‘metal and other metals having ‘because of their strong fof the ability of water to be unit of electricity. Volume of O,, H, and Cl, are 5.6L, 11.2 L and bridge can be replaced by a porous partition which + migration of fons without intermixing of solution wy can not be used as a salt bridge for the ce iSO qi)! |AGNO yaa |Agts) because ‘AgCI is precipitated 1s, AgNO,+KCI—» AgCl + KNO, We) concentration cell net redox change is zero and the ee energy during transfer of substance from one {s responsible for production of electrical gercury c#ll Ge a constant voltage throughout its lie we the eletralyte KOH isnot consumed inthe reaction. petriation a BH OL 8st aca In the elecrohnis of aqueous solution of CuSO, sng copper electrodes, the process that is (a) SO} + SO, + 2e (b) Cu+Cu' te (9 20H” -+H,0+1/20, + 2e (4) Cu Cu" +2e Strong electrolytes are those which [MNR 1983; AMU 1983, 84] {a) Dissolve readily in water (b) Conduct electricity {c) Dissociate into ions at high (4) Completely dissociate into ions a all diutions Which of the following reaction cannot be a basis for electrochemical cell [AMU (Engg.) 2009) ditution (a) Hy +0;—H,0 (b) AgNO. »2riNO), + Ag (9) AgNO AgCl 4 + NaNO, (a) KMnO, + H,SO, —+K7S0, Fe,(SO,), + MnSO, + H;0 Which pait stinguished by the products (Kerala PMT 2011} fa) 1M CuSO, solution, IM CuCl, sokuti (b) 1M KCI so 1M KI (c) 1M AgNO, solution, IM Cul on (d) 1M KCI solution, 1M Nat (e) 1M CuBr, solution, 1M CuSO, solution The electrolyte used in Lechlanche cells (Kerala PMT 2012] (a) Paste of KOH and ZnO (b) 38% solution of H,SO, (@) Moist paste of NH,CI and ZnCl (d)_ Moist sodium hydroxide (e). Moist potassium hydroxide Electrolyte can conduct electricity because | ta) Thee molecules contain unpaired eects, which ate (0) Their molecules contain loosely held electrons which get {ree under the influence of voltage (6) The molecules break up into ions when 2 voltage (@) The molecules are broken up into ions when the electrolyte is fused or is dissolved in the solvent15. 16. 17. the fc could not be obtained on ‘of aqueous solution ofits salts (IIT JEE 1990] (b) Mg (d) Cr ‘aqueous solution will conduct an (MP PMT 1987) (b) HCI (d) Pure water On the electrolysis of aqueous solution of sodium sulphate, ‘on cathode we get IMP PMT 1992, 2002) (2) Na (b) Hy (9 SO, (4) so, ._ Bectrolysis involves oxidation and reduction respectively at (AMU 1983; MH CET 2001) {a) Anode and cathode (b) Cathode and anode {c) Atboth the electrodes (d) None of the above Which of the following compounds will not undergo Secomposiion on passing lectrcity through aqueous solution IAMU 1982, 83; MP PET 2001) (2) Sugar (b) Sodium Chloride (6) Sodium Bromide (4) Sodium Acetate ‘During the electrolysis of an electrolyte, the number of ions ‘Produced, is directly proportional to the (2) Time consumed {b) Electro chemical equivalent of electrolysis (c). Quantity of electricity passed (4) Mass of electrons When the sample of copper with zinc impurity is to be Purified by electrolysis, the appropriate electrodes are IAFMC 2002} (AIEEE 2002) Cathode ‘Anode (a) Pure zine Pure copper {b)_ Impure sample Pure copper (6). impure zine Impure sample (4) Pure copper Impure sample In the electrolytic cel, flow of electrons is from INT Screening 2003) (2) Cathode to anode in solution (b) Cathode to anode through external supply (c) Cathode to anode through internal supply (4) Anode to cathode through intemal supply ‘An electric current is passed through an aqueous solution of the following. Which one shall decompose (a) Urea (0) Glucose () AgNO, (€) Ethyl alcohol Jn the electrolysis of which solution, discharged in preference to CI ions (2) Dilute NaCi (0) Very dilute NaCl (c) Fused Nat (@) Solid Nact ‘A solution of sodium sul Iphate in water is electrolysed using inert electrodes. The products at the cathode and anode are OH" ions are {CPMT 2010) respectively {IT JEE 1987.96) (a) Hy, O, (0) 02, H, (©) Q,,.Na (a) 0, So, 19, 20. a. 22. 23. 24. 25. 26. 27. (@) ‘The addition Of apolar solvent toa solid electors in INP Pa 200 (a) Polarization (b) Association (c)_ Ionization (2). Non-lberation of heat During the electrolysis of fused NaCl, which reaction atanode _ {AFMC 1992; MP PMT 2002; MH CET ani (2) Chloride ions are oxidized (b) Chloride ions are reduced (0) Sodium ions are oxidised (d)_ Sodium ions are reduced The products formed when an aqueous solution of Na electrolysed in a cell having inert electrodes ar re(AIIMS 2006) (a) Na and Br, (b) Nando, (4) Hyand oO, Electrolysis of aqueous HCI solution produces (c) Hy, Br, and NaOH {CPMT 1987) (a) Hy gas at the anode (b) Hy gas at the cathode (c)_ Ch, gas at the cathode (d) Cl, and O, gases both at the anode During electrolysis of NaCI solution, part of the reaction is Na* +e" ~+ Na, This is termed as IMP PET 2011) (a) Oxidation (b) Reduction (4) Cathode reaction, electrolysis will not give (DCE 2006) (b) Cl, (4) 0, ‘The passage of curent liberates Hy at cathode and Clp at anode, The solution is (c) Deposition Brine solution on (a) NaOH (cH, {EAMCET 1987) (2) Copper chloride in water (b) NaCl in water () H,S0, (4) Water Pure water does not conduct electricity because it (Manipal MEE 1995) (a) Has a low boiling point {b) Is almost totally unionized (c)_ Is neutral {d) Is readily decomposed Which of the following metal can be obtained by the electrolysis of the aqueous solution of their salts (5 & K CET 20061 fa-cu (Mg (b) Na (a) K29. 31. 32. 37. Th eleciciyra of aqueous copper sulphale, the go at snode and cathode is (AFMC 1995] (@) 0, and H, (0) SO, and Hy (0) H, and 0, (a) SO, and 0, Use of electrolysis is [AFMC 1995] (2) Electroplating (6) Bectrorefining (c) Both (a) and (b) {d) None of these Sodium is made by the electrolysis of a molten mixture of about 40% NaC! and 60% CaCl, because (CBSE PMT 1995) (2) CaCl, helps in conduction of electricity (b) This mixture has a lower melting point than NaCI (©) Ca** can displace Na from NaCI (4) Ca* can reduce NaCI to Na Electrolysis is a process in which the cations and anions of the electrolyte are IMP PET 1995] (a) Hydrated (b) Hydrolysed (c) Charged (a) Discharged Degree of ionisation of a solution depends upon [BHU 1998) (a) Temperature (b) Nature of the electrolyte (c) Nature of the solvent (d) None of these Which of the following is non-electrolyte IKCET (Med) 1999] (a) Noct (o) CoCl, (2. CyH2Oy (4) CH;COOH Which of the following does not conduct electricity IKCET 2006] (2) Fused NaCI (b) Solid NaCI (c). Brine solution (4) Copper During electrolysis, the species discharged at cathode are IAFMC 2000} (a) tons (b) Cation (c) Anion (d) All of these Blectrolysis of molten anhydrous calcium chloride produces IAlIMs 2000) (2) Calcium (b) Phosphorus {c) Sulphur (4) Sodium Which of the following properties of pure metal makes it more useful than the corresponding alloy (RPET 2000) (2) It is harder than corresponding alloy (©) Ithas high density (c) ttean be extracted easily (d) It conducts heat and electricity easily Which of the following liberate hydrogen on reaction with dilute H,S0, [Roorkee 2000] o) Fe (o) Cu ( Al (4) Hg 41. 42. 43. ‘Which one of the following material conducts electricity ‘(Kerala PMT 2003) (a) Diamond yen ae (b) Crystal sodium chloride ol aioe (¢) Bariurn sulphate iw {d) Fused potassium chloride a ow (e) Molten sulphur Which of the following metals will give Hy on reaction with NoOH IRPET 2003] (a) Mg (0) Ba () Ca (d) Sr Which of the following is nota non electrolyte (J & K CET 2005) (a) Acetic acid (0) Glucose (6) Ethanol (@) Urea In the electrolytic refining of zinc, (KCET 2010) (a) Graphite is at the anode (b) The impure metal is at the cathode (c) The metal ion gets reduced at the anode (d) Acidified zinc sulphate is the electrolyte In a galvanic cal, the electrons flow from (a) Anode to cathode through the solution (b) Cathode to anode through the solution (c) Anode to cathode through the external circuit (d) Cathode to anode through the external circuit Which ofthe following will give Hy, at-cathode and Ong) at anode on electrolysis using platinum electrodes [KCET 2004} [GUJCET 2014) (a) Molten NaCl (bo) Concentrated ag. solution of NaCl (c) Dilute aq. solution. of NaCl {d) Solid NaCI Faraday's law of electrolysis. ‘Amount of electricity that can deposit 108 gm of silver from AgNO; solution is IAFMC 1993; MP PMT 2004] (a) Lampere (b) Leoulomb (c) 1 fereday (d) None of the above When 9.65 coulombs of electricity is passed through 2 solution of siver nitrate (atomic weight of Ag = 10787 taking as 108) the amount of siver deposited is IEAMCET 1992; KCET 2000) (2) 108mg (b) 54mg (¢) 162mg (A) 212mg ‘Three faradays electricity was passed through an aqueous solution of iron (ll) bromide. The weight 0 ron metal (at. wt. = 56) deposited at the cathode (in gm) is (EAMCET 1991) (a) 56 (o) 84 (9 12 (a) 168 A silver cup is plated with silver by passing 965 coulombs of electricity, the amount of silver deposited is [EAMCET 1990; MPF 1994, 97) (a) 9.899 (b) 10787 g (c) 1.0787g (@) 1,002.g | .6. An apparatus used for the measurement of quantity of electricity is known as a (BHU 1979] 46, (a) Calorimeter (b) Cathetometer (ce) Coulometer (d) Colorimeter 7. On passing C ampere of current for time t sec through 1 litre ‘of 2 (M) CuSO, solution (atomic weight of Cu = 63.5), the (9 193 (@) 30.7 amount of m of Cu (in g) deposited on cathode will be 17. The desired amount of charge for obtaining one (WB JEE 2012) from Al** o (a) 3x96500 C (b) 96500 C 11.25 x 96500) 96500 96500 75x Cxt (c) 3 Cc (d) erm ' aon 18. On passing one faraday of electricity through the 8. A certain current liberated 0.504 gm of hydrogen in 2 hours. cells containing Ag*, Nitand Cr*ions How many grams of copper can be liberated by the same current flowing for the same time in a copper sulphate deposited Ag(At. wt. = 108), Ni(At.wt, = 59) solution [CPMT 1989; AIIMS 1998; J & K CET 2010] Cr(At-wt. = 52) is (a) 12.7 gm (b) 15.9 4m (c) 31.8.9m (a) 63.5 gm fe pl @ 9. What weight of copper will be deposited by passing 2 Seer ACEH through a cup salt (Arnie weight a ia gm ey gm uA gm of Cu = 63.5) IVITEEE 2008; JEE (Main) 2015] (B)" 108 gr .0 gm .0 gm (a) 2.0.gm (b) 3.175 gm (c) 108.0gm 108.0gm 108.0 gm (6) 68.5 gm (a) 127.0 gm (a) 089m -117.5gm 166.0 gm 10. If the current is passed into the solution of an electrolyte 19. One Faraday of electricity when passed through (b) 1 gmatom of Cu. (d)_1 gm equivalent: of copper sulphate deposits (a) 1 mole of Cu (c)_ 1 molecule of Cu [AIIMS 1979} {a) Anions move towards anode, cations towards cathode (b) Anions and cations both move towards anode (c) Anions move towards cathode, cations towards anode 20. A curent Is passed trouot iuglosts ‘connected in ser PEN treateasent of iors tekecs place frst cell contains X(NOs)ijaq) and the seond eal 11. Electrolysis of water with 1 Faraday electricity gives Y(NO3)2(0q)- The relative atomic masses of X an i reeeaaee 2012) the ratio 1:2. What is the ratio of liberated mass) (2) 1 mole of oxygen of Y (b) 1 gram equivalent of oxygen (@) 3:2 () 1:2 ieee () 1:3 @ 3: (a) Latom of oxygen noe 12. On passing 0.1 Faraday of electricity through aluminium 2]. chloride, the amount of aluminium metal deposited on ‘The platinum electrodes wens, aaa cupric sulphate and electric current passed cathode is (Al= 27) (MP PMT 1991] solution. After some time it was found that (a) 09.gm (b) 039m sulphate disappeared with evolution of gas! () 0.27 am (4) 2.7 gm The colourless solution contains i 13. Which of the following represents the first law of Faraday = (a) Platinum sulphate (b) Copper! s IMP PMT 1991) (c) Copper sulphate (d) Sulp (a) E=me () E=hv 22. On passing C ampere of electricity as ()_ m=ect (¢) PV=nRT solution for t second, m gram metal ‘5 amperes is passed through a solution of zinc sulphate for ‘The equivalent weight E of the a 40 minutes. Find the amount of zinc deposiaa at tne Baw Cx cathode [CBSE PMT 1996} 2) B= 36500 (0) 46.65 gm (b) 4.065 gm 96500xm 2) 04065 SH (a) 65.04 gm (eh E sierra24. 26. 27. 29. 31. How many Faradays are required to generate one gram ‘atom of magnesium from MgClp [MADT Bihar 1982; MP PMT 2007] fa) 1 (b) 2 3 (d) 4 To deposit 0.6354 gm of copper by electrolysis of aqueous cupric sulphate solution, the amount of electricity required (in coulombs) is (MP PMT 1989) (a) 9650 (b) 4825 () 3860 (d) 1930, In electrolysis of a fused salt, the weight of the deposit on an electrode will not depend on. ICPMT 1973) (a) Temperature of the bath (b) Current intensity (©). Electrochemical equivalent of ions (4) Time for electrolysis Faraday's laws of electrolysis will fil when (a) Temperature is increased (b)_ Inert electrodes are used (c)_ A mixture of electrolytes is used (4) In none of these cases According to the first law of Faraday, the weight of a substance discharge at the electrode is () W=2Q (b) W=eF z ( W=5k (a) Wz ‘When 0.04 faraday of electricity is passed through a solution of CaSO, then the weight of Ca®* metal deposited at the cathode is [BHU 1996] (2) 02gm (b) 0.4m (9) 06gm (4) 084m A current 2.0 A is passed for 5 hours through a molten metal salt deposits 22 g of metal (At. wt. =177). The oxidation state of the metal in the metal salt is IKCET 1996] () +1 (b) +2 9 +3 (@ +4 How many atoms of calcium will be deposited from a solution of CaCl, by a current of 25 milliamperes flowing {for 60 seconds [BHU 1999, 2004) (a) 468x10" (b) 4.6810 () 468x107 (d) 4.6810? ‘On passing 0.5 faraday of electricity through NaCI, the ‘amount of Cl deposited on cathode is (BHU 1997; RPET 1999) {a) 355 9m (b) 17.75 gm aie (a) 142 gm ‘What is the amount of chlorine evolved when 2 amperes of ‘curent is passed for 30 minutes in an aqueous solution of aay [BHU 1998; AIMS 1999} (b) 132g (a) 999 (2) 66g () 33g 33. 34. 35. 36. 37. 38. 39, 40. 41. (On passing a current through KCI solution, 19.5g of potassium is deposited. If the same quantity of electricity is passed through a solution of aluminium chloride, the amount of aluminium deposited is IEAMCET 1997] (a) 459 (o) 90g {c) 135g (d) 27g {e), None is correct Electrolysis rules of Faraday’s states that mass deposited on electrode is proportional to ICBSE PMT 2000] (a) mel? (b) m=Q () m=@ (4) None of these ‘Accurrent being passed for two hour through a solution of an acid liberating 11.2 litre of oxygen at NTP at anode. What will be the amount of copper deposited at the cathode by the same current when passed through a solution of copper sulphate for the same time {BVP 2003), (a) 16g (b) 63g (9) 315g (@ 8g In a metal oxide, there is 20% oxygen by weight. Its equivalent weight is (Pb. PMT 2000) (a) 40 (b) 64 (c) 72 (a) 32 On the basis of the information available from the reaction Saivo, = 2 Al,O;,4G =-827kimol! of». the minimum emf required to carry out an electrolysis of Al,Os is (F = 96500C mol") [CBSE PMT 2003) (a) 856V (b) 214V () 4.28V (a) 642V Then during electrolysis of a solution of AgNO, 9650 coulombs of charge pass through the electroplating bath, the ‘mass of silver deposited in the cathode will be [AIEEE 2003) (a) 1.089 (b) 10.89 (c) 2169 (d) 108g Total charge on 1 mole of a monovalent metal ion is equal to (DPMT 2001) (a) 9.65x10* Coulomb — (b) 6.2810" Coulomb: (©) 16x10" Coulomb (4) None of these When an electric current is passed through acidulated water 112 ml of hydrogen gas at N-T.P. collect at the cathode in 965 seconds. The current passed, in amperes is [MNR 1991; UPSEAT 2001] (a) 10 (b) 05 x (©) 01 (a) 20 How much chlorine wil be liberated on passing jompere ‘current for 30 minutes through NaCl solution. 4 nix (a) 0.66 mole ee a 0,66 (b) 0.33mole (@) 0.66 am (4) 033gm43. 45. 47. 49. 51. "The number of electrons involved in redox reactions when @ Faraday of electricity is passed through an electrolyte in solution is (Pb. PMT 2002), (a) 6x10" (b) 6x10 (c) 96500 (d) 8x10” Coulomb is equal to [Odisha JEE 2002} (a) Ampere x second (b) Ampere « minute (c) Watt x second (4) Volt x second Calculate the volume of H, gas at NTP obtained by passing 4 amperes through acidified H,O for 30 minutes is (DCE 2005) a) 0.0836 L (b) 0.0432 L (9) 0.1672. (4) 0.836 L Faraday/s laws of electrolysis are related to the {IIT JEE 1983] {a) Atomic number of cation (b) Atomic number of anion {c) Equivalent weight of the electrolyte (a) Speed of the cation The electric charge for electrode decomposition of one gram equivalent of a substance is [IIT JEE 1984; KCET 1992] (a) One ampere per second (b) 96500 coulombs per second (c) One ampere for one hour (d) Charge on one mole of electrons The number of electrons passing per second through a ‘cross-section of copper wire carrying 10°° amperes of current per second is found to be [EAMCET 1985] (a) 16x10" (b) 6x10* () 6x10" (a) 6x10" The electrolytic cells, one containing acidified ferrous chloride and another acidified ferric chloride are connected in series. The ratio of iron deposited at cathodes in the two cells when electricity is passed through the cells will be [CPMT 1989} (a) 3:1 (b) 2:1 Cate (a) 3:2 ‘When 96500 coulomb of electricity is passed through a copper sulphate solution, the amount of copper deposited will be [MP PMT 1995, 96] (a) 0.25 mol (b) 0.50 mot (c) 1.00 mol (d) 2.00 mol During electrolysis of fused aluminium chloride 0.9gm of aluminium was deposited on the cathode. The volume of ‘chlorine liberated at the anode will be (a) 2.24 litres (b) 11.2 litres (Q) 1.12 litres (a) 56 litres Faraday has the dimensions of [MP PET 1995} (a) Coulombs {b) Coulomb equivalent {) Coulomb per equivalent (d) Coulomb per degree Kelvin mae 54. 55. 56. a 58. (0) 9.65x108C (c) 9.65x10°C (4) 9.65x10°C {Al,Oyis reduced by electrolysis at low potential and high currents. f 4,0%10* amperes of current is passed throw ‘molten Al,0, for 6 hours, what mass of aluminium is produced (Assume 100% current efficiency, At. mass of Al = 27g mol) [CBSE PMT 2009) (2) 9.0x10°g (b) 8.1x10"g (9) 24x10° ¢ (d) 13x10" g ‘A current of strength 2.5 amp was passed through CuSO, solution for 6 minutes 26 seconds. The amount of copper deposited is (Atomic weight of Cu = 63.5) (J faraday = 96500 coulombs) (EAMCET 1989; MP PET 1994; Kerala PMT 2012) (a) 0.31759 (b) 3.175g (c) 0.635 (4) 635g A certain quantity of electricity is passed through an aqueous solution of AgNO, and cupric salt soliton connected in series. The amount of Ag deposited is 1.08 gm, the amount of copper deposited is (atomic weight of Cu = 63.5; Ag = 108) (EAMCET 1986] (a) 0.6454 g (b) 6.354g () 0.3177 (@) 3.1779 The number of electrons required to deposit 1gm_atom of aluminium (at. wt. = 27) from a solution of aluminium chloride will be (where N is Avogadro's number) {Als 1992] (a) 1N (b) 2N (9) 3N (a) 4N Three faradays of electricity are passed through molten Alz0,, aqueous solution of CuSO, and molten Nol taken in different electrolytic cells. The amount of Al,Cu and Na deposited at the cathodes will be in the ratio of [BHU 1990; Kerala PET 20101 (a) 1 mole: 2 mole; 3 mole (b) 3 mole : 2 mole : Imole (c) 1 mole: 1.5 mole : 3 mole (d) 1.5 mole ; 2 mole : 3 mole {An electrolytic cell contains a solution of Ag2SOs platinum electrodes. A current is passed until 1.6 9 has been liberated at anode. The amount of at cathode would be (a) 107.88.gm (c) 08am eae]61. 62. 63. 64. 65. 67. 70. The amount of copper deposited by one Faraday current will be maximum in an acidic solution of one litre of [Kerala PMT 2006) (@) IMCuCl, (b) 2MCuINO,), (0) 5MCusO, (@) 5MCu\PO,), (e) 10M CuF, The number of Faradays needed to reduce 4 gram equivalents of Cu°* to Cu metal willbe {BHU 1981] (a) 1 (b) 2 (c) V2 {d) 4 When electricity is passed through the solution of AICI,, 13.5 gm of Al are deposited. The number of Faraday must be IMP PET 1992; MP PMT 1994] (a) 0.50 (b) 1.00 () 150 (a) 2.00 The value of one Faraday is [AMU 1983; AFMC 1989; MP PET 2001; MP PMT 2009} (a) 95500 C mol"? (b) 96550 C mol (c) 96500 C mol"! (4) 98500 C mol The quantity of electricity needed to liberate 0.5 gram equivalent of an element is [CPMT 1988; MP PMT 1997] (a) 48250 Faradays (b) 48250 Coulombs (c)_ 193000 Faradays (a) 193000 Coulombs The number of coulombs required for the deposition of 107.870 g of silver is [MP PET/PMT 1998] (a) 96,500 (b) 48.250 (c) 1.93.00 (a) 10,000 When one of ampere current flows for Isec through a conductor, this quantity of electricity is known as IMP PMT 1993) (2) Faraday (b) Coulomb () EMF. (4) Ohm ‘The mass deposited at an electrode is directly proportional to IAFMC 1987; MP PET 2000} (@) Atomic weight (b) Equivalent weight (6) Molecular weight (a) Atomic number From the solution of which of the following one faraday of electricity will liberate one gram atom of metal [MP PET 1993, 2000; MH CET 1999; AFMC 2000) (a) NaCl (b) BoCl, () CuSO, (@) AlCl, On electrolysis, 1 mole of aluminium will be deposited from its molten salt by [MH CET 2000] (a) 3 moles of electrons (b). 4 moles of electrons (€) 2moles of electrons _(d)_1 mole of electrons ‘The atomic weight of Fe is 56. The weight of Fe deposited from FeCl, solution by passing 0.6 Faraday of electricity is [MH CET 2000) (@) 56g (b) 112g (c) 224g (@) 3369 25 F of electricity are passed through a CuSO, solution ‘The number of gm equivalent of Cu deposited on cathode is [DPMT 1982; MP PMT 2001) (a) Zero (b) 1.25 () 25 (d) 5.0 72. 73. 74. 75. 76. 77. 78. 79. If the aqueous solutions of the following salts are for 1 hour with 10 ampere current, which solution will deposit the maximum mass of the metal at the cathode. The atomic weights are, Fe = 56, Zn = 65, Ag = 108, Hf = 178 and w= 184 [Kerala PMT 2006] (a) ZnSO, () FeCl, (ce) HACh, (d) WCl, (e) AgNO; Silver is removed electrically from 200 mL of 2 0.1.N solution of AgNO, by a current of 0.1 ampere. How long will it take to remove half ofthe silver from the solution TAMU 1999] (a) 16 see (b) 96.5 sec () 100 see (@) 10sec How many coulombs of electricity are required for the oxidation of one mol of water to dioxygen IRPET 1999; KCET 2015] fa) 1.93x10°C (b) 9.65x10*C ( 193x10°C (d)_ 1.93x10°C A current of 0.5 amperes is passed for 30 minute through @ voltmeter containing CuSO, solution. Find the weight of Cu deposited [BHU 2001; AMU (Engg.) 2010) (2) 3.189 (b) 0318¢ (0) 0.296 g (a) 0.150g 9.65 of electric current is passed through fused anhydrous magnesium chloride. The magnesium metal thus, obtained is completely converted into a Grignard reagent. The number of moles of the Grignard reagent obtained is IKCET 2010) (a) 5x10 (b) 1x10 (9) 5x10 (a) 1x10 1f 0.5 amp current is passed through acidified silver nitrate solution for 10 minutes. The mass of silver deposited on cathode, is (eq. wt. of silver nitrate = 108) [AFMC 2001) fa) 0.235g (b) 0.336 g (6) 0536 (d) 0.636 g ‘The unit for the electric current is. (KCET (Med.) 2001) (2) Ohm (b) Volt (c) Ampere (@) Coulomb ‘The quantity of electricity required to liberate 112 cm? of hydrogen at STP from acidified water is IKCET (Med.) 2001} (a) 0.1 Faraday (b) 1 Faraday (c) 965 Coulomb (4) 96500 Coulomb Which solution will show highest resistance during the passage of current (BHU 2001) (2) 005.1N NaC (b) 2N Noct eon Ne (@) 1 Noch Es 4.9 of copper was dissolved in concentrated nitric acid. The Copper nitrate solution on strong heating gave 5 g of its ‘oxide. The equivalent weight of copper is IKCET 2004) (2) 23 b) 32 (e) 12 @ 20 Ee Cl87. 91. ied by passing 241.25 silver nitrate solution is [MH CET 2003) (e) 2.79 _ 0) 27mg () 027g (d) 054g ‘When IF of electricity is passed through acidulated water, , evolved is [MH CET 2004) (a) 11.2dm? (b) 5.6dm* (c) 22.4dm? (4) 1.0dm? Charge required to liberate 11.5 g sodium is fe [ANIMs 1992; DCE 2002) (2) OSF (b) O1F (9) 15F (a) 96500 coulombs In the electrolysis of water, one Faraday of electrical eneray would evolve {DCE 2004} (a) One mole of oxygen _(b)._One g atom of oxygen (©) 8g of oxygen (4) 22.4 litres of oxygen When a quantity of electricity is passed through CuSO, solution, 0.16 g of copper gets deposited. If the same quantity of electricity is passed through acidulated water, then the volume of H, liberated at STP will be Igiven : at. wt. of Cu = 64) (KCET 2006} (2) 4.0 cm® (b) 56m? (©) 604 em? (@) 80cm? ‘An electric current is passed through silver nitrate solution using silver electrodes. 10.79 g of silver was found to be deposited on the cathode if the same amount of electricity is through copper sulphate solution using copper electrodes, the weight of copper deposited on the cathode is [Kerala PMT 2004) (a) 649 (bo) 239 () 128g (4) 169 (e) 32g The law of electrolysis were proposed by [CPMT 1982; Pb.CET 2003) (@) Kohlrausch (b) Faraday (c)_ Nernst (d) Berthelot The approximate time duration in hours to electroplate 30g of calcium from molten calcium chloride using 2 ‘current of 5 amp is (KCET (Med.) 2012) [At. mass of Ca = 40] (o) 8 (b) 60 (©) 10 (a) 16 The number of coulombs required to reduce 12.3 g of nitrobenzene to aniline [UPSEAT 2003) (a) 115800 C (b) 5790C (c) 28950C (4) 57900 C During the process of electrolytic refining of copper, some metals present as impurity settle as ‘anode mud’. These are [AIEEE 2005} (@) Sn and Ag (b) Pb and Zn (c) Agand Au (4) Fe and Ni A galvanic cell is set up from a zinc bar weighing 50g and LOlitre, 1.0M, CuSO, solution. How long would the cell up, assuming it delivers a steady current of 1.0 ampere [Roorkee 2000} (2) 48 hrs (b) 41 hrs : (c) 21 hrs (4) Vhr 94. 95. 96. 97. 100. On passing chloride, 112 litre oh Cle is quantity A absminium deposited at cathode is (at. wt. of Al =2) (UIPMER 2002) () 99 Oo 186 © 29 Rs connected to a water voltameter. The cathode of the silver voltameter weighed 0.108 g more at the end of the dectrokysis. The volume of oxygen evolved at STP is Kerala PMT 2003) (2) 56 on’ (b) 550 on? (c) 56 om” (8) 11.2 on? (e) 224 cm® During electrohysis of aqueous NaOH.4g of O, ga is liberated at NTP at anode. H, gas liberated at cathode is [CBSE PMT 1998) (a) 28 itres (b) 56 litres (c) 11.2 litres (A) 22.4 hires The amount of ion discharged during electrolysis is not Gitectly proportional to (2) Resistance (b) Time (c) Current (4) Chemical equivalent of the ion What current is to be passed for 0.25sec. for deposition of conain weight of metal which is equal to its electrochemical equivalent 1AM 2006} a) 4A (>) 1004 (c) 200A (d) 2A queaus NaC! sokution wes carried out npere current . The time required to OA Hz cas at the cathode is (1 Faraday OT SEE 2008) f sec (b) 193%10* sec (c) 28.95%10* sec (d) 38.6710" sec A direct current deposits 54 g of silver (Atomic mass = 108) during the electrolysis reaction. How much aluminum (Atomic mass = 27 ) would be deposited from aluminium chloride solution by the same amount of electricity [Kerala PMT 2008} (a) 45g ) 54g () 54g (4) 27g (¢) 27g ‘The amount of substance deposited by the passage of 1 amp of current for 1 second is equal to (Odtsha JEE 2008] (a) Equivalent mass (b) Molecular mass (0) Electrochemical equivalent (d) Specific equivalent A current of 96.5 A is passed for 18 min between nickel electrodes in 500 ml. solution of 2M NiNOs)z- The _ molarity of solution after electrolysis would be (AMMS 2007) (2) 046M {c) 0625M (bo) 092M (4) 125M =101. In the electrolysis of acdulated water, its desired to obtain 1,12 ce of hydrogen per second under S.T-P. condition. The current to be passed is IKCET 2009} (a) 9.654 (b) 193A {) 0.9654 (a) 193A 102. Faraday's constant is defined as IKCET (Med.) 2001; J & K CET 2010] (a) Charge cartied by 1 electron (b) Charge carried by one mole of electrons {c) Charge required to deposit one mole of substance (a) Charge carried by two moles of electrons 103. During the electrolysis of molten NaCI solution, 230g of sodium metal is deposited on the cathode, then how many moles of chlorine will be obtained at anode (MP PET 2010} {a) 10.0 (b) 3.48 (©) 355 (@) 170 104. When same quantity of electricity is passed for half an hour, the amount of Cu and Cr deposited are respectively 0.375g and 030g. Ratio of electro chemical equivalent of Cu. and Cris [Odisha JEE 2010) (a) 08 (b) 1.25 () 25 (a) 1.62 105. How many grams of cobalt metal will be deposited when a solution of cobalt (Il) chloride is electrolyzed with a current of 10 amperes for 109 minutes (NEET (Karnataka) 2013) (1 Faraday = 96, 500; Atomic mass of Co = 59u) (a) 40 (b) 20.0 () 400 (d) 0.66 106. The amount of current in faraday required for the reduction of 1 mol of Cr,0?> ions to Cr** is IKCET 2016} (a) 1F (0) 2F () 6F (a) 4F 107. How many Faradays of electricity are required to deposit 10g of calcium from molten calcium chloride using inert electrodes (molar mass of calcium = 40.gmol-*) (MH CET 2016] (a) OSF (o) 1F (0) 025F (@) 2F 108. During the electrolysis of molten sodium chloride, the time required to produce 0.10 mol of chlorine gas using a current of 3 amperes is INET (Phase-II) 2016] {a) 330 minutes (b) 55 minutes () 110 minutes (d) 220 minutes 109. The number of electrons delivered at the cathode during electrolysis by a current of 1 ampere in 60 seconds is {change on electron =1.60x10""°C) [NEET (Phase-Il) 2016) (a) 7.48x10% (b) 6x10" {c), 6x10" (@) 3.75x10” {a} The oxidation number of oxygen in KO, fer (b) The specific conductance of an sept solution decreases with increase in dilution (c)_Sn® oxidises Fe"* (€)_ 2n/ ZnSO, is a reference electrode tn infinite dutions, the equivalent conductances of Ba®* and CI are 127 and 76 ohm tem equt', The equivalent conductivity of BaCl, at indefinite dilution s_ [CBSE 2000), (a) 1015 (o) 139.5 (c) 208.5 (a) 2795 The factor which is not affecting the conductivity of any solution is (a) Dilution (b) Nature of electrolyte (c). Temperature (q) None of these Specific conductance of O.1M nite ackd is 6.310? ohm tem”. The molar conductance of solution Is [Kerala PMT 2003} (b) 315 ohm’ tem*mole”! (a) 6300 ohm "em?mole"! (a) 630 ohm’ tem*mole* () 100 ohm’ tem*mole* {e) 63.0 ohm tem*mole! The conductivity of strong electrolyte Is IKCET 1993; CPMT 2003] (a}_ Increase on dilution slightly (b) Decrease on dilution (c} Does not change with dilution (a) Depend upon density of electrolyte itself IX is the specific resistance of the solution and M Is the molarity of the solution, the molar conductivity of the solution is given by [Kurukshetra CEE 2002) 1000X 1000 fa) M (b) wK 100M MX ©) =¥ (d) 000 Conductivity (unit Siemen’s) is directly proportional to area of the vessel and the concentration of the solution in it and is inversely proportional to the length of the vessel then the ‘unit of the constant of proportionality is [AIEEE 2002) (a) Smmol" (b) Sm? mol" () S*m? mol (a) S*m? mol? If one end of a piece of a metal is heated, the other enc becomes hot after some time. This is due to (CBSE PMT 1995) (a). Energise electrons moving to the other part ofthe metal (b) Resistance of the metal (c) Mobility of atoms inthe metal (d) Minor perturbation in the energy of atoms ms Conductivity ofa solution is directly pro eee (2) Dituon {b) Number of ons {c) Current density (d), Volume of the solution.The E°of zine is -0.76V and that of coppers +0.34V Identification of cathode and anode is done bby the use of a thermometer. Higher is the value of reduction potential, greater would be its reducing power ‘An electrochemical cell can be set up only if the redox reaction is spontaneous. A reaction is spontaneous if free energy change is negative Galvanised iron does not rust Zinc has a more negative electrode potential than iron. [AIIMS 2005) In an electrochemical cell anode and cathode are respectively positive electrodes. At anode oxidation takes place and at cathode reduction takes place. 1.0m) negative and Au? (.0M)| Au this cell emf is 2 are same for The current carted by cation and anion is ahuays equal. TANIMS 2007], In the electrolysis of aqueous NaC! , Na is preferentially discharged at mercury ‘cathode forming sodium amalgam. It is due to the fact that hydrogen has a high over voltage at mercury cathode. {ALIMS 2007) Lead is most effective in shielding radiation. It is very stable, and many radio-active reactions finally yield lead. (MP PMT 2008) Oh iis inswers Electrolytes and Electrolysis ¢ 2 3 ‘ 5 7 ’ * mr Ga ou ‘fume eo @ ® ¢ (aus ac (ae) ae qs } a> is Ge © mb él! ee b Ss 6 —: ao: oo a é a Te Tx va «ta «in +e «ono fia > lee ae 7 te. 3 2 ae «ee = ok me ¢ nm ts me 6 DB =u. a> o> a: oe es = «nm t+ @ t+ @ ss @ nT Tl mo mM 25 Ee rm rn oe > a a. «is a. =o: oe oe. ee @® » @ ss @ 2 @ & Be a a oe ae - - “Se ot = osCorrosion JEE Section Assertion and Reason 5 3 $s o 2 = f= = 3 g oO Cell constant and Electrochemical cell Electrode potential, E..y, Nernst equation and EC: