Unit- I

Molecular structure and Theories of bonding

Short questions ( 2 or 3 Marks)

1. What are atomic and molecular orbitals?

2. What is linear combination of Atomic Oorbitals?

3. Explain molecular orbital energy level diagram of N2 ?

4. Write salient features of Crystal Field Theory?

5. Explain crystal field splitting of d-orbitals in tetrahedral geometry?

Long questions ( 5 Marks)

1. Explain molecular orbital energy level diagram of O2 ?

2. Explain molecular orbital energy level diagram of F2 ?

3. Explain crystal field splitting of d-orbitals in octahedral geometry with example?

4. . Explain crystal field splitting of d-orbitals in squar planar geometry with example?

5. Explain band structure of solids?

6. Explain effect of doping on conductance?

 Unit-II

WATER AND ITS TREATMENT

Short questions (2 or 3 Marks)

1. Write the causes of hardness water?

2. Explain types of hardness of water?

3. Write the units of hardness water?

4. Write the specifications of potables water?

5. what is calgon conditioning?

6. what is phosphate conditioning?

7. what is colloidal conditioning?

Long questions Long questions ( 5 Marks)

1. Explain estimation of temporary & permanent hardness of water by complexometric

(EDTA) method?

2. What are steps involved in treatment of potable water?

3. Explain disinfection of water by chlorination and ozonisation?

4. Explain external treatment of water by ion exchange process?

5. Explain desalination of water by reverse osmosis process?

 Unit –III

Electrochemistry and corrosion

Short questions (2 or 3 Marks)

1. What is calomel electrode?

2. Explain determination of pH using glass electrode?

3. Derive Nernst equation and write its applications?

4. what are the causes of corrosion?

5. Write the reactions involved in Lithium ion battery?

6. What is chemical corrosion?

Long questions Long questions ( 5 Marks)

1. What is quinhydrone electrode? Explain determination of pH of a solution by using

quinhydrone?

2. What is the difference between primary and secondary cell? Explain the reactions involved in
lead acid storage battery?

3. Explain theory and mechanism of electrochemical corrosion?

4. Explain types of corrosion?

5. Write a note on cathodic protection?

6. Give the construction and electrode reactions of saturated calomel electrode?

7. Explain electroless plating of Nickel?

 Unit IV

Stereochemistry, Reaction Mechanism and Synthesis of drugs

Short questions (2 or 3 Marks)

1. What are the structural isomers?

2. What is enantiomer?

3. What is diasteriomer?

4. What is optical activity?

5. what is saytzeff rule?

Long questions Long questions ( 5 Marks)

1. Explain π (pi) molecular orbitals of butadiene and benzene?

2. Write a note on Nucleophilic substitution reactions?

3.Explain addition of HBr to propene by Markovnikoff and anti Markovnikoff’s rule?

4. Explain conformation analysis of n-butane?

5.Explain the Grignard additions on carbonyl compounds?

6. Explain structure, synthesis and pharmaceutical applications of Paracetamol and Asprin?

 Unit-V

Spectroscopic techniques and applications

(2 or 3 Marks)

Short questions (2 or 3 Marks)

1. Write the selection rules electronic spectroscopy?

2. Write the selection rules and applications of vibrational and rotational spectroscopy?

3. How CO2 is IR active?

4. Explain Magnetic resonance imaging?

Long questions ( 5 Marks)

1. Explain the principle involved in vibrational and rotational spectroscopy?

2. Write the principle involved in NMR spectroscopy?

3. What is chemical shift? Explain factors affecting on chemical shift?

4. Write the applications of electronic spectroscopy?