JALKENES(OLEFINS) Fa eae QE! Gin # co bybridig-he + Sp™ Shudune + “ “< eA ® Geomeby: planar te (e ae 4 mod, 3) Tk * 3,9 — Peeltion ys ol Ge AT a = a — chatn © g Lrorcers A Gurmebiod Spomenige: (cis) Teams J Ren - Go 4¢| Prepanation MethodePreparation Methodg : Fiver Victnnk_dthabi diy: [6g dehatogenabion] ‘ayhun tao heligin adem pryenk on adjatmb Crtmy” 9 Vicinel Uebady H Reagent: En JAleehel, & lead RViUbak abide +2 SEAT, attcone of 207 w aw Lat = - aa ide eo Alend, = A te me foal + ane ow 2,3- Dibveme_butane From Alyy) Hebicey: — (R-x) [ey Dehydre halegenoken] Pemneh ef Ho ond haligin fie Adjnank c's = CS Ysaee Farre 1 = fod (Fiend Nani 4 Reagmt: — fle KoM * & Climinakio Roa” , Sie He Mo vemeved — fxnn Brconben Rearbivily WIV, _dift Halugens Res > Roby > ROA Reashilg ehh UH lly Grampa: ° a>2- >t +m > >= > = — Rox emi ety ate Bs ctsa_ + Kat Ho 7 + Kd 4 the Bi gubczeme i Malet {22 . fa taka 5 maine 7 ta ees Sy we ko o oH * a Pe (etal U % Faller Soyer ¢ Role 7 Lo Wighly Subetitaled Aiken ig moe ohnble rem Ved Sah bihied Aliicome, Ream: Apdy Hyper Gygetion = 1 J oe — Bufois ove Zaitee'® _Gliminabinr Hakwann _Gltmination ; 3 Small Raye — ale kow = i Rae = £185 fully Bowe D> Smut Raye — ake ko Nanya ens | crhame) Geo? ot From Peleohols By Dekydeahion % Reagents «Come H,sey * Cr. Hg Pay * Poe aH Dy He. cade, kysoy HH Actd Cobelyged dlabydeatin ot Aledhslg ——> Alleere + loge o& Yas HW 4 zi ep Scot oop =e ee _ Ebene try fleshed & Rooetivily ot Aleshe Beo>7. siz: =e > pm > gan | | |e _® 56 p-8) > Tes) >0 = soy” base, @___pretrmation of Aleahel chy edo HS erg SO @_—FermHon of Carbo Cabin eity-etn C2 ® Deprtonation fom ® cy Sy + the Beh + Hasey + use AN kee Erna Craguet OF 0 Ree Ysy ae + HSop Nn OB Sh »shite 2 “oO ay el ie Free Alleynes: By partial Reduction [Cdertted overeune of a) G) Lindlane Red" [entalygt] — —+ (cis Artere J Reagent i a + Pole + sors cable Potion) a auinelve Rg R! a Pllc Ned =¢ ie a FES (ee -Alewre] Yen te = (cis - Geomety ) Ci) Bich Reduchion | —> [Tromp Alene ) Rengeaks Ne) tis-oty a f ~ / “a! 24) ” Trang Allee 4 4 Tyemg —Alkeme I, a Pajc|s _ = a = (ne -cu [TH ) Nia) tip- otemar Ne ee tmy nla] tsp 0 va Sa [nee cit | Tes) Physical Proparky: > q=4 > Gag Canty Mae | prygid stoke feom Gy —? Slits = Salmnlegy | Seed Sonal CEPeve) aden Remaining Alkamy —+ odemlys Sabi: 4 Easflabk tn Mp ¥ Silable in Nowpilan selvents > Be 4 by Pome CF RPT fw Wry ome —eth add” | BP T by do-so kK KL Alkamy — Shrnipht hatin Alltemy awe Mid BP eae Alknws) ” [eee Alkamey Chemical Properties Reartivily: — Allkemey > Alkeooney Reaper i Alicemeg have” pi” bend (sense bed) HK Alicarmuy —* Gladven Rich Speci Cledrephiles Com aHmik om Alkerss ¢ Hum NuRte wmeypming Lam men emo Alkamy = (Rl Glechephilic Add” Rex” Alar peatione: @ AU" ob _Dihydeegem ; (us) ni { Rie ee as nT ‘ (rk) Bee -EsHte ae Allene Alkeme @®_ Add™ of Halogen: (oa) Reivih s R277 OTE deg vat Show nck Nerd Goplegive — Smeothly Cond wo ela gt REE EE TOT” Lvtetnadl atbreme dansentve] ene (Rath } UV [vietned libre Ovenye Ls cnn diphey # Ope i Tat for Ungahnetion Cthea ey Sot siete (naDilon Elane) fot @ Ad? of Wx: > Rearbivt ty of ax; HI > HBy > HU # Aad” of By:# Syn heed Alkeeny : Lies Pos) SHB + By oe Gey ty =O + H=Ry \ wo SL, en hy 9 ~, (= rma bute) # Onsymme tion Alkeney [Ne ae 5 5 . sons Pape ‘'—<— FF ee = Majyw Rule os i chyna =e + RRP cect {es become Rich ts ie Peer becomy Poo By 4 KONE pont 1h added to = bend Corben hey Lag vows ws S port if added ty = bend Canbon hog mere nant H's "echoon eo H-By — Be Gin feline, S coh OH SH we 2S } © iy set = th (28 - cambe carin]) " oy eo 8} Galt of m2, ens 2) en, + 2 city a EHcy Sq ew, + BYP cg “CH, Gg) By [2-Brene propane) mae 2 eo cry -en, a4 + cy ey “th 09 [i-Dveme Propene) 3 Ant Mankevntkev'g Rule i Ge) Peri thet 679 Khenarch ~ mayo Efleck. ec (ate Ae | a Pour becomy Ric 1 Brome _Brpene oiet Face Radical _Mechanigm: HEME [penecl OY Homdlysis ob Pereuice Mashomie mi 5 ° f Grp = OS =o eH eH Bengoyt _perorile Bengt pereutde_Redient SY me Bion + eos — pe @ Berget_ol@& o) co @ Berget_oo pyc fk + cn Gerey pos Her > phon + (aegis) salve By Leese vo. ° cu la tay [0 ee Basten) ae ee {- ety oa me [2° - Fre Padied) ama ite 32> 28 > hls fe Redick stability oy Enea SG, @ ™ cu tat wiley ee oma” yee By By ! ce 7 Y= bse) Reeser: ~~ beth) Chew i¢ Recstble only wilh Hoy bak ne cw God ME wine bead Gregg [Strang Gend} 9 permtde Com't bree [uso ier] te ig CT pork com brenk [5.9 85] fe rents bend porntide Com break (297 B/nd J A HD a w+ tT ver — & [te x We nek righty foe mean ne Alkewe JGaur of 504+ (CAR) Fallang _M-Rale + o 6 Mm Wise encun * ee DD 1 ley ohn a iL ty Pen Sodan Solphete Aad” Ame: (MR) @ prema soy; . NS oe OO we = encom + Nth cy eS Han m SONG Sg, SF, uU ES | “ we} ea wre teneded ao" [rer GS) Depo timate: NYG foe + Ys sy n-@ om Soper Aled ® By Hyde bevation — Oru dation + [1480 => 7 MY —2* oa ) Bade [THE oat S en sa es , R—cH —th ge Ronse wo AN Hae boL®oa 1) fame THE og pence OI a 1%, Joye > @) Hae ons ik (u-en) Ho ow Recut, B= Hy aR am Bao et “en Diallegl berevne Ss BRec~ah-o + BCom, CD H58Q Has oo Aas © canation — DewatnCunakion ratthod: — [tt-Rule] Todi yo oh Reagint: (i) yeah — Mae [ omymercurction] A) nlathy (Reducbion) 60 (Demercurchn) vas@a0, Jae ono f= ‘nln By (4 na) wee eS (bere er, ea fc Bg Gye), AS! =He i men bac ‘ uw coy —cy - th J Aes? ay) ent ee ee GaAs ~ Act tyre cage @ le as x 4 a OB etg-ba spe Nc tc cn Nt5 ; om on 8) cagclo gen FO cg ae ee, ec ae rs) ; ere \, — Bate tHe oe . Mase a Fee Gong a Gah $ Fe) ou Nn bHy mage Reductive cleavage Cornelyaia Zn )ine addition Wier "> ga Conte ay ee eS ee She Ik Chan rd Nae we § En ees ae ie Se =, Seo mcte + Zn Nak No tek + 20 : Acane Polymersgetion an(Menerntn) + Pabyrntr Gtngle uth) (Cw vet onthe) eee es wee wer fanaa eiiaee Plas ame obi Compra aay Mee +0Sane UE feeb coblgtt aa pi Marae osu, =a, fou sea} by i Prepere pay prepene Mest rr On dation HK Baeyer's Reagent 4A ea he —eypad For Teh ob a 2K tae Gaeterasls — Get K Decolmnrigebion ef kvmey Vicined_slinle Nery cg ay —_ propamets* diel CD) + =, “ — ee : I (isan) Hea SP 5 en +h Ny EM a ice ee we Bees