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Soils form the skin of the Earth. Their thickness varies from a few millimetres – there where the
soil is very young or scraped-off by external forces (e.g. water, wind, human activity) – to
several metres – there where they occur in protected or stable places. They comprise of layers or
soil horizons, each with their own characteristics. Soil material consists of a variable and often
complex mixture of organic matter, sand, silt and clay particles, or is composed of dominantly
organic debris.
Soils are formed under the influence of climate, the material they occur on, the flora and fauna
(including human activity), the topography of the terrain, and time. These five factors are
commonly known as the Soil forming factors.
Functions of soil
Soil is our life support system. Soils provide anchorage for roots, hold water and nutrients. Soils
are home to myriad micro-organisms that fix nitrogen and decompose organic matter, and armies
of microscopic animals as well as earthworms and termites. We build on soil as well as with it
and in it
Soil plays a vital role in the Earth’s ecosystem. Without soil human life would be very difficult.
Soil provides plants with foothold for their roots and holds the necessary nutrients for plants to
grow; it filters the rainwater and regulates the discharge of excess rainwater, preventing flooding;
it is capable of storing large amounts of organic carbon; it buffers against pollutants, thus
protecting groundwater quality; it provides Man with some essential construction and
manufacturing materials; it also presents a record of past environmental conditions
Soil functions are general capabilities of soils that are important for various agricultural,
environmental, nature protection, landscape architecture and urban applications. Six key soil
functions are:
Soil formation starts by desintegrating the rock under the influence of climate. Rainwater will
dissolve rock elements, temperature fluctations will cause differential expansion and contraction
of rock-forming crystals, and the freezing and thawing of water captured in the rock will widen
existing cracks and cavities. Pioneer vegetation, at first lichens, will settle and their roots will
further loosen the rock. Moreover, decaying plant debris will produce organic acids, which
further attack the rock. Organic matter will start to accumulate and be mixed with the mineral
material provided by the rock. A soil is born.
Over time, rock minerals will be dissolved or transformed. Elements released from the rock will
precipitate and new minerals may be formed. For example, iron will be oxidized and precipitate
as iron oxides or hydroxides, giving the soil reddish or yellowish-brownish colours. Soil fauna
will settle and mix (‘homogenize’) the soil. The soil will grow in depth through newly formed
soil material at the bottom. The soil matures.
Given sufficient time under stable environmental conditions, soils will reach a steady state,
whereby soil build-up matches their breakdown. Production of humus from decaying
vegetational debris will equal its consumption by soil microbae, fauna and flora. Transformation
of rock minerals into soil minerals will keep pace with the removal of earlier formed soil
minerals. Slow surface wash of topsoil is matched by new formation of soil material from the
bedrock. The soil has aged.
Dramatic events can interrupt the life cycle of soils. A soil may be covered suddenly by a
volcanic eruption or by submergence under water. They may disappear in part or altogether by
water or wind erosion.
On steep slopes the newly formed loose soil material will be removed fairly easily by runoff of
rainwater or gravitational forces. Therefore, soils in mountainous regions are often shallow. On
footslopes and in more level areas soil material will accumulate and this leads to deeper soils.
Components of soil
Soil Components: Soils consist of four major components:
(1) mineral (or inorganic),
(2) organic,
(3) water and
(4) air.
The relative proportions of these four soil components vary with soil type and climatic conditions. Review
the approximate proportions (by volume) of the four soil components in a mineral soil under optimum
conditions for plant growth.
1. Mineral Components
Mineral particles are inorganic materials derived from rocks and minerals. They
are extremely variable in size and composition.
1.1.Composition
Primary minerals are formed at high temperature and pressure, under reducing
conditions without free oxygen. These minerals are mainly present in soils as sand
and silt particles. They are not crystallized and deposed from molten lava.
1.1.2. Weathering
Biological Weathering
The median and range of various elements present in soils from around the world
are given in Table 1. The elements that are found in soils in the highest quantities
are O, Si, Al, Fe, C, Ca, K, Na, and Mg. These are also major elements found in
the Earth’s crust and in sediments. Oxygen is the most prevalent element in the
Earth’s crust and in soils. It comprises about 47% of the Earth’s crust by weight
and more than 90% by volume.
Particle density () is mass of solids (Ms) per volume of solids (Vs).
= Ms/Vs
In most mineral soils the mean density of the particles is about 2.6-2.7 gm/cm3 (or
2600 - 2700 kg/m3). Soils with a high content of iron oxides and various heavy
minerals have a particle density of 5.2-5.3 gm/cm3, while soils with high organic
matter content can have a particle density as low as 1.3 gm/cm 3.
Bulk density (b) is the mass of solids (Ms) per total soil volume (Vt).
b = Ms / Vt
Bulk density is always smaller than rs. Since in a general case pores constitute
half the volume, rb is about half ofrs, namely 1.3-1.35 g/cm3 (or 1300-1350
kg/m3).
Volume Density: Animation is to illustrate relationships among the weight and
volume of soil air, water, and solids
The mineral particles present in soils vary enormously in size from boulders and
stones down to sand grains and minute clay particles that cannot be seen by an
optical microscope. An arbitrary division is made by size-grading soil into material:
a) that passes trough a sieve with 2-mm diameter holes - the fine earth
(consisting of sand, silt, and clay particles),
b) that is retained on the sieve (> 2 mm) - the coarse fragments (gravel, cobbles,
and stones).
Coarse fragments (diameter > 2 mm) are defined as rock fragments and do not
include fragments of pads or concretions.
Soil texture refers to the relative proportions of sand, silt, and clay in a soil. It is
often the first and most important property to be determined when describing a
soil, since many conclusions can be drawn from this information (water intake or
infiltration, water storage in the soil, soil aeration, soil fertility, trafficability, etc.).
Textural names are given to soils based on the relative proportions of each of the
three soil particles - sand, silt, and clay. Soils that contain predominantly clay size
particles are called clay (textural class), those with high silt content are called silt
(textural class), and those with a high sand content are called sand (textural
class). A more complicated soil textural class that is called a loam is a mixture of
sand, silt, and clay particles and it exhibits the properties of those particles in
about equal proportions.
When suspended in water, colloids do not readily settle out due to Brownian
motion (when particles are moved around by collisions with other small particles).
In chemistry, colloids where particles smaller than 0.001 mm (or 1 m), but it has
been observed that soil particles smaller than 0.002 mm (or 2 m) still behave in
the same manner, hence they are called soil colloids.
2) Oxides and hydrous oxides of iron and aluminum (e.g., gibbsite, goethite,
hematite)
4) Organic colloids
Two types of phyllosilicate clay minerals that are commonly present in soils are
montmorillonite and kaolinite.
Kaolinite Diagram
Imogolite and allophane are minerals found in many soils including soils formed
on volcanic ash parent material and Podzolic soil type. They are very small (about
2 nanometers in diameter) and a very reactive component of soils.
Imogolite and allophane are amorphous, which means that they do not have a
repetitive structure with atoms arranged in a regular pattern over relatively long
distances (at least tens of nanometers). Because their structure is somewhat
ordered on a few nanometers scale, they are said to be 'paracrystalline' or to have
'short range order'.
Imogolite and allophane are both aluminosilicates, which means that they are
made of variable amounts of aluminum (Al), silicon (Si), oxygen (O), and hydrogen
(H) ions. They have a rather similar composition but their morphology is different.
Imogolite forms tubes while allophane forms hollow spheres:
Specific surface area is defined as the surface area of particles per unit mass or
unit volume of particles. Because of their large size, sand particles have small
specific surface area (e.g., 0.1 m 2/g). Clay particles, on the other hand, have a
very large specific surface area, giving them a tremendous capacity to adsorb
water and other substances (e.g. 10-1,000 m2/g).
SOIL COMPONENTS
Soil Components:
INTERACTIONS AMONG SOIL
COMPONENTS
2. Organic Components
NUTRIENT CYCLES
Soil organic matter (SOM) can be of plant, animal, or microbial origin and may
be relatively fresh or highly decomposed and transformed. In this course, terms
�soil organic matter� and �humus� are considered synonyms.
One of many definitions of soil organic matter states that �it is a complex and
rather resistant mixture of brown or dark brown amorphous and colloidal organic
compounds that result from microbial decomposition and synthesis and has
chemical and physical properties of great significance to soils and plants�.
Many species of fungi and bacteria soil particles decompose soil organic matter.
The fungi and bacteria that can break down the woody tissues and cellulose of
intact leaves, stems and dead roots of plants perform the function of
decomposition of organic matter that often builds humus and returns nutrient
back to the soil. When the species that are capable of decomposition are
lacking, leaves and other organic matter remain intact and the food energy they
contain are not released to drive the foodweb.
Soils may vary greatly in their organic matter contents. For example, a typical
prairie grassland soil (Chernozem) may contain 5-6% SOM (by weight) in surface
horizons, sandy desert soil may have <1% of SOM, while Organic soils (by
definition) contain >30% SOM (by weight).
A simple test that allows qualitative comparison of soil organic matter content
Organic matter is an important soil component because it:
a) holds soil particles together and stabilizes the soil, thus reducing the risk
of erosion;
b) aids crop growth by improving the soil's ability to store and transmit air
and water;
c) stores and supplies many nutrients needed for the growth of plants and
soil organisms;
SOM includes primary components that are inherited from plant and animal
residues entering the soil. Primary components are sometimes referred to as
non-humic substances. These compounds are relatively easily decomposed by
microorganisms and they persist in soil for a brief time (e.g. several months or
years). They make about 20-30% of total SOM. These include
carbohydrates and several derivatives (monosaccharides, and
polisaccharides such as cellulose, hemiscellulose)
amino acids and several derivatives (proteins)
lignin (condensed polyphenil-propane structures of extremely large
molecular weight, very resistant to microbial decomposition)
lipids (a class of organic compounds which is a convenient analytical
group rather than a specific type of compound. They include fats, oils,
waxes, phospholipids, and resins)
a variety of other compounds.
RELATED LINK:
Agricultural University of Wroclaw
Non- humic substances characteristics
Detailed characteristics:
http://www.ar.wroc.pl/~weber/no.htm
SOM also includes secondary compounds, compounds formed within the soil by
breaking down organic structures and synthesizing new ones. The secondary
components include carbohydrates, amino acids, lipids and others, more or less
resembling many primary components. In addition, secondary components also
include humic substances, which are rather different from most primary
components.
Humic substances can be classified based on their behavior in acids and bases.
There are three general groups of humic substances: (1) fulvic acids, (2) humic
acids, and (3) humin. These three groups are nondescript mixtures of many
chemical compounds and should not be considered as distinct chemical entities.
Humins are particles with large molecular weight, relatively small specific surface
area, relatively low number of carboxyl groups, and are inactive.
Humic acids are smaller in size then humins (approximately colloid-sized) and
have more carboxyl groups than humins.
Fulvic acids are the smallest in size among humic substances, and have a large
number of carboxyl groups per unit mass. For this reason they are the most
active among humic substances.
The humic substances posses carboxyl groups (*R-COOH), which give them their
acidic character and make them effective in buffering soil pH:
R-COOH ↔ R-COO- + H+
The percentage of the humus which occurs in the various humic fractions varies
considerably from one soil type to another. The humus of forest soils is
characterized by a high content of fulvic acids while the humus of peat and
grassland soils is high in humic acids (see figure). The humic acid / fulvic acid
ratio usually, but not always, decreases with increasing depth.
RELATED LINK:
Agricultural University of Wroclaw
Properties of humic substances
Detailed characteristics:
http://www.ar.wroc.pl/~weber/kwasy2.htm
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SOIL
COMPONENT Soil Components
S
INTERACTIO
NS AMONG
SOIL
3. Soil Water
COMPONENT
S
NUTRIENT 3.1 Soil Water Content
CYCLES 3.2 Soil Solution
SOIL
CLASSIFICAT 3.3 Soil Water Flow
ION
SOIL
3.4 Qualitative Description of Soil Wetness
MANAGEMEN
T
SOIL Water is the major transport agent for fluxes within and between terrestrial ecosystems. It is a
ORGANISMS prerequisite for all active life, and participates in geochemical cycles by weathering geological
substrates, by leaching materials to groundwater and by moving ions and particles through the
soil profile.
Soil water is part of the global hydrological cycle, which shows how water that falls as
precipitation returns to the atmosphere through transpiration and evaporation. On a local scale,
how well the soil stores water is of great importance to crop production and the vitality of the
land.
Hydrological Cycle
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SOIL COMPONENTS
INTERACTIONS AMONG Soil Components:
SOIL COMPONENTS
NUTRIENT CYCLES
SOIL CLASSIFICATION
SOIL MANAGEMENT
4. Soil Air
SOIL ORGANISMS
Soil pores, the voids between minerals, organic matter, and living organisms, are filled
with air or water. There is a dynamic equilibrium between water and air content within
a soil. When water enters the soil, it displaces air from some of the pores.
The composition of soil air is different from that of the atmosphere because it cannot
readily mix with air above the soil. The metabolic activity of plant roots, microbes and
soil fauna all affect the composition of soil air. For example, the concentration of
carbon dioxide (CO2) in soil (between 0.3 and 3%) is often several hundred times
higher than the 0.03% found in the atmosphere. In extreme cases oxygen can be as
low as 5-10%, compared to 20% in the atmosphere. Soil air has a higher moisture
content than the atmosphere, with relative humidity approaching 100% under optimum
conditions. (humidity is not as variable in soil as it is in the atmosphere). The amount
and composition of air in soil are dynamic and to a large degree are determined by
water content and activity of soil organisms.
CO2 chambers
CO2chamber is used to measure soil's respiration
Source: UBC Biometeorology Group
Faculty of Land & Food Systems
CO2 chambers
The exchange of gases between the atmosphere and soil is facilitated by two
mechanisms:
1) Mass flow (convection) of air - the moving force is a gradient of total gas
pressure, and it results in the entire mass of air streaming from a zone of
higher pressure to one of lower pressure. Mass flow of air is much less
important than diffusion, except perhaps in layers at or very near the soil
surface.
The oxygen flux density due to diffusion is proportional to the oxygen concentration
gradient along the axis, and the proportionality factor is called the (oxygen) diffusion
coefficient (D). This statement is an example of Fick�s Law of Diffusion, which can
be expressed as follows:
where J is the diffusive flux density of the gas (oxygen in this example) (mg/m 2/s)
along the x-axis, C is oxygen concentration in the soil air (units are g/m 3), x is distance
along x-axis (m), dC/dx is the oxygen concentration gradient (g/m 4), and D is the
(oxygen) diffusion coefficient (m 2/s).
The oxygen diffusion coefficient (D) for diffusion in air is about 10,000 times as large
as the coefficient for diffusion in water. Thus the oxygen diffusion coefficient (D) of a
soil is very strongly influenced by three factors:
1) air-filled porosity (Va/Vt), which decreases with increasing soil water content
2) the continuity of air-filled pores, which decreases with increasing soil water
content
3) the tortuosity of air-filled pores, which increases with increasing soil water
content.
Growth of most plants and survival of their roots normally requires maintenance of
adequate soil oxygen. This in turn requires maintainance of soil water well below
saturation, to enable rapid gas diffusion in the soil.
Soil porosity (f) is the ratio of pore volume (Vf) to total soil volume (Vt)
f = Vf / Vt
It is generally between 30-60%. Porosity tells us nothing about the relative amounts of
large and small pores, and should be interpreted with caution. Generally, high porosity
(e.g. 60%) is an indicator of lack of compaction and good soil conditions.