HUNAN YIXIANG

Farida BIPB-96
1. 产品与企业标识
产品标签名称 : 双叔丁基过氧异丙基苯
供应商：
湖南以翔科技有限公司
电话 : 86 (020) 39966769
传真: 86 (020) 39966759
紧急电话
Tel: +86-020-39966769（24 小时）
用途
交联剂
最后一期日期/修订版本号
化学族
2016/04/01

有机过氧化物
2. 危险概述
可能起火。
3. 成分/组成信息
有害成分信息
化学描述 双叔丁基过氧异丙基苯，结晶状粉末
成分组成信息
序号 CAS 号码 化学名称
双叔丁基过氧异丙基苯
% w/w
1 >=96% 025155-25-3

4. 急救措施
必要的急救措施描述
一般情况
如有疑问或者症状持续时，就医。
吸入
迅速移至空气清新处。如没有呼吸，进行人工呼吸。可额外增加氧气，可能时由受过培训的人员提供。 出
现症状时，进行诊治。
皮肤接触
脱去被污染的衣物，用肥皂和清水冲洗。若皮肤有出疹现象，立即就医。用大量水进行冲洗。如刺激产
生并且持续，应就医。衣物重复使用前请清洗。彻底清洗或销毁受污染的鞋子。
眼睛接触
立即用大量清水冲洗。在冲洗时由受过训练的人员取下隐形眼镜。冲洗时不时抬起眼睑，确保用水冲洗
到整个眼球及眼睑表层部分。如刺激产生并持续，应就医。
吞入
立即咨询医生或毒物控制中心，必须在医务人员指导下立即进行催吐。病人应在呕吐时应向左侧卧，降 低
呼吸危险。对于无意识或者痉挛的病人，不得通过口部输送任何物品。
对医生的建议
无治疗该疾病的资料，通常被认为是暴露而加量。主治医师应治疗出现症状的暴露病人。
5. 消防措施
灭火介质
水雾、泡沫、沙土、化学干粉、二氧化碳
Page 1 of 5
 HUNAN YIXIANG

不适合的灭火介质
卤化物
危险分解/燃烧产物
二氧化碳、一氧化碳、叔丁醇、甲烷、丙酮、二乙酰基苯。 防
护设备
消防人员必须带上防火的个人保护装置，使用良好的呼吸器和防护手套。
其他
疏散所有非必需人员，小火：用干粉和二氧化碳灭火器扑灭。然后撒水防止复燃，用水冷却封闭的容器。
用于灭火的水不允许进入排水系统和水道。发生火患后，让该区域完全通风，并用肥皂水清洁墙壁和金
属表面。
有火灾或爆炸危害
注意：可能再次燃烧。在加热的情况下会自动分解（参见第 5 章加热分解/或燃烧时产生的有害产物） 如
果发生火患此物质可能会助燃。如发生火灾或爆炸不要吸入烟尘。
泄露应急处理
个人防护措施
6.

不要吸入烟尘。见第 8 章个人防护。
环境预防措施
不得进入排水管或河道。
抑制或清除溢出物的方法和材料
可能时，阻止泄露。清除所有火源，且不要引起火花或者火焰。扫除干净后放入容器中待处理。避免产 生
粉尘。保持潮湿。废弃物不应被封闭起来。用大量的肥皂水冲洗环境。
其他
注意：可能再次燃烧，将人员疏散到安全地点。
7. 操作处置与贮存
安全操作的注意事项
不要在仓库内称量，以避免污染或者被污染，使用时不要进食、饮酒或抽烟。勿吸入粉尘。在通风良好
的区域进行操作。移去所有点火源，且不可产生火花火焰。远离还原剂（如胺类）、酸类、碱类及重金属
化合物类（如干燥机、加速剂、金属脂肪酸盐）。使产品远离热源及火源。必须避免封闭和不相容物（见
第 10 章）。
火患和爆炸的预防
避免产生粉尘。即使容器是空着的，也不要在容器上或者容器附近进行切割或者焊接。安
全贮存的条件
按国家/地方规章贮存。远离食品、饮料及动物饲料。贮存在干燥、通风且远离热源或阳光直射的地方。 与
其他化学品分开储存。只装在原装容器里。
贮存
为保证质量，贮存温度应低于 30° C.
其他
建议使用 T3 温度组的电器设备，但不排除自燃的可能性。操作或接触后彻底洗手。分开工作服，不可带
回家。
8. 接触控制/个体防护
控制参数
确保工作区域通风良好，局部抽风好，进行防爆通风。 个
人防护
呼吸
如产生粉尘，请使用防毒面罩。
手
戴上合适的防护手套：氯丁橡胶手套，合成橡胶手套。
眼睛
戴上眼罩/面罩
皮肤和身体接触
穿上合适的防护服
其他
紧急淋浴和洗眼设施必须是易于使用的。衣物在再次使用前请洗净。中
国还没有制定暴露限值。
Page 2 of 5
 HUNAN YIXIANG

9. 理化特性
外观 晶体状粉末固体
颜色 近于纯白
气味 微弱
沸点/沸程 不适用（分解）
溶点/溶程 40-50° C
闪点 不适用
燃烧特性 分解产物易燃
爆炸特性 不是
氧化特性 不适用
饱和蒸汽压 不适用
堆积密度 3
580 kg/m (20°C / 68°F) Specific gravity = 0.58(20° C / 68°F)
溶解度 不可溶 (20°C / 68°F)
PH 值 中性
其他溶剂中的可溶性 可溶于大多数的有机溶剂中
有效含氧量 8.51%
过氧化物含量 ≥96 %
引燃温度 测量方法不适用(见第 7 章)
自加速分解温度 80° C. 参见第 10 章
爆炸极限 未确定
10. 稳定性及反应性
化学稳定性
SADT-(自加速分解温度): 80° C
避免接触的条件
为保持质量，须贮存在原容器中，温度低于 30° C. 必
须避免密封。
不相容物
避免接触锈、铁、铜及其他不相容物（如酸、碱、重金属及还原剂）。接触会产生有害分解物。不得与过 氧
化物加速剂混合。仅可以配合使用不锈钢 316、PP、聚乙烯或玻璃衬等设备。欲了解更多信息，请联 系湖
南以翔。
危险反应的可能性
不会发生聚合反应
分解产物
加热或者燃烧产生的有害分解物：甲烷、叔丁醇、丙酮、二乙酰基苯。
其他
紧急情况据情况而定，客户必须制定一个紧急反应计划。请与湖南以翔联系，协助制定紧急反应计划。
11. 毒理学资料
双叔丁基过氧异丙基苯
急性毒性
口服 半数致死量 LD
大鼠: >5000 mg/kg 50

皮肤 半数致死量 LD
大鼠: >2000 mg/kg 50

刺激性
皮肤
Page 3 of 5
 HUNAN YIXIANG

无刺激性
眼睛
无刺激性
致敏感性
不致敏
生殖毒性
Ames test（艾姆斯实验）: 非诱导有机体突变物质。

12. 生态学资料
双叔丁基过氧异丙基苯
生态毒性
鱼
细菌
96h-LC : 750 mg/l
50

无观察效应浓度 (NOEC) >1000 mg/l

归趋
可降解生物的
希望在下列范围内: 不易生物降解的
13.废弃处置
产品
由于污染危险性大，建议不要回收利用。根据相关法规处理废弃物（很可能是受控的焚烧） 污
染的包装
遵守当地法规要求，用完的包装桶可能会有产品残留物，即使是空容器，也应遵守警示要求。
其他
有关进一步建议请联系生产厂商。
14. 运输信息
陆运
运输危险级别
包装类别
5.2

UN 编号
II

适当的运输发货名称
3106

D 型有机过氧化物，双叔丁基过氧异丙基苯
所需标签
5.2
海运
运输危险级别
包装类别
5.2

UN 编号
II

3106
EMS

海洋污染物
F-J, S-R

不是
适当的运输发货名称
D 型有机过氧化物，双叔丁基过氧异丙基苯
其他
标签 5.2
空运
Page 4 of 5
 HUNAN YIXIANG

运输危险级别
UN 编号
5.2

适当的运输发货名称
3106

D 型有机过氧化物，双叔丁基过氧异丙基苯
其他
标签 5.2
15. 法规信息
产品标签名称
双叔丁基过氧异丙基苯，晶体状粉末
危险性类别
描述 适用
分类 《常用危险化学品的分类及标志》（GB13690-92 将其划为第五
类有机过氧化物
危险化学品法规 《危险化学品安全管理条例》(2002 年 3 月 16 日起施行)针对危
险化学品的安全生产、使用、储存运输、装卸等方面均作出了
相应的规定。
危险警句 (EU 分类)
代码 描述
R07. 可能起火
安全措词(EU 分类)
代码 描述
将容器保存在阴凉处密闭。
远离还原剂（如胺类）、酸类、碱类及重金属化合物类（如加速剂、干
S03/07.

燥剂、金属脂肪酸盐）
S14B.

S36/37/39. 穿戴适当的防护服、手套和眼罩/面罩。
符号(EU 分类)

氧化剂（O）
其他
列入指令 96/82/EC 中的产品。
16. 其他信息
本资料只适用于上述提到的产品。如果与其他产品混用或者其他工序中则不一定适用。出于善意，我
司基于现有的知识出具并判断本资料是正确及完整的。但对其内容不作任何保证。如使用者用 本产
品做特殊用途，则使用者应承担验证此资料是否适用和完整的责任。
版本
编写者 谈洁
2016

Page 5 of 5
 HUNAN YIXIANG

FARIDA BIPB-96
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product label name : FARIDA BIPB 96
Chemical name : Bis (tert-butylperoxy isopropyl) benzene
Supplier
Hunan Yixiang Technology Corporation ltd.

Postal code :
Tel : 86 (0
Fax: 86 (0

（
Emergency telephone
+86-020- 39966769 Available outside office hours)
Guangzhou Delman Chmical Co.,LTD
Intended use
Cross-linking agent.
Date of last issue / Revision
2016/04/01
Chemical family
peroxides

2. HAZARDS IDENTIFICATION
Heating may cause fire.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Information on hazardous ingredients
Chemical description Bis(tert-butylperoxy isopropyl)benzene, crystalline powder
Composition / information on ingredients
Number % w/w CAS-number Chemical name
1 ≥ 96.00 025155-25-3 Bis(tert-butylperoxy isopropyl)benzene

4. FIRST AID MEASURES

First aid
General
In all cases of doubt, or when symptoms persist, seek medical attention.
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. Oxygen may additionally be given, by trained
personnel, if it is available. Get medical attention if symptoms occur.
Skin
Flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation
develops and persists. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes.
Eye
Immediately flush eyes with plenty of water. If easy to do, contact lenses should be removed during the flushing, by
trained personnel. Occasionally hold the eyelids apart during the flushing to ensure rinsing the entire surface of the
eye and lids with water. Get medical attention if irritation persists.
Ingestion
Call a physician or a poison control center immediately. Induce vomiting only if directed by medical personnel. The
patient should lie on their left side while vomiting to reduce the risk of aspiration. Never give anything by mouth to
an unconscious or convulsing person.
Most important symptoms and effect, both acute and delayed
The product is not classfied as harmful to human effect.
Advice to physician
There are no data available that address medical conditions that are generally recognized as being aggravated by
exposure to this material.
Attending physician should treat exposed patients symptomatically.

Page 6 of 6
 HUNAN YIXIANG

5. FIRE-FIGHTING MEASURES
Extinguishing media
waterspray, foam, sand, dry chemical powder, CO2.

Unsuitable extinguishing media

Halones.
Hazardous decomposition/Combustion products
CO2, Carbon monoxide.
Methane, tert-Butanol, Acetone, Diacetylbenzene.
Protective equipment
Firefighters must wear fire resistant protective equipment. Wear approved respirator and protective gloves.
Other information
Evacuate all non-essential personnel. Extinguish a small fire with powder or carbon dioxide then apply water to
prevent re-ignition. Cool closed containers with water. Water used to extinguish a fire should not be allowed to enter
the drainage system or water courses. After a fire, ventilate thoroughly the area and soak with water, clean the walls
and metallic surfaces.
Fire and explosion hazard
CAUTION: re-ignition may occur. Decomposition under effect of heating (See also Section Hazardous
decomposition products). If involved in a fire, it will support combustion. In case of fire and/or explosion do not
breathe fumes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Do not breathe dust. For personal protection see Section 8.
Environmental precautions
Do not allow to enter drains or water courses.
Methods for cleaning up
Stop leakage if possible. Eliminate all sources of ignition, and do not generate flames or sparks. Sweep up and put it
into a container for disposal. Avoid dust generation. Keep contents moist. The waste should NOT be confined.
Flush surroundings with large amounts of water and soap.
Other information
CAUTION: re-ignition may occur. Evacuate personnel to safe area.

7. HANDLING AND STORAGE

Handling
Never weigh out in the storage room. When using, do not eat, drink or smoke. Do not breathe dust. Handle in well
ventilated areas. Eliminate all sources of ignition, and do not generate flames or sparks. Keep away from reducing
agents (e.g. amines), acids, alkalies and heavy metal compounds (e.g. accelerators, driers, metal soaps). Keep product
and emptied container away from heat and sources of ignition. Confinement must be avoided. Avoid Incompatible
materials (See Section 10).
Fire and explosion prevention
Avoid dust generation. Dust explosion possible in the presence of air. Use non-sparking tools in areas where dry well
ventilated place away from sources of heat and direct sunlight. Do not cut or weld on or near this container even when
empty.
Storage requirements
Store in accordance with local/national regulations. Keep away from food, drink and animal feeding stuffs. Store in a
dry well ventilated place away from sources of heat and direct sunlight. Store separate from other chemicals. Keep only
in the original container.
Storage
For maximum quality store below: 30 ℃
Other information
It is recommended to use electrical equipment of temperature group T3. However, autoignition can never be
excluded. Wash hands thoroughly after handling or contact. Keep working clothing separately and do not take
them home.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls
Ensure good ventilation and local exhaustion of the working area. Explosion proof ventilation recommended.
Page 6 of 6
 HUNAN YIXIANG

Personal protection
Respiratory
In case of dust formation use dust mask.
Hand
Wear suitable protective gloves of neoprene or synthetic rubber.
Eye
Wear eye/face protection
Skin and body
Wear suitable protective clothing.
Other information
Emergency-shower and facilities for rinsing eyes must be accessible. Launder clothes before reuse.

In this country no exposure limit has been established

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance crystalline or powder
Colour white
Odor faint
Boiling point/range not applicable (Decomposes)
Melting point/range 40-50℃
Flash point not applicable
Flammability decomposition products may be flammable.
Explosive properties no
Oxidizing properties not applicable
Vapour pressure not applicable
Bulk density 580 kg/m3 (20℃/ 68°F)
Specific gravity = 0.58 (20 °C / 68°F)
Solubility in water insoluble
Solubility in other solvents in most organic solvents
Ph value neutral
Viscosity not applicable
Active oxygen content 8.51%
Peroxide content ≥96%
Autoignition temperature Test method not applicable.(See Section 7)
SADT 80°C. See also Section 10.
Upper/ower flammability explosion limits not determined
Volatile Not determined

10. STABILITY AND REACTIVITY

Stability
SADT(Self accelerating decomposition temperature): 80°C.
Conditions to avoid
To maintain quality store in original closed container below: 30°C.
Confinement must be avoided.

Incompatible materials
Avoid contact with rust, iron and copper. Contact with incompatible materials such as acids, alkalies, heavy
metals and reducing agents will result in hazardous decomposition. Do not mix with peroxide accelerators. Use
only Stainless steel 316, PP, polyethylene or glass-lined equipment. Contact Hunan Yixiang for more
information.

Page 6 of 6
 HUNAN YIXIANG

Polymerization
Polymerization does not occur.
Hazardous decomposition products
Hazardous decomposition products: Acetone, tert-Butanol, Diacetylbenzene, Methane
Other information
Emergency procedures will vary depending on conditions. The customer must have an emergency response plan in
place. Contact Akzo Nobel for assistance with developing an emergency response plan.
11. TOXICOLOGICAL INFORMATION
No experimental toxicological data on the preparation as such available. The following data are applicable to the
ingredient(s) listed below.
Bis (t-butylperoxy isopropyl) benzene
Acute toxicity
Oral LD50
rat: >5000 mg/kg
Dermal LD50
rat: >2000 mg/kg
Irritation
Skin
Non irritating
Eye
Non irritating
Sensitization
Not sensitizing
Genotoxicity
Ames test: Not mutagenic

12. ECOLOGICAL INFORMATION

No experimental ecological data are available on the preparation as such.
Bis (tert-butylperoxy isopropyl) benzene
Ecotoxicity
fish
96h-LC50; 750 mg/l
bacteria
No Observed Effect Concentration (NOEC) >1000 mg/l
Fate
Degradation Biotic
Expected to be in the following range: Not readily biodegradable

13.DISPOSAL CONSIDERATIONS
Product
Due to the high risk of contamination recycling/recovery is not recommended. Waste disposal in accordance with
regulations(most probably controlled incineration).
Contaminated packaging
According to local regulations. Emptied container might retain product residues. Follow all warnings even after the
container is emptied.
Other information
For further advice contact manufacturer.

14. TRANSPORT INFORMATION

Land transport (ADR/RID)
ADR class 5.2
Packing group Ⅱ

RID class 5.2

UN number 3106
Proper Shipping Name Organic peroxide type d, solid;
( Bis(tert-butylperoxy isopropyl) benzene)
Page 6 of 6
 HUNAN YIXIANG

Other information Label(s); 5.2

Sea transport (IMDG-code/IMO)
Class 5.2
Packing group Ⅱ

UN number 3106
EMS F-J, S-R
Marine pollutant no
Proper Shipping Name Organic peroxide type d, solid;
(Bis(tert-butylperoxy isopropyl) benzene)
Other information Label(s); 5.2
Air transport (ICAO-TI/IATA-DGR)
UN number 3106
Class 5.2
Proper Shipping Name Organic peroxide type d, solid;
(Bis(tert-butylperoxy isopropyl) benzene)
Other information Label(s); 5.2

15. REGULATORY INFORMATION

FARIDA BIPB-96
Chemical description
Bis(tert-butylperoxy isopropyl) benzene
Hazard classes
Description Applicable
Chinese classification This product is classified ORGANIC PEROXIDE in accordance with
"Chinese regulation of classification and labeling of dangerous
chemicals"(GB 13690-92).
Dangerous Chemical Regulation Regulation on Safe Management of Dangerous Chemicals (take effect
from March 16, 2002) gives out the corresponding requirements on
dangerous chemicals in the areas of safe production, use, storage,
transportation, load and unload etc..

R(isk) phrase(s)
Code Description
R07. May cause fire.

S(afety) phrase(s)
Code Description
S03/07. Keep container tightly closed in a cool place.
S14B. Keep away from reducing agents (e.g. amines), acids, alkalies and heavy metal
compounds (e.g. accelerators, driers, metal soaps.
S36/37/39. Wear suitable protective clothing, gloves and eye/face protection.

Symbol(s) (EU classification)

OXIDIZING (O)
Other information
Substance and/or product listed in Directive 96/82/EC.

Page 6 of 6
 HUNAN YIXIANG

16. OTHER INFORMATION

This information only concerns the above mentioned product and does not need to be valid if used with other
product(s) or in any process. The information is to our best present knowledge correct and complete and is
given in good faith but without warranty. It remains the user’s own responsibility to make sure that the
information is appropriate and complete for his special use of this product.

Revision 2016
Composed by Tanjie

Page 6 of 6