Log (lenlzation exergy) ee eee age ‘Which of the following types of radiation is MOST likely to be measured using a Geiger ) Beta , @ (© Microwave @) Ultraviolet Item 2 refers to the following graph which shows the log of successive ionization energies for ten electrons of an element, P 123 65 67 8 9 Io Nomber of electrons lost Element P is MOST likely (©) magnesium Which of the following electronic conf gurations is for the Cu(T) ion? ®) 2) io (©) [Ar] 3a? 4a! @) [Ar] 3d" as? Item 4 refers to the following sketch which shows the variation of the boiling points of the hydrides of Group V. Bolling point (°C) NI PHy Aslly SbHy Hydrides Ammonia bas the highest boiling point because (A) the N-H bond is the shortest and strongest (B) there are more van der Waals forces NH, (D) the eletronegativicy of nitrogen is much higher than that of the other elements in the group ' ‘Yellow metal’ is a type of alloy (brass) used to make omaments. Jt contains 60% copper and 40% zinc by mass. How many ‘moles of zinc atoms are there in260 prams 2 oy? AR PAI TA TUR NEXT PAGE“3 Iem_6 refers ta the following diagram of 9, Which off the following compounds has a ‘a water molecule showing the angle X in giant molecular structure? A) jum oxide # 1) Silicon(TV) 0: fam ebloride (D) Phosphorous pentachloride 10, The value of X is 104.5 @) é (c) 1200 @) = 180.0 Which of the following statements is tue about 5 dm! of hydrogen and 3 dm? of ‘oxygen at °C and 101 kPs? (A) They react to produce 5 dm’ of , water, (B) They react completely with each (C) They possess the same amount of [tem 8 refers to the following reaction, 2PL(NO,), —H+ 2PbO +4NO, +0, ‘The molar volume of gas at rtp. is 24 dm’, ‘The maximum mass of lead(II) oxide which can be obtained from 13.23 g of lead(T) nitrate is (A) 223g 4.46 @) 13328 GO ON TO THE NEXT PAGEi 4, Items 11-12 refer to the following halfequations for the reaction between iodine and thiosulfate. 2.$,0,(aq) —> S,0,*(0q) +2 Taq) + 2° ——> 21a) ‘The overall balanced chemical equation for the reaction is: (A) 28,0*(aq) + 2-(2q) —> $0,409) + L(o9) ®B) faq) + 8,0) (eq) —> 25, 0,*1aq) + 2F(09) r 4g) —> 28,0,(aq) + L(en) (D) —28,0,%{ad) + (aq) ——> §,0,'1aq) + 2a { ‘The oxididag agent is _——————— (A) Maq) © $000 ©) 5,009) S,04aq) + 2F ‘Sodium can form ionic bonds with each of the halides. ‘Which sodium halide is expected to have HIGHEST lattice energy? Mel ‘The standard embalpy changes for two reactions are as follows: 2Fels) + 2042)—> Fe,0,(s), Al = ~822 4d mol" ls) + 40,44) —+ cow, aif* = 110K met ‘What is the standard enthalpy change, in XJ, for the reaction Fe,0, (8) + 3C(s) ——> 2Fe(s) + 3CO(8)? (Ay 932 @) -712 492 @ +492) | GO ONTOwhe 15. Which of the following gates is CLOSEST to bebaving as an ideal gas oder the ented conditions? (B) — CH{g) at 30°C and | atm pressure (©) COg) at 30*C and 250 atm pressure (D) — NEL(g) at 400°C.and 250 atm presse 16. Which of the following phrases describes the activation energy ofa reaction? aoa (A) Affected by temperature Reduces speed of reactant malecules we John plans to measure the rate of the reaction between calcium carbonate and dilute hydrochloric acid. ‘Which of the following pisces of apparatus is MOST suitable for this investigation? (A)18, LS -6- ‘Item JB8 refers to the following reaction which occurs in the presence of CH,COCH, (aq) +I, (ag) ——> CH,I COCH, (eq) +H" (aq) + I-(aq) ‘The mate equation for the reaction is Rate = K(CH,COCH, (aq)] [H"(aq)]. Which of the following equations BEST illustrates the SLOW step? ° OH on, —t—en, +H = @ ll | 2 Sarg @ I © cH— heen +r cyto, OH @) ell ce, +1+H een f =a, I Which of the following eT 20. ‘The value of K, for the equilihcimm, fer to Si epee Spot seals HY) +(e) —! 2) (A) The resction is reversible, {B)_The amomes of al he species in he in 860 at 25 °C, The consentrdiees of all reactants What is the value of K, er 25 °C for the equilibrium? (D) The rate of the ferward reaction is: following ‘equal to the rate off the backward vn sna + Lit) =— HMw)2. 22. aie: In the Haber process, N,(g) + 3H(g) == 2NH,(), AH=-90 kJ mol", e the MAXIMUM yield of ammonia is obtained at Compounds P, Q and R form aa equili- brium as shown below. 2P(aq) + Qfaa) ==" 2RCaq) ‘The units for the equilibrium constant, K., dm mol? Which of the following pairs of acid and conjugate base is correctly aligned? Acid Conjugate Base (a) NE, NH @) 0 HO" @) HPO? HPO; A buffer is made by dissolving 28.8 g of sodium benzoate, C,H,COONa, ia | dm? of 0.4 mol dar benzoic acid, CH,COOH. Ke in “64 X10 enol den, ‘The pH of the buffer is “a 23 @ 29° ©) 39 25. 27. ‘Which of the following pairs of substances would make a good buffer? (A) HCif(ag) and NaCl(aq) (B) —-HCK(aq) and NH,Ci(aq) (€) NH(@q)and NH,Cl(aq) (D) —_NH,(aq) and NaNO, (aq) The solubility product of BaSO, at 25 °C is 1x 10" mo dar‘, The aumber of moles of BaSO, that will dissolve in | dex’ of water to form a saturated solution is (A) x10” ®) o tases D 2x10 Which of the following expressions represents the solubility product of iron(QIN) hydroxide? (A) tre} (308) (8) (rey (oHry © eeBor Fe(OH, @ Fe Nor) FaOH), ‘What is the potential for a cell with the following reaction? Zo(s)+Br,(0q)—> Zo” (04) + 2B (09) [+1.07+-070)V [-1.07 + (-0.76)) V «a @) c)age ltem29 referstothefollowingeelldisgram. 31. Zn(s) | Za* (aq) || Cu* (aq) | Cus) 29. Which of the following, conditions will cause an increase in the cel! potential? “A ing concentration of Zn**(aq) ions only (B) Decreasing concentration of Cu?*(aq) ions only (C) Adding NaOH to Cu” solution and increasing the concentration of 32. n* ions Decrensing concentration of Zn (aq) ions and increasing concentration of Cu” (aq) ioas Item. 30 refers to the following diagram of an electrochemical cell. wire 3. 30. Which of the following situations does NOT occur in the ¢éll shown? MM. (A) No current flows when the salt bridge is removed. (B) = Magnesium ions migrate into the (D) The reaction at the maguesium electrode is Ma(s) ——> Mg'(aq) +2¢". ‘There are eight elements of the third period, sodium to argon. Which of these elements existsas a diatomic molecule? — ( (D) = Sulfur An element in Period 3 combines with oxygen to form aa ouds Which reacts with water to produce a strong afcali- That element is (A) Al @® a ‘Which of the following elements in the third. period has the same oridarion number in ALL. of its known compounds? © Sulfur (©) Phosphorus Calcium carbonate lower temperature than brim eben because (A) calcium oxide is less stable than barhim oxide (B) the ealeium ion is targer than the barium ion 7 (C) the = standard §— enthalpy of formation of calcium oxide is less negarive than that of re Mande energy of calelum oxide is larger than hat of bariucao 38. 35. Which of the following statements ebout oxides of the elements in Period 3, sodium to chlorine, is NOT true? (A) Across the period, the oxides change from basic to amphoteric to acidic ter. The oxides react with water to form \Ikaline solutions. (C) Theoxidation number of the element in the oxide increases across the period. ‘The structure of the oxides changes from giant ionic to simple 39. covalent molecules. ©) 36. Which of the following propertics belong to Group 2 elements of the periodic table? fea ec ali a (A) High melting points and low densities (B) Low melting points and poor electrical conductivities (CE) Low densities and poor electrical enductivities (D) ‘High melting points and igh) 4, electrical conductivities 37. ‘The insolubilities of the Group 2 sulfates make them very useful in diagnostic medicine because they appear opaque to X-rays, ‘Which sulfite is MOST commonly used for X-rays? T_T) Which of the following statements about bromine are CORRECT? Which of the following complexes would ‘show the GREATEST paramagnetic property? — —— A) [Cu(CN), @) [Fe(CN Je 3 —_ @) — INi(CN),* ( Copper (II) sulfate gives (a) 0 deep blue solution with excess ‘NH,(0q) (>) —_ayellow-green solution with excess concentrated HCL Which of the following deductions can be de from these observations? ‘The complex ion [CUu(NH,))" is formed in (#), I, (CuQHL,),)* has » higher stability onstant than (Cu(H,O),)*. MT, [Cut y* has a lower stability constant than (Co(H,0),F".41. 42. “10s Which of the following statements describes the tread in physical properties of the halogens as the group is descended? (A) Volatility and atomic redii increase (B) —_Blectronegativity and volatility Electeonegativity decreases and solver deepens. « @) ponding decrease ‘in density as states change frem gas to liquid to solid. In which of the following options are the ING halide ious placed in order of INCREASI reducing power? —. (A) Br,ClyI- (B) Ch t-,Br () 1, Be, CF — C| ‘Which of the following solutions is BEST suited to determine the presence of hali in river water? —— ———_—. (a) HCL (®) HINO, =) NaOH (D) AgNO, G0 ON TO THE NEXT PAGE