @pGLr Gsiow 1. BsHy (b) y7&Gent Cainoid 2. [Beets © @GamGsr Ceo 3. BH, @ ® © Qa 2 23 (By 2k 8 2 Ore fa O38 (BE) Ber As fussddrare CYPG/2022 58 93. Match : (a) Ht 1. (b) Pa* gz. © NHg Ss @ 4, @ ® © @ Qe? 4 3 1 are 4 3 (Oe 6220 a 4 (Dyes 8. 8, 1 (E) Answer not known Gung see : (@) Ht 1 () Pa** 2: © NH; a. @ 4 @®@ ® © @ Gye. 4 253 1 (ye ie 40 a 3 (() i eee ees) 4 Ort. 8. 22 1 E) dle Agflucdana Hard base Hard acid Soft base Soft acid Sigen spb igen siSled Quwebrenw ampid Qweérew sled 59 CYPG/2022 [Turn over 94, Which is the stronger acid of each paix? (1) H,O* or H,0 (2) NH,‘or NH, (3) H,S or HS (4) H,0 or OH- MH #,0°,NH;, H,S and H,0 (B) H,0*,NH,,H,S and H,O (C). H,0,NHj,H,S and OH- () H,0,NH,,HS" and H,O (E) Answer not known Epscin Ggmgsciia qaiGeurenfland octet ofiflu Sard org? (1) H,0* sag H,0 Q) NH,’ saog NH, (8) HS sag HS (4) H,0 sag) OH™ (A) H,0*,NHj,H,S wg H,0 (B) H,0*,NH,,H,S oppo H,0 (© H,0,NHj,H,S wig OH- @) H,0,NH;,HS~ wig HO ©) Alar Asfudia@me CYPG/2022 60 95. In gas-liquid chromatography, this is not used as carrier gas ic) Helium 7 Oxygen © @) © Nitrogen Argon Answer not known amy-Aj = augremiiAflensuded Bs) aOSHe Gsdveud cumujains LUETUGSSLUBAPom. (A) abiciuw CB) BsAlger (©) @pioger @) ayitsnen = ©) Har Qsfuclowe 61 CYPG/2022 (Turn over 96. The hybridization found in XeOF, is @) ®) ae ©) © sp°d dsp? sp°d? sp*d? Answer not known XeOF, -@ sramiu@d Qarssociy (A) @) © @) @) 97. The sp°d dsp® sp'd® sp*d® Bln Ap fucAkdera term symbol for the ground state electronic configuration of hydrogen atom is (A) ie © () () 1g, "Sin 25, 23, Answer not known Sap ge sepicller senfleow coscqrafler @HuS@ créren? @) @) © () (EB) CYPG/2022 1g, 2S 25, 3g, Ben Asfluicflerera 62 & 98. 99. For a three component system, the phase rule becomes (A) F=4-P yr F=5-P () F=5+P @) F=4+P (E) Answer not known YseAp AEO.LI4sS, Heros IB (A) F=4-P (BR) F=5-P (© F=5+P @) F=4+P (B) Bar Apfiuctacon The Silver-Lead System has (A) one component and two phases (B) two components and three phases JP" two components and four phases (D) one component and one phase (E) Answer not known Geudraf — srfubd Senody Quppierengy. A) 96 ap Lppb QE Aoomwacr B) Qo agscr wpm epenp Hlnersnwser O Qo amacr opp prove Hemweroacr ©) 9G =p vppd EG Hlmaeno (©) dle Agfucdera 63 CYPG/2022 [Turn over 100. Equation for the temperature dependence of equilibrium constant is d(nKp) _ AH? wy a0 RT (B) AG=AH-TAS dinp, _ dinpy (aie @) K “=e (E) Answer not known Gaitiifleweous smi sole wmpplSuder sweum_reng) d(nKp) _ AH® . gr ORT (B) AG=AH-TAS dinp, _dinp, dinx, dinx, ©) =2:308),,_@ Ges @) K E) Beor GpiuscAerenas CYPG/2022 64 101. Which of the following statement(s) is/are false with respect to equilibrium constant? () Kp=Kg when An =0 (i) When the value K is high it shows before attainment of equilibrium the forward reaction was more facile (iii) The equilibrium constant has no unit (A) @ and Gi) only (B) Gi) and (ii) only (© Gi) only FP (ii) only (E) Answer not known sxpeo onpcd upp sauprer anéAunscar some : @ Kp=Kg An=0 fooute Q@sew ung, Gi) GG Aeromunergy sora flow soraishe eparannd qper Cons Haw dae casns flop uLssse K -wWen vsti Be sigsors Qs Gd (ii) snore wnfidsg sig Heung (A) @) wpm (i) oe @ (B) Gi) wpm Gii) we @w (©) Gi) wt @o @) Gii) ve @b (E) Bla Agfusiea & 65 CYPG/2022 [Turn over 102. Match the following : (a) Internal conversion —_(1) (b) Inter system crossing (2) (©) Fluorescence @) (a) Phosphorescence (4) @ ® © (a) 3 4 i Gee 4 2 3 © 4 oo 8 @) 4 t 2 (E) Answer not known on Ah Spsam_aypenp Qunasgie : (a) adres wnpowd () soot pFeCu esse (©) ALepGqrecrev @) unevGunpeciren (a) o © @ @, 73 4 1 ® 1 2 3 ©. 4 Bd @) 4 1.3 (B) Aer Gsfuciarce co Rb CYPG/2022 Radiative transition from Si state to So state Radiative transition from T; state to Sostate Excited molecules lose energy in the form of heat by molecular collisions Non-radiative transition between states of different multiplicity (1) Si Pnauiedgpg) So flowarg, pecGupd Ss Lomppid 2) Tiflmodd eg: So flaws BeOLGupd sPflués wmbowd (8) Aaiapp posmpisdt Congora BOp@o Gari ugarsSed QpsAerpar @) QadGap eye AuKssid a.crar flenasersdlenCus Ploeg SAlt Quissd soeng wmhob 66 & 103. The rate constant will be independent of the ionic strength when, (A) Z2p =2 ST Ealn=0 (©. 2 +Zp=-2 @) 2, -Za=-1 (©) Answer not known QuiGumgg: AwerCas wiped swels Power eniioSongs (A) Z,Zp=2 @) ZZ, =0 © 2Z+2Z, @) 44 °2p = ©) lav Asflucilome 104. The colloiding molecules must posses a certain minimum amount of energy is required is known as (A) Free energy \M Threshold energy (©) Activation energy (@) Kinetic energy (E) Answer not known Consdad cOUuGd smasg HYosmpsebd AupAMGsGd GMI sarey SONS boorengs A) scyor appa B) Gappsucs yppo © Aare, appa ©) Qués oped CE) Al@r siueildoene & 67 CYPG/2022 [Turn over 105. 106. Saponification of ester by an alkali is an example for the order of (A) First ST Second (©) Third @) Zero (E) Answer not known sims sien aperaenaide croviey Ceniin&geib eflenanuder aflaner Lig. A) aarp B) Qra0q © wag D) ugesuw ©) Aewr Asifuiidere Todine is liberated when an iodide is reacted with a nitrite solution according to the equation 2NO; +4H* +2I- -> 1, +2NO+2H,0. The experimental rate law for the reaction has been found to be R=KNO;][I-][H*? when [H*] is halved the other two concentrations unaltered. The rate is equal to () R (B) R/2 (© 4R AB BIA (E) Answer not known SACUTEOLO, aBLGr seonsgror Amenjipg oGuTg@e AuchIPSpg. oppsren Gast sndnin@ : 2NOz+4H*+2I~ +I, +2NO0+2H,0 Gsigpnpuiler pad senGMgseucr 265 Aeneidr enerCasonergs R=KNOz| TAP. [H*] Gedeoa: undunss wip Qo AerariGGurepafer Geflne unpmod Mas Gb Gung HcislmonIer AmeiCassHer sera () R (®) R/2 (© 4k @) R44 () Alen Apifueiierene CYPG/2022 68 & 107. Choose the correct statement(s) with regard to zero order reaction : (i) The rate constant of zero order reaction depends on the concentration of products only (i) Enzyme catalysed reactions are example for zero order reaction (ii) The unit of zero order reaction is mol- L Sec (A) @ and Gi) only @®) (ii) and Gii) only ™ (i) and Gi) only (@) only (E) Answer not known SpanGssciuc Geran Ys curs Aeersenon sflunen eunssussisanar soir ffle = @ YQu ams Bear Gas wrplSuireng, cereniu® Gungefler Geifleres WL Aw emipAGSG Gi) Apr Amrenyssd eBiicieensar ygehus ais Blenensiapssnen 2siyanrtisser Gil) Yassur aioe cBlenenCars nfleBuder sig mol-! L Sec (A) @) wig Gii) oo @o @®) Gi) opp Gi) wr @w (© @ wppr Gi) o- @w ©) @ucoo (©) Ber Aguirre 6 69 CYPG/2022 [Turn over 108. 109. . Write the product of the following reaction H,C-HC=CH-CH, EGsOalethery Hs A 2,3-butanediol (B) 1,2-butanediol (©) 3,2-butanediol ) 2,1-butanediol ) Answer not known Gerard Aenenden enoruingsarcr «rapsis. H,C-HC=CH—cH, 1:080a/ether » 2. H20. (A) 2,3-tuytGreren_usme (B) 1,2-cwye Greren_wire (©) 3,2-sye Geéron_ume @) 2,1-cyyt Gerona (LE) Aer Asfiuaeose Which among the following is correct selection rule for an electrocyclic reaction? (A) 4nze”-A-DIS (n+2)re"-A- over @) 4nze"-hy- ere E) Aer Asfiucidma CYPG/2022 70 & 110. Identify the product of the following reaction. GU. -b-H2®, » 0 I CoHs 6-0" + C,H, -CH,OH (B) C.H,CH,COOH (©) CgH,;COCH,COO- ©) C,H;CH; + HCOOH (BE) Answer not known Epangpd Aenendsran Llenanchlenat ungelesen snare. A) Hee CgH, - C- O° + CH, - CH,OH (B) C,H CH,COOH (©) C.H,COCH,COO- (D) C,H,CH, + HCOOH ©) Bor Gsfudda & n CYPG/2022 [Turn over 111. a-methyl cinnamaldehyde can be prepared from and (A) Benzaldehyde, acetaldehyde (B) Benzaldehyde, propionaldehyde (C) Acetophanone, acetaldehyde (D) Acetone, acetaldehyde (E) Answer not known a— QvsAe Achanondyman® sumféss uweériGeugy ‘9b ——— A), Guérsndyman®, SALLdy mand Gudrendxman®, yGyreiIGunenradig mang (©) aA CimsGarrer, SACL Td gemanG @M) SACGCLiét, FALLIOQ@aDg (BE) Alar Asfuciarenss 112. Match List (1) with List (ID) and select the correct answer using the codes given below. List I List II (a) Claisen condensation (1) _ Nitrene intermediate (b) Friedel-Craft’s reaction (2) Hydride transfer (©) Cannizaro reaction (3) Carbanion intermediate (d) Hofmann rearrangement (4) Arenium ion @ 6 © @ (A) 2 1 3 4 (B) 84 4 2 3 4 2 L @) 4 3 2 x () Answer not known Sartir@ anor Gee on SaMgONSSO™ FOR GarDAninic GihSQamas ucigwed I Lege IT (a) AGewedr Gps 1. @pt_fer Qo paaiQungser () cfg. -Aprsc. Alene 2. e@ani_er@ wpb (©) screfieGyr Aener 3. smiGuaflurer Ben slaw Quncper @) anrésGwer @iomhp Hlener 4. siflefund swall @ © © @ Bee Bw (a) (BW ae 8 (OC). Sade oe a (Dy ear ge ges a CE) Aer Qgfuciorce CYPG/2022 12 & 113.-The stability of carbocation of the order CH3< Primary < Secondary < Tertiary is due to AF Electron releasing effect @®) © @) () Electron withdrawing effect Sterical effect Tonic effect Answer not known sonics Conder swetlider flenwciy sero CHy < pgérnw < @)yeim mb © Fe? Phenolphthalein Methyl Orange KMnO, K,[Fe(CN)¢] Answer not known Smefismer GuninAuid oieGrGot. Garen® smbuntésSér Gung, UWA Qasiifeosm @) @) © @) ® CYPG/2022 GearmedciseSer Bsmse ares KMn0, KglFe(CN),] Bor. Apfuscilerere 4 w 116. Match the following : (a) Dehydrohalogenation of bromo butane (b) Decomposition of Ethane (©) Hydrolysis of t-butyl chloride @) Solvolysis of methyl iodide with Ammonia @) 6) © @ G4 1 8 2 (@) 1 2548 meee 1-28 () 1.3 4 2 (E) Answer not known Epssan adap GunGss ayes : (2) UGmnGiomIuye Ge afte e@ani_Gym apmerggesr Gesu (0) FECsér Aosaorso © eponcarus Iyer GGorrenjan_ Srmpuesoe ) AngHeo sGureo_@ oCorafumay er senqcivinén eye @ ® © @ @ 41 3 2 @. 1. 24> 3 (ye 4 1 12) 8 i) 1 8 a? ) Ber Agfucidcne & cr) Free Radical Mechanism Unimolecular Nucleophilic substitution Bimolecular Nucleophilic substitution Bimolecular elimination sell opty aeperp aigaeut gore Epaseng! UBILO afl ep sgseut Ow pasegy UBELG anf perp 9G Yosmp fis as wan CYPG/2022 [Turn over 117. Third law of thermodynamics can be defined as km (-TAS) = 0, which - is based on the Nernst heat theorem (B) Planck statement (C) Charles law () Kirchoff's theorem (E) Answer not known Baits Qusschlucder sb AGunengy kim TAS) =0, Qaa AQUUMLWTES Qemeéor_gy. (A) Gpiteirev Gouin A$) (B) Gernid ances: (©) smiacy of D) AiGovrews AD (©) Alar Asfwcoane 118. Entropy change in heat transfer (AS,,, ) is given by, (1, = Temp. of hot body, T, ='Temp. of cold body) YH 48,.= Cp In 140, 7.747, TI @B) AS, = Cy In[1+(Z,-T,)?/2T, T.)] () ASg. = Cp logli+(Z, -T,)/(4T, T.)] @) AS,,5= Cp logli+(Z,-T,)/(2T, T.)] (E) Answer not known Gaui Udita; sJer_uyd Cuingy, rdre Gym omppsPar wiry (ASj,,)? (Th = GLrer Gun@afer Ganuples, T, = Gafliihs Gumgafler Garten) (A) AS,,=C, In (1+, -7,)° (47, T.)] ®) AS, =C,nf+(Z,-T,)?/2T, 7.) © AS,,.= C,logl1+(%, -T,)/(4T, T,)) @) AS,,.= C, log[1+(Z,-T,)/(2T, T.)] @) Aer asfuciioes CYPG/2022 6 wB 119. The entropy change value for one gram of an ideal gas at 27°C, having heat capacity at constant volume as 200 Cal k"’ is heated to its ten times its initial temperature will be A) 4606 kCalk~* I 160.6 Calk7} © @) 46.06 Calk* 4.606 kCalk™* (E) Answer not known 27°C faavtgysrar gq BaSwery eunuycHler cronCom wmho wALIY. wapT ser orc sige Gesigglér Aanérorara, 200 Cal k"*. ymbu Plead Geutis re & Blneenu Gund 10 wimg Gai flenoew ouisgd Gung) 21ser —pybu eutiissleneo (A) 4606 kCalk™ (B) 460.6 Calk* (©) 46.06 Calk" @) 4.606 kCalk* (BE) Ber Gpfuseildenn 7 CYPG/2022 [Turn over 120. Pick out the correct relationship for one mole of gas undergoes adiabatic irreversible expansion. BR : BR ) (B}com-cuim,( jr P, T, 8 (2) C,(m) = Cy ome( Fa T, Ne (2) C,(m) = C,(m)+ Be ©) (2) C,(m)=C, om(2)a q (E) Answer not known 9G Gord aun Gascileoe impr Ba Qeudgpenpie Aflanssid s1e01Angy. Dowd Cpenpuler swenin® ogi? (A) (2 t}c, (m)= cumo( BR ®) (2) im) = Gym ir BR 0 Ts © (2) C,(m) = cum{ 2] ©) (2 #)cxem = cpima[ 2) F CE) Aer Qgfuciirae cYPG/2022 78 & 121. Calculate the percentage of reflection for a particle whose energy E=2v. er 2.5% (B) 25% (©) 3.6% @) 36% (E) Answer not known E=2v ope 2aiw 9G gsaflér gal AjSusiiy sslsses somsAOs. (A) 2.5% (B) 25% (CC) 3.6% () 36% (B) Aer Qpfuctirea 122. The degree of degenergy of a rigid rotator when J=2 is (A) Four Five © Six @) Seven (E) Answer not known J=2 calle Swen spoluder Fj flay utd erdueueray ? (A) preg @®) abs © «ao @) sw E) clo Asfiuddas & 79 CYPG/2022 . [Turn over 128. Tp Au4s?, at and f(x)=ax°, then AB f(x) is (A) 12ax? (B) 12ax* MF 1ax* (@) 12ax° 124. 125, (E) Answer not known Ants? BS wip fla)nar? cof, AB f(x) ar oping (A) 12ax? (B) 12ax8 (C) 12ax4 @) 12ax*° (BE) Aer Aguiar . The debroglie wave length of the particle of mass 1g moving with a velocity of 3000 ms” is YF 2.209x10™ m (B) 2.209 x10°97 m (© 2.209 x10-°5 A (D) 3.309 x10-9 A (E). Answer not known ge, & Plepujérar 3000 8A Causpger pardengus GurGoter _IpracS ine jem (A) 2.209x10-* is (B) 2.209 x10" 16 (© 2.209 x10 A @) 3.309 x10 A ©) Her Gpfusciirme If A and B are two operators such that (A, B)=1, then, (4 B*)=? (A) 2 erB © 4 @) 4B (E) Answer not known A vppd B 24 Qe Qeudsafer wan, (A, B)=1 aor Qepere (4 B?) en woes winga2 (A) 2 ®) 2B © 4 ©) 4B @) Aer AsAucoms CYPG/2022 80 t & 126. 127. 128. . If an operator A has two eigen functions y and ¢. Then, condition for Hermition is Wr [vA e)de=fldy)oar ®) fy (Adlde=jldy dar © feld)yac=fldy)odr @) flAgy)dr=fAar oy (E)_ Answer not known. aS, ue io See, Foe ¢ con Qren® ged sniysdr acin@gafe @ fyldd)ar=j(Ay)par ®) fy(Ag)dr=[(Ay dar © fola)yae=flAv)ode Wy JlAdy)dr=[Adr oy E) Awr Asfiwedeoane Rubredoxin is the simple (A) Inorganic sulphur protein (B) Organic sulphur protein Tron-sulphur protein (D) Magnesium - sulphur protein (E) Answer not known GUALréaMlet Qo cats (A) sefw-sige ys B) sfw-sps5 Usp ©) Qobu-siss usp OD) QnéefAund-sb5e 7s (©) Aes Ag fiuseilerena Cytochromes are classified a (A) Cytaandcytb (B) Cyt a only (©) Cytxandcyty Drcyt a, cyt b and cyt ¢ (E) Answer not known oe GLréCymbadr Deraugb obs asus umsUBSslUAerper. (A) eat a ppb mab (B) ws a wl @d (C) mex wppib wey (CD) @sc_ a, wat b wppibd mac (E) flor Asfiudeame 81 CYPG/2022 [Turn over 129. Rubredoxin, protein chain folded has ————— cysteinyl moieties. (A) a ©) ) @) 2 Oa A Answer not known AraMnééeér sGcituc. YyCymiiect side sienwidd Adviecnerd wrrciviacv acrergl. @ @®) © () © 2 4 6 8 lon. Op fusflereoe 130. Which one of the enzyme is used in diagnosis of Hepatitis? Yr 5 -Nucleotidase () () @) © Aldolase Amylase Lipase Answer not known Spserapga ops WprA wesc smormoeu sem Sw uweruGdAngi? ) @) (©) @) () CYPG/2022 5’ — BuysohGumgG_oo BOCLIGodr PenawWgyerangs TIL. Fe (1) 92 pm grsesujorugs creep po 2 crorgs IV. @iwréailgér Fe (I) rer Qenawuyd Gung smp spd d& fewmu si Apgs. (A) Loppo IV ®) Tvpge TI (©) Twpme IV @) IVuc@n ©) dar sium 134. Which of the following is related to “Blue blood”? (A) Hemeprotein 3) Hemocyanine (©) Hemerythrin (D) Hemoglobin (©) Answer not known Sthacir_aubpicr “fo Qysesgi_cn” smi wg) og? (A) abidyssb (B) adGurswmafler (CO) abbberiigmesr (D) abGiomgGermder (E) Aw Asfudese CYPG/2022 84 & 135. Match the following : Ligand Neutral atom electron count (a) 7® cyclo octa tetraeryl te 8 (b) 7° Allyl De 7 (©) 7’ cyclo heptatrienyl 8 8 4. 6 @ ® © (Ae 8 G4. BS tC) 2 a a 2 (E) Answer not known Gung gis : rafledt pOGew 2 corse gren cretraaflésanes (a) 78 asenorus aS QL gn-syenqe Tee Gi ) Proemoe 22 aT © acer Aamci_mgenqusencsred 3. 8 4. 6 @ 6) © (A) 2 3 1 @®) 4 3 1 (Cc) 2 i 4 @) 3 1 2 (E) dla Apfuciema & 86 CYPG/2022 [Turn over 136, What is the hybridisation of Cr atom in Cr(CO), molecule? iS d?sp* ®) sp® (©) dsp? (D) sp? (E) Answer not known Cr(CO), gporsonmefle Cr -sigpcfer seciGenb rere? (A) d?sp* ®) sp* (©). dsp” ©) sp? ©) der Asfuctiae 137. The hybridisation involved in the central metal of the complex Fe(CO), is (A) dsp? WS asp’ (©) sp*d? ©) sp*a (E) Answer not known Fe(CO); sinanafér eu 2 Gonag Aer syn Lne Qoné seociinengy (A) d?sp” (B) dsp* (C) sp’a® @) sp*d ©) Ber Opfuciiase CYPG/2022 86 & 138. Which of the following is a third generation petrochemical? (A) Benzene @®) Xylene (©) Glycerol we DDT (©) Answer not known Acragacabye ag eperpmb seacpep GuiGyrflu Cagi@unger amseus Emiipsgi? (A) Queer B) wader (©) Sefleyre , @) DDT (B) Aen Qgfucidree 139. In sewage treatment excess soaps are oxidised to () CO, (@®) CO (©) CO and H,O PF CO, and H,0 (BE) Answer not known ci Tae Be cabanaace Gung, aBsuiquren Cemtijscr ——————_ @) CO, @®) CO (© CO and H,O @) CO, and H,0 (B) Ae Gsfucome & 87 CYPG/2022 [Turn over 140. In thermoanalytical methods, which of the following statements is/are true? @) TGA needs reference material (ii) TGA does not need reference material ii) DTA needs reference material (iv) DSC does not need reference material A) Gi), Gii), Gv) ®) @), Gi), Gv) GH Wi), Gi) ©) @, Gy) (E) Answer not known Gotu ugdumie) apse Bcrougd smppachd agi/crma sflusmengi/efusmenenes 2 @ TGA-Aps GiopGardr Gungér Gsancu Gi) TGA-clie CiopGamar Qumepér Czenau9dena Gi) DTA-cilp GipGarar Qumger sera (iv) DSC- OCH; > NHCH, > CH, (B) CH, > NHCH, > OC,H, > Br (©) Br>NHCH, > OC,H; > CH, @) OC,H, > NHCH, > Br > CH, (E) Answer not known Epsdn_mascia R-S ePuicors sem Pus uweruGid sfluner apergpifleno euflens orgs? (A) Br> OCH, > NHCH, > CH, (B) CH, >NHCH, > OC.H, > Br (©) Br>NHCH; > OCH; > CH, (D) OC,H, > NHCH, > Br > CH, (BE) der Qsfiucome 6 - 91 CYPG/2022 [Turn over 157. Label the chiral carbon in the following compound as R or S @ Se i) Ger oO H "an a oO» A @S GR Basis (© @R GR @M) @RGS (E) Answer not known Epssngnrd Comomacia snemiuGo ws7 smc aérues R sag S crend EHS. ° Ho is CH (A) @S GR ®) @S@s © @R@R @) @R@S ©) Alor Qsfucdrcre 158. Optically active 2-methyl cyclohexanone undergoes racimisation on treatment with base because (A) Free radicals are produced ) » Carbonium ion is formed MO The Carat gh cuced aad usderpost aeoiee te () Base hydrolysis ketone and then regenerates its (E) Answer not known anspor Coiéoiu@id Gung, goflsapoAs usimym wu 2-Awsh anon GabdeGennar eMiniees sere ae Pr npanee aera es (A) sell egiiysdr 2 Gamenper B) sriGunehub sweh eGardng: ©) 2@anSénp sniinonuner ronConnsag iss 2 UGS ng @) sipb &.CLrmer fom UG sg) Deron UPsns 2 Gaindngs (BE) Ale Agfusierea CYPG/2022 98 & 159. The efficiency of a heat engine operating between 373 K and 173 K is (A) 49.3% (B) . 72.1% 53.6% (D) 67.8% (E) Answer not known Be cea ake rane Aatusaoss Bon Gu Quags gq Gatun (A) 49.3% (B) 72.1% : (©) 53.6% ) 67.8% (E) Gar Agflucildenan 160. The uses of salt of Er and Ce are @) @) @) © Germicids To treat vomiting and sea-sickness To increase red blood corpuscles and haemoglobine Fertilizer Answer not known Er wig Ce eciyjsafer Uwe eng @), @) © @) @) pieirepudit Geirarall anpS opgib 6LO-Asnpsray Gpranuw Gass Qvd5 Aci Sesser opgd afCongGamMaar ewitssiso amb Aa AgsfMweslerene 99 CYPG/2022 [Turn over 161. How many optical isomers are possible for the complex [Pt(en)Cl, Br. |? a1 Os © 3 @) 4 (E) Answer not known [Pt(en)Cl, Br] cep simaraé GCs agsmer gail sipbA wmbshluitisenar GanG@sew? @ 1 @®) 2 © 3 @) 4 (E) Aer @gfusdrere 162. The charge transfer transition occurs in the region (A) _ Visible region Near UV region (C) IR region (@) Far IR region (E) Answer not known Wiérsa1 Qionppd por Gum sHicsiss ue (A) stymenngb uss: B) upeagr sAireisAng aGhe (CC) sesMay sditesée MD) ssa sAireiex srotrg. (E) Aer Agfuieen CyPG/2022 100 & 163. 164, Additive combination of the six ligand orbitals to form a,g LGO is represented as A Lan Tae $0_p-0y—O-y +0, +05) ®B) Lass Bl $0.y-0,+0.,-0,-0-s) +0,-0,+0_y-0,-0-2) © a. wr Lae yes $6.4 40, 40_y +0, +0-2) (E) Answer not known Bp rallsciler anIcindsafler Gaibgs a, 8 LEOe Garaasé GPU OUGag @® Lass ae 40g -0y-0-y +0n 40-5) ® Das= Eo $0.,-0,40-,-0,--x) 1 © a ee @) oT Fpleat ea tes ¥O_y +0, +0, J () feo ies The isomerism not exhibited by co-ordination compounds is (A) Ionisation Isomerism ‘Chain Isomerism (C) Co-ordination Isomerism () Ligand Isomerism (E) Answer not known. simewre; Geiomisdr amLng wmpslutb (A) swat np pub QB) sHAAS Qsrt waHAuwd (C) sremoeray tors Slund @) ref wnpgflurd (BE) Bor. Agflucilaes 101 CYPG/2022 [Turn over 165. Match the following : (a) [Co Gien),] [CoCl,] 1. (b) Cs,CoCl, 2. © TI,AIF 8; 4. @ 0%) © (ASB sk ese Gps sai, 2 Qo sBse 1 (@) 8-5 a (E) Answer not known Qume sais : (a) [Co (@uSex)2] [CoCl,] 1. () CssCoCl, 2. © T,AIF 3. 4. @ ©) © re 1 aa! Os 43 Oo eee Oi. 1.4 ©) Bar QpfucAerane CYPG/2022 infinite chains ‘oh’ cations and ‘Td’ anions discrete MCI} anions and free Cl~ ions co-ordination number 3 (ucion Agni «idle ‘crainap al Gpmusel wmud ‘paérapd? oAlywel salsa ‘prérapd’ MCI2- a@jwallsdr wppid sef Cl” swear 0* (B) n>0* Nn > 2* and zo x* ) rn" (E) Answer not known yp sagr oft Apwr@wvrahie, sfloCaguvud Conomeciler apsais sr@sismér Hlene wrppgserg sreearmb ? A oe (@) n>o0* (© n>x* oppo t>2* @) z7n* CE) Aer. Asfusciirenc 171. Which of the following ionic species undergo cleavage easily in: mass spectrometry? (A) *CH,R (B) *CHR, wercr, ©) *CH, (BE) Answer not known — AunGereo fj WrT@oTEMId Teragb a5 wal AsngAureng ead crafigmes 2601 wid gchronio ©enLUig? (A) *CH,R (B) *CHR, © *CR3 @) *CHy (B) or Gsiuscherener & 105 CYPG/2022 [Turn over 172. The 70 NMR spectrum of H,0 shows only a (A) doublet triplet (C) quartet (@) quintet (E) Answer not known H,O @er 170 NMR -Alpwonenaude Carengid asens(scr) A) Qrce B) wobow, © prenog. @) gpg ©) der asfucddera 173. The angular momentum of an electron that occupies the 1s atomic orbital'is 0 B) V2 h/2n © V6 h/2x @) VieA/2x (E) Answer not known 1s 2) BRILL Sd Qi Guppicrar cosicgrailesr ospaHlens (A) 0 () V2 h/2x © V6 h/27 @) Vi2h/2z ©) Aa sfucdwe CYPG/2022 106 174, The relation between electrical energy and enthalpy of a cell reaction is (a) pi .2(2) 3 nF oT AH oE @ ear, AH dE @ nM _o(28) -AH (aE oon ee wr nF (Fl, (©) Answer not known OG Dera Aenea er yond ppd crengnd.IsG.leo_Gus 2drar Gsm Ay Sd. nF (eT AH _;,(9E We oo nF iG 1 -AH , (aE ©) E-— -1(38) ©) Aer Aghwee & 107 CYPG/2022 [Turn over 175. According to Laporte transition rule, the allowed transition is A goog B®) uou gou (D) d-d inacentero symmetric molecule (©) Answer not known enGunh ceéconér wp APuy, Epscrapydr sewossssuG eras gma Lomppib A goog B® wou © gou DO) 9G @ow Siowuysror posenplo dd wnppb (E) Aw Qsfucees 176. How many lines will appear for Mn* ion in ESR spectrum? (A) 2 @® 4 ws @) 8 (E) Answer not known Mn* swiahider, ESR AychIuse agseren moos Can @sdr Gane? @) @®) (©) @) ©) Alor Asfweilosa 2anrn CYPG/2022 108 w 177. The reaction by which ethylacetoacetate can be prepared is called as ) Claisen condensation (B) Dieckmann condensation (C) Aldol condensation (D) Benzoin condensation (E) Answer not known ash SACGLe SALCLL pwnflest UueriGib fleemfeer Qaanp enpasoomb (A) AGaniiAer GHSG Sener (B) gsQwen MSG Serer (C) gearra GSE era @D) Quérender Gpsq Barer (BE), Alor Ag fucleena 178. The ESR spectrum of benzene radical anion (CgH,¢”) shows a signal lines of (A) Four (B) Five GO Seven ©) Six (E) Answer not known Queréer salugiy afer swe (CgHe”) crasigner spapps Gensa, Apwreauvle sm_Gid nsens arfleatler C1 ear oT CO (A) paeng, ®) abs © «we ©) wo (BE) Alar Asfucloae & 109 CYPG/2022 [Turn over 179. The cathodic reaction in Hydrogen-Oxygen fuel cell is (A) 2H, +40H@, > 40g + 4e7 V7 02, + 2H20q) +4¢° > 40H, (©) 09, +H0 +e” + OH @) 0,,, +2H,0@ +2e > 40Hay (E) Answer not known san ree ~ aablger ofAungar Wersagsler aBinser cpemenddy BerAupid ner (A) 2Hy,, +40H Gq) > 4H,0¢) +4e7 ®B) 02, +2H,0p +4e° > 40HG) © Oy, +H;09 +e > OHg a) @) 0,, +2H,0@ +20" > 40H, @) Aor Qpfiueioerc 180. Dry cell is Primary cell (B) Secondary cell (C) Ni-Cd cell () Both (B) and (C) are correct (E) Answer not known Rett Bldrsarb crerig, (A) apscronésard B) Qyermd flow said (©) Ni-Cdsaw @) ©) vpgw (C) «fi (EB) Ber Qsifwehaenco CYPG/2022 110 &B 181. At infinite dilution of an electrolyte, the equivalent conductance of cations and anions are ——————— of each other. 182. (A Dependent SH Independent (©) @) () Partially dependent Partially independent Answer not known aby sigs Bids Hood eden HemigatiIe Epinser wpgud erfirsler Swahiler sonar s_ sgsspor Gem ty A @) ©) @) © as @) aston Herp Eni sIl>I>Iv ~ I>I>I>IV © @) ®© TI>I>I>IVv IvV>l>I>01 Answer not known Spscin Aeonnér Cotwmacier sas scrmodasr ssc Oot auflensuvle auflensuGbeis : @ @®) © @) ©) XeO,, Xe0,R%, XeOK, XeF, © aD qa) av) I>I>1>Iv Il>I>II>IV II>I>I>Iv IV>l>I>m eo GpfuscSlerenc u7 CYPG/2022 [Turn over 192. Choose the correct increasing order of acidic character of oxy acids of Cl (A) JHCIO > HClO: > HC103 > HC1O. gman HCIO2 > HClO > HCIO, (B) HClO

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