Mat03 3

1.
Examples of calculation in typical processes
This section gives examples of calculation in the following 11 processes,

which are assumed to be included in various business categories.
1-1 Storage process (including acceptance and delivery facilities)

(→ pIII -4)
1-2 Reaction/mixing process (→ pIII-21)
1-3 Machining process (→ pIII-42)
1-4 Washing process (→ pIII-47)
1-5 Painting process (→ pIII-59)
1-6 Printing process (→ pIII-66)
1-7 Adhesion process (→ pIII-74)
1-8 Plating process (→ pIII-81)
1-9 Dyeing process (→ pIII-95)
1-10 Sterilizing and disinfecting process (→ pIII-101)
1-11 Process of using other solvents (→ pIII-106)
The table on the next page gives examples of correspondence between

designated businesses (pIII-165, pIII-172) and the processes that may be
performed by those businesses. Note that exceptions may exist.
III - 2
Example of correspondence between designated businesses and processes
1 2 3 4 5 6 7 8 9 10 11
Sterilizing
Process Reaction Process of
Storage Machining Washing Coating Printing Adhesion Plating Dyeing and
and mixing using other
process process process process process process process process disinfectin
process solutions
g process
Raw materials or materials handled
Raw
Sterilizing
materials, Detergent,
Raw Paint, anti- agent,
semi- dry Dye,
materials or Cutting oil, corrosive Printing Plating antiseptic Various
processed cleaning Adhesives bleaching
materials etc. coating, ink solution agent, solutions
materials, solution, agent, etc.
stored etc. disinfec-
Industrial classification additives, etc.
tant, etc.
etc.
1 Metal mining ○
2 Crude petroleum and natural gas production ○
3 Manufacturing
a Manufacture of food ○ ○
b Manufacture of beverages, tabacco and feed ○ ○
c Manufacture of textile mill products ○ ○ ○ ○ ○
d Manufacture of apparel and other finished products
made from fabrics and similar materials ○ ○ ○ ○ ○
e Manufacture of lumber and wood products, except

furniture ○ ○ ○ ○ ○
f Manufacture of furniture and fixtures ○ ○ ○ ○ ○

g Manufacture of pulp, paper and paper products ○ ○ ○ ○ ○ ○
h Publishing, printing and allied industries ○ ○ ○
i Manufacture of chemical and allied products ○ ○ ○
j Manufacture of petroleum and coal products ○ ○ ○
k Manufacture of plastic products, except otherwise
classified ○ ○ ○ ○ ○ ○ ○ ○
l Manufacture of rubber products ○ ○ ○ ○ ○ ○ ○ ○

m Manufacture of leather tanning, leather products
and ○ ○ ○ ○
n fManufacture
ki of ceramic, stone and clay products ○ ○ ○ ○ ○ ○
o Manufacture of iron and steel ○ ○ ○ ○ ○ ○
p Manufacture of non-ferrous metals and products ○ ○ ○ ○ ○ ○ ○
q Manufacture of fabricated metal products ○ ○ ○ ○ ○ ○ ○
r Manufacture of general machinery ○ ○ ○ ○ ○ ○ ○
s Manufacture of electrical machinery, equipment and
suplies ○ ○ ○ ○ ○ ○ ○
t Manufacture of transportation equipment ○ ○ ○ ○ ○ ○ ○

u Manufacture of precision instruments and machinery ○ ○ ○ ○ ○ ○ ○
v Manufacture of ordnance and accessories ○ ○ ○ ○ ○ ○ ○
w Manufacture of ordnance and accessories ○ ○ ○ ○ ○ ○ ○
4 Electricity industry ○
5 Gas industry ○
6 Heat supply industry ○
7 Sewage industry
8 Railway industry ○ ○ ○ ○ ○ ○
9 Warehouse industry*1) ○ ○
10 Petroleum wholesale industry ○
11 Scrap iron wholesale industry*2)
12 Automobile wholesale industry*2)
13 Fuel retail industry ○
14 Laundry industry ○ ○
15 Photography industry ○
16 Automobile maintenance industry ○ ○ ○ ○ ○ ○ ○
17 Machinery and equipment repair industry ○ ○ ○ ○ ○ ○
18 Product testing industry ○ ○
*3)
19 Measurement certification industry ○ ○
20 Household waste disposal industry*4)
21 Industrial waste disposal industry*5)
22 Higher educational institutions*6) ○ ○ ○
23 Research institutes for natural science ○ ○ ○
*1) Limited to the cases where agricultural products are stored or gaseous or liquid substance is stored in a storage ta
*2) Limited to the cases where the substances sealed in air conditioners for automobiles are handled.
*3) General measurement certification industry not included.
*4) Limited to waste disposal industry.
*5) Specific control industrial waste disposal industry included.
*6) Ancillary facilities included, and facilities related to cultural sciences not included.
III - 3
1-1 Storage process (including acceptance and delivery facilities)
This is a process where raw materials, materials, products, etc. are stored
in storage tanks such as follows.
• Fixed-roof tank
• Floating-roof tank
• Underground tank (such as gas stations)
The release to the environment includes the air emission resulting from the
following losses.
• Fixed-roof tank: Breathing loss *1, Acceptance loss *2
• Floating-roof tank: Discharge loss *3
• Underground tank: Acceptance loss *2, Refueling loss *4
If exhaust gas is treated by activated carbon adsorption treatment in

exhaust gas treatment facility, waste (such as spent carbon) may be
generated.
The following methods can be used to calculate the released quantity.

(1) Engineering calculations
(2) Use of emission factors
(3) Use of mass balance
* 1 R el e a s e o f v a p o r co n ta in i n g a s p e c i f ie d s u b s t an c e d u e t o in t e r n a l p r e s s u r e ch a n ge
o f th e ta n k r e s u lt i n g f r o m t h e t e mpe r a t u r e ch an g e b e t w e en d a y an d ni g ht
* 2 R el e a s e o f v a p o r co n ta in i n g a s p e c i f ie d s u b s t an c e at t h e ti me o f a c c ep t a n c e o f th e
li q ui d co n t a in in g th e s u b s t a n c e
* 3 R el e a s e o f a sp e c i f i ed s u b s t a n c e a tt a c h e d to t h e i n t e r n a l w a l l o r t h e co l u mn s o f
th e t an k a t th e ti me o f d i s c h a rg e o f t h e s t o r ed ma t e r i a l s
* 4 R el e a s e at th e ti me o f r e f u e li n g o f a u t o mo b i l e s , e t c .
[Examples of subject substances]
Subject substance contained in raw materials, materials, and products stored
[Example of calculation (1)] Engineering calculations
This method can be used to calculate breathing loss and acceptance loss.
The method presented by the United States Environmental Protection Agency
(USEPA) is shown below.
① Formula to calculate breathing loss

Partial
pressure of
subject 0.68 1.73
Molecular substance Internal
Breathing Pa
weight of diameter
loss Released to
kg/year ＝ 0.3 × the
subject × Partial
× of
tank the
atmosphere
substance pressure of m
3
g/mol
101.3 ×10 − subject
substance Expansion
0.51 Pa Va p o r and
Difference 0.5 contraction
Height Average in phase
of the storage Factor Factor caused by
average of difference
tank of of tank
× m − height
m × outside air
×
Te m p e r a t u r e
tank × diameter
in
temperature
m color
III - 4
※1 I f t h e a v e r a g e a t mo s p h e r i c p r e s s u r e i s n o t k n o w n , u s e 7 6 0 m mH g ( 1 0 1 . 3 ×1 0 3 P a ) .
※2 U s e t he f o l lo w i n g f o r mu l a t o ma ke c a lc u la t i on s u s in g m mH g a s t he un i t o f
pressure.
Partial
pressure of
the subject 0.68 1.73
Molecular substance
mmHg Internal
Breathing
loss ＝ 0.3× weight of
the × × diameter
of the
kg/year subject Partial tank
substance
g/mol
760 − pressure of
the subject
m
substance
mmHg
0.51 0.5
Average Difference
Height
of the storage in annual Factor Factor
× tank − height × average of
outside air
× of × of tank
m m tank diameter
temperature color
m
※ 3 W h en e x h a u s t g a s t r ea t me n t i s ca r r i e d o u t, mu l t i p l y t h e r e s u l t o f th e ab o v e
f o r mu l a b y [ (1 0 0% − R e mo v a l e ff i c ie n c y % ) / 1 0 0 ] .
※ 4 W h en th e s u b s t an c e s t o r ed i n t h e t an k i s a mix t u r e , c a l c u l a t e t h e p a r t ia l
p r e s s u r e o f th e s u b j e ct s u b s t a nc e b y u s in g t h e f o r mu l a s ho w n be l o w ( E x a mp l e :
w h en t h e s t o r ed s u b st a n c e i s co mp o s e d o f s u b j e c t su b s t an c e X , o t h e r s u b s t a n c e s
A, and B).
Content
of X
%
Va p o r Molecular
Partial pressure of weight of
pressure of X g/mol
the subject ＝ the pure
subject ×
substance X Content Content Content
substance X of X
Pa or mmHg of A of B
Pa or mmHg
+ +
% % %
Molecular Molecular Molecular

weight of weight of weight of
X g/mol A g/mol B g/mol
※5 I f t h e a v e r a g e s t o r a g e h e i g h t i s n o t k n o w n , u s e 1 /2 o f t h e t o t a l h e i g h t o f t h e
t an k . W h e n th e s to r a g e h e ig h t i s ma i n t a in e d f o r c e r t ai n p u r p o s e s ( s u c h a s
s t oc kp i l in g ) , u s e t h e v a lu e o f t h at h e i g h t .
※6 T h e a v e r a g e o u t si d e ai r t e mp e r a t u r e d i ff e re n c e o f t h e y e a r i s t h e a n n u al a v e r a ge
v a l u e o f t h e d i ff e r e n c e b e t w e en t h e h ig h e st an d th e lo w e s t t e mp e r a tu r e o f a d a y.
※7 F a c to r o f t h e t an k co l o r (− )
W h it e : 1 . 0 , S i lv e r : 1 .2 , Li g ht b r o w n an d c r e a m: 1 . 3 3 , O t h e r s : 1 . 4 6
※8 Co r r e c t i o n f a c to r o f t h e t a n k o f s ma l l d i a me t e r
W h en th e t an k d i a me t e r i s 5 m o r s h o r t e r : 0 . 3
W h en th e t an k d i a me t e r i s 5 t o 9 m: 0 . 8
W h en th e t an k d i a me t e r i s 9 m o r lo n g e r : 1 .0
III - 5
② Formula to calculate acceptance loss
Released to
Partial the
pressure of atmosphere
Molecular Annual the subject
weight of substance
quantity
Acceptance
loss ＝ 0.041 × the
subject
× brought in × Pa
Va p o r p h a s e
kg/year to the tank Internal
substance m
3
Increase of
pressure
g/mol liquid level
of the tank
Pa
※1 T h e a n n u al av e r a g e t e mp e r a t u r e i n s id e t h e t a n k i s a s s u med t o b e 2 0 ° C .
※2 U s e t he f o l lo w i n g f o r mu l a t o ma k e c a lc u la t i o n s u s in g m mH g o r k g / c m 2 a s t h e
unit of pressure.
Partial
pressure of
Acceptance weight of substance
quantity
loss ＝ 5.5 × the
subject
× brought in × mmHg
substance m
3
pressure
g/mol
of the
tank
2
kg/cm
※3 W h en e x h a u s t g a s i s t r e a te d , mu l ti p l y t he r e s u lt o f th e ab o ve f o r m ul a b y [ ( 1 0 0 %
− R e mo v a l e ff i c ie n c y % ) / 1 0 0 ]
※4 I n th e ca s e o f a mi x t u r e , r e f e r t o ※ 4 o f b r e a th i n g lo s s .
III - 6
The following is an example of calculating the release/transfer from the
storage facility (fixed-roof tank) described by Table 1-1-1 and Fig. 1-1-1.
Table 1-1-1 Outline of the storage tank (fixed-roof tank)
Handling status of specified substance
① Outline of the work of handling specified substance
St o r a g e me t h o d , St o r a g e in f i x e d - r o o f t a n k ( R e f e r to F ig . 1 - 1 - 1 . )
etc. G e n e r a t i o n o f e ff l u e n t / w a s t e a n d l e a k a g e t o l a n d :
None
D e s c r i p t i o n o f th e Internal diameter: 10m Capacity: 500m3
storage tank
H e ig h t : 6 . 4 m Color: Silver
Internal pressure 9.81 × 104Pa (Absolute pressure)
Av e r a g e o u t d o o r a i r t e mp e r a t u r e v a r i a t i o n o f t h e
year: 5 °C
Av e r a g e s to r a g e h e i g h t : N o t k n o w n
Exhaust gas None
t r e a t me n t f a c i l i t y
② Raw material/material containing a specified substance handled
• Solvent A
Annual quantity 2,000 m3/year (Gravity: 0.87)

brought in
St o c k a t b e g in n i n g 120 m3
of fiscal year
St o c k a t e n d o f 170 m3
fiscal year
Content of
specified substance
listed in MSDS Name of
Substance No. Content
substance
63 Xylene 45%
227 To l u e n e 40%
299 Benzene 15%
③ Molecular mass and vapor pressure of specified substance contained in

the raw material/material
Substance Name of Molecular Va p o r p re s s u re

No. substance mass
63 Xylene 9 2 . 1 g / mo l 1.33 × 103 Pa
227 To l u e n e 1 0 6 . 2 g / mo l 3.75 × 103 Pa
299 Benzene 7 8 . 1 g / mo l 13.3 × 103 Pa
III - 7
Air
emission
( To l u e n e ,
xylene,
benzene)
②
Bring in Delivery
Fixed-roof tank
①
( To l u e n e , ( To l u e n e ,
xylene, xylene,
benzene) benzene)
Solvent Solvent
Fig. 1-1-1 Outline of storage tank (fixed-roof tank)
To make engineering calculations of the quantity released/transferred from

the storage facility, follow the procedure shown below, which is distinct
from the procedure using mass balance described in Part I and Part II.
Examples given are of calculation of toluene. Follow the same procedure to
calculate the quantity of xylene and benzene.
Step 1: Calculate the annual quantity of specified substance

handled.
Step 2: Calculate the release/transfer to medium other than air.
Step 3: Calculate the air emission of the specified substance.
Step 4: Sum up the quantities of specified substance released or
transferred.
Step 1 Calculate the annual quantity of specified substance handled.
Step 1-1 Calculate the annual quantity of specified substance

manufactured.
Since specified substance is not manufactured in the storage

facility, 0 is assumed as the annual quantity of specified
substance manufactured.
Annual
quantity
of specified
substance ＝ 0 t/year
manufactured
t/year
Step 1-2 Calculate the annual quantity of Solvent A used.
Quantity of Quantity
Annual Annual quantity solvent A of solvent
quantity of of solvent A stored at A stored at
solvent A
used
t/year
＝ purchased
2000m /year
3
− the end of
the fiscal
year 3
+ the
beginning
of the fiscal
× 0.87 t/m 3
170m year 3
120m
＝ 1696.5 t/year
III - 8
Step 1- 3 Calculate the annual quantity of specified substance
used.
Annual Annual Content of
quantity of
quantity of
toluene ＝ solvent A
used
× toluene in
Solvent A ÷ 100
used 40%
t/year 1696.5t/year
＝ 678.6t/year
Step 1-4 Calculate the annual quantity of specified substance handled.

Annual Annual Annual
quantity of quantity of
toluene ＝ quantity of
toluene + toluene
handled manufactured used
t/year 0 t/year 678.6 t/year
Designated
value of
specified
＝ 678.6t/year ≧ substance
(Class 1
designated
chemical
substance)
1t/year
Since the annual quantity of toluene handled is larger than the specified
quantity (1t/year), it is designated as requiring notification.
Step 2 Calculate the release/transfer to medium other than air.
Since this tank does not have contact with water and there is no
leakage to land and generation of waste, 0 is assumed as air or
land emission of the specified substance.
Release of Land Quantity of

specified emission of specified
substance to
water
＝ specified
substance ＝ substance
in waste
kg/year kg/year kg/year
＝ 0 kg/year
III - 9
Step 3 Calculate the air emission of the specified substance.
Step 3-1 Calculate the partial pressure of toluene in mixed vapor.
Since the stored solvent is mixed liquid of three substances,

calculate the partial pressure of toluene using the formula shown
in *4 in pIII-6.
Content
of toluene
40%
Molecular
weight of
toluene
Partial Va p o r 92.1 g/mol
pressure of
toluene ＝
pressure of
toluene ×
Pa Content Content Content
+ +
3 of toluene of xylene
3.75×10 Pa of benzene
40% 45% 15%
Molecular Molecular Molecular
weight of weight of weight of
toluene xylene benzene
＝ 1.55×10 Pa
3 92.1 g/mol 106.2 g/mol 78.1 g/mol
Step 3-2 Calculate the breathing loss of toluene.
Make calculations using the formula in pIII-5.
Partial
pressure of
toluene 0.68 1.73
Molecular 3 Internal
Breathing 1.55×10 Pa
loss ＝ 0.3 × weight of
toluene × × diameter
of the
kg/year
Partial tank
92.1g/mol
101.3 × 10 3 − pressure of
toluene
10m
3
1.55×10 Pa
0.51 0.5
Average Difference
Height
of the storage in annual Factor
× tank − height × average of
outside air
×
Factor
of tank × of tank
6.4m 3.2m color diameter
temperature 1.2 1.0
5m
＝ 424kg/year
Step 3-3 Calculate the acceptance loss of toluene.
Make calculations using the formula in pIII-7.

Partial
pressure of
weight of s u b s t a n c 3e
quantity
Acceptance
loss ＝ 0.041 × toluene
92.1g/mol
× brought in × 1.55×10 Pa

3
2000m pressure
of the tank
4
9.81×10 Pa
＝ 543kg/year
III - 10
Step 3-4 Calculate the air emission of toluene.
Sum up breathing loss and acceptance loss to obtain the air

emission of toluene.
Air Breathing Acceptanc

emission
of toluene
kg/year
＝ loof stso l u e n e
424kg/year
+ e loss
of toluene
11 9 k g / y e a r
＝ 543kg/year
Step 4 Sum up the quantities of specified substance released or

transferred.
Toluene (unit; kg/year)

Classification for Classification for Notification
Calculation
(Releases)
A Air emission; 543 a. Air emission; 540
B Release to water; 0 b. Surface water discharge; 0.0
C Land emission; 0 c. Land emission in the business
e s ta b l i s h m e n t ; 0 . 0
D Quantity in waste; 0 d . L a n d f i l l s i n t h e b u s i n e s s e s ta b l i s h m e n t ;
0.0
( Tr a n s f e r s )
e . Tr a n s f e r t o s e w a g e ; 0 . 0
f . O ff - s i t e t r a n s f e r i n w a s t e ; 0 . 0
III - 11
[Example of calculation (2)] Emission factors

storage facility (gas station) described by Table 1-1-2 and Fig. 1-1-2.
Table 1-1-2 Outline of gas station

St o r a g e me t h o d St o r a g e a n d r e f u e l i n g o f r e g u l a r g a s o l i n e t o g a s
s t a t i o n ( u n d e rg r o u n d t a n k ) ( R e f e r t o F i g . 1 - 1 - 2 . )
G e n e r a t i o n o f e ff l u e n t / w a s t e a n d l e a k a g e t o l a n d :
None
Exhaust gas None
② Raw material or material containing specified substance handled
• Regular gasoline
A n n u a l q u a n t i t y b r o u g h t in 1,500 kL/year (Gravity: 0.73)
Annual quantity of 1,420 kL/year
refueling
St o c k a t b e g in n i n g o f 5 kL
fiscal year
St o c k a t e n d o f f i s c a l y e a r 8 kL
Content of specified
substance (average value
i n th e i n d u s t r y ) Substance Specified Content
No. substance
40 Ethylbenzene 1.4 %
63 Xylene 6.1 %
227 To l u e n e 9.1 %
299 Benzene 0.64%
III - 12
Air emission ( To l u e n e ,
xylene,
benzene)
②
Bring
in Gas station Delivery
( To l u e n e , ( To l u e n e ,
xylene, Delivered
xylene,
benzene) benzene) fueled in
vehicles
Regular Underground
gasoline tank
Fig. 1-1-2 Outline of gas station (underground tank)
To calculate the quantity released or transferred from the storage facility

using emission factors, follow the procedure shown below, which is distinct
from the procedure using mass balance described in Part I and Part II.
Examples given are of calculation of benzene. Follow the same procedure to
calculate the quantity of ethylbenzene, xylene and toluene. (Refer also to
Q105 (→ pIII-152) in 2. Questions and Answers of Part III.)
Step 1: Calculate the annual quantity of specified substance

handled.
Step 2: Calculate the release/transfer to medium other than air.
Step 3: Calculate the air emission of specified substance.
Step 4: Sum up the quantities of specified substance released or
transferred.
Step 1 Calculate the annual quantity of specified substance handled
Step 1-1 Calculate the annual quantity of specified substance

manufactured.

Annual
quantity
of specified
manufactured
t/year
Step 1-2 Calculate the annual quantity of regular gasoline used.
Annual Annual quantity ｒegular of ｒegular
quantity of of regular gasoline gasoline
regular
gasoline
＝ gasoline
purchased
− stored at
the end of + stored at
the × 0.73 t/kl
used the fiscal beginning
1500kl/year year of the fiscal
t/year
8kl year
5kl
＝ 1092.8 t/year
III - 13
Step 1-3 Calculate the annual quantity of specified substance used.
Annual Content of
Annual benzene
quantity of
quantity of
benzene ＝ｒegular
gasoline
× in ｒegular
gasoline
÷ 100
used 0.64%
t/year used
1092.8t/year
＝ 6.99 t/year

benzene ＝ quantity of
benzene + benzene
t/year 0 t/year 6.99t/year
Designated
value of
specified
substance
＝ 6.99t/year
≧
( Sp e c i f i c
class 1
designated
chemical
substance)
0.5t/year
Since the annual quantity of benzene handled is larger than the specified
quantity (1 t/year), it is designated as requiring notification.
Step 2 Calculate the release/transfer to medium other than air.
Since this tank does not have contact with water and there is no
leakage to land and generation of waste, 0 is assumed as air or land
emission of the specified substance.
Release of Land Quantity of

specified emission of specified
specified
substance to
water ＝ substance
kg/year
＝ substance
in waste
kg/year kg/year
＝ 0 kg/year
III - 14
Step 3 Calculate air emission of specified substance.
Calculate the air emission from the gas station by multiplying the
following emission factors (→ pIII-250) at the time of acceptance to
and delivery from the gas station by the annual quantity of regular
gasoline accepted and fueled.
• Emission factor at acceptance of benzene : 0.0025759 kg/kL
• Emission factor at delivery of benzene : 0.0032437 kg/kL
Step 3-1 Calculate the acceptance loss of benzene.
Quantity of Emission
Acceptance regular factor at
loss
of benzene
＝ gasoline × acceptance
brought in of benzene
kg/year 1500kl/year 0.0025759kg/kL
＝ 3.86kg/year
Step 3-2 Calculate the refueling loss of benzene.
Quantity of Emission
Refueling regular factor at
loss
of benzene
＝ gasoline × delivery
refueled of benzene
kg/year 1420kl/year 0.0032437kg/kL
＝ 4.61kg/year
Step 3-3 Calculate the air emission of benzene.
Sum up the acceptance loss and the refueling loss to obtain the air
emission of benzene.
Acceptance
Air Refueling loss
loss
emission
of benzene
＝ of benzene × of benzene
kg/year 3.86kg/year 4.61kg/year
＝ 8.47kg/year
III - 15
transferred.
Benzene (unit; kg/year)

Calculation
(Releases)
A Air emission; 8.47 a. Air emission; 8.5
0.0
III - 16
[Example of calculation (3)] Mass balance

storage tank described by Table 1-1-3 and Fig. 1-1-3.
Table 1-1-3 Outline of storage tank
① Outline of the work handling specified substance

St o r a g e me t h o d St o r a g e o f t h in n e r A t o s t o r a g e t a n k ( R e f e r t o F i g .
1 - 1 - 3 . ) G e n e r a t i o n o f e ff l u e n t / w a s t e a n d l e a k a g e t o
land: None
Exhaust gas None
• Thinner A
Annual quantity 3.0 t/year
brought in
delivered
St o c k a t b e g in n i n g 0.7 t
of fiscal year
St o c k a t e n d o f 0.4 t
fiscal year
Content of
specified substance
listed in MSDS Specified
substance
63 Xylene 45%
III - 17
Air
emission
(xylene)
Bring in Delivery
Fixed-roof tank
① ②
(xylene) (xylene)
Thinner A Thinner A
Fig. 1-1-3 Outline of storage tank
Follow the procedure based on mass balance described in Part I and Part II
to calculate the release/transfer from the storage tank.
Step 1-1 Calculate the annual quantity of specified substance manufactured.

Annual
quantity
of specified
manufactured
t/year
Step 1-2 Calculate the annual quantity of thinner A used.

Annual Annual quantity thinner A of
quantity of of thinner A stored at thinner A
thinner A
used
＝ purchased − the end of
the fiscal + stored at
the
year beginning
3.0t/year of the fiscal
t/year
0.4t year
0.7t
＝ 3.3t/year
Annual Annual
quantity of Content of
quantity of
xylene ＝ thinner A
used
× xylene
in thinner A
÷ 100
used
t/year 45%
3.3t/year
＝ 1.49t/year
III - 18

xylene ＝ quantity of
xylene + xylene
t/year 0t/year 1.49t/year
Designated
value of
specified
substance
＝ 1.49t/year ≧ (Class 1
designated
chemical
substance)
1t/year
Since the annual quantity of xylene handled is larger than the specified
quantity (1t/year), it is designated as requiring notification.
Step 2 Calculate the quantity of specified substance released as

manufactured goods.
Quantity of
xylene Annual Content of
released as
manufactur
＝ quantity
of thinner A ×
xylene
in thinner A ÷ 100 × 1000kg/ｔ
ed goods purchased
kg/year 2.8t/year 45%
＝ 1260kg/year
Step 3 Calculate the quantity of specified substance in waste.
Since no waste is generated, 0 is assumed as the quantity in waste.
Quantity
of xylene
in waste ＝ 0 kg/year
kg/year
Step 4 Calculate the maximum potential release of specified substance

to the environment.
Maximum Annual Quantity of

potential quantity of xylene Quantity
release of
xylene to the
＝ xylene × 1000kg/ｔ − released as
manufactured
− of xylene
in waste
handled
environment 1.49t/year goods 0kg/year
kg/year 1260kg/year
＝ 1260kg/year
III - 19
Step 5 Calculate the land emission of the specified substance.
Since there is no leakage to land, 0 is assumed as land emission.
Land
emission of
xylene ＝ 0 kg/year
kg/year
Step 6 Judge to which medium, land or water, larger or smaller

quantity is released.
Since the storage tank does not have contact with water, it is
assumed that larger quantity is released to air.
Step 7 Calculate the release of specified substance to water.
Since the storage tank does not have contact with water, 0 is
assumed as the release to water.
Release of
xylene to
water ＝ 0 kg/year
kg/year
Maximum
potential Land Release of
Air emission
of xylene ＝ release of − emission of
xylene − xylene to
water
kg/year xylene to the 0kg/year
environment 0kg/year
230kg/year
＝ 230kg/year

transferred.
Xylene (unit; kg/year)

Calculation
(Releases)
0.0
III - 20
1-2 Reaction/mixing process
This is a process where raw materials are made to react to generate a new
chemical substance, raw materials are mixed (without chemical reaction),
distilled for purification or separated into solid and liquid to manufacture
products.
The release to the environment and off-site transfer in waste include the
following.
• Volatilization of specified substance contained in raw materials or
manufactured goods into air or mixing into effluent
• Transfer as spent solvent
When exhaust gas or effluent generated from the process is treated by

activated carbon adsorption treatment in an exhaust gas/effluent treatment
facility, waste (spent carbon, etc.) may be generated.
[ Ex am p l e s of s u bj e ct s u b st a n ce s]
Subject substances contained in raw materials or products
[Example of calculation (1)] When new substance is manufactured with

specified substance used as raw material

reaction facility (1) described by Table 1-2-1 and Fig. 1-2-1.
Table 1-2-1 Outline of reaction facility (1)
Description of reaction C y c l o h e x a n e i s ma n u f a c t u r e d w i t h b e n z e n e
u s e d a s r a w ma t e r i a l . ( R e f e r t o F i g . 1 - 2 - 1 . )
Reaction rate of benzene: 99%
Wa s h in g e ff l u e n t r e l e a s e d f r o m r e a c t i o n
f a c i l i t y : 2 m 3 / t i me , 1 0 t i m e s / y e a r
E x h a u s t g a s t r e a t me n t None
facility
E ff l u e n t t r e a t me n t Activated sludge treatment
facility ( R e mo v a l r a t e : 6 0 % , D e c o mp o s i t i o n r a t e : 0 % )
E ff l u e n t r e l e a s e d t o : ***** river
III - 21
(cont’d)
② Raw materials or materials containing specified substance handled
• Raw material A

purchased
of fiscal year
fiscal year
Content of
specified substance
substance
299 Benzene 100%
Air
emission
（Benzene）
④
Bring in Reaction tower Delivery
①
（Benzene） ②
Reaction
Benzene Air
（Benzene） emission Cyclohexane
③-1 ③-3
Effluent
treatment
(activated
sludge
treatment)
③-2
Effluent
Fig. 1-2-1 Outline of reaction facility (1)
Calculate the release/transfer from this reaction facility using mass balance
that has been described in Part I and Part II.
III - 22
Since no specified substance is manufactured in this reaction

facility, 0 is assumed as annual quantity of specified substance
manufactured.
Annual
quantity
of specified
manufactured
t/year
Step 1-2 Calculate the annual quantity of raw material A used.
Annual Annual quantity raw material of raw
quantity of of raw material A stored at material A
raw
material A
＝ A purchased − the end of
the
used year beginning
4.7t/year 0.3t of the fiscal
t/year
year
0.6t
＝ 5.0t/year
Annual Annual
quantity of
benzene ＝ raw material
A
× benzene in
raw material A
÷ 100
used
t/year used
100%
＝ 5.0t/year

quantity of
benzene ＝ quantity of
benzene + quantity of
benzene
Designated
value of
specified
substance
＝ 5.0t/year ≧
( Sp e c i f i c
class 1
designated
chemical
substance)
0.5t/year
Since the annual quantity of specified substance handled is larger than the
specified quantity (0.5 t/year), benzene is assumed as requiring notification.
III - 23
manufactured goods.
Since the quantity of benzene released as manufactured goods from

this reaction facility equals to the value consumed by the reaction,
make calculations using the following formula.
Quantity of Quantity of
benzene benzene Annual Reaction rate
released as
manufactur
＝ consumed
by the
＝ quantity
of benzene ×
of benzene
÷ 100 × 1000kg/ｔ
ed goods reaction purchased 99%
kg/year kg/year 5.0t/year
＝ 4950kg/year
Since waste such as waste liquid containing benzene is not

generated from this reaction facility, 0 is assumed as the quantity
in waste.
Quantity
of benzene
kg/year
Step 4 Calculate the maximum potential release to the environment.

potential Quantity
quantity of benzene of
release of
benzene to
＝ benzene × 1000kg/ｔ − released as
manufactured
− benzene
handled in waste
the 5.0t/year goods 0kg/year
kg/year
＝ 50kg/year
Since there is no leakage from this reaction facility to land, 0 is

assumed as land emission.
Land
emission of
benzene ＝ 0 kg/year
kg/year
III - 24
Since benzene has high volatility, it is assumed that larger quantity

is released to air.
Step 7 Calculate the release of the specified substance to water.
Calculate the potential release of benzene to water using the

solubility of benzene to water, 1.8 g/L (=1.8 kg/m 3 ).
Potential Annual effluent quantity Solubility of

release of
benzene to ＝ × benzene to wa 3
ter ÷ 100
1.8kg/m
water 3
2m /washing×10times/year
kg/year
＝ 36kg/year
Calculate the quantity of benzene released to water after effluent treatment

and that released to air during the treatment process using the
removal/decomposition rate of activated sludge treatment.
Removal
Release of Potential rate of
benzene release of
to water ＝ benzene to ×(100− activated
sludge )÷ 100
water treatment
kg/year 36kg/year 60％
＝ 14kg/year
Decompo
Removal sition
Quantity of Potential
benzene rate of rate of
released to
air during
＝ release of
benzene to ×( activated
sludge − activated
sludge
) ÷ 100
water treatment treatment
the 36kg/year 60％ 0％
treatment
process
kg/year
＝ 22kg/year
Step 8 Calculate the air emission of specified substance.
Calculate the air emission from reaction facility to air using mass
balance.
Maximum Potential
Air emission potential Land
emission of release of
of benzene release of benzene to
from reaction
facility
＝ benzene to
the
− benzene
0kg/year − water
36kg/year
kg/year environment
50kg/year
＝ 14kg/year
III - 25
Step 9 Sum up the quantities of specified substance released or transferred.
Benzene (unit; kg/year)

Calculation
(Releases)
A Air emission; a. Air emission; 36
Reaction facility 14 b. Surface water discharge; 14
E ff l u e n t t r e a t m e n t 2 2 c. Land emission in the business
B Release to water; 14 e s ta b l i s h m e n t ; 0 . 0
C Land emission; 0 d . L a n d f i l l s i n t h e b u s i n e s s e s ta b l i s h m e n t ;
D Quantity in waste; 0 0.0
[Example of calculation (2)] When specified substance is manufactured

reaction facility (2) described by Table 1-2-2 and Fig. 1-2-2.
Table 1-2-2 Outline of reaction facility (2)
Description of Tr i c h lo r o e t h y l e n e i s m a n u f a c t u r e d w i t h e t h y l e n e
reaction u s e d a s r a w ma t e r i a l . ( R e f e r t o F i g . 1 - 2 - 2 . )
Wa s h in g e ff l u e n t r e l e a s e d f r o m r e a c t i o n f a c i l i t y :
10 m3/washing, 12 times/year
G e n e r a t i o n o f w a s t e a n d l e a k a g e to l a n d : N o n e
Exhaust gas C o mb u s t i o n t r e a t me n t
t r e a t me n t f a c i l i t y ( R e mo v a l / d e c o mp o s i t i o n r a t e : 9 9 . 5 % )
E ff l u e n t t r e a t me n t A c t i v a t e d c a r b o n a d s o r p t i o n t r e a t m e n t
E ff l u e n t r e l e a s e d ***** river
to:
② Raw materials and materials containing specified substance handled
• Trichloroethylene manufactured
Annual quantity manufactured 3.0 t/year
Annual quantity delivered 2.8 t/year

(except for those kept within
business establishment as stock)
III - 26
(cont’d)
③ Waste generated
Ty p e o f w a s t e Quantity Content of specified Tre a t m e n t o f w a s t e

generated substance
Spent carbon Not known Not known Delivered to an industrial
w a s t e m a n a g e me n t c o n t r a c t o r
Air
emission
③-2
Exhaust gas
treatment
(combustion
treatment) （ Tr i c h l o r o
ethylene）
③-1
Bring in Reaction tower Delivery
① （ Tr i c h l o r o
Manufa ethylene）
cturing
Ethylene Tr i c h l o r o
（ Tr i c h l o r o
ethylene） ethylene
②-1
Effluent treatment
②-3 (activated carbon
adsorption treatment)
Wa s t e
②-2
Effluent
Sp e n t c a r b o n
Fig. 1-2-2 Outline of reaction facility (2)
to calculate the release/transfer from the reaction facility.
III - 27
Annual
quantity of
trichloroethylene ＝ 3.0t/year
manufactured
t/year
Since raw material or material containing specified substance are

not used in this reaction facility, 0 is assumed as the annual
quantity of specified substance used.
Annual
quantity
of specified
used
t/year
Since the annual quantity of trichloroethylene handled is larger

than the specified quantity (1t/year), it is designated as requiring
notification.

quantity of quantity of quantity of
trichloroethylene
handled
＝ trichloroethylene
manufactured + trichloroethylene
used
t/year 3.0t/year 0t/year
Designated
value of
specified
＝ 3.0t/year ≧
substance
(Class 1
designated
chemical
substance)
1t/year

manufactured goods.
Since the quantity of trichloroethylene released as manufactured

goods from this reaction facility equals to the quantity of
trichloroethylene delivered, make calculations using the following
formula.
Quantity of Annual
trichloroeth
ylenereleas
ed as
＝ quantity of
trichloroethylene × 1000kg/ｔ
delivered
manufactur 2.8t/year
ed goods
kg/year
＝ 2800kg/year
III - 28
In this reaction facility, spent carbon containing trichloroethylene

is generated by effluent treatment. Calculate the quantity in waste
when calculating the release to water using the removal rate of
effluent treatment.
Since this is the only waste that contains trichloroethylene, 0 is
assumed as the quantity in waste.
Quantity of
trichloroethylene
in waste
＝ 0 kg/year
kg/year

to the environment.
Maximum Quantity of Quantity

potential release Annual
trichloroethyl of
of
trichloroethylene ＝
quantity of
trichloroethylene × 1000kg/ｔ − ene released
as
− trichloroet
hylene
to the handled
3.0t/year manufactured in waste
environment goods 0kg/year
kg/year 2800kg/year
＝ 200kg/year
Since there is no leakage from this reaction facility to land, 0 is

Land
emission of
trichloroethylene ＝ 0 kg/year
kg/year

Since trichloroethylene has high volatility, it is assumed that larger

quantity is released to air.
III - 29
Calculate the release of trichloroethylene to water after effluent

treatment using the actually measured concentration of
trichloroethylene, 1.0mg/L (=1.0×10 − 3 kg/m 3 ).
Release of Actually
Annual effluent quantity
trichloroet
hylene to ＝ × measured
concentration of
water after 3 t r i c h l o r o e- 3t h y l e n3 e
10m /washing×12times/year 1.0×10 kg/m
effluent
treatment
kg/year
＝ 0.12kg/year
Calculate the potential release of trichloroethylene to water and

the quantity in waste (spent carbon) generated by the treatment
using the removal/decomposition rate of activated carbon
adsorption treatment.
Release of Removal
Potential trichloroethyl rate of
release of ene to water activated
trichloroeth ＝ after effluent ÷(100− carbon
adsorption
)× 100
ylene to treatment
water 0.12kg/year treatment
kg/year 80％
＝ 0.60kg/year
Removal Decompo Removal

Release of rate of sition rate of
Quantity of trichloroethyl activated rate of activated
trichloroethylen
e in waste ＝ ene to water
after effluent ×( carbon
adsorption
− activated
carbon
) ÷ (100− carbon
adsorption
)
(spent carbon) treatment treatment adsorption treatment
generated by 0.12kg/year 80％ treatment 80％
the treatment 0％
kg/year
＝ 0.48kg/year
III - 30
Calculate the air emission of trichloroethylene using the following

formula.
Maximum
Potential potential Land Potential
release of
release of
trichloroethyl ＝ trichloroethy
lene to the
− emission of
trichloroethyl −
release of
trichloroethy
ene to air ene lene to water
kg/year environment 0kg/year 0.60kg/year
200kg/year
＝ 199.4kg/year
Calculate the air emission of trichloroethylene after exhaust gas

treatment using the removal rate of combustion treatment. Since
the removal rate and the decomposition rate of combustion
treatment are the same, 0 is assumed as the quantity in waste
generated by the treatment.
Air Potential Removal

emission of release of rate of
trichloroeth ＝ trichloroethyl
ene to air
×(100− combustion )÷ 100
ylene treatment
kg/year 199.4kg/year 99.5％
＝ 1.0kg/year
Step 9 Sum up the quantities of the specified substance released or

transferred.
Trichloroethylene (unit; kg/year)

Calculation
(Releases)
A Air emission; 1.0 a. Air emission; 1.0
B Release to water; 0.12 b. Surface water discharge; 0.1
D Quantity in waste; 0.48 d . L a n d f i l l s i n t h e b u s i n e s s e s ta b l i s h m e n t ;
0.0
III - 31
[Example of calculation (3)] In the case of mixing process

mixing facility (1) described by Table 1-2-3 and Fig. 1-2-3.
Table 1-2-3 Outline of mixing facility (1)

Description of mixing To l u e n e a n d p i g me n t a r e mi x e d t o m a n u f a c t u r e p a i n t .
(Refer to Fig. 1-2-3.)
Q u a n t i t y o f p a in t ma n u f a c t u r e d : 4 5 t / y e a r, To l u e n e
content: 20%
Wa s h in g e ff l u e n t r e l e a s e d f r o m m i x i n g f a c i l i t y :
facility
facility ( R e mo v a l r a t e : 6 0 % , D e c o mp o s i t i o n r a t e 0 % )
② Raw material or material containing specified substance
• Raw material A
purchased
of fiscal year
fiscal year
Content of
specified substance
substance
227 To l u e n e 100%
III - 32
Air
emission
( To l u e n e )
④
Delivery
Bring in Mixing tank
① ②
( To l u e n e ) ( To l u e n e )
Air
To l u e n e ( To l u e n e ) emission Paint
③-1 ③-3
Effluent treatment
(activated sludge
treatment)
③-2
Effluent
Fig. 1-2-3 Outline of mixing facility (1)
to calculate the release/transfer from the mixing tank.
Since no specified substance is manufactured in the mixing facility,

0 is assumed as the annual quantity of specified substance
manufactured.
Annual
quantity
of specified
manufactured
t/year
raw
material A
the
used year beginning
t/year
year
0.6t
＝ 10.0t/year
III - 33
Annual Annual
quantity of
toluene ＝ raw material
A
× toluene in
raw material A
÷ 100
used
t/year used
100%
＝ 10.0t/year

quantity of
toluene ＝ qt oulaunetni tey o f + quantity of
toluene
Designated
value of
specified
substance
＝ 10.0t/year ≧
(Class 1
designated
chemical
substance)
1t/year
Since the annual quantity of toluene handled is larger than the

specified quantity (1t/year), it is designated as requiring
notification.

manufactured goods.
Since the quantity of toluene released as manufactured goods from
this mixing facility equals to the quantity contained in the paint
manufactured, make calculations using the following formula.
Quantity of
toluene Annual Content of the
released as
manufactur
＝ quantity
of paint ×
toluene
contained ÷ 100 × 1000kg/ｔ
ed goods manufactured in paint
kg/year 45t/year 20%
＝ 9000kg/year
Since waste such as waste liquid containing toluene is not

generated from this mixing facility, 0 is assumed as the quantity in
waste.
Quantity
of toluene
kg/year
III - 34
to the environment.
potential Quantity
quantity of toluene of toluene
release of
toluene to
＝ toluene × 1000kg/ｔ − released as
manufactured
− in waste
handled 0kg/year
the 10.0t/year goods
kg/year
＝ 1000kg/year
Since there is no leakage from this mixing facility to land, 0 is

Land
emission of
toluene ＝ 0 kg/year
kg/year

Since toluene has high volatility, it is assumed that larger quantity

is released to air.
Calculate the quantity of toluene released to water before effluent

treatment using the solubility of toluene to water, 0.58g/L
(=0.58kg/m 3 ).

release of
toluene to ＝ × toluene to water
water 3
2m /washing×50times/year 0.58kg/m
3
kg/year
＝ 58kg/year
III - 35
Calculate the release of toluene to water after effluent treatment
and the air emission by the treatment using the removal rate and
decomposition rate of activated sludge treatment.
Removal
toluene to release of
water ＝ toluene to ×(100− activated
sludge )÷ 100
water treatment
＝ 23kg/year
Decompo
quantity of Removal sition
Quantity of toluene rate of
toluene rate of
released to
air during
＝ released to
water ×( activated
sludge
) ÷ 100
before treatment treatment
the
treatment effluent 60％ 0％
treatment
process
kg/year
＝ 35kg/year
Calculate the air emission from the mixing facility using mass
balance.
Maximum Potential
release of
of toluene release of emission of toluene to
from mixing
facility
＝ toluene to
the
− toluene
0kg/year − water
58kg/year
kg/year environment
1000kg/year
＝ 942kg/year

transferred.

Calculation
(Releases)
III - 36
[Example of calculation (4)] When many types of products containing
specified substances are manufactured in small quantity

mixing facility (2) described by Table 1-2-4 and Fig. 1-2-4.
Table 1-2-4 Outline of mixing facility (2)

Description of mixing To l u e n e a n d p i g me n t a r e mi x e d t o m a n u f a c t u r e
p r i n t i n g i n k . ( R e f e r to F i g . 1 - 2 - 4 . )
Yi e l d o f t o l u e n e i n ma n u f a c t u r e o f p r i n t i n g i n k : 9 9 %
Wa s h in g e ff l u e n t r e l e a s e d f r o m m i x i n g f a c i l i t y :
facility
② Raw materials containing specified substance handled
• Raw material A
purchased
of fiscal year
fiscal year
Content of
specified substance
listed in MSDS Name of
substance
227 To l u e n e 100%
III - 37
Air
emission
( To l u e n e )
④
Bring in Delivery
Mixing tank
① ②
( To l u e n e ) ( To l u e n e )
Air
To l u e n e ( To l u e n e ) emission Printing
ink
③-1 ③-3
Effluent treatment
(activated sludge
treatment)
③-2
Effluent
Fig. 1-2-4 Outline of mixing facility (2)
to calculate the release/transfer from the mixing tank.
Since specified substance is not manufactured in this mixing

facility, 0 is assumed as the annual quantity of specified substance
manufactured.
Annual
quantity
of specified
manufactured
t/year
raw
material A
the
used year beginning
t/year
year
0.6t
＝ 10.0t/year
III - 38
Annual Annual
quantity of
toluene ＝ raw material
A
× toluene in
raw material A
÷ 100
used
t/year used
100%
＝ 10.0t/year

quantity of
toluene ＝ quantity of
toluene + quantity of
toluene
Designated
value of
specified
substance
＝ 10.0t/year ≧
(Class 1
designated
chemical
substance)
1t/year
Since the annual quantity of toluene handled is larger than the

specified quantity (1t/year), it is designated as requiring
notification.

manufactured goods.
Since the quantity of specified substance released as manufactured

goods equals to the quantity of toluene contained in manufactured
printing ink, calculate the quantity using the yield of toluene as
shown by the following formula.
Quantity of Quantity of
toluene Annual
toluene
released as
manufactur
＝ quantity of
toluene × contained in
manufactured ÷ 100 × 1000kg/ｔ
ed goods handled
10t/year printing ink
kg/year 99%
＝ 9900kg/year
Since no waste such as waste liquid containing toluene is generated

in this mixing facility, 0 is assumed as the quantity of specified
substance in waste.
Quantity
of toluene
kg/year
III - 39
to the environment.

potential Quantity
quantity of toluene of toluene
release of
toluene to
＝ toluene × 1000kg/ｔ − released as
manufactured
− in waste
handled 0kg/year
the 10.0t/year goods
kg/year
＝ 100kg/year
Step 5 Calculate the land emission of specified substance.
Since there is no leakage from this mixing facility to land, 0 is

Land
emission of
kg/year

Since toluene has high volatility, it is assumed that larger quantity

is released to air.
Calculate the release of toluene to water before effluent treatment

by using solubility of toluene to water, 0.58 g/L (= 0.58 kg/m 3 ).

release of
toluene to ＝ × toluene to water
water 3
2m /washing×50times/year 0.58kg/m
3
kg/year
＝ 58kg/year
III - 40
Calculate the release of toluene to water after effluent treatment by
using the removal rate and decomposition rate of activated sludge
treatment.
Removal
toluene to release of
water ＝ toluene to ×(100− activated
sludge )÷ 100
water treatment
＝ 23kg/year
Decompo
quantity of Removal sition
Air emission toluene rate of rate of
of toluene
by ＝ released to
water ×( activated
sludge
) ÷ 100
treatment before treatment treatment
effluent 60％ 0％
k / treatment
＝ 35kg/year
Calculate the air emission from the mixing facility using mass
balance.
Maximum Potential
emission of release of
of toluene release of toluene to
from mixing
facility
＝ toluene to
the
− toluene
0kg/year − water
58kg/year
kg/year environment
100kg/year
＝ 42kg/year

transferred.

Calculation
(Releases)
III - 41
1-3 Machining process
This is a process where metallic materials, etc. are cut or polished to obtain
desired form.
following.
• Mixing of specified substance contained in cutting oil (nonvolatile),
which is fed as an additive to prevent nick at the time of cutting or
polishing, into effluent
• Transfer as spent cutting oil
Boron and its compounds ( So di u m t et ra b ora t e ) , 2- a mi n oe t ha n ol , e t c .
[Example of calculation]

machining facility described by Table 1-3 and Fig. 1-3.
Table 1-3 Outline of machining facility
Outline of machining Metallic parts are washed with water

process a f t e r b o r i n g . ( R e f e r to F i g . 1 - 3 . )
facility
E ff l u e n t t r e a t me n t None
facility
② Raw material or material containing specified substance
• Cutting oil A
purchased
of fiscal year
fiscal year
Content of
specified substance
listed in MSDS Name of specified
substance
Boron and its compound

304 4.3%
(Sodium tetraborate)
III - 42
(cont’d)
③ Waste generated
Ty p e o f w a s t e Quantity Content of specified Wa s t e t re a t m e n t

generated substance
Spent cutting oil 20 t/year Not known Delivered to industrial waste
m a n a g e me n t c o n t r a c t o r
Handling
①
(Boron
and its
compound) Boring of Manufactured
Cutting metal goods (Metal
oil A Drilling plate with
Cutting holes)
oil
Metal plate
② (Boron
(Boron ③ and its
and its compound)
compound)
Wa s t e
Effluent
Sp e n t
cutting oil
Fig. 1-3 Outline of machining facility
III - 43
to calculate the release/transfer from the machining facility.
Since specified substance is not manufactured in the facility, 0 is

assumed as the annual quantity of specified substance
manufactured.
Annual
quantity
of specified
manufactured
t/year
Step 1-2 Calculate the annual quantity of cutting oil A used.
Annual Annual quantity cutting oil A of cutting
quantity of of cutting oil A stored at oil A stored
cutting oil
A used
the fiscal + at the
beginning
t/year year of the fiscal
23.8t/year 0.2t year
0.9t
＝ 24.5t/year

Annual Content of
Annual boron and its
boron and its ＝ cutting oil A × compound
in cutting oil A
÷ 100
compound used
used 4.3%
t/year 24.5t/year
＝ 1.054t/year

Annual Annual
Annual quantity of
boron and its
boron and its
compound
＝ boron and its
compound + compound
manufactured used
handled 1.054t/year
t/year 0t/year
Designated
value of
specified
substance
＝ 1.054t/year ≧
(Class 1
designated
chemical
substance)
1t/year
Since the annual quantity of boron and its compound handled is

larger than the specified quantity (1 t/year), they are designated as
the substances requiring notification.
III - 44
manufactured goods.
Since no goods are manufactured in the facility, 0 is assumed as

the quantity released as manufactured goods.
Quantity of
boron and its
compound
released as
＝ 0kg/year
manufactured
goods
kg/year
Spent cutting oil containing boron and its compound is generated

in the facility. However, as the content is not known, calculate the
quantity using the content in the cutting oil used.
Quantity of Content of
boron and Quantity of
boron and its
its
compound
＝ Sp e n t c u t t i n g
oil × compound
in cutting oil A ÷ 100 × 1000kg/ｔ
20t/year
in waste
kg/year 4.3%
＝ 860kg/year

to the environment.
Maximum Annual Quantity of Quantity
potential quantity of boron and its of boron
release of
boron and its ＝ boron and its
compound × 1000kg/ｔ − compound
released as − and its
compound
compound to the handled manufactured in waste
kg/year 0kg/year
＝ 194kg/year
Since there is no leakage from this facility to land, 0 is assumed as

land emission.
Land
emission of
boron and its ＝ 0 kg/year
compound
kg/year
III - 45
Step 6 Judge to which medium, air or water, larger or smaller quantity
is released.
Since sodium tetraborate has high melting point (741 °C), air
emission is assumed to be almost none. Therefore, larger quantity
is released to water.
Since sodium tetraborate has high melting point (741 °C), air
emission is assumed to be almost none. Therefore, 0 is assumed as
air emission.
Air
emission of
boron and its ＝ 0 kg/year
compound
kg/year
Calculate the release from this facility to water using mass

balance.
Maximum Land
potential Air
Release of emission of emission
release of boron and
boron and its boron and its of boron
compound
to water
＝ compound to − its
compound − and its
compound
the 0kg/year
kg/year environment 0kg/year
194kg/year
＝ 194kg/year

transferred.
Boron and its compounds (unit; kg/year)

Calculation
(Releases)
A Air emission; 0 a. Air emission; 0.0
B Release to water; 194 b. Surface water discharge; 190
0.0
f . O ff - s i t e t r a n s f e r i n w a s t e ; 8 6 0
III - 46
1-4 Washing process
This is a process where dirt attached to products and parts are washed
away using water-based detergent (such as surface active agent) or non
water-based detergent (such as chlorinated solvent).
Dry cleaning process of clothes, etc. is included in this process.
following.
• Air emission of specified substance in washing detergent by
volatilization or release in effluent from washing equipment
• Transfer as spent solvent
If exhaust gas or effluent generated in the process is treated in exhaust gas

or effluent treatment facility by activated carbon adsorption method, etc.,
waste (such as spent carbon) may be generated.
[Example of specified substances]

Dichloromethane, trichloroethylene, tetrachloroethylene, poly (oxy-ethylene)
= nonyl phenyl ether, etc.
[Example of calculation (1)] When volatile washing detergent is used and

waste is generated

washing facility described by Table 1-4-1 and Fig. 1-4-1.
Table 1-4-1 Outline of washing facility
Description of D e g r e a s i n g a n d w a s h in g o f me t a l l i c p a r t s
washing (Refer to Fig. 1-4-1.)
G e n e r a t i o n o f e ff l u e n t a n d l e a k a g e t o l a n d : N o n e
facility
III - 47
(cont’d)
• Detergent A

purchased
if fiscal year
fiscal year
Content of
specified substance
listed in MSDS Substance No.
Name of specified Content
substance
2 11 Tr i c h l o r o e t h y l e n e 100%
③ Waste generated

generated substance
S p e n t d e t e rg e n t 1.7 t/year Not known Delivered to industrial
w a s t e m a n a g e me n t
Wa s t e 1.0 t/year We ig h t o f waste before contractor
adsorbing s o lv e n t : 2 k g
We ig h t o f waste after
adsorbing s o lv e n t : 2 . 5 k g
Air
emission
Handling (Tri c h l o ro
ethylene)
① ③
(Tri c h l o ro
ethylene)
Metal plate Manufactured
Detergent washing tank goods
A (washed
metal plate)
Metal
plate
② (Tri c h l o ro
ethylene)
Wa s t e
Wa s t e
cloth Sp e n t
detergent
Fig. 1-4-1 Outline of washing facility
III - 48
to calculate the release/transfer from the washing facility.

manufactured.
Annual
quantity
of specified
manufactured
t/year
Step 1-2 Calculate the annual quantity of detergent A used.

Annual Annual quantity detergent A of
quantity of of detergent A stored at detergent
detergent
A used
the fiscal + A stored at
the
t/year year beginning
year
0.5t
＝ 2.8t/year

quantity of Tr i c h l o r o
quantity of
trichloro ＝ detergent A
used
× ethylene
in detergent A
÷ 100
ethylene
used 100%
t/year 2.8t/year
＝ 2.8t/year

Annual Annual
Annual quantity of
trichloro
trichloro
ethylene
＝ trichloro
ethylene + ethylene
manufactured used
handled 2.8t/year
t/year 0t/year
Designated
value of
specified
substance
＝ 2.8t/year ≧
(Class 1
designated
chemical
substance)
1t/year
Since the annual quantity of trichloroethylene handled is larger

than the specified quantity (1 t/year), it is designated as requiring
notification.
III - 49
manufactured goods.
Since products containing specified substance are not

manufactured in the facility, 0 is assumed as the quantity released
as manufactured goods.
Quantity of
trichloro
ethylene
released as
＝ 0kg/year
manufactured
goods
kg/year
Spent detergent containing trichloroethylene and waste are

generated in the facility. Since the content of specified substance
in spent detergent is not known, calculate the quantity using the
content in detergent A.
trichloroeth Quantity of
Tr i c h l o r o
ylene in
spent
＝ spent
detergent × ethylene
in detergent A ÷ 100 × 1000kg/ｔ
1.7t/year
detergent
kg/year 100%
＝ 1700kg/year
Calculate the quantity of specified substance in waste per 1kg from

the weight of waste cloth before and after adsorbing the detergent.
Weight of Weight of
waste Weight of
Quantity of waste waste cloth
Quantity cloth
trichloro
ethylene in ＝ of waste
cloth ×(
cloth after
adsorbing − before
adsorbing
÷ after
adsorbing
waste cloth 1.0t/year ) the
detergent the the
detergent
kg/year detergent
2.5kg 2.5kg
2 0kg
Content of
Tr i c h l o r o e t h y l e
× ne
in detergent A ÷ 100 ×
100%
1000kg/t
＝ 200kg/year
III - 50
The quantity of trichloroethylene released is the sum of the
quantity in spent detergent and in waste cloth.
Quantity of
Quantity of trichloro Quantity of
trichloro
ethylene in ＝ ethylene in
spent + trichloro
ethylene in
waste detergent waste cloth
kg/year 1700kg/year 200kg/year
＝ 1900kg/year

to the environment.

potential quantity of trichloroethyl of
release of
trichloroethylene ＝ trichloro
ethylene × 1000kg/ｔ − ene released
as − trichloroeth
ylene
to the handled manufactured in waste
kg/year 0kg/year
＝ 900kg/year
Since there is no leakage to land in the facility, 0 is assumed as

land emission.
Land
emission of
trichloroethyl ＝ 0 kg/year
ene
kg/year
Step 6 Judge to which medium, air or water, the larger or smaller

Since the facility does not have contact with water, it is assumed
that larger quantity is released to air.
Since the facility does not have contact with water, 0 is assumed as
release to water.
Release of
trichloroethyl
ene ＝ 0 kg/year
to water
kg/year
III - 51
Calculate the air emission from the facility using mass balance.
Maximum Land
Air potential Release of
emission of trichloroeth
emission of release of trichloroeth
trichloroethyle trichloroethyl ylene
ne ＝ ene to the − ylene
0kg/year − to water
0kg/year
kg/year environment
900kg/year
＝ 900kg/year

transferred.
Trichloroethylene (unit; kg/year)

Calculation
(Releases)
0.0
f . O ff - s i t e t r a n s f e r i n w a s t e ; 1 9 0 0
III - 52
[Example of calculation (2)] When dry cleaning is performed
The following is an example of calculating the release/transfer from the dry

cleaning facility described by Table 1-4-2 and Fig. 1-4-2. (Refer also to
“Cleaning business” in the manual by business.)
Table 1-4-2 Outline of dry cleaning facility

Description of dry Dry cleaning of clothes (Refer to Fig. 1-4-2.)
cleaning Q u a n t i t y o f e ff l u e n t : 1 , 2 0 0 m 3 / y e a r
Leakage to land: None
We ig h t o f l a u n d r y p e r c l e a n i n g : 3 0 k g
N u mb e r o f t i me s o f c l e a n in g p e r y e a r : 6 0 0
E x h a u s t g a s t r e a t me n t C a r t r i d g e f i l t e r ( R e p l a c e me n t p e r y e a r : Tw i c e )
facility A c t i v a t e d c a r b o n a d s o r b in g e q u i p m e n t
( R e p l a c e m e n t p e r y e a r : O n c e , We ig h t o f r e p l a c e d
activated carbon: 50 kg)
E ff l u e n t t r e a t me n t None
facility
② Raw material and material containing specified substance handled
• Dry cleaning solvent A

purchased
of fiscal year
fiscal year
Content of
specified substance
listed in MSDS Name of specified
substance
200 Te t r a c h l o r o e t h y l e n e 100%
③ Waste generated

generated substance
Filter Not known Not known Delivered to industrial
Distillation sludge Not known Not known w a s t e m a n a g e me n t
contractor
Spent carbon Not known Not known
III - 53
Air
emission
Wa s t e
② ④
Filter D i s t i l l a t i o n Sp e n t Exhaust gas
sludge carbon treatment
( C a r t r i d g e f i l t e r,
activated carbon (Tri c h l o roe
adsorption) thylene)
Handling
① Dry cleaning machine

for clothes Clothes
(Tri c h l o roe (washed)
thylene)
Dry
cleaning
solvent A
(Tri c h l o roe
Dirty thylene)
laundry ③
Effluent
Fig. 1-4-2 Outline of dry cleaning facility
to calculate the release/transfer from the dry cleaning facility.
III - 54

assumed as annual quantity of specified substance manufactured.
Annual
quantity
of specified
manufactured
t/year
Step 1-2 Calculate the annual quantity of dry cleaning solvent A used.
Annual Annual quantity dry cleaning of dry
quantity of of dry cleaning solvent A cleaning
dry cleaning ＝ solvent A
purchased
− stored at
the end of + solvent A
stored at the
solvent A
used the fiscal beginning of
1.3t/year year the fiscal
t/year
0.24t year
0.44t
＝ 1.5t/year

quantity of tetrachloroethy
quantity of
tetrachloro ＝ dry cleaning
solvent A
× lene in
dry cleaning
÷ 100
ethylene
used solvent A
used 100%
t/year 1.5t/year
＝ 1.5t/year
Annual Annual
Annual quantity of
tetrachloroeth
tetrachloroet
hylene
＝ tetrachloro
ethylene + ylene
manufactured used
handled 1.5t/year
t/year 0t/year
Designated
value of
specified
substance
＝ 1.5t/year ≧
(Class 1
designated
chemical
substance)
1t/year
Since the annual quantity of tetrachloroethylene handled is larger

than the specified quantity (1t/year), it is designated as requiring
notification.
III - 55
manufactured goods.
Since products containing specified substance are not

manufactured in the facility, 0 is assumed as the quantity released
as manufactured goods.
Quantity of
tetrachloroeth
ylene
released as
＝ 0kg/year
manufactured
goods
kg/year
Calculate the quantity of tetrachloroethylene contained in filter,

distillation sludge and spent carbon using the following factors (→
pIII-252).
• Factor for the quantity contained in the filter per laundry load
(weight) (per replacement of filter): 2L/((kg/cleaning)•Cleaning)
• Factor for the quantity contained in distillation sludge per
annual laundry load (weight): 0.004 kg/kg
• Adsorption rate to activated carbon per weight of replaced
activated carbon (per replacement of activated carbon):
5%/replacement
Quantity of Laundry load Number of Content of

tetrachloro- Factor for quantity in Gravity of
per cleaning times of filter tetrachloroethylene
ethylene in
waste
＝ filter
× × replacement × in dry cleaning
solvent A
× tetrachloro-
ethylene
÷100
2 L/((kg/time)・time)
30 kg/time 2 times/year 1.62 kg/L
kg/year
100%
Factor for Content of

Laundry Number of
quantity in tetrachloroethylene
load per times of
＋ distillation
sludge × cleaning × cleaning ×
in dry cleaning
solvent A
÷100
0.004 kg/kg 600 times/year
30 kg/time
100%
Adsorption rate Weight of Number of

to activated replaced times of
＋ carbon × activated
carbon
× activated carbon
replacement ÷100
5%/time
50 kg 1 time/year
＝ 268.9kg/year
III - 56
to the environment.

potential quantity of tetrachloroeth of
release of
tetrachloroethyle ＝ tetrachloro
ethylene × 1000kg/ｔ − ylene
released as − tetrachloroth
ylene
ne to the handled manufactured in waste
environment 1.5t/year goods 268.9kg/year
kg/year 0kg/year
＝ 1231.1kg/year
Since there is no leakage to land, 0 is assumed as land emission.
Land
emission of
tetrachloroeth ＝ 0 kg/year
ylene
kg/year

is released.
Since tetrachloroethylene has high volatility, it is assumed that

larger quantity is released to air.
Step 7 Calculate the quantity of specified substance released to water.
The concentration of tetrachloroethylene in effluent is not

measured. However, since the emission standard designates that the
concentration must be 0.1mg/L (=0.1×10 − 3 kg/m 3 ) or lower,
calculate the release to water on the assumption that the
concentration is that value.
The emission
Release of
tetrachloro
ethylene to ＝
Annual effluent
quantity × standard
designates of
tetrachloroethyle
water 3
1200m /year ne
kg/year 0.1×10− kg/m
3 3
＝ 0.12kg/year
III - 57
Calculate the air emission using mass balance.
Maximum Land Release of

Air potential emission of
emission of tetrachloro
release of tetrachloro ethylene
tetrachloroeth
ylene ＝ tetrachloroeth
ylene to the
− ethylene
0kg/year − to water
0.12kg/year
kg/year environment
1231.1kg/year
＝ 1230kg/year

transferred.
Tetrachloroethylene (unit; kg/year)

Calculation
(Releases)
B Release to water; 0.12 b. Surface water discharge; 0.1
D Quantity in waste; 268.9 d . L a n d f i l l s i n t h e b u s i n e s s e s ta b l i s h m e n t ;
0.0
III - 58
1-5 Painting process
This is a process where parts, surface of products, etc. are coated by

spraying or electro-coating.
following.
• Volatilization of specified substance (solvent component) in paint to air
• Mixing of solvent component or pigment component from wet booth to
effluent
• Transfer of solvent component or pigment component as spent paint, etc.
If exhaust gas or effluent generated from the process is treated in exhaust

gas or effluent treatment facility by activated carbon adsorption method,
waste (such as spent carbon) may be generated.
Solvent component: Toluene, xylene, etc.
Component of pigment: Hexavalent chromium compounds, lead and its
compounds, etc.
[Example of calculation]
coating facility described by Table 1-5 and Fig. 1-5.
Table 1-5 Outline of coating facility

Description of A ir l e s s s p r a y c o a t i n g o f me t a l p l a t e ( R e f e r t o F i g . 1 - 5 . )
coating G e n e r a t i o n o f e ff l u e n t a n d l e a k a g e t o l a n d : N o n e
Exhaust gas None
② Raw materials and materials containing specified substance handled
• Paint A
purchased
St o c k a t b e g in n i n g o f 1.22 t
fiscal year
St o c k a t e n d o f f i s c a l 0.78 t
year
Content of specified
s u b s t a n c e l i s t e d in Substance No.
Name of specified
Content
MSDS substance
227 To l u e n e 50%
3 11 Manganese and its 20%
compounds
III - 59
(cont’d)
③ Wa s t e g e n e r a t e d

generated substance
Spent paint 200 kg/year Not known Delivered to industrial
w a s t e m a n a g e me n t
contractor
Air
Handling emission
( To l u e n e )
①
( To l u e n e , ④
manganese
and its Coating booth Delivery of
compounds) manufactured
Paint A goods (coated
metal plates)
②
(Manganese
Metal and its
plate compounds)
( To l u e n e ,
manganese
③ and its
compounds)
Wa s t e
Sp e n t p a i n t
Fig. 1-5 Outline of coating facility
to calculate the release/transfer from the coating facility. (Refer also to the
example of calculating the release from the wet booth in coating facility in
Part I.)
III - 60
Since no specified substance is manufactured in the facility, 0 is

manufactured.
Annual
quantity
of specified
manufactured
t/year
Step 1-2 Calculate the annual quantity of paint A used.
Annual Annual quantity paint A of paint A
quantity of of paint A stored at stored at
paint A
used
the fiscal + the
beginning
t/year year of the fiscal
14.7t/year 0.78t year
1.22t
＝ 15.14t/year

Annual Annual
quantity of
toluene ＝ paint A × toluene in paint
A
÷ 100
used used
t/year
15.14t/year 50%
＝ 7.57t/year

quantity of quantity of manganese and
manganese
and its
＝ paint A
used
× its compounds
in paint A
÷ 100
compounds
used 15.14t/year 20%
t/year
＝ 3.028t/year
III - 61
Annual Annual
Annual quantity of
toluene
toluene
handled
＝ toluene
manufactured + used
0t/year 7.57t/year
t/year
Designated
value of
specified
substance
＝ 7.57t/year ≧
(Class 1
designated
chemical
substance)
1t/year

quantity of quantity of quantity of
manganese manganese
manganese
and its ＝ and its
compounds + and its
compounds
compounds
Designated
value of
specified
substance
＝ 3.028t/year ≧
(Class 1
designated
chemical
substance)
1t/year
Since the annual quantity of toluene and manganese and its compounds
handled is larger than the specified quantity (1t/year), they are designated as
requiring notification.
Procedure of calculating solvent component (toluene) and pigment

component (manganese and its compounds) is described separately in the
following sections.

manufactured goods.
○ Solvent component
Since specified substance is not contained in manufactured

goods (coated metal plates), 0 is assumed as the quantity
released as manufactured goods.
Quantity of
toluene
released as
manufactured
＝ 0kg/year
goods
kg/year
III - 62
○ Pigment component
Calculate the quantity using the following adherence
efficiency.
• Adherence efficiency of airless spray to metal plate: 60 to

70% (Use 60% to be on the safe side.)
Annual quantity
Quantity of of manganese Adherence
manganese and its and its efficiency of
compounds released as
manufactured goods
＝ compounds
handled
×1,000kg/t × airless spray to
metal plate ÷ 100
kg/year 3,028 t/year 60%
＝ 1,817kg/year
Since the content of specified substance in spent paint is not
known, calculate the quantity using the content in paint A.
Quantity of
toluene in ＝ spent paint × toluene
in paint A
÷ 100
waste
kg/year 200kg/year
50%
＝ 100kg/year
Since the release to the environment is assumed to be almost
none, calculate the quantity using mass balance.
(The quantity in waste includes the quantity that attached to the
floor during coating process and not delivered as manufactured
goods as well as the quantity in spent paint.
Annual Quantity of
Quantity of quantity of manganese
manganese and manganese and its
its compounds ＝ and its
compounds
× 1000kg/ｔ − compounds
released as
in waste
kg/year handled manufactured
3.028t/year goods
1817kg/year
＝ 1 2 11 k g / y e a r
III - 63
to the environment.
Maximum Quantity of
potential Annual toluene Quantity
release of
toluene to the ＝ quantity of
toluene × 1000kg/ｔ − released as
manufactured − of toluene
in waste
environment handled goods 100kg/year
kg/year 7.57t/year 0kg/year
＝ 7470kg/year
Since the release to the environment is almost none, 0 is
assumed as the maximum potential release to the environment.
(The subsequent procedure will be omitted.)
Maximum potential
release of
manganese
and its compounds
＝ 0 kg/year
to the environment
kg/year
Since there is no leakage to land in the facility, 0 is assumed as

land emission.
Land
emission of
kg/year

is released.
Since the facility does not have contact with water, 0 is
assumed as release to water.
Step7 Calculate the release of specified substance to water.
Since the facility does not have contact with water, 0 is
assumed as the quantity released to water.
Release of
toluene
to water ＝ 0 kg/year
kg/year
III - 64
Calculate the air emission using mass balance.
Maximum
potential Land Release of
Air toluene
emission of release of emission of
toluene ＝ toluene to
the
− toluene
0kg/year
− to water
0kg/year
kg/year
environment
7470kg/year
＝ 7470kg/year

transferred.

Calculation
(Releases)
0.0
Manganese and its compounds (unit; kg/year)

Calculation
(Releases)
A Air emission; 0 a. Air emission; 0.0
D Q u a n t i t y i n w a s t e ; 1 2 11 d . L a n d f i l l s i n t h e b u s i n e s s e s ta b l i s h m e n t ;
0.0
f . O ff - s i t e t r a n s f e r i n w a s t e ; 1 2 0 0
III - 65

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1.

Examples of calculation in typical processes

This section gives examples of calculation in the following 11 processes,

1-1 Storage process (including acceptance and delivery facilities)

The table on the next page gives examples of correspondence between

e Manufacture of lumber and wood products, except

f Manufacture of furniture and fixtures ○ ○ ○ ○ ○

l Manufacture of rubber products ○ ○ ○ ○ ○ ○ ○ ○

t Manufacture of transportation equipment ○ ○ ○ ○ ○ ○ ○

If exhaust gas is treated by activated carbon adsorption treatment in

The following methods can be used to calculate the released quantity.

[Examples of subject substances]

Subject substance contained in raw materials, materials, and products stored

[Example of calculation (1)] Engineering calculations

① Formula to calculate breathing loss

Molecular Molecular Molecular

Table 1-1-1 Outline of the storage tank (fixed-roof tank)

Handling status of specified substance

① Outline of the work of handling specified substance

② Raw material/material containing a specified substance handled

Annual quantity 2,000 m3/year (Gravity: 0.87)

③ Molecular mass and vapor pressure of specified substance contained in

Substance Name of Molecular Va p o r p re s s u re

Fig. 1-1-1 Outline of storage tank (fixed-roof tank)

To make engineering calculations of the quantity released/transferred from

Step 1: Calculate the annual quantity of specified substance

Step 1 Calculate the annual quantity of specified substance handled.

Step 1-1 Calculate the annual quantity of specified substance

Since specified substance is not manufactured in the storage

Step 1-2 Calculate the annual quantity of Solvent A used.

Step 1-4 Calculate the annual quantity of specified substance handled.

Step 2 Calculate the release/transfer to medium other than air.

Release of Land Quantity of

Step 3-1 Calculate the partial pressure of toluene in mixed vapor.

Since the stored solvent is mixed liquid of three substances,

Step 3-2 Calculate the breathing loss of toluene.

Make calculations using the formula in pIII-5.

Step 3-3 Calculate the acceptance loss of toluene.

Make calculations using the formula in pIII-7.

kg/year to the tank Internal

Sum up breathing loss and acceptance loss to obtain the air

Air Breathing Acceptanc

Step 4 Sum up the quantities of specified substance released or

Toluene (unit; kg/year)

The following is an example of calculating the release/transfer from the

Table 1-1-2 Outline of gas station

Handling status of specified substance

① Outline of the work of handling specified substance

② Raw material or material containing specified substance handled

Fig. 1-1-2 Outline of gas station (underground tank)

To calculate the quantity released or transferred from the storage facility

Step 1: Calculate the annual quantity of specified substance

Step 1 Calculate the annual quantity of specified substance handled

Step 1-1 Calculate the annual quantity of specified substance

Since specified substance is not manufactured in the storage

Step 1-2 Calculate the annual quantity of regular gasoline used.

Step 1-4 Calculate the annual quantity of specified substance handled.

Annual Annual Annual

Step 2 Calculate the release/transfer to medium other than air.

Release of Land Quantity of

Step 3-1 Calculate the acceptance loss of benzene.

Step 3-2 Calculate the refueling loss of benzene.

Step 3-3 Calculate the air emission of benzene.