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    6 views22 pages

    Co-Ordination Chemistry (1) MM

    Uploaded by

    Dark invader yt

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    Uniti 9 Co-ordination Compounds > Ganition meats form no af compere du 40 the peste @ “al orbitale”. > These adems «On waceept leaden from digards ( AvIoMs Cy Meloendes > Many pickegiccdley, Smportant _ matacute shee chieroprye?, Harmegtabin A Vidamtin Big OMe co erdinah ev. compounds op mq Fe & Co sespeadively Poet Valente Valenee. vu a Usd va Specdtic vor , secupied) Adabishied aS aa gremy by dhe anna, i Pach, heamidi®n — yotal « ext , Cott, ipa ye art Cr 3S, rd, PaA- 2. 1 mate CoChy: GNH, Yellow ) — > 3 mate Agee 1 male Col, SNH, ( Ample) dma Age | male cody ANH, Commond >» | malt Agee 1 mabe Cott: ANH, ( Vitlet? > Imele Agee Corus’ @ + dn all Cases at Jtart Yours Cettha hy or oD gomaln bendid 4 Me to ions = A) indicates = 48me signif cance jock the spetic «NOs 6 ' “gs — On Beis bale = Werner prepared = thay actually nig hor 6 Ko the secordavey votunse. ef the ten and = Armed fateh « at [oo cetayT see= — tra Brot cle, [eo crarge J? neem et 2 elealyte [eo CuHargcta T com 5 tl Ghretelyte, > dn con erdination — compounds, nchats — #hovo oo Sypls a nkages (valores ) Prima > Primary —valleners ane jevtsable 4 sohabied by negative Jens. ¢ Antena) @ velemon ane hen. lonizable and fahstid by cline, — Neuter! meloeutes er anions and the gh desmd os Agen G>T beurd bye dineeg do dhe ‘natal Jom fave eharaetenictic padi ee Palydna ore formed @ a oo : Co CNS), Co CRC NM), Ss (oom, S te] {ee a Ceaes, cnM74 J (ti ceor J 7 Truc 1°" > Tehahedwal , Differance bebwenn Dowsta alt LQ Compline Double. pola cam be sosily Aimodladed Ande compenerds~ ROM CHD > RE amyl a ee Coarnadile> enue fase « CntHy),80 ° CHP —> Rr, soy ant 18%” | CHS Maly Zaid > dn wnker Hae double adds — ane soni atiesahed: s Sf we — Cowidah «Compe Compound Bua Ky CeCe T wv ae [recent Sahn. 2 [eo CNHI, Cooc T su CmptoxD Dapirvions of _Seme__Srrporteret. “Tews (o- erdination ently ® : gh eomithes carrera Jen Jatem tended 2 fina hos of fem er molecules » e [eo Cty CHa), Leoents eT" Emery Green enn} TL recent Caaat_om / ten Sn co-ordination sudity, the afem| jen Jo which O fred nes 4 digonds ane — boumel~ & Lcocastns 2 J — ee" : — Ni 2b =~ ff [ricco [ Feeeny y~ Troe cha He; mmpteeues J nagative fone bound de Bo conrad tem} ton, th erdor do ft thle seman volanery + ; \ Or Netal molecule » pain of do the contrat fe Ya alorales| —? Unidentote- ja dovaked «> Didawlate- we chon we race EO an pie Unidarlode > oc, Be, oT, wt, Ny © Didowlake = — {2 cn Ni, ot CQetale) — (eHan=1,2- + haba 5G . [ceso*3st 7 eo ™ v® ah Oe Ry L Fecenyey Co- ordination Sphone & bs Sgands nm Jn pgp, ~Prackelt» — > Corovetinartion — #FEM* atoms atloohedt Spahal oosangpn: ot ‘te A jo the aitra ater | Zon Wes a co erdination. payhudron, about laaiubail Mat cemmev one ® er Oetahetrat ets _eae ate prownt 5a ae ameunt of charge oF A compl — cemporrrals the. * antes a zy [cottarg 1M aaeoTErl Hem: A Herenos Compeeuids @ Sf Mata adem Jk beunct. Je only One det ae doner qreeps —> Hemelepte Compeunrcls . Yeo Malat atom A beund «= do mone than one fund of donor groups = > Hetereleptic — Compoturels [esentat, Jeg > Hemeleptic: [te CHOON, J Cl Heteroleptic Corordixadion oucity ——. , i feegidag wenn ei ordination — 4prore Co-ordination Nov Nemenctadure ©} Co-ordinaHen —_ Compounds t (The = tantra atom ated fist ancl Ws enddation «Noss ebtained + @? Lyaras sare wrcien dn alphabetical manner. for mow than ene 0 Di, OL teha- For Nuutrat Ligands —= HO 4 agpta, e Nt = Amine ¢o = ccheaid- in NO — Nidreage ; For lagative Jigania. — cuftix + -O- padded tn > Gyanato ~ No, — Nitvite . coo _, Oxalate, bov~ Nauka —rroitentas cand compton Ong ‘wu wsitter © jm dhe bracket = fer vbmbidaxtate Nigande’ = “Tha donee atom js nenfievad aliens + eg, Nittito —N Ninite —O. @ For compen Mgands , bir, tole , ehaltin ame ted CD Sf cor erdivation —aprose fas SF ve charge = thon caxsad «atem's name is woolen as auch wie Ms oldodien nos byoabott + ©) S$ corerdivation Aphere how ve sharge, » dro rame of vandal — atom a waiter WiLL sae Sate? . 9 Cobattate Cont, Nov Or bracket pgatinale © wien — present outside tha Co ona on one nome “in foe + CThily umbor 4s net mentiengd.’)- CD yo any Gee igs ja ahead 9} Co- orcttnaction Apo it wertiond — fist of all: (Oxidation Nov J antral atom. we alusaiys montowed Ue emo numerals. CI) CH? Cy) ete, Q: T Gr CNM >5 CHP, Ch Oxi: Nev ef co-ordination phone > “+ve charg. C= Ariammine telaquac remit CHT Yehiowide + . Q. [eo Cyr rete HILT, CHD Lris(ethane-1,2-clammine) cobatt Cmrautphake ali oy & > ® fo-ecdivastion Aphence Ye ve Bending in Cer trdiration Com ® > Wem could ret Cue bale @ dromidion — alamants — @ wy bods ave qpisations se , co-ordination ; dutional properties 2 — ® Uehy Abotackniable magnetic. sand ophitat properties 7 ag oka Valence Bend. cveT cgitat Pus. Sra cern Ligand Fick aes vislooufan Orbital Thwory (MOT) Nolanee ond “Theory * Involvement of orbital ike. OO Grd rns np or (hs np nk Co-ontitetion Ne» My bohddzation 7 a Tetronalrat a asp Spore, planar 7 spa “Tayoral bipyvamitas : spd? otakadvad i at se* Cetahedval . Mosport | sipediigg, yeast CO) Memic No & ehetveiie (2 Configuration, en the contra «atom. (a) a -erchtnatien nov of cena atom: (DH Neco = Sigand © Ahog | Weak) _ Abviveg 05 satotibve 2 we _ptitorsg © & Frd Hybridization of [co cnrirg tea, . ast Fiat of at — G-ordlination eid Hy- [oom T* te Ish) (a) se) Cl _ Avi 4 pert oop » es eo (w>whv) = (av Tavlv av aviv} ain paivs of e° from “Rig melouten « 0) Hybadisation — d*sp* C2 Ceomoarey = Octahadeal. @D — Qnner Avbitad ample Co inner “at outta co CD Lo Spin er spin painal compte. © Diamag ratic Jn nade (No Uhpalsad ebeercons.S ge. Comment Upon [core] o = mits a Oo m7 1o rt i) frre (1 IT] OT ye Fee ew ch wee Oo cn wybaaizadion Spa Geomehty 7 Schahedal. CH dur Anbitad - Compton @ High spin Comptox er Spin doce complex. it) Rerramangnetic th nakuu. Sa < Re “Neqrotc _Teopaties of _ Coreen: _ Compounds — Due 40 presence of unpaired — elaodvens , those Compounds may. Aho aginst: Prepertios Nepretic. Memon = Yncnaad % dn (ook Mogrotic Mement = tease = Jae 7 = [ar = 4-28 (rete) me Bupa em [reeeeY > 4 unpoiisud 7 Nolet Strong, Aigards — Mke (ND 4 ED can coune, pohing of eked =o in te orbyals of tondrad = atom 2 excaphenallyy Ty 7 Attneugh — nat thad Adrng: Jigand out can Came patting, ty cot den. 7 ert Posamagneic C4 unpated & > = [wtetaay = Dlamagehe- Oralates Howe Db comes poling @} — efoatcons, gsomeriam _—_bu_Co- eration. Compounds: ® _Seomenian Asomerian Bhuetuvol : ee Taomextiar Linkage Asomerism covovctiedion 7? Cheometrcot caption Tapmesdiam Agemeusm densoh® 77 Reale ” of Higrole Linkage Semmaris = tompuns” Madigan of imbhatandate tga £5, fies oc Eon No, er ONO. Teo Crihads (NIT, & [co CNH Comer Cf _Go- erdinaton _4aemestamy we fawn due 80 indevehange blo Byers co osdinatien — Spheres: %- Lcoc nar Ler Cente k : Lorene 3 CT cocened Jonsation _ Ssomentsm > Wins due do S betneon dems of ve orctication pI & ire Oh primanug valency. + €. — CeocnargS% I By A Teo Citas Br 5% Solvale _ Ssemesism Ae kno as & Hycwate ernest» = Roe vantey = moleculer = ANE sxchangel betweon, eoreardinaion —aphine & Hychrate mmolaeslea « Cer CrP Jet, Cviott> Ler scr] ta:40 — C Gvey- eeond. Creematiead Asemesiam dn Hebexoheptic compounds due, 40 . pense geome covrangements « t 5 Tue posibilities «> Cs ortination N= Co-exdivation Nov 6, - Co-echination Ne 4 aa Square — planay = tetrohsdred — Complexes dent shod he Geemahrical agemenism a petattve = pauiitiom Of = garda ame ame wish aspect de gach other Sn Sqporne — plowar Complinces Ccee Nem 4D > Mylo = CX, Lr unidentate ) ere os & ene dram ister. Sy (aon, J Ni a 4 Hs a ae we Cos = Sn [maexy = AB, — Uni, Haley Ts os treme ene tam Lzomen = Jn Coordination No - 6 Fee GE, = XL SOW dontale. u One cia, ove + trong 2 few [Leo CNS? Ch, t For MeO, — KR Unldentte LL Didentale, sy Teoc, cen 'd Ss a [ \ OF Soy ; en : foams aig, — frolvey — Aype | Magba"\ a,b —UWdadale, & Foap.tnad, | NM Nils \ NW NO, NO \ eye ae 4 ee Ney: \ Nw No), no, facial Meridiena? gocit, Cmrer) fae- —— Optical _dssmerdam @r > Hee again, the cenoph Sf mivroy dnoge 4 applicable > Porte Sm both §— Homeliptic: A Helerakeptic comp: . + Beth dutmende fem one ivweor Imagen of ond cant be Aupertimpased on ene — another. shoe ce erm 4 OvOnHOWed » %: [co cen rey —_— a) oD Jone _Seado 4 a « a ) a Crypto Aiedd They t @ Following —austumpfem are ceonsidwina « o Melat —Sigewd bert =k dhe tasdant of eleetraxtotic cthachen betwen — metot & Algad- © z Aden > point changer adae CH when tigands —C Arlens / Nauded molecules approseh de the dromsition meta , the fi2hl ancuncl =the Q@tom becomes Lmaymmetoticae — ana ap stata Aa distured + 3 susulta fn the aptittie ct the {debited ?, (5? The pattern, ati fea 2 et the rahe’ of Coupstest Cet Aptittig In detahetal —Co-evcination entities day .clys dex Aye ae > Enagy separation a doveted by As Mighoy energy — exbitals = &- C3l¢ BoD taser sanrggy SBR 8 dee Co BaD > Cystat fiatel aphitting upen. the. fioset peduecd by Fhe gard 4 change en the mata jen. s Sf field — produced the __ sigand ik act > lage “pitting St fink — procuead $k me eM pithy, Jigar. we Weak Yo2e7 gsen7 ce es 2 6 SZ Onn Ze Lomo < nes < edta CNH, cen Zw g2co O 4 FF e& ents. Be wilh choose. ony | the Sowoy 425 orbital « (ay sf mt em enten, ogain ona af athe dower tag orbitals — Subse qpiond at eloatron elfen ~ She Ahi bg erbirtol - (2) whan 44 eboton ante pit des two options | ey GG) st gee into higher & exbrial + ov @ wB pos into One of tue tag erbHals, fax gaining of 2 in orbidat , She paling cnorgy A pega CPD Ss A cP, Jhon ane with onter in tie © fovet. Poppe $M coe of Wank — Higands ushene A, yas small value - > 4 as>p, aren 48 em with ke pertheet mone Oo] Ae Jowey eregy Devel tg fovel. HY teppw In came af aheog — Mgards use. 4, ter forgery valu. Hare few spin compares Cuystad — fintd —— aptittivg Sn tebrabkadrot Co-ordination Srtities ay, dys, dom Colour in Co- evddinachon. Cony When —uohite Bight a pated dhe Aamplo. ] coecthation eempaunck , dhe tight emerges JA no Sorgar whi: The eetouy a the compton. is complornesc do dhe ealour jushieh a observed: > Glouy se due to She ptoence Unpaid em jm Fhe cemptone/ co-orchination — competuncls- + Mang Hes tHe esteur of — complare —compotincls doperds = upon he Ayydated. mevecute. @ Ti cap,” + en — Ni cn, en) a eae pag blue (ing ef en CNICHOZEN,T + ago Blue f Purgte . a te Ti cH09, Cen] $n — Ew cont a aii | Nieto __dn_ Mote _Cononyyts (Ni coy] 4 Tehohadrag [Feteoe] > Trigorat Sipyramicar [ex ceode J > Odtahatsad eo to co. t SI 0o JIN. a u l ee L TBugorad bp Tetahectsal 00 © <> Melad- cavbeny? berd tar beth = wath as @ KR chesoeten- mre > oo bed be formed by devation af Lene Fay ef conbony? carbo fo “a exbitad metal: M-@* — 7 bend formed by the donation. Of a pov of elretrons from a filled aA ortilal af rofl into the Vaca antibonding 7" exbital @t Carbon. Monoxide. Slabity ef _Co-ordivation Compounds M+ 4b SS My nS w= CMe. /emiees Me + CS MM, Ke = CMlad [ted CLT Mm, + Lo == Ma k= CMta7 /omtces = My Kye = CMT /Mes eq Mag + & Kye Ka Ry one Mepwize Mabitity Constants» Great, emg tmicut By = KX BX Ry hy + @ulbpiative Arolyle => EDTA, Dma © Dinetytgtyordimes rempval Hordes pee ee ai? ce Of wlan Ca R mg se A evra. Tae atin OO ae = een I. Becenn v dm Fastfiation of Mi — [Riccey, J a ayia ee, Hamman Vik Ba > Cyenagatomins Ce “1 momy engyres > Cartenugpeption. A, Carbonk. inhapbocane <7 Wittens Cela Thea), 64] ‘ ® ayetrapration of.

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