EQUIMOLAR COUNTER DIFFUSION

1 2

Diketahui :

Tangki 1 : Tangki 2 :
Fase : Gas Fase : Gas
Komp. : NH3 Komp. : N2
PA1 : 10130 Pa PA2 : 5070 Pa

DAB = 0.000023 m2/s

Z1 = 0m
Z2 = 0.1 m
DZ = 0.1 m
P = 101320 Pa
T = 298 K
R = 8314

Ditanya : a. Flux J*A steady state

b. J*B

Jawab :
a.

= 4.697341E-07 kg mol A / s. m2

b.
PB1 = P - PA1 = 91190 Pa DBA = 0.000023 m2/s

PB2 = P - PA2 = 96250 Pa

-4.697341E-07 kg mol B / s. m2
= DAB
DIFFUSION THROUGH STAGNANT

B = Pure Air

A = Water

Ditanya : Rate of evaporation ( diffusion water to air) at steady state ?

Jawaban :

PB1 = P - PA1 = 0.976921 atm

PB2 = P - PA2 = 1 atm

= 0.988416 atm
= 1.17E-04 lb mol/h.ft2
Diketahui :

Temp. = 293 K = 20 oC = 68 F = 528 R

P = 1.01E+05 Pa = 1 atm
DZ = 0.1524 m = 0.499994 ft
DAB = 2.50E-05 m2/s = 9.69E-01 ft2/h

Dari Appendix A.2-2 Geankoplis, untuk nilai vapor pressure water pada 20 oC = 17.54

Sehingga :
PA1 = 0.023079 atm = 2338.474 Pa
PA2 (pure air) = 0 atm
R = 0.73 ft3.atm/lb mol .R
mmHg
ESTIMATION OF DIFFUSITIVITY OF

Diketahui :
Komp. A = Etanol
Komp. B = Methane
MA = 46.07 g/mol
MB = 16.04 g/mol

Jawaban :

S VA = 50.36
S VB = 24.42

a). Pada P1 = 1.01E+05 Pa = 1.00E+00 atm

T1 = 298 K

DAB P1T1 = 1.43E-05 m2/s

Pada P1 = 1.01E+05 Pa = 1.00E+00 atm

T2 = 373 K

DAB P1T2 = 2.11E-05 m2/s

b). Pada P2 = 2.03E+05 Pa = 2.00E+00 atm

T1 = 298 K

DAB P2T1 = DAB P1T1 x PA1 = 7.13E-06 m2/s

PA2
DIFFUSION THROUGH STAGNANT IN LIQUID
Diketahui :
A =
B =
DAB =
DZ =
MA =
MB =
Ditanya : r1 =
The Flux of HCl ? r2 =
CA1 =
Jawaban : CA2 =
CB1 =
Asumsi jumlah larutan campuran = 100 kg =W CB2 =

XA2 = CA2/MA = 6 / 36,458 = 0.0306

CA2/MA + CB2/MB 6 / 36,458 + 94 / 18,02

XB2 = 1 - XA2 = 0.969416

XA1 = CA1/MA = 12 / 36,458 = 0.0631

CA1/MA + CB1/MB 12/36,458 + 88/18,02

XB1 = 1 - XA1 = 0.936856

M2 = W = 100 = 18.584 kg/kg mol

CA2/MA + CB2/MB 6 / 36,458 + 94 / 18,02
W = 100 19.184 kg/kg mol
M1 = CA1/MA + CB1/MB 12/36,458 + 88/18,02

= 55.365 mol/m3

= 0.953043173
= 2.36E-06 kg mol/s.m2
HCl
H2O
2.50E-09 m2/s
2 mm = 0.002 m
36.458 g/mol
18.02 g/mol
1060.7 kg/m3
1030.3 kg/m4
12 wt %
6 wt %
88 wt %
94 wt %
ESTIMATION OF DIFFUSIVITY LIQUID

Diketahui :

T = 293 K = 20 oC

µ H20 = 1.01E-03 Pa.s

j = 2.6 for water solvent

DIFFUSION METHANE THROUGH HELIUM

Diketahui :

Temp. = 298 K
P = 1.01E+05 Pa
DZ = 0.1 m
DAB = 6.75E-05 m2/s
PA1 = 1.40E+04 Pa
PA2 = 1.33E+03 Pa
R = 8314.34 m3.Pa/kgmol.K
PB1 = P - PA1 = 8.73E+04 Pa
PB2 = P - PA2 = 1.00E+05 Pa

Jawaban :

= 9.35E+04 Pa

= 3.74E-06 kgmol A/s.m2

460 R