oh CALORIMETRY 3 ai In an experiment, 0.750 g of benzene (CeHs) were completely bumed in air. The heat evolved raised the temperature of 200 g of water by 43.7°C. Use this data to calculate the enthalpy of combustion of benzene (the ‘specific heat capacity of water is 4.18 J g" K”). Dy ROAR te BREA ANE KAZ T=... 20S33.T, nse Clete 2 OF 1 OP ELS. At 2 BOS BB Fo EB EOO. Me Toney Las. P.COAGIS. 7 a) (60 108) 25.0 cm? of 2.00 mol dm* hydrochloric acid was added to 25.0 em of 2.00 mol dm ammonia solution, The temperature ose by 12.4°C, Calculate the enthalpy of neutralisation for ths reaction. Assume that the density of the solution is 7.00.9 em” and the specific neat capacity of the solution is 4.18 3g K" Dp FO CAM ik Se MOAB MDM SAR. TD neh. AEA, PER Pt OP. OS OR. ase ORR NOL 2 RD Mi AOD Ho AOSD. SKA Hd RC ., . Ath ce AB SIRE SAB eT met). CBSO. 2: 9520. ou 6 (B50 169) ‘When 0.500 g of powdered ron is added to 100 cm’ of 0.200 mol dmi* copper sulphate solution in an insulated vessel, the temperature rises by 3.3°C, Fo(s) + CuSO,(aq) -+ FeSOx(aq) + Culs) 2) Why is theron aed a a powcor? YZ longget. surtese..ccem, Mand BHA CANAD. a b) Calculate the heat evolved in the reaction. The specific heat capacity ofthe solution can be taken as 4.18 J a” and the heat capacity ofthe iron can be ignored. OF ONAN VR ABM BBB ARIAS. @ ) Calculate the numberof moles of ron and copper suiphate, and so sale which reagents in excess? ON PPE fF OBE, nh CASS RE 022 OREO so CASOKAE ADE KES. : : @ 4) Coleuate the enthalpy change forthe reacton. ; Abb Fo BERT conto ESOT 9 (23k). 0: O88Ale. Cavede 33°C) @ Goer 0 © www.CHEMSHEETS.co.uk 26-Jun-2015 ‘Chemsheets AS 10494a) Write an equation to represent the al of butan-1-0l(CsH:OH(). CHH@QAWD.. GOUM.. 3. ACO... Stl19.0. o ) A simple flame calorimeter was used to measure the AH? of butan-t-ol. 0.600 g of butan-tol was burned in a ‘simple lamp bumer under a container of water. There was 250 g of water in the container and its temperature rose by 19.4°C. Using the specific heat capacity of water as 4.18 J g" K”, calculate the enthalpy of combustion of butan-1-0l. FOREN 0 RSD. A NB MINA AOI. eae. CAM 9 OE Bb Oe POBIOB, AW. Fo EI AIR, Fico SOS te Tone. BSD. 6.025198 : = ® ieaor 17) 5 When20.0 of ammonium nitrate dissolves in 2:50 cm® of water, the temperature falls by 5.0°C. Calculate the enthalpy change of solution of ammonium nate (.e. the enthalpy change when one male of ammonium nitrate dissolves). Apt AD GK Fins 2S OM ASE Sa An SASF, ONS SIMI EO HB Be OP RSS AO AE ARIE Bd eT nae (ashen. S80) OcnSe. « ‘wa0- 17) 6 When 0.400 gof calcium reacts with 100 cm* of 2.00 mol dm hydrochloric acid, the temperature rises by 12.0°C. “The equaltio? for the reaction is shown below. The specific heat capacity ofthe water is 4.18 J mor! K* Cals) + 2HCKaq) + CaCiaq) + Ha) 2) Calculate the heat released inthe reaction a a Foun. @) 'b) Calculate which reagent is in excess. “ SO AER ROO. RSTO. 0.200 Bo AAR I i SAA EP OLD ON AER. COBY, ONE AACA. (3) ©) Caleulate the enthalpy change fortis reaction per mols of calcium reacting. Av rE SMe, .0:9948.... Fi SOB NT. 000% CBs, @ (@0F 180) (© www.CHEMSHEETS.co.uk 26-Jun-2015 Chemsheets AS 1049