@ CASE 1: If the reaction Is elementory 5 then the rate of Formation of R waild be given by tp = kp CaCe Thus, the reaction is 1° order with respect to A 1* order with respect to B 2™ order overall CASE 2° \f the reaction is nenelementary, then the rate of equation ray not be an expression of tne forrn fp = kp CRCE. \n thot case. the reaction order is rot defined. @ 2NO2 + £02 = NeOs =la _=fe _ tR a b r ~ Enos. Tfee Tce VNos Voz “Vyyos — Eros . rome 2(-foe) = T Neos ® socnmenc, \+2B A> on+s EQUATION 2 RA “nek Expressen? TA = kaCaCe UNITS OF tt 2 oak RATE contrast? (time)~'( concentration)? ka PAGE 1 OF Scanned with CamScanner@ _mol _ 1760 (mah )mat*) 1760 (Mel *\_mer me = © 6 ic) mol) metre? oF = 1760 (22) ew ae G mol “m 17GG j © No, they are not related by rate = TR they are related as follows: From +he Stoichionm etry TTA _ ore Te 4 BS - 2 ney Ss 2 FAGE 2 OF Scanned with CamScannerFurthermore, aL GOmin yy [_om? -| x Semin y kr h-wel Thus, mot = 3x1lo74 L /h-mol (a) (hate b = (> pA, = Ne = CaRT «(6208S na sda aco =) Ca * sabe Ca A Ka [sam] Beco ral a ~ sigt2ce = 61760000 — aPa _ 1 2 Se = (255) pa -4 fs ( ca) =( a0 aN) dt\i2s0 sl 1280 dt (44) ~ E86 geo hot az) Ca — 1 aN a a = (3.25333 x1O*) C2 => [ka = 3.25335 x10-¢ m/mors| Scanned with CamScannerMixed eder ; ki CN2O1 a as’ [N2Q} >. > — "Ro? Fau—NOD k,DN201", second mder Me Ol ee hve __kilN203" >[N.05, First mader ‘ 14 k2DN-OJ Scanned with CamScanner