00 [oTcs ON MH/EL] LT!eT Taz 86/10/0T Page 1 of 3 ‘MILLENNIUM PETROCHEMICALS INC. S / ) A MATERIAL SAFETY DATA SHEET SDA 40-2 ANEDROUS MSDS No. ALC_2/147302 Issue Bate DEC 1S, 1995 SRCYION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NOMBER: 147302 PRODUCT DESCRIPTION: SDA 40-2 Anhydrous SwWowENS: Specially Denatured Alcohol SPA 40-2 Anhydrous, Denatured Alcohol, Denatured Eehanol NAME AND ADDRESS: MILLENNIUM PETROCHEMICALS INC. 13500 NORTHLAKE DRIVE P.O. BOX 429550 CINCINNATI, OH 45249 EMERGENCY NUMBERS: PRODUCT INFORMATION: ELLENNIUM (713) 209-7000 PRODUCT APPLECATIONS (600) 543-5900 CHEMTREC = (800) 424-9300 REGULATORY (MSDS) 4513) 530-3057 SECTION 2 - COMPOSITION, INFORMATION OX INGREDIENTS compost Tiox NOMINAL Wr. © EXPOSURE LIMITs* TWA: 1000 ppm Bthy1 Alcohol (Ethanol) CAS RN: 64-17-5 T-Butyl Alcohol on TWA: 200 ppm ~ (?-Butane?) PEL-STEL: 150 ppm CAS PN: 75-65-0 Brucina Sulfate (2:1), 0.04 None Heptahydrate CAS RN: 5787-00. * RXPOSURE LIMITS include ACGIH TLVs and OSEA (vacated) PELs.10/01/1989 FRI 13:28 FAX 1+501+055+8870 Ic CHEM LAB ovs/005 Millennium petrochemicals Inc. ISSUE DATE: DEC 1S, 1995 Page 2 of 9 Product No. 17302 SDA 20-2 ANHYDROUS 5 Bi SECTION 3 - HAZARDS IDENTIFICATION BMSRGENCY OVERVIEW: Clear liquid with alechol oder. Colorless vapor. FLAMMABLE. High vapor concentrations can caure narcotic effects (like dizziness and fatigue). May be irritating to the eyes. PRIMARY ROUTES OF ENTRY: Swallowing, Skin Contact, Rye, or Inhalation. MEDICAL CONDITIONS POSSIBLY AGGRAVATED: Any pre-existing disorders or diseases of the nervous system, liver, gastrointestinal tract, respiratory syatom,akin, and eyes. POTENTIAL HEALTH BFPECTS OF ETHYL ALCOHOL: ETHYL ALCOHOL may cause eye and upper respiratory tract irritation. Short-term overexposure above 1,000 PPM by the inhalation route may suse central nervous syatem (CNS) effects such as headache and ieritation of eyes, nose and throat. If continued for more than an hour further CNS effects may appear such ag: dizzinces, drowsiness, loss of appetite, and an inability to concentrate. Gastrointestinal (stomach) effects may occur vith Buch symptoms as nousea and vomiting. Prolonged or repeated contact may dry okin and cause irritation. Chronic exposure owy result in irritation ef mucous wembranes, headache, and/or oymptoms of CNS depression such as drowsiness and lack of concentzation. Excessive long-term exposure may also produce liver damage, Moderately toxic if swallowed. Also see Toxicological Info. (Section 11) and Ecological Info. (Section 12) SECTION 4 - FIRST AID MEASURES FOR OVEREXPOSURE BY: SWALLOWING: If victim is conscious and able to ewallow, have victin drink water to dilute. Never give anything by mouch if victim ia uncenscious or having convulsions. This product posec a poecible lung aspiration hazard ir it is ingested. Induce vomiting only if advised by physician or Poison Control Centar, CALL A PHYSICIAN OR POISON CONTROL CENYER IMMEDIATELY. SKIN CONTACT: Inmediately flueh affected area with plenty of water while removing contaminated clothing. Wash contaminated clothing before reuse. EYE CONTACT; Immediately flush eyes with plenty of cool water for at least 15 minutes. Do not permit victim to rub eyes. GET MEDICAL ATTENTION IMMEDIATELY./T0/0T 00 (Ores ON MA/KL] LT:eT THE willenniun Petrochomicale Inc. ISSUE DATB: DEC 15, 1995 Page 3 of 9 Product No. 147302 SDA 40-2 ANHYDROUS SECTION 4 - FIRST AID MEASURES (continued) INHALATION: Inmediately zemove victim to fresh aiz. 4€ viccim has etopped branthing, give artificial respization, preferably mouth-to-mouth. GET MEDICAL ATTENTION IMMEDIATELY. SECTION § - FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES: FLSH POINT: $$ deg F¥ 13 deg C) ASTM D-56 (Tag Closed Cup) AUTO-IGNITION TEMPERATURE: 6aS deg F* (363 deg C) FLRIMABLE LIMITS KN AIR, % BY VOL. LOWER: 3,3¢ ‘UPPER: 19" NFPA RATING: HEALTH ( 0)* FIRE (3 )* REACTIVITY ( 0 }* (Does not apply to exposure hazarda other than during a fire.) Xow! OR ANTICIPATED HAZARDOUS PRODUCTS OF COMBUSTION: Carbon monoxide and carbon dioxide can form upon combustion. EXTINGUISHING MEDIA: Use dry chemical. “alcohol resisrane® foam, or carbon dioxide: water may be ineffective, but water applied as a spray can absorb some of the fire's heat and should be used to keep fize-exposed containers cool. FIRE FIGHTING INSTRUCTIONS: (Note - Individuals should perform only those fire-fighting procedures for which they have been erained.) If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spille away from exposures and to dilute : spills to nenflammable mixtures. Firefightere should wear full fixe fighting turn out gear (full Bunker Gear). They should use self-contained breathing apparatus operating in the positive Pressure mode and equipped with full eye protection and a full face piece when there is a possibility of exposure to smoke, fumco or hazardous decomposition products. Bthanol vapors axe heavier than aix and may travel s congiderable distance to a source of ignition and flash back. Alcohols burn with a pale blue flama which may be extremely hard to see under normal ligating conditions. Personnel may only be able to feel the heat of the fire without seeing Flames. Extreme caution must be exercised in fighting alechol fires “for Bure Ethy2 Alcohol10/01/1909 FRI 13:27 FAX 1+501+985+8870 Ic CHEM LAB Boosvoos Millennium Petrochemicals Ine. ISSUE DATE: DEC 15, 1995 Page 4 of 9 Product No. 147302 SBA 40-2 ANHYDROUS SECTION 6 - ACCIDENTAL RELEASE MEASURES ENVIRONMENTAL PRECAUTIONS: Avoid uncontrolled releases of this material, Where spills are possible, a comprehensive spill xeoponse plan should be developed and implemented, ACCIDENTAL RELRASE PROCEDURES: Wear appropriate respizatory protection and protective clothing aa described in Section 8 of the MSDS. Turn off or remove ali ignition nouxces. See Section 5 for further information on handling fire and explosion hazards Contain spilied material. Transfer to secure containers. Woe: necessary, collect ugiag absorbent media. In the event of an uncontrolled release of thie material, the user should determine if the release is reportable under applicable lava and regulations. SECTION 7 - HANDLING AND STORAGE Protect container against physical damage. Detached or outaide aterage is preferred. Inside sterage should ba in an NFPA approved flammable liquids storage room or cabinet. 222 ignition sources should be eliminated. Smoking should be prohibited in storage areas. lectrical inetallations should be in accordance wich article 501 of the National Rlectrical Code. NFPA 30, Flamnable and Combustible Liguids Code, should be followed for all storage nd handling. Frequent careful leakage inspection should be done. Automatic sprinkler system should be provided. Taolate from oxidizers, chemicale capable of spontancous heating, materials reacting with air or moisture to liberate heat, igniticn sources and explosives, Congult local fire codes for additional storage information. Keep packaged material out of oun and away fxom heat. Remove clegure carefully; internal preasure may ba present. Keop closure up to pravent leakage When contents are beiag transferzed, the metallic container must be bonded vo the receiving container an@ grounded to avoid ecatic @iacharges. Never use presoure to eupty. Replace closure securely after each opening. Since emptied containers xetain residual product (vapor or liquid), all precautions described on thie MSDS must be obsezved. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION CONTROL MEASURES: Engineexing controls should bs used whenever feasible to maintain concentrations below accoptable exposure limits (Section 2), ineluaing but not limited co enclosures, local ventilation and dilucion ventilation.00%} Loree ON XU/KL] LT:eT Tad 96/TO/Or Millennium Petrochemicals Inc. ISSUE DATE: DEC 15, 1995 Page 5 of 9 Product No. 247302 SDA 40-2 ANHYDROUS SECTION @ - EXPOSURE CONTROLS, PERSONAL PROTECTION (continued) RESPIRATORY PROTECTION: Where engineering controls are not feasible OF aufficient to achieve full conformance with acceptable exposure Limite (Section 2), use NIOSH/MSHA approved xespiratory pretection equipment. Respirators should be selected bared on the form and concentration of contaminant dn air and in accordance with OSHA (29 CPR 1520-134) / ANSI Stendaxd ZaB.2. PROTECTIVE CLOTHING: Wear gloves and protective clothing which are impervious to this material for the duration of anticipated exposure if there ia potential for akin contact. SYS PROTECTION: Wear safcty classes meeting the specifications of OSHA Z9CPR 1910.223 / ANSI Standard 267.1 where no contact with the eye is anticipated. Chemical safety goggles meeting the spacifications of OSHA 29CPR 1910-123 / ANSI Standard 287.1 should be vorn vhenever there i the possibility of aplaching or other contact with the eyes. SECTION 9 - PHYSECAL AND CHENICAL PROPERTIES BOILING POrRT. MSLTING POINT. VAPOR PRESSURE: 273 deg F* (70 deg c) : 173 deg Fe (-114 dag c) 6 mm Hg ® 68 dag F* (20 deg ©) SPRCIFIC GRAVITY: 0,78 - 0.85 @ 60 deg /60 deg F (26 deg c) VAPOR DENSITY (ATR=1); 1.59+ SOLUBILITY IN WATER: Complete* APPEARANCE AND ODOR: See Section 3 - Emergency Overview. “for Pure Ethyl Alcohol SECTION 10 - STABILITY AND REACTIVITY STABILITY: Generally table HAZARDOUS POLYMERIZATION, Wot likely CONDITIONS & MATERIALS TO AVOID: Contact with acatyl chloride or other oxidizing agenta may result in a violent reaction. HAZARDOUS DECOMPOSITTON PRODUCTS: None expected.Novo1/i999 FRI 13:27 PAX 1+501+955+8870 IC CHEM LAB ooso08 Millenniun Petrechemicais Inc. IsSuz DATE: DEC 15, 1995 Page 6 of 5 Product No, 147302 SDA 40-2 ANHYDROUS SRCTION 11 - TOXICOLOGICAL INFORMATION No data available on this product mixture. Caleulaced Leo (inhi) tor mixture: 5000 ppm Calculated LDSO (skin) for mixture: > 1000 mg/kg Calculated uD50 (oral) for mixture: > $00 mg/kg Note: These values were calculated per the United Nations "Recommendations on the Transport of Dangercus Geoda (8th Revised Edition) " and/or Transport Canada's “Transportation of Dangerous Goods." TOXICOLOGICAL INFORMATION (FROM THE LITERATURE) FOR ETHYL ALCOHOL: Acute Data neSO (inhi) rat: 20,000 ppm/10 hours LDL (skin) rabbic: 20,000 mg/ke psa (oral) rate 7080 mg/kg uphe (oral) human: 1400 mg/kg Irvitation Data (rabbit) Standard Draize Test Skin: 20 mg/24H, Reaction: Moderate Bye: 500 mg/24H, Reaction: Mild ‘Yerategenicity: No evidence of teratcganicity (birch defects) vas noted following inhaletion exposure by pregnant rats of airborne vapor concentrations of up to 16,000 ppm for 7 hour on days 1-9 of geatarion. In the came study, pregnant rate exposed to 20,000 ppm ohowed severe narcosis; offspring of these rats did nor show clear evidence of increased incidence of sbnormaliti OSHA TOXICITY LEVELS Toxicity Level C50 Inhalation Rat DSO Skin Rabbit -LDS0 Oral Rat (2-hour) (gases or vapozs) (24-hour) Wighly Toxic Lees than oz Less than or Less than or Equal to Equal to Equal to 200 ppm 200 mg/kg 50 mg/kg Toxie Greater than Greater than Greater then 200 ppm ana 200 mg/kg and 50 mg/kg and Less than or Leas then or Less than or quel to qual to Equal to 2000 ppm 1000 mg/kg S00 mg/kg Note: This table was constructed based upon information from Appendix A of the OSHA Havard Communication Standard, 29 CFR 1910.1200.00@) (Ores ON XH/KL] LTieT THA a8/To/or Millennium Petrochemicals Tne. ISSUE DRE: DEC 15, 1595 Page 7 of 9 Product No. 147202 SPA 40-2 ANHYDROUS SECTION 22 - ECOLOGICAL INFORMATION Mo daca available on thie preduct mixturs ENVIRONMENTAL FATE INFORMATION (FROM THE LITERATURE) FOR ETHYL ALCOHOI Wuen spilled on the land ethyl alcohol is apt te volatilize, biodegrade, and/or leach inte the ground water. It is anticipaced based on physical properties of ethyl alechol including water solubility, vapor pressure, and octanel/water coefficient (log Ps 70.31) that wecer will serve as the terminal media. Based on these factors it ie anticipated thet this substance will neither adsorb to soil nor bioconcentrare in aquatic organisms. Once in water Photolysie, oxidation, hydzolysia, and biodegradation ia anticipated to occur. RCOTOXICITY DATA (FROM THE LETZRATURE) FOR BIHYL ALCOHO! Fish: Static and/or flow-through 1c50(96-br)= 13,000-25,300 ma/1 ECOTOXICITY TEVELS Hazard Parameter nigh Middle Aquatic acute Zese chan or Greater than 3 Greater than Toxicity (mg/1) qual to 2 and Lees than or 00 Equal ce 100 * This parameter (static or Zlow-through) applies to test results for the following: 96-hour L050 (fish), 48-hour KCSO (invertebrates), and 96-hour ECS0 and/or IC50 (algae). Nove: This table is adapted from one which appears in "Environmental Toxicology and Risk Agsessment", ASTM STP 1179, p. 34, 1993. SECTION 13 - DISPOSAL CONSIDERATIONS Information provided in this Material Safety. Data Sheet applies only to the product a9 manufactured by Millennium Petrochemicals, Processing, use, and contamination may make this information inappropriate for the material requixing disposal. State and local laws and regulations may differ from federal requirements, and requirements may change or be re-interpreted it is the responsibility of the waste generator to characterize waste streams relative to the pertinent regulatory provisions {including RCRA "characteristic" waste definitions 40 CFR 261 Subpart C) to ensura ‘that10/01/1989 FRI 18:27 FAX 1+501+955+8870 IC CHEM LAB foo2/005 Millennium Petrochemicals Inc. ISSUs DATE: DEC 15, 1995 Page 8 of 9 Product No. 147302 SDA 40-2 ANHYDRcUS: SECTION 13 - DISPOSAL CONSIDERATIONS (continued) applicable requirements are reviewed and met. SECTION 14 - TRANSPORTATION INFORMATION DEPARTMENT OF TRANSPORTATION (DoT) : DOP Hazara Class: Class 3 - Flammable Liquid bor Proper Shipping Name: Denatured Alcohol, Other DOT information: Zdentification No, NA1ge7 Packing Group II Emergency Response Guide No. 127 For further information see Title 49, Code of Federal Regulations, parte 172 and 173 SECTION 15 - REGULATORY INFORMATION TOXIC SUBSTANCES CONTROL ACT (TSCA) This product is (or if a mixture, the components of this product are) lieted in the TSCA inventory of Chemical Substances. SARA TITER XT (SECTIONS 312/312) HAZARD CATEGORIES: Inmediate/Acute, Dalayed/Chronic, Fire one or more of the components of this praduct is associated with the nealtn hazard(s} lioted above, Since in most cases we have no data on the mixture and this component (s) is present at greater than 0.1 or 1.0 percent, we are conservatively assigning this hazard(s) te cur product. APP DISTITLED SPIRITS ACT: Use of ethyl alcohol without prior payment of applicable excise tax is strictly controlled by regulations promulgated and enforced by the Bureau 9f Alcohol, Tobacco and Firearms, Dept. of the Treasuzy. Governing regulations have been defined in Title 27, Code of Federal Regulations. COMPONENTS OF POSSIBLE REGULATORY SIGNIFICANCE; can SARA 223 Prop 65 Component, CAS EN Amount =— = Lieted - listed othert200@) (ores ON MU/RL] ATCT TUX 86/To/oT willennium Petrochemicals Ine. ISSUZ DATE: DEC 15, 1995 Page 9 of 9 Product No. 187302 SDA 40-2 ANHYDROUS SECTION 35 - REGULATORY INFORWATION (continued) Ethyl Alcchol 6417-5 99.9 & o vo Yeo T-auty] Alcohol 75-65-00 Oe Yen No Yes Bensone 74-43-2<0.5 ppm Yes Yee Yee * ‘This category applies to a chemical if listed on one or mora of the following additional regulatory liste: NJ and/or PA Right-to-Know; NTP Carcinogeas; IARC Carcinogens Groups 1, 2A, or 2B; ACGIH TLVs; OSHA 29 CFR Part 1910, Subpart 2; WHMIS IDL; CRRCLA Haeardous Substances; SARA 302 EHSs; and TSCA 12(b) . WARNING) This product contains (or may contain) a chemical (or chemicale) known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16 - OTHER TRFORMATION FOR INDUSTRIAL USE ONLY. NOT FOR HOUSFHOLD USE. NOT INTENDED OR PERMITTED FOR DRINKING BEVERAGE PURPOSES. ‘The information presented herein has been obtained from sources believed to be reliable. The information in Sacrion 11 (Toxicological Information), 12 (Reological Information), and 15 (Regulatory Information) represents selected data which Millennium Petrochemicals Inc. believes may be pertinent for the use of this material, Fovever, because of the possibility of human or mechanical exror by our sources, Millennium Petrochemicals Inc., or others, Millenium Pecrochomicals Inc. does not guarantee the accuracy, adequacy or completencas 92 any information, and is not responsible for any exrore or omissions ox for any reaults obtained from use of such information, We accume no liability or responsibility, express or implied, for exrors or omiseione of any kind, and no warranties of merchantability or fitness, express or implied, are made or are to be implied. Consaquently, you should review the information to Gevermine whether ie ig adequate and appropriate to all aspects of your intended use of thie material. ISSUE DATE: DRC 18, 1995 SUPERSEDES: MAR O1, 1999