Name _____________________

Chem 222 Physical Chemistry II

Exam 4
Spring 2022
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et
Good luck!

 ∂T   ∂P 
U TdS − PdV
dU =  = −

he
 
 ∂V  S  ∂S V

 ∂T   ∂V 
H=
U + PV dH =
TdS + VdP   =  
 ∂P  S  ∂S  P

rS
 ∂S   ∂P 
A = U − TS dA =
− SdT − PdV   = 
 ∂V T  ∂T V

 ∂S   ∂V 
G=
H − TS dG =
− SdT + VdP   =− 
 ∂P T  ∂T  P
G= A + PV

 ∂ ln Q   ∂ ln Q  e
ov
U = −  =kBT 2  
 ∂β  N ,V  ∂T  N ,V

U
S= + k B ln Q
T
C

1
β=
k BT
4

qN
Q = qN Q=
N!
ln N ! N ln N − N
=
am
Ex